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By T. Lee

The mining industry, both here and internationally, is continually developing increasingly sophisticated software to compute mineral resource estimates, but these processes cannot compensate for a flawed geological interpretation of the geology of the economic commodity(s) concentrations. Quality assurance and quality control (QA/QC) is becoming increasingly common in association with the sampling and assaying practices within the industry. However, it is rare in the case of a geological interpretation associated with mineral resource estimation. Why? In the context of this paper, QA/QC relates to the use of statistical and graphical tools to show that the geological economic commodity concentrations have been appropriately domained. Domaining is essential to improve the chance of getting a mineral resource estimate right. Commodity value and acceptable concentration variation within a mineral resource can be ingredients that make mineral resource estimation difficult to get right. But it is possible to get it right a very high proportion of the time. It is more likely to occur when inappropriate data consolidation is minimised. In any case, inappropriate data consolidation is significantly reduced when the geological interpretation is strongly consistent with the data and it is demonstrable. To achieve quality global estimates of geological domain concentrations, it is essential that the geology of the prospect is understood sufficiently that the deposit is appropriately domained. Appropriate domaining occurs when sample populations are separated in such a way that only data in harmony with each other within the population contributes to the domain's concentration estimate. The paper will use four brief case studies to illustrate how QA/QC can be used to display data and validate the underpinning geological interpretation through its associated domaining to get it right when it comes to a mineral resource estimation.

Jan 1, 2007

By C. W. P. Finn

On 14th April, 1980, 76 delegates from industry, universities, and research laboratories gathered at the University of the Witwatersrand to attend the Pyrometallurgy Vacation School. Professor H. B. Bell, Chairman of the Department of Metallurgy at the University of Strathclyde, Scotland, was there to lead the School, along with 12 local lecturers, who had gathered at the Hotel Devonshire at 07h30 for an Authors' Breakfast. Analytical chemistry Euroanalysis IV will be held in the town of Espoo, approximately 9 km from the centre of Helsinki, from Sunday, August 23rd, to Friday, August 28th, 1981.

Jan 1, 1980

By J. Arzuúa, U. Castro-Filgueira, L. R. Alejano, F. Malan

"Pillar design for underground mining is typically done using empirical formulae or numerical modelling. Practical experience and recent literature, nevertheless, illustrate the shortcomings of these design approaches. Ongoing monitoring of pillars is therefore recommended to minimize the risk associated with these designs.In a mine where a large number of pillars are cut, different pillar strengths can be expected owing to variations in rock mass strength from area to area. This problem is compounded by the fact that in mining environments the pillars are not always cut according to the prescribed dimensions. Although the original design using either empirical methods or modelling may predict stable pillars, unstable pillars will be encountered in reality. Very conservative designs with large factors of safety may circumvent this problem, but this approach is uneconomical.A possible solution to localized stability problems may be to enhance the strength of a few unstable pillars. It may even be hypothesized that reinforcing a few critical pillars may prevent ‘pillar runs’ on a much larger scale. Rockbolting, strapping of pillars, and pillar shotcreting have occasionally been used in the past as possible solutions. It appears that these have not been successful in all cases and large collapses have occurred in spite of the pillar remedial work.The authors investigated the strapping of pillars by conducting laboratory tests on cabled rock specimens. The results were qualitatively compared to actual attempts of pillar reinforcement available in the literature, as well as additional observations in an old haematite roomand- pillar mine in Spain. Based on these results, the value of steel cabling and mesh wrapped around pillars to improve stability is demonstrated. Some cases where this approach will not be successful are also discussed."

Jan 1, 2017

By M. Wrobel, J. Hammerschmidt, M. Runkel

Fluid-bed technology is a key pyrometallurgical step for processing a vast number of ores and concentrates. Over the past 50 years, considerable research and development efforts have been made by Metso Outotec to expand the application window of this technology. This paper illustrates different processing routes where fluid-bed technology plays an important role in the production of the copper. The fluid-bed processes utilized are partial, sulfate-producing, and dead roasting. The focus of this paper considers the advantages of the dead-roasting process. This “zero waste” process can provide copper oxides, steam, electrical power, and sulfuric acid for new and existing solvent extraction–electrowinning plants. In a case where an operation is running out of oxidic ores and concentrates, fluid-bed roasting can be applied to close this gap and provide the required copper oxides in a sustainable way.

Jan 1, 2023

By Y. Rao, Y. Huang, G. Wang, W. Liu

The properties and deterioration in strength of cemented tailings backfill (CTB )in the underground acidic environment under oxidizing conditions were studied. X-ray diffraction analysis and scanning electron microscopy of the surface of the CTB was carried out, and the sulphuric acid corrosion mechanism elucidated. The properties tested included compressive strength, elastic modulus, cohesion, internal friction angle, variation in the hydrogen ion concentration, and stress-strain relationship in different corrosion periods. The damage model of the CTB was established considering the effects of parameters such as corrosion time and strain on the damage evolution. It was found that the compressive strength, elastic modulus, cohesion (binder effect), and internal friction angle increased at first and then decreased with exposure time. In the long term, the peak stress decreased with corrosion time while the peak strain increased; elastic modulus, and deformation modulus also decreased. The damage caused by corrosion and by load were related by means of a mathematical model, which revealed the relationships between sulphuric attack, load, and damage to backfill in complex underground environments. During corrosion, the expansion of gypsum and ettringite caused microfractures in the CTB. With increasing corrosion time, micro-cracks developed and proliferated. The mechanism of corrosion damage was found to be the dissolution of hydrogen ions and a sulphate ion reaction that produces an expansive substance, resulting in deterioration of the strength of CTB.

Jun 1, 2021

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

The November General Meeting of the Branch was held at the S1. Helena Club on Friday, 15th November, 1968. Mr. J. G. Kirchner (Chairman of the O.F.S. Branch) was in the chair. There were also present: President: Mr R. C. J. Goode. Eighteen Members: Mr A. E. Gilfillan (Council Member), Messrs T. Zadkin, J. N. Saunders, N. A. Honnet, D. D. Waterman, C. R. Netscher, (Committee Members), Messrs G. Thorburn, Z. Lombard, H. V. Henwood, C. J. Isaac, S. L. S. Swart, J. D. McNamara, H. H. Schellhorn, J. W. Wilson, G. C. P. Labuschagne, L. J. Thorne, R. C. Espley-Jones, J. Handley. Seventeen Associate Members: Messrs H. J. Reeders, R. Campbell, P. A. Hoffman, D. E. Couperthwaite, M. D. de Lange, G. J. C. Young, G. W. Futcher, U. Visser, F. H. De Groot, E. Schmid, K. G. Pearce, D. A. Viljoen, H. W. M. Eschenburg, R. Still, W. B. Howe, A. H. Edwards, R. H. Drake. Three Graduates: Messrs T. R. Stromsoe, J. G. Cockburn, T. A. Ward. One Affiliate: Mr O. A. Huss. Twenty-three visitors. Total present: 64. Apologies were reseived from Messrs L. O. W. Leimer, V. C. Barnes and A. Louw. WELCOME TO VISITORS The Chairman declared the meeting open and extended a special welcome to the following: Mr R. C. J. Goode, President of the S.A. Institute of Mining and Metallurgy; Mr A. E. Gilfillan, Member of Council and Mr D. A. Viljoen, all from Johannesburg. Also to Mr J. D. McNamara, the guest speaker for the evening who had made the trip from Oranjekrag. MINUTES OF PREVIOUS GENERAL MEETINGS The minutes of two meetings, viz., the General Meeting held on 26th June, 1968 together with those of the Annual General Meeting held on 14th August, 1968 were taken as read and their adoption moved by Messrs T. Zadkin and D. D. Waterman. MATTERS ARISING FROM THE MINUTES There were no matters arising from the minutes. ADDRESS BY PRESIDENT OF COUNCIL, MR R. C. J. GOODE With regard to the 75th Anniversary of the Institute, the President called upon those present to bear the following two dates in mind, viz.: 21st March, 1969-Banquet at the Wanderers' Club, to which ladies are invited. 24th March, 1969-General Meeting at Kelvin House at 9.30 a.m., the speakers being the President of the Institute, the President of the Chamber of Mines and Dr H. J. van Eck.

By S. Kauvosaari, M. Olofsson, O. Haavisto, M. Kosonen, J. Martikainen

The target in grinding circuit operation is usually to maximise the throughput and energy efficiency while keeping the product particle size on an optimal level for downstream operations. Furthermore, feed ore variations in size and hardness need to be compensated in order to stabilise the process. This is a challenging task for any circuit and requires good instrumentation, combined with careful control design. This study investigates the control of a two-stage iron ore grinding circuit with an AG and pebble mill at LKAB Kiruna KA3 concentrator in northern Sweden. A new control approach based on multivariable model predictive control (MPC) is designed, implemented and evaluated for the circuit. Additionally, advanced instrumentation including a volumetric charge measurement for grinding mills is utilised. The MPC control approach starts with step tests that are used to model the effect of manipulated variables (MVs) like feed rate, water addition and primary mill speed on controlled variables (CVs) such as final product particle size, power consumption and volumetric charge of the mills. In the control implementation phase, the models are then utilissed together with current process measurements and known operating limits to predict optimal future changes for the manipulated variables in order to reach the desired process output values. It is shown that the new control approach improves the stability of the circuit and reduces energy consumption. Keywords: Model predictive control, grinding, optimisation

Jan 1, 2020

By N. Coulson, P. F. Stewart

The Mine Health and Safety Act No. 29 of 1996, as amended, embeds an occupational health and safety management system that facilitates communication between representatives of the state, capital, and labour. In underground mines, two communication loops between these role players serve to separate the production chain of command from the political tripartite relations. Worker-elected health and safety representatives are involved in both communication loops, but are severely constrained in escalating their occupational health and safety concerns to the legalpolitical level. This has a direct bearing on the exercise of the Right to Refuse Dangerous Work (RRDW). As previously reported, health and safety representatives were found to primarily consult their production supervisors in preference to their trade-union representatives. This follow-up article presents production supervisor perspectives on the RRDW. The study demonstrates how, for mineworkers, the two distinct communication subsystems constrain, rather than facilitate, implementation of the RRDW.

Apr 14, 2024

By M. Grave

Rock Engineers are required to design safe cost effective support systems and stoping layouts for their respective mines. As each stope has its own unique environment, continual re evaluation is required in all stopes to maximize extraction and achieve value from the support standard. This paper presents numerical modelling used to plan early mining within the shaft pillar and a reevaluation of an existing stope support standard.

Jan 1, 2009

By Moraka N. V., van Rensburg M. Jansen

"SynopsisGoing beyond transformation claims contained in employment equity scorecards and industry compliance reports, this article provides qualitative insight into the initiatives employed and challenges experienced by mining companies in a quest to transform the mining industry. Perceptions expressed during in-depth interviews with 10 senior executives showed that the assumption that mining companies are reluctant to transform is erroneous. Results from this study suggest buy-in and commitment to transformation. This article describes specific initiatives undertaken by mining companies to transform. The most notable initiatives include staff recruitment efforts to appoint historically disadvantaged South Africans (HDSAs), staff development initiatives, as well as community development. The findings furthermore contextualize the challenges experienced by industry participants in their quest to transform. Despite accusations that industry participants are not taking responsibility for the implementation of the transformation agenda, government needs to recognize that they too have a role to play and need to appreciate and assist in the current challenges experienced by the industry.IntroductionWe need a mining sector that works. Mining employs over half a million people. It is the biggest earner of foreign exchange in our country. It also contributes about 20 billion rand directly to tax revenue. Mining also makes a far larger contribution as a buyer of goods and services, and a supplier of inputs to other sectors of our economy and other economies around the globe’ said President Jacob Zuma during the 2014 State of the Nation Address (Zuma, 2014). However, despite apparent commitment from government, enforced compliance with social and labour plans, regulations and Mining Charter targets, the South African mining industry is slow to gain local and international investor trust (Deloitte & Touche, 2013; Mashego, 2013).Industry players acknowledge that their context has changed – creating various challenges (Davis, 2014). In the past few years, such challenges included subdued commodity prices, increased working costs, constrained infrastructure, and high labour costs, coupled with poor levels of productivity, strained labour-management relations, an uncertain regulatory environment, and the inevitable maturation of the industry (Deloitte & Touche, 2013; Davenport, 2014). Mining affected communities also became more cognisant of their rights, and politicians more vocal in their expectations from their relationships with the mining giants (Davis, 2014). One of the main issues that contributed to the difficult operating conditions was claims from organized labour and Minister Shabangu that this industry is too slow to transform. Specific claims were made in terms of employment equity, fair salaries and wages for mineworkers, housing and living conditions, health and safety issues, and general working conditions (Limpitlaw et al., 2005; Miningmx, 2013; Shabangu, 2010). These claims were followed by what Gill Marcus, Reserve Bank Governor, explained as ‘unprotected strike action [that] has escalated into an uncontrolled, violent and unlawful landscape, led by a mob mentality in the absence of formal and recognised leaders’ (Mavuso,2013)."

Jan 1, 2015

1. Book reviews Physiochemical properties of molten slags and glasses, by E.T. Turkdogan. London, Metals Society, 1983.516 pp. £35. Reviewer: A.F .S. Scboukens Microstructural characterisation of metals and alloys, by P.E.J. Flewitt and R.K. Wild. London, Institute of Metals, 1984. £14. Reviewer: M.P. Sbaw Metallurgical applications of magnetohydrodynamics, edited by H.K. Moffatt and M.R.E. Proctor. London, Metals Society, 1984.346 pp. U.K. £35, U.S. $70. Reviewer: N.A. Barcza Extractive metallurgy symposium. Proceedings of a meeting on 12-14 November, 1984, organised by the Melbourne Branch. Parkville (Victoria), Australasian Institute of Mining and Metallurgy, 1985. Reviewer: B.K. Loveday Conference on gold mining, metallurgy and geology. Proceedings of a meeting on 9-11 October, 1984, organisedby the Perth and Kalgoorlie Branch. Parkville (Victoria), Australasian Institute of Mining and Metallurgy, 1985. Reviewer: B.K. Loveday Corporate policies for the 1980's in the steel industry, by Patrick Genevaz in collaboration with B.A. Bloom. La Chambre des Cartes, 26 rue de Piepus, 75012 Paris (France). U.S.$7oo, additional copies $140. Reviewer: D.C. Maree Mineral processing technology, by B.A. Wills. Oxford, Pergamon Press, 1984 (3rd edition). 629 pp. Hard cover £31.50, soft cover £9.75. Reviewer: B.K. Loveday Ma1lllgement information-ma1lllging for improYement, volume 2: symposium proceedings and additional papers. edited by M. Hammond. Doncaster (England), The Institution of Mining Engineers, 1984. 86 pp. £60 for vols. 1 and 2 (124 pp.). Reviewer: M.J .R. Meyer 2. Recent publications Tins and its and its uses no. 144, 1985. This issue by the International Tin Research Institute (Fraser Road, Greenford, Middlesex, UB6 7AQ, Canadian minerals yearbook 1983-84. Department of Energy, Mines and Resources Canada, Mineral Report 33. Ottawa, Canadian Government Publishing Centre, 1985. $35.40. 82 Year 1984, edited by 1.0. Jones and RM. Louthean. Kalgoorlie (Australia), Western Australian School of Mines, 1985. 100 pp. Johnson Matthey Chemicals 1984-85, issued by Matthey Catalogue Sales (Orchard Road, Royston, Hertfordshire SG8 SHE, England). 416 pp. South Africa's mineral industry 1984. Johannesburg, Minerals Bureau, 1985. 190 pp. Coal 1985. Operating and developing coal mines in the Republic of South Africa. Johannesburg, Minerals Bureau, Directory 2/8S. 1985. 72 pp. Gold 1985. Operating gold mines and gold recovery plants in the Republic of South Africa. Johannesburg, Minerals Bureau, Directory 3/8S. 98 pp. 3. New journal Pergamon Press, New York, have announced the publication of a new quarterly known as the International Journal of Plasticity. 4. Mintek reports Report M93D Hydrochloric acid leaching and low-temperature roasting of tin-tungsten concentrates from Van Roois Vley. (First issued April 1983.) Report M99D The upgrading of coarse kyanite crystals. (First issued Report M105D The development and installation of a microcomputer based data logger, and the analysis and evaluation of data. (First issued July 1983.) Report M109D The remelting ofsi/iconfines. (First issued July 1983.) Report M180 An assessment of available corrosion inhibitors for the reticulation systems of South African gold mines. Report MW1 Quantitative assessments of abrasive and impactive wear from ball-size distributions in rotary mills.

Jan 1, 1985

By M. Z. Emad, A. Hassan, M. A. Raza, M. U. Khan, S. A. Saki

Digital modelling of a surface is crucial for Earth science and mining applications for many reasons. These days, high-tech digital representations are used to produce a high-fidelity topographic surface in the form of a digital terrain model (DTM). DTMs are created from 2D data-points collected by a variety of techniques such as traditional ground surveying, image processing, LiDAR, radar, and global positioning systems. At the points for which data is not available, the heights need to be interpolated or extrapolated from the points with measured elevations. There are several interpolation/extrapolation techniques available, which may be categorized based on criteria such as area size, accuracy or exactness of the surface, smoothness, continuity, and preciseness. In this paper we examine these DTM production methods and highlight their distinctive characteristics. Real data from a mine site is used, as a case study, to create DTMs using various interpolation techniques in Surfer® software. The significant variation in the resulting DTMs demonstrates that developing a DTM is not straightforward and it is important to choose the method carefully because the outcomes depend on the interpolation techniques used. In mining instances, where volume estimations are based on the produced DTM, this can have a significant impact. For our data-set, the natural neighbour interpolation method made the best predictions (R2 = 0.969, β = 0.98, P < 0.0001).

Feb 6, 2023

By F. C. Harris, S. J. Gaab, J. Sattarvand, S. Duzgun

Underground mines are inherently dangerous due to potential hazards such as fires, explosions, and caving of rock. Although these events are rare, once they occur a speedy and safe egress of mineworkers is critical to survival. Static evacuation systems use exit signs or directional lines but can get obstructed or be hardly visible in smoky or dusty conditions. This paper presents the investigation of the effectiveness of a smart evacuation technology in underground mining, where a real-time guidance system leads individuals on an optimised path to the egress while avoiding danger zones, compared to conventional practices. Participants simulated an evacuation from a virtual reality mine, using the conventional system and the smart evacuation system with real-time guidance. The highest reduction in evacuation time using the smart method amounted to nearly 40% on average. Moreover, 83% of participants preferred the smart guidance system, and agreed that it could enhance safety.

Sep 1, 2021

By B. O. Odera

The Pt-based alloys have a high potential for replacing some Ni-based superalloys (NBSAs) used in the highest temperature and most aggressive environments, and vanadium would be a beneficial alloying element. Six alloys of average compositions Pt-26.6Al-9.1V, Pt-23.1Al-17.8V, Pt-9.6Al-21.1V, Pt-17.4Al-6.4V, Pt-22.3Al-7.9V, and Pt-6.0Al-10.1V (all in at.%) were manufactured by arc-melting and examined in the as-cast condition using scanning electron microscopy and X-ray diffraction (XRD). Five samples were heat treated at 1 000°C for 1 500 hours and water quenched, then examined. The phases were identified using energy-dispersive X-ray spectroscopy and the identities were confirmed by XRD. In most of the samples, the phases existing in the as-cast condition were different from those at 1 000°C after ~1500 hours heat treatment. A solidification projection, an isothermal section and a liquidus surface projection were determined for the Pt-rich corner.

Jan 1, 2012

By J. F. Brand, J. C. van Dyk, F. B. Waanders

"Syngas from Africary’s Theunissen underground coal gasification (UCG) project will be used for power production and synthesis of liquid fuels and commodity chemicals. However, some of the coal components, especially condensable water, oils, tars, inorganic trace elements, and a small fraction of fly ash and particulate matter, make their way to the surface via the production well and can cause adverse impacts on downstream processes. Africary’s standard design incorporates a cold gas clean-up system that relies on relatively mature techniques based on highly effective wet scrubbers and acid gas removal (AGR) systems such as Rectisol®, but with the downside of low energy efficiency and waste water generation. In this paper, novel technologies for removing contaminants and species separation from the hot (T > 300°C) raw syngas are compared. Comparisons are made between supersonic gas separation (SGS), Ranque–Hilsch vortex tube (RHVT), vortex gradient separation (VGS), and inertia vacuum filtering (IVF), and a vortex-based gas separation concept is proposed for UCG applications. IntroductionImpurities in gasification feedstock (coal, biomass, waste, etc.), especially sulphur, nitrogen, chlorine, and inorganic mineral matter, often end up in the syngas and can cause adverse impacts on downstream processes. Africary’s standard design incorporates a cold gas clean-up system that relies on relatively mature techniques based on highly effective wet scrubbers and acid gas removal (AGR) systems such as RectisolR, SelexolR or aMDEAR; but with the downside of low energy efficiency and waste water generation.Hot (T > 300°C) gas clean-up technologies are attractive because they avoid cooling and reheating of the syngas stream. Some available warm gas cleaning technologies include traditional particulate removal devices such as cyclones, candle filters, membranes, and molecular sieves. The warm gas desulphurization process technology developed by RTI LLC (2018) requires hot syngas to remove sulphur and has become commercially ready. Many other hot gas cleanup systems are still under development, given the technical difficulties caused by extreme environmental and operating conditions."

Jan 1, 2018

By P. L. Ngwenyama, W. W. deGraaf

South Africa is one of the leading producers and exporters of coal globally. A significant amount of the country’s production is obtained from previously mined underground bord and pillar workings. This coal is in the form of pillars and remnants on the roof and floor of the old workings. The good quality coal pillars were left behind as primary support during underground bord and pillar mining operations. Due to the depletion of virgin coal reserves, the pillars and remnant coal are now removed using opencast mining rather than underground methods. However, the secondary extraction of pillars and remnant coal from the old workings using opencast methods entails some serious challenges that have a negative impact on the safety and productivity of the operations, affecting both personnel and machinery. If these risk factors and challenges are managed properly, then the opencast mining operations could remove the pillars safely at recoveries competitive with those of virgin coal operations. In this study we review the recurring challenges affecting opencast pillar mining by means of field investigations and consultations with experts at five opencast pillar mining operations, and evaluate the best practices used to combat these challenges. It was found that each mine has its own unique conditions and challenges.

Dec 1, 2021

By F. Navarro, F. Soto, G. Díaz, E. Jélvez, G. Morales, N. Morales

The increasing availability of tools on the web provides a great opportunity for the research community to boost investigation by accessing computational resources from all over the world. For example, data analytics libraries implemented in languages like Python can be accessed through many open and commercial platforms, therefore providing researchers with a common set of tools or shared datasets. Unfortunately, that is not the case with research in resource assessment and mine planning, where the most standardised tools are commercial applications designed to work on the desktop, but there are not many standard platforms for research. As a result, researchers from different groups often need to start from scratch in order to develop their work, and rarely share implementations details. Similarly, apart from a few publicly available examples, there is a lack of common datasets that are validated and can be used to compare results between different approaches. In this paper, we introduce a platform that provides tools for resource assessment and mine planning, which can be accessed remotely utilising Jupyter Notebooks. In its current version, the platform provides (i) definition and implementation of basic structures for managing samples and models (loading, saving, adding or removing columns, etc.), (ii) definition of experimental and modelled variograms for spatial continuity analysis, (iii) definition of standard interpolation methods in resource evaluation (inverse distance and kriging), (iv) definition of standard problems in mine planning (ultimate pit and precedence constrained production scheduling), (v) generation of 2D standard graphs like grade distribution, conditional means, tonnage-grade, and production plans (vi) a set of datasets, which can be used for case studies, and (vii) a set of notebooks with examples and documentation. In this paper, we introduce the platform and show some examples that illustrate some of the possibilities that it has for research and education in the area of resource assessment and mine planning.

Sep 1, 2021

DD3-tunnels (PD BH&apos;s) ? Rotary coreholes 111no. (124) ? Percussion holes Ono. (37) ? Sampling (rock and soil) ? Soil and rock permeability ? testing ? BH Televiewer Surveys [ ]

Jan 1, 2007

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025