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By P. Lloyd

Perceptions of disaster caused by burning fossil fuels have reached such a pitch that they seriously threaten the very future of the industry. Coal is a dirty word. A leader in Business Day(January 192009) claimed ?There is no disputing that renewable and non-polluting energy sources are preferable to the country?the true cost of so-called cheap coal-fired power stations is neither reflected nor accounted for by Eskom?the true and immediate but unacknowledged cost of continued coal mining is apparent in the catastrophic level of acidification from mining runoff of all significant natural water resources in the country?and their waters have been rendered unfit for human consumption. Air quality is in a similar state with?increases in pulmonary disease causing workforce absenteeism and compromised childhood development, among many other health problems recorded in areas polluted by coal mining.? The upshot is that our latest coal-fired power station, Kusile, is being required to use flue gas desulphurization. The costs are considerable, and the benefits minimal. Meanwhile, exports are being threatened by EU directives and an assumption that South African coal gives off excessive quantities of SOx and NOx when burned. The industry needs to arm itself with clear responses to these and similar misconceptions, and to communicate those responses loudly and clearly, if it is to survive.

Jan 1, 2011

By C. N. Eze, C. K. Ezeh, O. Nnabuife, N. M. Ugwoju, S. C. Enemuor, V. Okechukwu

In this study, the efficacy of Providencia vermicola KUBT-1 in the leaching and beneficiation of Agbaja iron ore was evaluated under varying conditions of temperature, ore particle size, and pH. Agbaja iron ore is a Nigerian low-grade ore containing about 43%–52% iron and a high amount of gangue materials, including phosphorus (1.4%–2.0%) and sulphur (0.12%). The study was organised in triplicate in shake flasks with 48 samples. One millilitre of washed cells of Providencia vermicola KUBT-1 suspended in normal saline at 0.5 McFarland standard (108 cells ml-1) was introduced into each flask containing 50 g of sterilised ore in 100 ml of bioleaching medium, and the samples incubated at room temperature for eight weeks. The levels of upgraded iron, mobilised sulphur, and phosphorus were determined by atomic absorption and ultraviolet spectrophotometric analyses, respectively. Results showed that a particle size of 0.8 mm was optimal for iron upgrading and sulphur mobilisation while 1.0 mm ore size was optimal for phosphorus mobilisation. Up to 89.60% of the iron was upgraded while phosphorus and sulphur were mobilised, leaving residual values of 0.223% and 0.02%, in the ore, respectively. The organism produced best beneficiation results at a pH of 2.5 and a temperature of 3ºC. Correlation analysis with the Pearson’s correlation model showed a positive correlation between iron upgrading and sulphur-phosphorus removal (r =1.000, and r =0.967), respectively. These results present Providencia vermicola KUBT-1 as a promising candidate for large scale leaching and beneficiation of Agbaja iron ore.

Dec 15, 2025

By I. A. Mwamba

Titanium aluminide of composition Ti-47.5 at.% Al was prepared by melting titanium and aluminium of commercial purity with additions of precious metals of 0, 0.2, 1, 1.5 and 2 at.% content. The microstructure, hardness and oxidation properties were assessed. It was found that at 47.5 at.% Al, the microstructure of plain TiAl alloys was duplex, consisting of duplex lamellar grains and ? grains. The lamellar grains consisted of alternating lamellae of ? (TiAl) and a2 (Ti3Al), with overall aluminium content in the range of 43?47 at.%. The ? grains had a aluminium content above 50 at.%. The addition of precious metals to the TiAl alloy resulted in the formation of a new phase, with a high precious metal content, occurring mostly in the ? phase, without any major change to the microstructure. Increasing the amount of precious metals resulted in an increase of the new phase amount, at the expense of the ? phase. The hardness of the different alloys was around 300HV10. Overall, the research has shown that addition of precious metals to TiAl resulted in a slight increase in hardness and a significant improvement of the oxidation resistance. This shows that alloying TiAl with precious metals, at the addition levels investigated, does not alter the mechanical properties very much, but improves oxidation resistance.

Jan 1, 2012

By L. Petzold

The demand for stainless steel is ever-increasing. As an essential element in stainless steel-making process, so is the demand of chromite concentrate. At the same time, the industry proven technologies for beneficiation of chromite are limited. Chromite is only crushed, screened and jigged to produce a concentrate. However, for ultrafine and low-grade material, no satisfactory beneficiation methods for the enrichment of chromite fines exist in industrial operation. This poses a clear challenge for the industry, which Primetals Technologies has addressed with the development of a new beneficiation process. The aim of this process was to enrich low grade chromite tailings to a quality suitable for the smelting process. Required concentrate grades are different over the world, concentrate grades of Cr2O3=40% and lower are found at the Bushveld Complex, South Africa. The target for the present study was a Cr2O3-grade in the area of 49%. Three different chromite tailings with Cr2O3 grades between 16 % and 29 % were part of a study, executed by Primetals Technologies. All three tailing materials were characterised by Mineral Liberation Analysis (MLA). Based on the physical, chemical and mineralogical findings, process flowsheets were developed. The process flowsheets included grinding to ensure a full liberation of the chromite. The liberated material was classified at a cut size of 63 μm to a coarse and fine fraction. Gravity separation and flotation processes were tested with the coarse particle fraction. Due to the limitations of gravity separation with fine particles, only the flotation process is suitable and was tested with the fine fraction < 63 μm. A Design of Experiment (DoE) with six factors, each three levels, was conducted to identify optimal parameters for the fine chromite flotation. Two different collectors were tested: a phosphoric acid ester and a fatty acid type collector. In small scale test work a chromite concentration suitable for the smelting process was achieved. On this basis Primetals Technologies will develop a pilot-scale test program to research recirculation effects and upscale potential of the process. Keywords: Mineral processing, tailings beneficiation, flotation, density separation, process development, chromite

Jan 1, 2020

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By Q. Cui, B. Z. Zhou, Z. G. Song, Y. G. Zhu, G. B. Zheng

The complex refractory Cu-Pb-Zn polymetallic ore in Xinjiang, China is a massive sulphide ore with complex mineral components. In the past two years, the ore mineralogy has changed, resulting in a decline in metallurgy, with too much zinc reporting to the lead and copper concentrates. A detailed mineralogical study indicating the presence of secondary copper minerals, which could be activating the sphalerite early in the present circuit, was used to develop a novel reagent and flotation flowsheet termed “Pb-Cu co-flotation, Cu intensified flotation, Zn flotation”. It was tested and found to significantly contribute to improving the flotation performance of the ore. In the Pb-Cu co-flotation circuit, successful depression of pyrite and sphalerite was achieved using a BK612- Na2S based depressant system. Most of the galena and some of the Cu bearing minerals with excellent floatability were collected with the use of the selective collector BK906. The rest of Cu bearing minerals were floated in a copper Z200 circuit using a BK537-lime-zinc sulphate based depressant scheme. Zinc flotation from the copper tailing was performed in a SIBX circuit using lime as a pyrite depressant. Using the proposed flowsheet, overall Pb, Cu, and Zn recovery increased significantly to 88%, 87%, and 90% respectively. Keywords: Complex polymetallic ore, Cu-Pb-Zn, Pb-Cu co-flotation, particle size

Jan 1, 2020

By R. Kuyvenhoven, A. Parbhakar-Fox, X. Prieto, J. Quevedo, L. V. Danyushevsky

This paper presents the results of a study focussed on determining the distribution of cobalt in different types of pyrite of the La Estrella IOCG deposit in Chile. In the IOCG mineral deposits, where copper is the main product, the quantification and distribution of cobalt is required to correctly define the technical and economic viability of recovering cobalt as a by-product. In the La Estrella mineral deposit, seven alteration and mineralisation events were recognised through both optical and automated electronic mineralogical analysis. Of these seven events, five different types of pyrites were identified, each with unique characteristics of the pyrite crystals. Through advanced elemental analysis of these five types of pyrites, it was determined that the concentration and distribution of cobalt within the pyrite crystal is dependent on the mineralisation event. The results indicate high cobalt concentrations in the early pyrite mineralisation events, associated with relatively fine pyrite grains, and cobalt generally occurring in a solid form in the pyrite core. The late pyrite mineralisation event exhibits the lowest concentrations of cobalt, with cobalt predominantly present along the outer periphery of the pyrite. These results are relevant from a metallurgical point of view because the preferential location of cobalt within the pyrite crystal will influence the maximum metallurgical recovery of cobalt. For this, a cobaltiferous pyrite concentrate must be formed which, according to the characteristics of pyrite, must be processed with the optimal solubilisation method. The overall objective is to ensure both good cobalt recovery and a high concentration of cobalt in the leach solution resulting from pyrite leaching. Keywords: Cobalt, pyrite, IOCG, copper, metallurgical recovery, solubilisation, Chile

Jan 1, 2020

By E. Córdova, A. Anani, W. Nyaaba

Optimization of panels, haulage fleet, and waiting area involves deterministic and low-fidelity methods and experiential knowledge. The process is challenging because coal recovery and operational capabilities must be considered in the solution. The approach in this manuscript comprises the development of an integrated stochastic simulation model of a coal room-and-pillar system that addresses these challenges. The decision variables evaluated are panel width, number of shuttle cars, and change-out time (COT). The results show that the mine should implement the shortest possible COT, decreasing the cycle time and thereby increasing productivity and continuous miner (CM) utilization. The highest productivity and CM utilization for a fleet size of three shuttle cars is found in the 15-entry panel width. For the evaluated fleet sizes, the 19-entry panel width is optimal for the four and five shuttle cars. Among the three variables studied, panel width and fleet size had the most significant effects (5% increase) on the CM productivity, cycle time, and utilization.

Apr 2, 2022

By Huanhuan SU, Jianqiang Zhang, Zhongyuan Liu, Junwei Ma

The high-sulfur bauxite in Henan Province was used as raw material. The grinding fineness, pH value and collector dosage on its desulfurization performance, and industrial flotation desulfurization process were studied. The best flotation desulfurization conditions were grinding fineness of 75%, pH of 8.5, and collector of 600 g/t. “One coarse, one cleaning and one sweep” closed-circuit flotation was established as the industrial flotation desulfurization process. After the closed circuit test, the sulfur content of aluminum concentrate with the yield of 93% was 0.23%, and the sulfur removal rate was 83.16%, and the sulfur content of tailings (sulfur concentrate) was 15.09%. Keywords：High-sulfur bauxite under coal mines, flotation, desulfurization

Jan 1, 2020

By K. C. Sole, M. Makonese

Bushveld Belco is commissioning a plant for production of electrolyte used in vanadium redox flow batteries. Owing to the source material, the electrolyte is contaminated with Fe, at concentrations up to 140 mg/L, which negatively affects battery performance. This study examined the use of ion exchange to reduce the Fe concentration to the target value of < 100 mg/L from a feed solution containing 100 g/L V in 4 M H2SO4. Four resins with possible application were identified: Puromet MTS9570, Puromet MTX7010, Puromet MTS9500, and Puromet MTC1600H. Puromet MTS9570 outperformed the other three resins in all batch experiments with respect to loading capacity and selectivity over V, and was evaluated for Fe removal in fixed-bed column loading tests. Based on these data, preliminary sizing and design of a full-scale column was undertaken. Owing to the difficulty of eluting this resin, a philosophy of discarding the resin on loading to full capacity was considered. These data revealed that, despite the high selectivity of this resin for Fe over V, it would be too expensive and impractical to use this resin for full-scale operation under such conditions. It is recommended to remove iron earlier in the flowsheet prior to generation of the 4 M H2SO4 electrolyte.

Dec 11, 2024

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By E. Tabosa, S. Vianna, K. Duffy, W. Valery, B. Andrade, L. Pyle, P. Holtham

Pneumatic flotation cells are high-intensity flotation machines with rapid kinetics, resulting in short residence times. Examples include the Jameson, PneuFlot and ImhoFlot cells. These cells do not use impeller-like mechanical cells. Rather, the air and pulp are mixed in a continuous stream of high fluid velocity through a downcomer or venturi to disperse the air into fine (approximately 0.5 mm) bubbles and maintain particle suspension. Froth wash water is often used to enhance concentrate grade, minimising recovery by entrainment. With the growing application of these types of cells, not only in cleaner stages (their traditional use) but also in pre-flotation and scalping duties, there is a need to predict their performance more accurately for circuit design and optimisation. No widely accepted model for pneumatic flotation cells is available and their metallurgical performance is often scaled up from laboratory and/or pilot plant testing by assuming fixed values for metal recovery, concentrate grade and concentrate percent solids. This paper describes a new approach to simulate pneumatic flotation cell performance and presents case studies demonstrating its applicability. Keywords: Pneumatic flotation, flotation modelling, flotation circuit design, flotation circuit optimisation, Jameson cell

Jan 1, 2020

By D. Weijie, S. Kai, Y. Hu, X. Ning, M. Shiyi, W. Junpeng, Z. Guihong, L. Xianjie

Flotation is one of the most important processes in the copper production industry. The copper grade in the concentrate is a pivotal indicator of the flotation process performance. However, it is difficult to achieve real-time measurement through hardware sensors. Based on the production data provided by an industrial operation, a novel soft sensor based on multi-layer perceptron (MLP) is proposed for effective monitoring of this pivotal indicator. The proposed soft sensor uses the nonnegative garrote (NNG) to perform global variable selection for MLP, while a local search (LS) approach is incorporated to improve the model presented by NNG. Simulation results show that the proposed algorithm has higher prediction accuracy and better model simplicity than other algorithms. Furthermore, the variables selected are consistent with the field experience, and the developed model can provide reference of feedback control for the optimisation of the process. Keywords: Flotation process of copper ore, nonnegative garrote, local search, soft sensor, multi-layer perceptron

Jan 1, 2020

By L. J. Su, J. Y. Zhang, P. W. Gu, J. F. Xu

Surface tension of mold flux is a key factor affecting optimum casting conditions. A thermodynamic model was developed to determine the surface tension of mold flux containing fluoride based on the ion and molecule coexistence theory of slag structure and Butler’s equation. The relationship between composition and surface tension was investigated by this model. Results indicated that the calculated values showed good agreement with literature data, and the average error was 8.19%. The surface tension value of the CaO–Al2O3-based mold flux was larger than that of the CaO– SiO2-based mold flux. The surface tension in a multi-component system decreased with increasing contents of SiO2, CaF2, and Na2O, which are considered surface-active components. This trend was more significant in the CaO–Al2O3-based mold flux.

Dec 11, 2024

By W. Guiye, L. Chongjun, L. Huinan, Z. Yangge, H. Long

The current application of copper-molybdenum (Cu-Mo) separation inhibitors is often associated with large dosage, high toxicity, environmental pollution problems. In order to solve these problems, a light sensitive Cu-Mo separation inhibitor LS（light sensitive inhibitor，abbreviated to LS） was developed. In this paper, inhibitory performance, photodegradation rule, and acting mechanism of LS were studied. The subsequent test results showed that, compared with traditional inhibitors, LS has shown comparative advantages, with lower dosage and good inhibiting effect. A series of flotation tests with LS as inhibitor were conducted on a Cu-Mo concentrate. A locked-cycle test showed that a molybdenum concentrate containing Mo 49.88% and Cu 0.6%, with 93.23% molybdenum recovery and a copper concentrate containing Cu 29.92%, with 99.99% copper recovery can be obtained. The photodegradation performance of the reagent was investigated under 365 nm, 254 nm and sunlight irradiation. The degradation of the reagents could be completely achieved by irradiation of three wavelengths of light. However, with the different wavelength of irradiation light, the degradation rate is different, the time required to reach 50% degradation rate being 3 h (254nm), 4 h (solar light) and 6 h (365nm) respectively. The inhibition mechanism on chalcopyrite was studied. FTIR study showed that LS could be adsorbed on the surface of chalcopyrite by chemical adsorption, which could enhance the hydrophilicity of chalcopyrite. Ultraviolet adsorption tests indicated that the adsorption capacity of LS on chalcopyrite surface was greatly affected by pulp pH value, and the proper pH value was 5-9. Keywords: Copper-molybdenum separation, Inhibitor, Light-sensitive, Photodegradation, Mechanism.

Jan 1, 2020

By T. H. Yang, Q. K. Wang, T. Song, J. W. Zhou

The grinding circuit can be one of the most important mineral processing circuits in plants. Along with the application of large-scale milling machines, the design and optimisation of the operation strategy for grinding circuits is more complicated. An in-house grinding process simulation tool was developed to mass balance, model fit and simulate crushing, grinding and classification circuits. An industrial grinding and classification circuit in a copper mine was modelled, and the modelling parameters were verified by a particular group of plant survey data. To justify the prediction ability of the fitted models, the model predictions under different operation conditions were compared with another group of plant survey data. Then the model predicted the effects on the circuit of changing operating conditions. Circuit analysis of the comminution process for water feed to a SAG mill, water feed to sump, the rolling speed of a SAG mill and the percentage of ball filling in a SAG mill was put into practise, based on the simulation results. The simulation results can be used to help plant operators understand the features of the comminution process and may help to build a knowledge library for process control. Keywords: Process modelling, grinding, comminution, circuit analysis

Jan 1, 2020

By J. A. Sweet, T. BACHMANN, G. E. Sandoval, T. M. Hauyon, F. A. Contreras

In many respects a porphyry copper ore concentrator plant can be considered as a simple system. Chalcopyrite typically liberates well at relatively coarse sizes, and even low grade ores are amenable to upgrading 20 to 30 times to produce concentrate grades in excess of 25 % in very simple Rougher- Regrind-Cleaner+Scavenger flotation circuits. The flotation response of chalcopyrite has been well characterised in many fundamental and applied research studies and the conditions necessary to depress pyrite and other floating gangue species are well understood. But what happens to the particle surfaces when you have a 50 km pipeline between the grinding circuit and the flotation plant? How does the seasonal variation in water quality affect your ability to control pulp chemistry? What impact does the relative concentration of the different sulphide species have on their separability? Why do two plants that receive nominally the same ore produce consistently different results? And most importantly, what do you need to do to improve the performance of both plants? To answer these and other questions, a focussed sampling and analysis programme was carried out at the Las Tórtolas flotation plants in 2018 and 2019. The work included full down-the-bank sampling, hot floats, the use of radioactive tracers for determining residence time distribution profiles, gas dispersion measurements, detailed mineralogy by size across the circuits and multiple regrind surveys. This comprehensive study was augmented by analysis of historical mineralogy, geometallurgy and operating data using modern data science techniques, and has provided the foundation for current and future optimisation initiatives. Some of the findings and their implementation will be presented in this paper. Keywords: Circuit optimization, Residence time, Gas dispersion, Pulp chemistry

Jan 1, 2020

By A. J. H. Newell, K. Doherty

A copper-gold project has required a number of trade-off studies underpinned by test work to settle on pragmatic flowsheets and throughputs to support a pre-feasibility study that provides a compelling financial case. The primary trade-off studies were based on the mine schedule, ore type feed-grade recovery relationships, likely concentrate grades and typical marketing terms as well as the estimated capital and operating costs for a range of throughputs and mining strategies. Secondary trade-off studies were conducted for specific circuits and additional processing options. Although the details of these studies are not presented, the technical options and subsequent flowsheets are discussed. While the flowsheets will be optimised during the feasibility study stage, the basis is now fixed for the four ore types that would be mined from the copper-gold orebody. The ore types, resulting from a strong weathering profile, exhibit a wide range of copper mineralisation and gold associations, as well as gangue types. They display a range of characteristics that necessitated a nuanced approach to flowsheet development. The primary separation techniques that have been employed include gravity, classification, flotation and leaching while a range of comminution methods have been selected to suit the properties of the ore types. While technical issues are important factors in terms of maximising the quality of separations, recoveries and revenues, attention to material handling, equipment characteristics, the mine schedule, and capital and operating costs are equally important considerations for settling upon a suitable and robust flowsheet. Keywords: Flowsheet, testwork, studies, saprolite gold, native copper, chalcocite, chalcopyrite

Jan 1, 2020

By L. Zhang, Y. Zhou, H. Wang, C. Mo

Fluorination of magnetite (Fe₃O₄) by NH₄HF₂ was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and observing the morphology and phase changes using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffractometry (XRD). The results indicate that fluorination with the involvement of oxygen begins at room temperature, peaks at 178.40C, and is completed at 2000C with the formation of only (NH₄)₃FeF₆. On heating, (NH₄)₃FeF₆ gradually releases NH₄F by the formation of NH₄FeF₄ at 2590C, then (NH₄)0.18FeF₃ at 3270C, and finally FeF₃ with minor FeF₂ at 4000C due to the partial reduction of Fe (III) to Fe (II). At 5500C, FeF₃ is oxidized to FeOF/Fe₂O₃.

Dec 13, 2022

By N. Hadebe, A. Mampuru, F. Jantjies

Mintek conducted test work to study the effect of media wear when using Mintek’s Milling-in-raffinate technology. The grinding media consisted of high-chrome and ceramic balls. The tests were conducted using a laboratory 5L 316 stainless-steel rubber-lined mill. Magotteaux supplied the high-chrome and ceramic balls. The raffinate was synthetically prepared using a typical Cu/Co (2.2 g/L Cu, 3 g/L Co) composition. The milling rate, media wear, mill, leach extraction efficiencies, gangue acid consumption, and residence time were studied. The tests indicated that the high-chrome balls had a higher corrosion rate than the ceramic balls. The ceramic corrosion rate was lower than 0.1 mm/y. The highchrome balls performed better during the leach stages with faster milling time, higher leaching efficiencies for both Cu and Co, lower gangue-acid consumption, and lower residence time

Jan 1, 2023