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By Alla D. Mah

No experimental heat-of-formation value has been reported in the literature for cerium sesquioxide. The heat of formation of bismuth sesquioxide has not been determined in recent years, and the older value was subject to large uncertainty. Accordingly, the heats of combustion of cerium sesquioxide and bismuth metal were measured by the Federal Bureau of Mines. The heats of formation were: ?H°298.15 = -427.01 ± 0.70 kcal. /mole for cerium sesquioxide and ?H°298.15 = -137.16 ± 0.30 kcal./mole for bismuth sesquioxide. The free energy of formation was estimated for cerium sesquioxide and accurately calculated for bismuth sesquioxide. The data were compared with values in the literature.

Jan 1, 1961

By A. B. Hooker

Investigations at the Pittsburgh Experiment Station have shown that the satisfactory operation of aflame safety lamp depends not only upon proper design and assembly of the lamp but upon the kind of fuel used, and that much of the trouble experienced with permissible flame safety lamps at mines is due to the common use of motor gasolines, none of which is suitable in the present types of permissible flame safety laps. This report gives the results of a limited study to determine what satisfactory fuels are available, the specification limits of such fuels, and to suggest modifications of assembly and care of the lamps to improve performance with any satisfactory fuel.

Jan 1, 1938

By Dana Reinke, Launa Mallett

Interest in training evaluation in the mining industry was piqued with the promulgation of Title 30, Part 46, of the Code of Federal Regulations. Under Part 46.3, a training plan is considered to be approved if it contains certain information, including “The evaluation procedures used to determine the effectiveness of training.” The present paper is a broad overview of training evaluation and is intended to give trainers and decision-makers a framework for planning or assessing training evaluation strategies. It discusses questions to consider when starting an evaluation plan, Kirkpatrick’s model of evaluation categories, and various ways to collect data. It does not provide detailed instructions on how to develop evaluation methodologies, but reviews topics to consider when creating an evaluation plan. Training evaluation is a term that has many different meanings: assessing the quality of a course, effectiveness of materials used, teaching style of an instructor, or the comfort of a classroom. An evaluation can be done informally over lunch or with highly structured data-gathering tools. It can produce results that are useful to trainers, program administrators, corporate decision-makers, or no one. The key to a worthwhile evaluation is clearly defining why the evaluation is being conducted. Once the purpose is defined, planning the evaluation strategy can begin. For an evaluation to be effective, it should be incorporated into the development of the training activity itself. The training evaluation worksheet at the end of this paper can be used to guide evaluation planning.

Jan 1, 2002

By Launa G. Mallett, Charles Vaught

This report is intended to help mine safety trainers better prepare to teach the influx of new underground coal miners who are entering the industry. This is done by identifying two different approaches to instruction and discussing the ways they may affect how well prepared new hires are to deal with a dynamic and hazardous workplace. One approach is based on the use of a syllabus. Those using a syllabus are more likely to rely on lecturing or direct instruction. This is a good way to get across factual information, but does not provide a context within which miners can fit the discrete facts so that they form an integrated whole set of concepts, principles, and skills. The other approach is based on the use of a curriculum. Those using a curriculum may be more likely to help miners integrate concepts and skills that give them an overall picture of the complex mining environment and how they fit into the workplace. This will better prepare them for the decision-making and problem-solving activities that will help them work safely and productively

Jan 1, 2008

By Rex D. Thomas

Concentration of the kerogen (organic material) in oil shale was accomplished by centrifuging after pretreating the oil shale with carbonic acid to remove the carbonates and pretreatment with sodium hydroxide (pH 11.5) to remove the claylike minerals. Analysis of the materials obtained showed that the concentrations of organic sulfur and organic nitrogen compounds were not affected by centrifuging. These compounds are evenly distributed in the kerogen and are not strongly bound to the mineral constituents. Organic oxygen compounds, however, were concentrated in the light fraction. These compounds are more closely associated with the kerogen and are not bound to the mineral constituents. Iron compounds other than pyrite apparently are closely associated with the organic material.

Jan 1, 1970

By R. W. Crocker, H. H. Clark

The purpose of the investigation discussed in this bulletin, one of a series dealing with the use of electricity in mines, was to study the various means and methods used to confine the flashes that occur when a switch carrying electric current is opened. The flash result- ing from the opening of a 250-volt direct-current circuit carrying more than half an ampere will ignite explosive mixtures of mine gas and air. An equally dangerous flash may be produced by even less cur- rent from a 500-volt circuit. Few mine electric circuits carry less than half an ampere when in use. The need of protecting the switches of such circuits in places where gas is likely to be present is therefore obvious. Two general methods have been proposed for preventing switching flashes from igniting gas surrounding the switch. One method is to inclose the switch in a casing provided with openings that are covered with wire gauze or otherwise designed and equipped for preventing the passage of flames from the interior to the exterior of the switch casing. Switches so protected are called explosion-proof switches. The second method is to immerse the switch contacts in oil to a depth sufficient to quench any flash that may occur when the switch is operated. Switches so protected are called oil switches. The success of the first method of protection depends upon the proper design and construction of the switch casing. It is essential to the successful operation of the second method that the switch contacts be surrounded by the proper kind of oil in good condition. There are several ways in which an oil switch may be deprived of its protective feature. The oil tank may not be filled or, if filled, the oil may leak out or be spilled. The oil tank may be removed (in some designs) and not replaced or through neglect the condition of the oil may become such that it is no longer an efficient protection. While such contingencies are not likely to occur, and although oil switches may be so designed that the loss of oil is not probable, nevertheless, as compared with oil switches, explosion-proof switches seem to

Jan 1, 1913

Simplify the spraying of sealants onto coal mine roofs. Approach A nonclogging system in which dry-fed sealant is mixed with water down-stream of the spray nozzle, has been developed and tested. How It Works The two-channel nozzle of this spray discharges two separate flows, a mixture of air and dry sealant from a central cylinder, and an encircling spray of water from a concentrically mounted water ring (a ring-shaped manifold). Downstream of the nozzle, the water mixes with the air and sealant to form a wet sealant spray that adheres to mine surfaces with very little rebound. (See photograph.) Extensively modified commercial spray machines are used to feed the sealant to the spray nozzle smoothly, without raising dust. Plugging of the nozzle is practically eliminated by two self-cleaning design features of the nozzle. These are the air gap and the tapered bore of the cylinder, (See drawing.)

Jan 1, 1979

By Charles E. Whieldon

The importance of recovering more oil from known petroleum reserves has placed increased emphasis on the application of secondary-recovery methods. It is hoped that these reports will stimulate interest in improved waterflooding techniques, thereby discouraging premature abandonment of oil leases. A previously published report4/ described the highly successful results of waterflooding in the Weir sand in eastern Kentucky. A more recent report5/ evaluated the results of waterflooding in Roane County, W. Va. (See fig. 1.) Two waterflooding projects have been operated in Pleasants County, W. Va. (fig. 2), one by the Dearborn Oil & Gas Corp. in the Cow Run sand near Calcutta, McKim and Washington districts, and the other by George C. Schoonmaker in the Maxton sand at Bens Run, Union district. This report report describes the waterflood operation near Calcutta, W. Va.

Jan 1, 1960

By Donald O. Capstick

A mineral survey of a 13,525-acre portion of the 21,875-acre Owyhee Canyon Wilderness Study Area in northern Nevada was conducted by the U.S. Bureau of Mines in 1984. Two samples from sand and gravel deposits in the study area contained minor placer gold typical of the Owyhee River area. The gold-bearing gravels are too low grade or of insufficient volume to support commercial placer mining operations. The sand and gravel deposits might have minor local construction uses.

Jan 1, 1986

By R. D. Leitch

The pollution of streams by acid mine drainage has become of great importance in the past few years in certain regions of the United States. Large quantities of acids are used in a discharged from other industries than mining, notably in tube, sheet, tin-plate and era hell inn works. These are usually less important then coal mines as a source of acid drainage, because of their more limited distribution throughout the States most affected by acid waters and their relatively smaller numbers. Streams are naturally alkaline and are, therefore, able to take care of rather large quantities of acid wastes, but when such enormous quantities as are often found in mining districts enter the streams, the natural alkalinity is quickly overcome. When a neutral or almost neutral condition has been reached, the further addition of a relatively slight quantity of acids will cause a great difference in the quality of the water.

Jan 1, 1926

Permit visual inspection of underground cavities dam the surface. Approach A closed circuit TV camera and a 35mm still camera are lowered down a borehole, and remotely operated. How It Works A platform holding the cameras, and other equipment is lowered on a graduated cable until the depth of interest is reached. Then a quartz lamp and the TV camera are turned on. The television picture is monitored at the surface and recorded on video tape. Areas of special interest are photographed with a 35mm still camera. These photographs contain more detail than TV images because photographic film is capable of higher resolution than a TV transmission.

Jan 1, 1979

By R. B. Tippin

Research investigations conducted on five ore samples show the applicability of heavy liquid separation (HLS) techniques to mineral processing. Under proper operating conditions, semicontinuous tests in small fluid cyclones yielded 90 percent sink-float concentrates with recoveries exceeding 90 percent on minus 35-mesh ore samples of kyanite, potash, spodumene, fluorspar, and beryl. Although none of the ores were examined in detail, their response to this novel concentration method provides basic examples that are typical of the process. Various aspects of cyclone design and operational characteristics of heavy liquid cyclone circuits were studied which demonstrated the flexibility of HLS by using multiple units connected in series. A comparison of two heavy liquid solutions, tetrabromoethane and methylene bromide, exhibited their individual advantages and limitations. Unique problems relative to this process are discussed including liquid viscosity, mineral composition of the ore, toxicity, and material handling hazards.

Jan 1, 1968

By G. F. Kuncir

The funding tables included in this report were defined in support of an evaluation of the Advancing Oil Sale Mining Technology Program undertaken by The Aerospace Corporation. Because of the sensitive nature of the fiscal planning information, the tables have been separated from the main analysis report and given a limited distribution.

Jan 1, 1977

By E. D. Wilson

This is the second of a series of progress reports describing work undertaken at the San Manuel copper mine to study the geologic factors influencing block caving of the deposit. The first report described the work done from April 1954 to March 1956.3/ This report describes the progress from March 1956 through March 1958 and presents additional maps, factural data, inferences, and conclusions resulting from a continuation of the underground geological work. As outlined in these reports, the study thus far has shown that the principal geologic factors affecting block caving are structure, rock types, alteration, mineralization, oxidation, and presence of water. Structure is fundamentally the most important. Systematic fracturing governed the extent and grade of primary ore mineralization and tangibly affects the subsidence or ground movement, which extends from the mine workings to the surface because of the block caving.

Jan 1, 1960

By D. L. Pool

To increase metal recoveries and to minimize pollution by improved extraction technology, the Bureau of Mines investigated a hydrometallurgical technique to recover copper, lead, nickel, and cobalt from lead smelter mattes. The metals were converted from insoluble sulfides to soluble chlorides using a HCI-CI2-02 leaching system. Parameters studied in a 50-gallon, glass-lined reactor were the ratio of hydrochloric acid to chlorine, chlorine consumption per pound of matte, oxygen reaction pressure, and temperature. The matte material used contained, in percent, 19.7 Cu, 52 Pb, 2.9 Ni, 1.5 Fe, 0.38 Co, 0.19 As, 0.41 Zn, and 0.12 Cd. Extraction of Cu, Pb, Ni, Co, and Cd ranged from 92 to 98 pct, with concomitant extractions of Fe and As of <0.1 pct. The Cu and Pb were recovered as electrowon metals, while the Ni, Co, and Cd were recovered as mixed hydroxides.

Jan 1, 1981

Dec 1, 2007

By L. J. Prosser, A. T. Iannacchione

From 1991 through 1995, 44 miners out of a total workforce of less than 2,000 were fatally injured in the stone industry. Of these, 12 occurred at underground mining operations with nine deaths resulting from roof or rib falls. A safer environment can be achieved by evaluating the nature of the hazardous ground and by developing more efficient and effective ground-control strategies Roof and rib conditions were observed and assessed in 33 underground stone mines in Illinois, Indiana, Kentucky, Maryland, Missouri, Pennsylvania and West Virginia (Fig. 1). Hazard assessment indicated that the ground failures that occurred under moderate to substantial overburden. i.e., >30 at (100 ft), were caused by stress concentrations and geologic strictures. Ground failures near the surface are caused by solution (water) processes. Selection of the mining horizon and mine-layout decisions tremendously influence ground stability.

By S. J. Anderson

The Bureau of Mines compared three methods of rock cutting using drag cutters under controlled laboratory conditions. The methods tested were the conventional drag cutting method used on continuous miners, the kerf-core method used on some boring machines, and an experimental method called ripper cutting. All three methods were tested in blocks of Indiana and Kasota limestone. The results of this testing showed ripper cutting to be 30 to 40 pct more energy efficient than both the conventional and the kerf-core methods in Kasota limestone and 35 pct more efficient than the kerf-core method in Indiana limestone. The conventional method was, however, 9 pct more energy efficient than the ripper method in Indiana limestone. These results are considered promising, and more tests are planned with the ripper cutting system.

Jan 1, 1987

By Howard E. Parkinson

The mine pager phone to public telephone interconnect system permits mine paging telephones to be interconnected with the public phone system, thereby providing emergency and off-hours communications. The system, a push-to-talk, push-to-listen system, is compatible with any mine paging system utilizing dc voltage on the line to enable paging. A tone generator of the proper frequency enables an outside caller to page over mine pager system loudspeakers. A caller inside the mine can make an outgoing call to a preselected, preprogramed number with the use of a proper frequency tone generator. The system includes an automatic hangup timer that restricts the time off-line due to a wrong number or incorrect hangup to 20 seconds and 6 minutes, respectively.

Jan 1, 1974

By Robert P. Vinson, Fred N. Kissell

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SFG) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976