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By Bertrand L. Johnson

Fertilizers are indispensable to national preparedness and defense. Production of adequate supplies of nourishing food for sustaining life in the United States is absolutely dependent in many parts of the country on the use of artificial fertilizers of various types. Only by using fertilizers can we maintain our present volume of production without great additional expense. Otherwise we would have to increase crop areas constantly to compensate for declining yields, we would have to lower the quality of food marketed, and standards of farm living and rural civilization would decline. About 60 million of the 360 million acres of crops grown annually in the United States Vow require fertilizing each year, and between 7 and 9 million tons of commercial fertilizers are consumed annually for this purpose.

Jan 1, 1941

By E. S. Longfellow, S. H. Katz

Poisonous hydrocyanic acid gas (HCN) is sometimes evolved in dangerous quantities from cyanides used in metallurgical and chemical operations. This gas is much used for fumigating buildings, ships, greenhouses, and such commodities as grain and cotton to destroy rats, mice and insect pests. Wherever cyanide fumes are evolved, thorough ventilation is necessary in order to render the sur- rounding air safe to breathe. Many persons have been killed by entering tanks and fumigated places too soon, and a simple test for this gas would promote safety. In view of the need for an easy method for quantitatively determining HCN in air, the three color reactions used originally for testing HCN in solution tions *** were modified and adapted. The reactions employ (1) picric acid (CH(NO2)3OH) which is yellow but combines with hydrogen cyanide to form a red- purple dye, isopurpuric acid****; (2) phenolphthalin (CH1604), which is a reduc- tian product of the phenolphthalein (CH4) used for acid indicator, this colorless substance is oxidized***** by presence of HCN to pink colored phenolph- thalin; and (3) guaiacum which oxidized from colorless to blue******. Phenolph- thalin and guaiacum require the presence of copper compounds which catalize the color formation by reduction of cupric cyanide. The chemical processes involved *Associate physical organic chemist, Bureau of Mines, Department of the Interior. **Assistant gas chemist, Bureau of Mines, Department of the Interior. 2014 20 *** Kohn-Abrest, E., Notice toxicologique sur les gas: Arnales des Falsifica- tions, vol. 8, 1915, pp. 215-35. (Tested air with picric acid and guaiacum papers). **** Élasiwietz, H., Ueber eine neue Zersetzungsweise der Trinitrophenylsaure: Anal. der Chemie, vol. 110, 1859, pp. 289-303. ***** Weehuizen, F., Phenolphthalin as reagent for HCN: Pharmaceutrisch weekblad, Utrecht, vol. 42, 1905, pp. 271-2. Abstract, Jour. Chem. Soc., vol. 88, part 2, 1905, p. 489. ****** Schonbein, C. F., Ueber den thatigen Zustand der Helfte des in dem Kupfer- oxydenthaltenen Sauerstoffs und ein darauf beruhendes hochst empfindliches Reagens auf die Blausaure und die loslichen Cyanmetalle: Jour. fur. Praktische Chemie, vol. 106, 1869, pp. 263-70.

Jun 1, 1923

By Lucia Kuizon

Results of the U.S. Bureau of Mines' survey of mineral resources in the Cuyama RARE II study area indicate there is no potential for metallic minerals and low potential for the development of gypsum resources. There are no producing or developing mines within the study area. The Santa Barbara Canyon Prospect contains 30,000 tons (27,000 t) of subeconmic gyspum resources, the Wagon Road Prospect 276,000 tons (250,000 t), and the Brush Fence Canyon 61,000 tons (55,000 t). Most of the resource in the Brush Fence Canyon Prospect is outside the area. Gypsum was not observed at the Cuyama River deposit. Present gypsum and gypsite requirements are being met by larger deposits closer to major markets. INTRODUCTION Location (USGS) Present and Previous Studies (to be combined with USGS section) The Bureau of Mines reviewed literature and mining claim records for the study area. A field examination of known mineral properties was made in October 1980; it included mapping and sampling of prospects to evaluate the economic potential of mineral resources.

Jan 1, 1981

By E. C. Lane

"INTRODUCTION This is the fourth in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36 3/. The second resort gave the same data for motor gasolines sold during the summer of 1936 4/. The third report of the series gave the same data for motor gasolines sold during the winter of 1936-37 5/.This report covers 63 brands of gasoline represented by 1,136 samples excluding the Pacific Coast. Those from the Pacific Coast were averaged by the Pacific Coast technical group before being submitted and are published exactly as they were submitted. In some areas reports were received from five or six companies on the same brands of gasoline, whereas in other areas only one company reported on a brand. Thus, it can be seen that some of the data are more representative than others."

Dec 1, 1937

By P. G. Barnard

The Nation's steel industry is largely dependent on shipments of manganese from foreign sources for steel production. An adequate substitute for the manganese requirements of our present steel technology would improve our national self-sufficiency and also contribute substantially to the conservation of our manganese resources. As each of these objectives is a major interest of the Bureau of Mines, possible substitutes for manganese in steel were investigated. Titanium was selected as the most promising substitute because the published results of several investigations indicate that titanium would perform the most obvious function of the manganese in steel: The elimination of iron sulfide and its deleterious effects. The investigation involved extending the published data on titanium additions in steel to provide enough information for an accurate evaluation of the practical value of the substitute. Therefore, quantitative data were obtained on the partition of sulfur and carbon between iron and relatively small titanium additions.

Jan 1, 1962

Estimate costs for projected uranium in-situ mining operations. Approach Develop a computer model and an associated data base which will allow users to supply data applicable to a specific mining site in order to estimate total capital and operating costs for a potential in-situ mining operation at the site. How the Model Works The model requires a minimal amount of input from the user. The data input must be known or estimated information about a potential in-situ mining operation. The user can also supply any additional project specifications. The computer model uses a process-engineering approach and determines through a discounted cash flow analysis the total capital and operating costs for the life of the project. This time-span measures from the start of the pilot-scale operation through to the site's restoration and reclamation. The model will determine the production cost per pound of material mined subject to the rate of return identified by the user. Conversely, it will also solve for the rate of return realized for the specific sales price per pound. [ ] Currently the model's data base can tai ns costs, rates, and specifications for Texas and Wyoming, the only states where commercial uranium in-situ mining is being conducted. However, this model can be used by anyone who is conducting in-situ leaching or who plans to leach uranium in-situ. At least part of any uranium deposit has a potential for in-situ mining.

Jan 1, 1982

By Joseph P. Flick, Kathleen M. Kowalski, Lynn L. Rethi, Roberta A. Calhoun

Many miners are involved in tasks at the mine site that are similar to those sub-tasks performed in general construction, maintenance and repair (CMR) type work activities. As a result, many of the injuries in the mining industry today can be traced to employees performing these CMR type work activities. Indeed, a recent analysis of a major aggregate company revealed that 65% of all injuries documented originated from performing such CMR activities. It is hypothesized that the number of injuries to miners performing construction, maintenance and repair (CMR) work activities on mine property may be reduced through improved training that focuses on better hazard recognition using the numerous visual and other cues that are available for evaluating workplace health and safety hazards. To this end, researchers at NIOSH’s Pittsburgh Research Laboratory have merged two proven methods of training miners to recognize hazards, stereoscopic (3-D) slides and the concept of degraded images, into this training program. Stereoscopic (3-D) slides have been shown in earlier NIOSH and U.S. Bureau of Mines research to be an effective training aid for improving the ability of miners to recognize various geologic and mining-induced irregularities that can cause groundfalls.3 They realistically portray the natural mine environment, and thus are an excellent training aid for teaching miners to recognize such visual cues. The degraded image concept, originally developed by the military and used for target detection training, describes scenes where the target is partially hidden by cloud cover, dust, rain, natural barriers, buildings, or other obstructions that can camouflage or confuse the target. Research had shown that flight observers who were trained with less than ideal (or degraded) pictures were more successful in subsequent identification of targets than those trained using ideal (or highlighted) pictures of targets. In order to investigate this concept for training miners to recognize hazards, NIOSH researchers developed a prototype hazard recognition training program using such mining scenes. A control program based on traditional highlighted mining scenes was also developed. Both programs were applied to subjects in a field experiment. Results indicated that miners trained with the degraded images did significantly better on a follow-up test of hazard recognition.4 This hazard recognition program teaches trainees to look for hazards in a more realistic manner than that of the control program. This specific training program for CMR activities involves using the degraded image concept and 3-D slides. The module is designed to educate workers on hazard identification techniques and safe work practices. It focuses on teaching miners techniques for recognizing visual (sight) cues, and then uses these cues to evaluate mining conditions. It should be stressed that other senses, such as sound can also play an important role in hazard detection.

Jan 1, 1999

Develop an alternative to water bath exhaust conditioners (water scrubbers) for permissible diesel equipment used in gassy mines. Background Water scrubbers are a safety device used on diesel-powered vehicles in gassy mines. Exhaust from the engine passes through the scrubber, where it is cooled, and any flames or sparks present in the exhaust are extinguished. This prevents the ignition of combustible mine dust or methane that may be present. Unfortunately, water scrubbers consume large amounts of water and require frequent maintenance. Approach Methods that do not require water replenishment and frequent maintenance were investigated. The dry exhaust conditioning system was selected for investigation because no water is consumed and existing heat exchanger technology can be adapted to underground mine vehicles. In accordance with U.S. Mine Safety and Health Administration (MSHA) requirements, the system was designed to cool exhaust and trap flames and sparks. The U.S. Bureau of Mines (USBM) developed and evaluated a system for large engines and evaluated a second system for smaller engines. Both systems were evaluated on an engine test bed; if warranted, the system was then tested underground.

Jan 1, 1993

By Jeffrey M. Listak, Gregory J. Chekan

The U. S. Bureau of Mines is investigating longwall panel layouts to maximize coal recovery and minimize interactive problems in multiple-seam operations. When coalbeds are longwall mined in descending order, the transfer of stress from overlying gate roads is a major design constraint affecting pillar stability in the lower mine. The lower mine gate road pillars must be properly designed to withstand the additional load transfer if gate roads are superpositioned in successive seams. The Bureau's MULSIM/NL model, a boundary element computer program, was used to analyze load transfer mechanics for superpositioned gate road pillars. Analysis of Longwall Pillar Stability (ALPS), an empirically based design method for longwall gate road pillars, was used to calibrate model input parameters. ALPS provided a basis to verify model trends and to recommend limits for safe pillar design when superpositioning longwall gate roads. The attributes of the MULSIM/NL model and ALPS were combined to develop a modified method for estimating pillar stress for multiple-seam cases. The modified method uses a multiple-seam factor (MS) to estimate the stress on superpositioned lower mine gate road pillars. Numerical analysis shows that MS depends on the interburden thickness and pillar width.

Jan 1, 1992

By D. J. MacDonald

The Bureau of Mines has carried out investigations on a method for producing zirconyl sulfate solution from zircon sand, comprising (1) reacting zircon sand with molten NaOH, (2) leaching the resultant fusion frit with water to remove sodium silicate and to convert sodium zircon-ate to hydrous zirconium oxide, and (3) leaching the hydrous zirconium oxide from unreacted sand with hot, dilute H2S04 to produce crude zirconyl sulfate solution. The following conditions were found to be suitable: reacting 0.6 kg of NaOH per kilogram of zircon sand for 10 min at 600° C; leaching the frit with 3 to 4 liters of water per kilogram of solids; leaching the residue with 5.1 liters of water and 1.25 liters of 98-pct H2S04 per kilogram of original solids for 10 min at 90° C; and filtering or decanting to recover unreacted zircon sand. A preliminary cost estimate is included.

Jan 1, 1982

By Robert R. Stein, Roy C. Bartholomae, William W. Aljoe

This Bureau of Mines report describes in detail the design and operation of a test apparatus for measuring the sound power levels of drills used by the mining industry. The two major components of the test apparatus are a computer-controlled automated drill test fixture (ADTF) and a large (45,000-ft3) reverberation chamber that houses the ADTF. Design specifications and performance capabilities of the ADTF and the reverberation room are given. Initial test results for three types of drills--a pneumatic percussion drill, a hydraulic percussion drill, and a pneumatic rotary drill--are given to illustrate the types of experiments that can be conducted with the test appartus.

By T. R. Taubert, D. H. Carlson, J. H. Johnson

The U.S. Bureau of Mines and Michigan Technological University (MTU) are collaborating to develop an apparatus for measuring diesel tailpipe emissions in underground mines. A tailpipe emissions measurement apparatus (EMA) is described that dilutes diesel exhaust and measures the concentrations of diesel particulate matter (DPM), CO, CO, NO, and NO, at known dilution ratios. The EMA was evaluated by side-by-side comparison of its measurements with those by laboratory- grade instruments. Concentrations of CO and CO, measured by the EMA were usually within + 14 pct of concentrations measured by laboratory-grade instruments for CO and 220 pct for CO,. EMA- measured DPM concentrations were, on average, 29 pct lower than those measured by laboratory-grade instruments, with the differences being fairly consistent. The CO and CO, differences are related to the method of calculating the EMA's dilution ratio, and the difference in DPM concentrations is attributed to thermophoretic and/or condensation losses related to the EMA's unheated sample probe. Preliminary analysis of data obtained with a heated sampling probe and modifications in the sampling procedures have indicated reduced variability in DPM and in the calculated dilution ratios.

Jan 1, 1992

By Linda L. Chasko, Ronald S. Conti, John D. Cool

Mine operators often rely on mine rescue teams to save lives during an underground emergency such as an underground fire, explosion, roof fall or water innundation. It is extremely important that team members are provided with adequate exploration equipment and that training simulations are conducted in a realistic manner. A series of mine rescue training exercises was developed, conducted, and evaluated by the National Institute for Occupational Safety and Health (NIOSH) in cooperation with the Pennsylvania Department of Environmental Protection, Bureau of Deep Mine Safety and several mining companies. The exercises were conducted at NIOSH’s Lake Lynn Laboratory and operating mines during 1995 to 1999 and resulted in improved technology and training for mine rescue teams. For example, existing technologies were identified to help rescue teams during exploration. These included various chemical light shapes and laser pointers to identify team members and mark crosscuts and mine materials, strobe lights for mapping out escapeways and marking crosscuts, and thermal imaging systems to see through smoke. A hands-free communication system showed potential for enhanced communications between team members and the fresh air base. Anew team lifeline that allows for flexibility of movement between team members was developed. A positive-pressure inflatable escape device (IED) was used to isolate the “hazardous” environment from fresh air and allow rescue team members to traverse through. An inflatable feed-tube partition that can rapidly block large openings such as underground passageways and simultaneously provide a feed-tube for high-expansion foam generators was also deployed for several simulations. During the simulations, mine rescue team members donned self-contained breathing apparatuses (SCBA) and traversed more than 400-m of mine passageways filled with nontoxic smoke. Visibility ranged from 0.3 to 0.9-m. In one area of the mine, a kerosene heater was used to simulate a fire and reduce the oxygen concentration. In another area, a 1.5 pct methane zone was established. The team members searched for "victims,” administered first aid, mapped the passageways, built temporary stoppings, and ventilated the smoke-filled entries. Advanced training included the extinguishment of a conveyor belt fire in a surface fire gallery. Two teams, each carrying charged waterlines, were escorted into the fire gallery through both doors. These teams controlled the rollback smoke and extinguished 7 to 9-m of burning conveyor belt. Team members indicated that the exercises were extremely beneficial due to the realism of thetraining simulations.

Accurately measure time of detonation and explosive detonation velocity in a blasthole for analysis of explosive performance and delay intervals. Approach A blasthole-monitoring fiber optic probe was developed consisting of filer optic cable to carry the fight and a sensor to detect and convert the light signals into electrical signals. Events can then be recorded on an oscilloscope, tape recorder, digital computer, or start-and-stop timer. This method is simpler to use and more immune to electronic noise than existing resistance techniques. The fiber optic material,, are inexpensive and easy to obtain, and the recording devices, such as storage oscilloscopes, arc available or easy to obtain. The probe provides the mining industry, explosive manufacturers, and those studying blasting, with a practical alternative to complex and expensive coaxial cable reflectometry, resistor strings, or resistance wire methods for determining explosive and detonator performance. How It Works The fiber optic cable is a plastic light guide consisting of sixteen 0.01-inch-diameter optic strands having an overall outside diameter of 0.087 inch. The receiver module incorporates a photodiode to detect the signal and an integrated circuit receiver for signal amplification into one package about 1/2 by 5/8 by 7/8 inch.

Jan 1, 1989

By Donald A. Wilson

As part of a continuing effort to maximize metal recovery from domestic secondary resources, the Bureau of Mines investigated a process for recovering the metallic portion of scrap alkaline batteries. A pyrometallurgical method for recovering nickel and cadmium from Ni-Cd scrap batteries previously developed on a laboratory scale, was scaled up to 25-and 43-pound charges. The method employed reduction and/or decomposition in a retort using a minimum of 2.5 percent carbon as a reductant. Metallic cadmium was distilled at atmospheric pressure and a minimum of 900° C. Purity of the recovered cadmium was 99.8 percent minimum and the nickel-iron residue contained less than 0.02 percent cadmium.

Jan 1, 1981

By Peter Kovalchik, Ed Kwait, T. Michael Durr

1. BACKGROUND Many research projects on engineering controls for noise reduction in mining were conducted by the former U.S. Bureau of Mines, mostly under contracts from 1972 through 1986.1 Contracts were awarded to determine which mining equipment was responsible for worker noise exposure over the permitted Federal Regulation level of 90 dBA for 8 hours. Dominate noise sources, for each piece of equipment was also determined. The final goal was to develop engineering noise controls for those pieces of equipment and then evaluate them. This was the general approach taken in each research project or contract. This paper deals with what is known about the control of noise from continuous miners, one of the most commonly used underground mining machines. A literature review on continuous miners revealed that the relevant noise sources were divided into four categories: conveyor, cutting head, drive train, and motor noise. The dominate noise sources reported were the conveyor noise and the cutting noise.2 Conveyor noise consists of impacts and scraping at various locations on the conveyor structure. These impacts are associated with discontinuities on the top and bottom decks, impacts between the chain and the tail roller, impacts on the sidewalls at path points of discontinuity under horizontal pivot, and impacts on the flex plate.3 Scraping occurs along the entire length of the chain conveyor. The other dominate source, the cutting of coal, has also been addressed in past research.4, 5, 6 The research presented in this paper only addresses the controls associated with the conveyor. The literature suggests several effective treatments for noise control: retrofitting the chain conveyor with a urethane coating or a urethane sleeve on the chain flights, using a urethane coating or urethane sleeve on the tail roller, constrained layer damping of the decks, and the use of a modified take up plate.7, 8 However, the in-mine durability of these concepts has yet to be proven for the conveyor system. This paper analyzes extensive noise and urethane durability testing on a Joy 14CM9 continuous miner’s conveyor assembly, tail roller, and bottom plate conducted at the Pittsburgh Research Lab facilities. It will also discuss the initial underground testing results for the urethane-coated conveyor flights and tail roller.

By C. H. Elder, Fred N. Kissell, S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

By R. D. Saltsman

Under contract with the Federal Bureau of Mines, Bituminous Coal Research, Inc., performed a statistical study to find less expensive and time-consuming methods of monitoring the noncombustible content of coal mine dust. Calculations based on thermodynamic considerations verified the reasonableness of Federal rock-dusting requirements. The results of extensive sampling in southwestern Pennsylvania mines indicated that, at the 95-percent confidence level, the present system of sampling at 200-foot intervals may be replaced by sampling at 500-foot intervals, and that a 1-inch scoop floor sampler may replace the standard 6-inch scoop for floor sampling. Further field testing is recommended.

Jan 1, 1975

By M. R. Geer, H. F. Yancey

"INTRODUCTION The increased use of coal as pulverized fuel has focused attention on the grindability of coal and on the necessity of evaluating this property by a method suitable for use in the usual coal-testing laboratory. Without some knowledge of how various coals behave in the grinding operation, that is, how their use affects mill capacity and power requirements, the selection of coals for pulverized-fuel plants cannot be made on the same critical basis used in selecting coals for other types of burning equipment. The grindability of a coal, serves principally as an indication of the mill capacity attainable in grinding it - not as a direct index of the total cost of grinding. Although the grindability of coal may play a minor role at some plants, it is a decidedly important factor where pulverizer capacity limits the ability to carry high loads.Purpose Standardized tests for determining the grindability of coal are relatively new, so that the information now available on the grindability of various coals is limited in comparison, for example, with that available on proximate analyses. Published information is restricted to determinations on many important Eastern coals by the Fuel Engineering Co. of New York, 4/ a bulletin giving the results of numerous tests by the Babcock and Wilcox Co. 5/, and a comprehensive report on. Alabama coals by the Bureau of Mines. 6/This report presents the results of grindability tests of 34 samples of coals from Illinois, Kentucky, Pennsylvania, Utah, Virginia, Washington, West Virginia, and British Columbia at the Northwest Experiment Station of the Bureau of Mines, Seattle, Wash., in cooperation with the College of Mines of the University of Washington. In the future, as the laboratories of the Bureau make grindalility tests of other coals, additional reports will be issued."

Jul 1, 1938

By R. P. Vinson, D. P. Tuchman

The personal dust monitor (PDM) is a sampling device developed for measuring the personal exposure to coal mine dust of mine workers. The device is based on proprietary technology known as the tapered element oscillating microbalance (TEOM) originally developed as a fixed- site environmental particulate mass monitor by Rupprecht and Patashnick Co., Inc., Albany, NY. Currently, the monitoring of exposure to coal mine dust relies on periodic samples taken by traditional coal mine dust sampling units that use a cyclone, filter, pump, and laboratory measurement of the filter mass. Better measurement of mine dust levels has been the goal of industry and labor for nearly two decades. PDM technology offers accurate, end-of-shift and near real time assessment of worker dust exposure. Laboratory and underground tests compared measurements taken by a prototype PDM-2 (a two-piece TEOM) to the average of multiple personal dust samplers monitoring the same space. In the range of mass loadings P between 0.5 and 4.0 mg/m the PDM met a 25% accuracy criterion 95% of the time with 95% confidence. However, some questions still exist about potential bias between types of coal. The prototype two-piece device is in the process of being combined into a single unit that also contains the miners' cap lamp creating a more ergonomic dust sampling system.