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By Thomas G. Carnahan

The Bureau of Mines conducted research to simulate in situ leaching of a chalcopyrite ore. The purpose was to obtain a direct comparison between moderate-temperature and elevated-temperature in situ leaching of copper trom minus la-inch ore and to analyze the sulfuric acid and oxygen requirements of the leaching system. Experiments employing oxygen were conducted at 35° and 90° C on 362-and 367-1b ore charges, respectively, under flooded conditions and at 400 psig. At 90° C, 47 pct of the copper was extracted in 913 days of leaching; at 35° C, 27 pct of the copper was extracted in 915 days. Diffusion into and out of the ore fragments con-trolled the rate of leaching. Oxygen consumption was 1.46 lb/lb of copper extracted at 35° C and 3.15 lb/lb of copper extracted at 90° C. Sulfuric acid requirements of the ore were 5.49 and 7.48 lb/lb of copper extracted at 35° and 90° C, respectively.

Jan 1, 1982

"It is evident that the incidence of coal worker's pneumoconiosis (CWP) or black lung disease varies in different coal producing regions of the United States. Many people have hypothesized about the reasons for the differing occurrences. Because underground coal mining involves many mining methods under changing geological conditions, several factors may be involved in contracting CWP such as: the amount of quartz in the respirable dust, the trace elements in the respirable dust, the rank of the coal that produced the respirable dust (bituminous, anthracite), the amount and size of respirable dust, etc.Recognizing the uniqueness of underground coal mining and CWP, research investigations involving seam characteristics, mining system and worker position are being conducted in the center to establish standard procedures for characterizing some coal properties that may be involved in workers contracting CWP. This has been accomplished by the in-mine sampling of airborne dust at various worker locations and mining system configuration and by performing laboratory analyses of mined material (coal and rock) taken from the mines. (FIGURE 49 and 50)The investigations includes a method of classifying coal seams according to their potential to generate respirable dust. It includes statistical analyses of the size and locational variations of the elemental compositions of respirable coal mine dust in operating underground mines from seams located in the eastern, midwestern, and western United States, and is currently completing research which is investigating the relationship between the elemental compositions of respirable dust sampled near a continuous-mining machine and a laboratory-produced respirable dust."

Nov 1, 1988

By A. L. Engel

Included in the program of the Rare and Precious Metals Station, Metallurgical Division, Bureau of Mines at Reno, Nev., are investigations of treatment methods for ores representative of various mining districts throughout the country. The samples received for this work may come from areas only recently explored or from newly discovered ore deposits in older mining districts. The present investigation deals with a case of the latter type, the. ample having come from a section that has a past record of considerable precious. metals production. The application of current treatment methods to this type of ore seems to offer excellent possibilities of satisfactory economic results. Definite identification of the silver mineral in this ore asthe chloride cerargyrite, AgCl, adds considerable interest to, the investigation, as in many cases where silver occurs in comparatively small amounts in an ore it is not possible to identify the particular mineral carrying the silver or else it is contained in or combined with other more common minerals. Cerargyrite is the "horn silver" of the bananza period and is mentioned in many accounts of pioneer mining of high-grade ores The occurrence of this mineral in finely disseminated form it a low-grade ore is believed to be unusual. The sample investigated was obtained from the' Bullfrog District neat Beatty, southwest Nye County, Nevada. The ore contained 16.7 ounces of silver per ton of ore, 0.007 ounce gold, and 0.32 percent copper in a silicious gangue, with accessory minerals, including iron oxides and scorodite; the hydrous iron arsenate.

Jan 1, 1949

By Kevin Michael, David C. Byrne

In previous issue of Spectrum (October 1999, 16/4), a system of measuring the attenuation provided by insert-type hearing protectors was described, That report described experiences using the FitCheck (Michael & Associates, Inc.) system in a pilot project involving the steel industry during 1998.[ ]

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By Daniel C. Boteler

Data from 68 entrained-bed carbonization tests were treated statistically by the Bureau of Mines, and several useful relationships were developed among the major variables. Nine coals, ranging in rank from lignite A to high-volatile A bituminous, were carbonized in two entrained-bed carbonization pilot plants. The carbonizing reactors employed were vertically mounted cylinders, internally heated, refractory-lined, and 10 inches ID. The range of carbonization temperatures was from 825° to 1,600° F. Using a regression-analysis computer program, empirical equations were developed by which carbonization temperature, air-to-coal ratio, devolatilization of coal, char yield, and volatile matter content of product char may be predicted.

Jan 1, 1973

By Francis R. Redfern

Newton's method of solving a nonlinear equation is employed to develop a least-squares acoustic emission source location method in which the spatial residuals of the location equations are minimized. These residuals, related to the distances from the least-squares source location perpendicular to the surfaces described by the location equations, permit location error to be estimated to first order along the spatial axes. The solutions obtained by this method are the best spatial solutions to the location equations in the least-squares sense. Also presented is a procedure by which the geometrical control of a transducer array can be evaluated using the rate of change of source location with fractional velocity change.

Jan 1, 1982

By Isaac A. Zlochower, Michael J. Sapko, Eric S. Weiss, Kenneth L. Cashdollar

This paper describes dust explosion research conducted in an experimental mine and in a 20-L laboratory chamber at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH). The primary purpose of this research is to improve safety in mining, but the data are also useful to other industries that manufacture, process, or use combustible dusts. Explosion characteristics such as the minimum explosible concentration and the rock dust inerting requirements were measured for various combustible dusts from the mining industries. These dusts included bituminous coats, gilsonite, oil shales, and sulfide ores. The full-scale tests were conducted in the Lake Lynn experimental mine of NIOSH. The mine tests were initiated by a methane-air explosion at the face (closed end) that both entrained and ignited the dust. The laboratory-scale tests were conducted in the 20-L chamber using ignitors of various energies. One purpose of the laboratory and mine comparison is to determine the conditions under which the laboratory tests best simulate the full-scale tests. The results of this research showed relatively good agreement between the laboratory and the large-scale tests in determining explosion limits. Full-scale experiments in the experimental mine were also conducted to evaluate the explosion resistance characteristics of seals that are used to separate non-ventilated, inactive workings from active workings of a mine. Results of these explosion tests show significant increases in explosion overpressure due to added coal dust and indications of pressure piling.

By Maria I. De Rosa

Table 55 and figure 19 show the number of fires and fire injuries for stone mills by state during 1990-2001. Table 55 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 118 fires occurred in 33 states. Seventy-six of the fires caused 82 injuries (including 8 fires and 6 injuries involving contractors). The yearly average was 9.8 fires and 6.8 injuries. The Ewhr value was 873 x 106 hr (In = 0.019), and the LWD value was 1,911. Missouri had the most fires (16 fires and 9 injuries), followed by Pennsylvania (15 fires and 14 injuries), Michigan (9 fires and 5 injuries), and Virginia (7 fires and 5 injuries). Of these states, Virginia had the highest injury risk rate value (In = 0.09 1). Table 56, partly illustrated in figure 20, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires and fire injuries decreased during most of the periods, with a sharp increase during the last period. The number of employees' working hours increased throughout the periods. The In values follow patterns similar to those shown by the injury values. Tables 57-63 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 21 shows the major variables related to fires for 1990-2001. Table 63 shows the fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

This chapter describes the adverse health effects associated with exposure to respirable coal mine dust. Epidemiological studies of underground and surface coal miners in the United States and other countries are discussed. Also discussed are animal studies that add to our understanding of particle deposition and retention in the lungs and associated disease responses. This chapter emphasizes studies that (1) were performed since the passage of the Federal Coal Mine Health and Safety Act of 1969 [P.L. 91- 173], (2) used standardized methods of exposure monitoring and disease classification, and (3) investigated exposure-response relationships between respirable coal mine dust exposure and disease. Several published review articles contain further discussion of health effects studies of coal miners [Attfield and Wagner 1992b; Petsonk and Attfield 1994; Cotes and Steel 1987; Merchant et al. 1986; Morgan and Lapp 1976; Morgan 1975].

Jan 1, 1997

By J. J. Demeter

Anthracite from the four producing regions in Pennsylvania was both ashed in the laboratory and burned on a chain-grate stoker to determine the sulfur-retention properties of its ash. The retention of sulfur in laboratory-prepared anthracite ash was shown to be related to ashing temperature and to the amounts of sulfur and calcium present in the coal. At the usual laboratory ashing temperature of 750° C sulfur retention ranged from 0.8 to 13.2 percent of the total coal sulfur. Sulfur retention in the ash was negligible, o to 0.3 percent, at 1,200° C, which is the thermal decomposition temperature of calcium sulfate; thus calcium sulfate does not form and cannot serve as a sulfur-retaining agent. In several tests the anthracite was mixed with 6 or 10 percent dolomite prior to firing in the chain-grate stoker. The dolomite did not improve sulfur retention owing to the high temperature in the fuel bed. Sulfur retention was, however, related to the unburned carbon in the ash. The relationship of the percentage of original coal sulfur retained in the ash (Y) to the percentage of the original carbon in the coal remaining in the ash (X) is expressed by Y = -0.579 + 0.914X. The percentage of sulfur retained is almost directly proportionate to the percentage of original coal carbon in the ash.

Jan 1, 1968

By David F. Gearhart, Thomas M. Barczak

This U.S. Bureau of Mines report examines the roof and floor contact pressure provided by the interaction of a shield with the surrounding strata. Controlled forces were applied to an 800-ton two-leg shield in the Bureau's mine roof simulator; the distribution of forces acting on the canopy and base of the shield were measured with 24 hydraulic pressure cells. Several influential factors that affect the load distribution were investigated: (1) the magnitude of loading (leg pressure); (2) the profile of the canopy, principally the upward-sloping tip; (3) the base-lifting device; (4) horizontal load acting on the shield; and (9 compliancy of the immediate roof and floor. It was concluded that the shield does not develop full canopy or base contact without deformation of the strata. Maximum contact pressures are developed at the rear of the canopy and on the toes of the base. Less than 10 pct of the available shield capacity is developed at the canopy tip despite the design intention to ensure tip contact. Horizontal loading reduced the toe pressure acting on the base by as much as 75 pct. The base-lifting device exaggerated the inherently high toe loading, increasing the contact pressure by more than 200 pct.

Jan 1, 1992

By R. O. Kneisley

Rock mechanics measurements indicate that the present two-bed mine design used at the Big Island trona mine, Green River, Wyo., results in stable workings. Vertical pressure changes in the lower panel pillars and horizontal pressure changes in the lower bed roof and floor indicated negligible upper bed mining influence. Pillar stresses stabilized soon after upper bed mining was completed. Strata movements in the pillar ribs, roof, and floor were also negligible and stabilized soon after completion of upper bed mining. Using tributary area theory, the confined core approach, and studies of model trona pillars it is shown that increased extraction ratio is possible. A program of gradually increased extraction ratio accompanied by simple measurements should result in a mine design that includes both higher recovery and long-term stability.

Jan 1, 1981

By H. E. Powell

Because of increasing consumption of high-and super-duty refractories, the Bureau is studying the feasibility of beneficiating submarginal and marginal clays. Diverse mineral dressing tests were used to beneficiate samples from the east-central Missouri fire clay district. Standard ASTM tests were used to determine refractory properties of both crude and beneficiated clay samples. Marginal and submarginal clays containing impurities were effectively beneficiated by both wet-cyclone and wet-table treatment, but the wet-cyclone treatment was cheaper. Ion-exchange resins in the hydrogen form will probably prove more effective in removing potassium, the only alkali in Missouri fire clays to be a problem. Resins with greater cross linkage are more effective than resins with less. Roasting the crude clays before removing alkalis by chemical leaching was ineffective. By applying ultrasonic energy at a frequency of 10 to 25 kilocycles to aqueous suspensions of the clays, subsequent ion-exchange extraction of potassium was slightly improved. Higher frequency ranges did not help.

Jan 1, 1963

By A. T. Iannacchione

Designing coal pillars to provide resistance against overburden and gob loads has long been an aim of rock mechanics engineers. This requirement has become more imperative as greater overburdens are encountered and when mining in stiff coal-bearing strata. Current design procedures rely on theories of coal pillar behavior that take into consideration a common hypothesis. This hypothesis states that the elastic core is surrounded by an inelastic yield zone. The distribution of stress at low-to-moderate pillar loads has been effectively defined by this hypothesis. However, it suffers greatly when applied to large width-to-height (w/h >lo) coal pillars under considerable overburden (>500 m) . In these situations, the hypothesis says the elastic core can achieve unrealistic stress states giving the pillars extremely high calculated strength. A growing body of field studies has shown this is not the case. It has become clear that same other mechanism must be involved. It is the purpose of this paper to discuss the importance of an interface slip mechanism between the coal- bed and the surrounding strata in controlling the extent and pattern of stresses and deformations in a coal pillar.

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coal beds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

By C. M. McCulloch

A series of geological surveys were completed in six coal mines in connection with a Bureau of Mines research program on methane control. The aim of these surveys was twofold: First, to study the overall geology of the coalbed, and second to use the resulting data to evaluate the influence of the geological characteristics of the coalbed on safe and efficient coal extraction. This report explains the advantages of geologic maps and fence diagrams in coal mining, and how the knowledge gained from such geologic investigations of mines can help control many underground problems.

Jan 1, 1975

By Arthur M. Hartstein

The Bureau of Mines through contract with Ultrasystems, Inc., obtained gram per gram data of products formed on thermal oxidative degradation of selected compositions, both under dynamic and static conditions. Four broad classes of materials were studied! Polyvinyl chloride compositions, neoprene compositions, rigid urethane foams, and variously treated woods. Whenever possible, comparisons between pure components and composites were attempted. Thermogravimetric and differential thermal analyses were performed to gain understanding of the processes occurring and to explore the feasibility of using these analyses as a method of material identification. The toxic products detected and quantitated included HC1, H2S, CO, S02, CS2,COS, HCOOH, CH3COOH, formaldehyde, acrolein, C 6H6, chloroprene, chloroethanol, benzyl chloride, aniline, and furfural.

Jan 1, 1974

By Robert J. Timko, Edward D. Thimons

Sulfur hexafluoride (SF6) is an odorless, colorless, nontoxic gas that has found acceptance as a tracer gas in research on ventilation pat- terns, measurement of air leak rates, respirable dust reductions due to bagging hood modifications, and the study of airflows relating to gob boreholes. Following a short review of the SF6 sampling technique, this report describes recent Bureau of Mines projects in which SF6 was used successfully as a tracer gas, enabling researchers to acquire representative data quickly and inexpensively.

Jan 1, 1982