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By J. E. Dooley

An analytical procedure developed by the Bureau of Mines was applied to the separation and characterization of a 370° to 535° C distillate from Swan Hills (south field), Alberta, Canada, crude oil. Investigators determined the general characteristics of the crude oil by the Bureau's routine method for crude oil analysis. Suitable fractions were prepared for instrumental analyses by utilizing such techniques as isothermal and molecular distillations, chemical treatment, silica-alumina gel chromatography, and gel permeation chromatography (GK). A detailed characterization of the 370° to 535° C distillate was possible by the application of GPC-mass spectrometry correlations and nuclear magnetic resonance spectrometry. Semiquantitative data based on mass Z series distributions were determined and are shown. The data will be valuable in developing future processing techniques and in calculating yields for converting high-boiling distillates into more useful energy forms.

Jan 1, 1973

By M. L. Odenbaugh

The viscosity reduction effect of varied concentrations of leonardite (a naturally oxidized form of lignite) and leonardite-caustic on the rheological properties of a standard bentonite drilling fluid was studied and evaluated. The minimum plastic viscosity was found to occur at application rates of 4 lb of leonardite and 1.33 lb of caustic per barrel of drilling fluid. Leonardite-caustic treatment was not beneficial in treatment of salt-contaminated drilling fluids. Although filter loss rate was reduced; both yield values and gel strength were increased. Compared with other viscosity control agents) including quebracho) ligno-sulfonate) humic acids extracted from leonardite) as well as other reaction products of lignite) leonardite is less effective at low application rates but is an effective treating agent at rates of 2 Ib/bbl or more. Considering the comparable merits of the substance tested) the major factor in determining which agent to use should be based on cost consideration.

Jan 1, 1967

By W. P. Diamond, John C. LaScola, D. M. Hyman

In 1972, the Bureau of Mines developed a direct-method test for measuring the gas content of virgin coal core samples for coal mine health and safety considerations. Since that time, approximately 1,500 coal samples from more than 250 coalbeds in 17 States have been collected for gas content determination. The gas content data, when combined with geologic and engineering studies, can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if methane drainage in advance of mining should be considered. The data are also critical in delineating coalbed methane resources and in utilization feasibility studies. This report makes the Bureau's extensive data base of gas content data more readily available to the coal and gas industries. The data are presented in tabular form, alphabetically by coalbed name and by State. The components of the total gas content (lost, desorbed, and residual gas) are given, Location (State and county), sample depth, coalbed or formation name, and coal rank are included for geographic and geologic identification.

Jan 1, 1986

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By J. J. Forbes

The rapid increase in the quantity of coal being mined by stripping methods is one reason for the increased interest evinced by safety and other agencies in the hazards that are inherent in this Method of mining. The coal-mining laws of some States contain general provisions governing the mining of coal by open-cut methods, but none contains a complete list of specific safety regulations or laws for-the safe operation of such mines. The cool-mining laws of one State empower the head of the coal-mining inspection organization to proscribe regulations for coal-stripping operations and gave him the authority and power to enforce the rules and regulations promulgated by him.

Jan 1, 1944

By Frank A. Peters

This description of process evaluation techniques used by the Bureau of Mines for studying proposed processing techniques has been prepared to provide those interested in using these studies with an understanding of the methodology. The methods used for preparing both capital and operating cost estimates are described. Each step in preparing the evaluations is described. Types of equipment costs are shown and factors used in the estimates are defined. Uses of the estimates are suggested and several examples are included. The accuracy of various types of estimates is discussed, along with an explanation of the reason for selecting the type used in the Bureau's process evaluation studies.

Jan 1, 1987

By P. D. Bergman

To assess the efficacy and economics of producing power from coal, four open-cycle magnetohydrodynamic (MHD) processing schemes were selected for study. Each involved a different mode of coal combustion and level of gas cleanliness. The options considered were: (1) coal burned in a slagging combustor; (2) suspension gasification with slag removal prior to combustion; (3) parallel cyclone combustors, one operating fuel rich and the other operating with excess air; and (4) suspension gasification by the hot exhaust gases from the MHO duct with ash removed prior to combustion. Option 1 has the highest ash content in the combustion plasma and as a result would have the greatest operational difficulties associated with it. Options 2 and 4 have the cleanest MHD combustion plasma. For coal priced at $4/ton, the power generating cost of option 4,11.78 mills/Kw-hr, is the highest, with Option 1, at 9.04 mills/kW-hr the lowest. These costs may be compared with a conventional power cost of 9.92 mills/kW-hr for the late seventies. Capital costs of three of the four options were competitive with those of conventional thermal power plants employing stack gas S02 cleanup systems. Option 2 has the most favorable combination of operating characteristics and power cost. It was concluded that a clean, high-temperature working fluid can probably be produced from coal without leading to depressed system efficiencies and exorbitant capital costs.

Jan 1, 1973

By J. Hudy

The performance of six dense-medium washers was evaluated in five preparation plants. Three of the plants were making a two-product separation that produced a clean coal and a refuse; one plant employed dense-medium vessels in series to effect a primary and a secondary separation; and one plant was equipped with a two-compartment washer effecting two separations in one vessel. The separate secondary drum-type washer produced a low-ash metallurgical coal and an intermediate-ash product suitable for plant fuel or steam generation. The two-compartment washer produced a premium anthracite product and a middlings product. The sharpness-of-separation values ranged from good to excellent for the five primary separations and for the secondary separation.

Jan 1, 1968

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

MFIRE is a computer simulation program that performs normal ventilation network planning calculations and dynamic transient-state simulation of ventilation networks under a variety of conditions The program is useful for the analysis of ventilation networks under the influence of natural ventilation, fans, fires, or any combination of these MFIRE simulates a mine's ventilation system and its response to altered ventilation parameters such as the development of new mine workings or changes in ventilation control structures, external influences (varying outside temperatures), and internal influences (fires) Extensive output enables detailed, quantitative analysis of the effects that the alteration will cause to the ventilation system The program was developed at Michigan Technological University (MTU), Houghton, MI, with support from the Bureau of Mines A personal computer (PC) version of the program was completed under contract for the Bureau by MTU The purpose of this report is to document the installation and use of the PC version of the program MFIRE

Jan 1, 1990

By R. V. Lundquist

The work described in this report, part of the Bureau of Mines long-range program to develop methods of utilizing submarginal domestic sources of aluminum, was undertaken to investigate the effects of iron in the lime soda sinter process, The approximate Fe2O3 content in a sinter for maximum alumina and soda recovery was 8 to 9 percent. Fe2O3 appears to inhibit gelation, and 15.5 percent Fe2O3 produces effects similar to those produced by 1 percent sucrose. In the lime soda sinter process, aluminum silicates are sintered with limestone and soda ash to yield dicalcium silicate and sodium aluminate. The sodium aluminate is extracted by leaching in caustic solution. The solution is purified by heating in an autoclave with lime to remove silica, and alumina trihydrate is precipitated with carbon dioxide. The reactions involved in sintering and leaching are complex. A number of studies by the Bureau of Mines4-9 and others1 indicate that the iron content of sinters influenced the recovery of alumina and soda and the gelation characteristics.

Jan 1, 1962

By Charles L. Kimbell

Bulk carriers, freighters, and tankers are the three classes of marine vessels engaged in transporting mineral commodities. However, vessels in each of these categories are not devoted wholly to mineral commodity transport. Bulk carriers move agricultural products as well as crude minerals and mineral fertilizers, as ore/bulk/oil carriers also do. Freighters, owing to their great variety, can be devoted wholly to hauling mineral products or wholly to moving nonmineral goods, as well as carrying mixed mineral and nonmineral cargoes. They include general cargo carriers, full containerships, partial containerships, roll-on/roll-off ships, and barge carriers. Tankers, although largely engaged in moving crude oil and refinery products, also transport liquid chemicals, molasses, wine, liquefied natural gas, and other fluids. Although physical characteristics of vessels, such as sue, draft, crew requirements, and type of propulsion system, as well as fuel costs, have an undeniable influence on shipping industry performance, problems of and changes in the quantity and quality and types of material moved also significantly affect the shipping sector of the world economy. Unfortunately, comprehensive data in this regard are not available.

Jan 1, 1992

By C. G. Kirkland

An apparatus for determining trace impurities in Grade-A helium by mass spectrometer methods was designed and built by the Federal Bureau of Mines. Grade-A is the designation for helium commercially produced by the Bureau. Its nominal purity is 99.995 percent. The device, following a suggestion by Deaton, concentrates the impurities in the helium by freezing them out in a coil-and-trap assembly cooled by liquid helium. A known volume of helium is passed through the trap, the concentration ratio determined, and samples of the concentrated impurities are analyzed by mass spectrometer methods. The apparatus has been in service for approximately 20 months and has satisfactorily met all requirements. Over 200 analyses were made of helium contained in conventional cylinders, obtained from the Amarillo, Exell, Otis, and Navajo Helium Plants, during the 6-month period ending March I, 1959. Total impurity concentrations, in parts per million, were as follows: Amarillo, 19.1; Exell, 17.1; Otis, 11.3; and Navajo, 6.6. Neon and nitrogen were the major impurities. Complete data are shown in table 4 in the body of this report.

Jan 1, 1960

By George J. Conroy

Techniques for locating trailing-cable faults are discussed, particularly those techniques suitable for use in underground coal mines, which have been the subjects of Bureau of Mines research. The discussion concerns precautions and suggestions for locating faults, rather than detailed descriptions of apparatus.

Jan 1, 1979

Provide coal mine shafts/slopes with an optimum coal mine shaft fire and smoke protection system composed of reasonably-priced, reliable hardware. Approach Accident and injury data indicate that a relatively low percentage (5%) of underground coal mine fires occur in shafts or slopes. Nevertheless, shaft or slope fires are extremely serious because they block critical escape routes for miners. That also can happen when combustion products resulting from fires in other mine areas contaminate shahs and slopes. Seeking the optimum configuration for a shaft/slope fire and smoke protection systems, the Bureau of Mines gathered data on the performance of existing fire detection devices and signal telemetry systems In several mines, and analyzed the generic protection needs of the U.S. underground coal mining industry. The optimum system developed by the Bureau provided an adequate number of detectors, a wide area of coverage, and an extensive data acquisition, analysis, display, and storage capability. This system. recommended for fabrication and in-mine testing, consisted of a microcomputer-controlled master panel located in the test mine's slope hoist room, and four remote units. Two of the remote units were placed on the surface atop upcast ventilation shafts, a third was situated underground near the slope bottom, and a fourth was installed at the slope top in intake air.

Jan 1, 1986

By A. W. Ambrose

"Records of individual wells form the basis for the successful operation of any company engaged in the production of petroleum. The expense attached to the compilation of records is negligible in comparison with the benefits resulting from their use. There a company has not a complete system of records, immediate attention should be given to the preparation of forms upon which to collect data, and, to the collection of data for these forms. The records needed vary with each district, but for each field a set should be adopted that will best meet the needs of each property. Practically all operators, and particularly all successful operators, agree on the necessity of good records, shopping what the wells have done, are doing, and may be expected to do in the future. Any operator realizes the value of records of sales of oil and should place almost equal emphasis on the records of well logs and histories showing the east and present performances of wells. Indeed, trustworthy records are absolutely necessary for the proper operation of any oil or gas property.Complete records should be kept on each well from the time the location and elevation are determined until the well is abandoned, and the engineer should review old records often enough to be familiar with the past performance of the various wells and with the conditions that affect production. Some of the forms that may be prepared are:--"

Mar 1, 1920

By Manuel Gomez

Areal distributions for ash, total sulfur, and sulfur forms were developed for the top 12 inches, the middle section, the bottom 8 inches, and the total seam of Pittsburgh coal in southwestern Pennsylvania. The sulfur and ash exhibit an apparent high local variability. As a general rule, both the sulfur and ash show high concentrations in the top 12 inches and in the bottom 8 inches of the seam relative to the concentrations observed in the middle section of the seam. The high-low sulfur and ash concentrations in the top 12 inches of the seam are not coincident with the high-low sulfur and ash concentrations in either the middle section or the bottom 8 inches of the seam. With respect to sulfur and ash, it is suggested that the top and bottom sections of the Pittsburgh coal may reflect both a syngenetic and epigenetic origin. Present data support the belief that paleotopography controlled Pittsburgh seam deposition. Evidence is presented to show that channels were cut at various times into the semilithified sediments that buried the Pittsburgh seam. In this channeling process, portions of the Pittsburgh coal may have been eroded away. Following channel development, the lower part of the Pittsburgh sandstone filled the complex system of braided channels to produce the "want areas" encountered in present mining operations. In localized areas of the Pittsburgh seam, impingement of Pittsburgh sandstone may be responsible for the lateral displacement of the coal. Information of this type becomes important in the assessment of exploration data, in the development of a quality control system for mine output, and in mine life planning.

Jan 1, 1974

By C. P. Mangelsdorf

This report deals with the efforts to develop a portable device suitable for underground use for the purpose of measuring the frequency of vibration of the horizontal chords of Birmingham roof trusses. Four devices are investigated and evaluated. An approximate emperical expression developed from a mathematical analysis provides a means of converting the frequency into tension. The method appears to be effective in mines with shale roof but requires some modification for other roofs.

Jan 1, 1983

By Mark I. Copeland

The Bureau of Mines discovered that silicon and nickel additions can prevent the formation of copper alloys of Sn, Sb, and As on the surface of steel during reheating to hot-working temperatures. When molten, these copper alloys cause surface hot shortness during hot working. Wrought steels were reheated isothermally and by simulated industrial practice; the resulting surfaces were metallographically evaluated. The steels contained, In weight-percent, 0.20 C, 0.45 Mn, and up to 1.00 Si, 1.00 Cu, and 0.15 Ni, and up to 0.30 Sn, Sb, or As. The larger the Cu, Sn, Sb and As content of the steels, the greater the amount of silicon necessary to prevent copper alloy formation. A content of 0.10 Ni considerably decreased the amount of silicon necessary for copper steels containing tin and antimony, but not for those containing arsenic. Theories for the beneficial effect of silicon and nickel additions are presented.

Jan 1, 1975

By R. V. Ramani, A. S. C. Owili-eger

Mathematical modeling is a scientific exercise with the objective of developing simplified mathematical statements that relate to one another the same way as the processes that are being modeled. The utility value of the model is dependent on the ability of the model to closely approximate prototype behavior. Development of a perfect model, therefore, is an unrealistic objective because of the simpli¬fying assumptions made in building it. However, for a model to be acceptable for application, its operating characteristics or data generated from it should, within reasonable accuracy, duplicate proto¬performance. The validity and accuracy of a model depends on the mathematical constraints presupposed in model formulation. The final model must be tested for mathematical validity and for closeness of representation of the prototype. Mathematical validity, does not, however, imply that the model is accurate and correct but is prerequisite. Model testing and verification for the steady state model are given in Owili-Eger et al (1973). The unsteady state model has been tested for mathematical validity and found to be correct but has not yet been applied to a field condition for lack of data. However, in the application discussed below, the unsteady state model results are compared with pressure curves reported in literature and also with results from the steady state model. Coal seam characteristics and gas reservoir pressure used in this application are extracted from Kissell (1972). These characteristics are for the Pittsburgh seam, Federal No. 2 Mine, Fairview, West Virginia.

Jan 1, 1974

By Richard H. Spencer, Warren G. Bender

Since the passage of the Coal Mine Health and Safety Act of 1969, the Bureau of Mines has made many advances in mine communications. These efforts have resulted in the following developments and demonstrations: • Surface-to-surface electromagnetic transmission of baseband voice signals through overburdens as deep as 600 feet. This transmission was achieved with equipment from the Interim Mine Rescue and Survival System Program, and demonstrated that baseband voice communications could be obtained through these overburdens in the absence of mine-generated noise; that is, when the mine power system was shut off. However, during mine operational conditions, the mine-generated noise proved to be so large that effective baseband voice communications to the desired depths could not be effected. • The development of beacon transmitters for locating trapped miners. This work was again the outgrowth of the Interim Mine Rescue and Survival System. Extensions of this work have led to reliable detection and location of trapped miners to depths of 1000 feet. The system, which makes use of a loop antenna deployed where the trapped miner is located, uses low-duty-cycle, tone-burst transmission. Portable tuned receivers and loop antennas are used on the surface to determine the location of the trapped miner. An extension of this work has led to a call-alert paging system concept, wherein a transmitter, similar to that used in the trapped miner system, is used to audibly and/or visually alert key mine personnel carrying pocket receivers that they are wanted at the nearest mine telephone. In addition, a roof-bolt paging system has been developed, wherein commercial paging and mine carrier phone equipment are used in conjunction with a long-wire "roof bolt" antenna to page individuals and relay to them short voice messages.

Jan 7, 1975