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By S. M. Shelton, F. D. DeVaney, M. M. Fine

Ferrograde manganese ore or its equivalent is essential to the manufacture of every ton of steel produced ; although it is well -known that there are large deposits of low - grade ore in the United States , the production of substantial amounts of ferrograde material from domestic sources presents a problem that becomes more and more critical as the stockpiled ore is depleted through inability to obtain adequate supplies from foreign sources . Consequently, a program of laboratory and pilot - plant investigations designed to solve the problem of obtaining a domestic supply of manganese has been undertaken by the Metallurgical Division, Bureau of Mines . This paper is one of a new series that will include reports of results obtained in the various investigations conducted under the manganese program . The scope of the program and the organization that was set up to direct and supervise the work were discussed in the foreword of the first paper of this series , Report of Investigations 3606 , Manganese Investigations 1. Concentration of Manganese Ores from the Drum Mountain District, Utah, by S. R. Zimmerley, J. D. Vincent , and C. H. Schack . Other reports will be published as the work progresses .

Feb 1, 1942

By C. W. Sill

[In the original Norris and Fay method for determining selenium, selenious acid is reduced by an excess of standard thicsulfate in accordance with the following reaction: H2Se03 + 4Na2S203 + 4HC1 = Na2SeS406 + Na2S406 + 4NaC1 + X20. (1) The excess thiosutfate is then back-titrated with standard iodine solution. The disadvantages of ouch a method are obvious. On an unknown sample, the quantity of thiosutfate required would be difficult to determine; a definite excess is required, but large back titrations would be undesirable. Inasmuch as thiosulfate is decomposed by acid, considerable error may be introduced in this method, the amount depending on the acidity, temperature, concentration of excess thiosulfate, duration of contact between thiosulfate and acid, and other factors, In a critical study of the Norris and Fay method, Coleman and McCrosky3/ show that the method is accurate to less than .1 part per thousand if the excess of this sulfate Is not greater than 5 ml. of 0.1 N solution (in 1.0 ml. of 0.x4 N sulfuric acid) whether the titration is made at 0° or 20°C. A greater excess produced unsatisfactory values at either temperature. Coleman and McCrosky regulated the excess thiosulfate by adding 5-ml. portions of thiosulfate solution followed by the addition of 1 to 3 drops of 2.5 percent potassium iodide in the presence of starch. If a starch-iodine blue color formed locally around the drops of potassium Iodide, the reduction of selenious acid was not complete. On stirring the solution, the local blue color fades and another 5-ml. portion of thiosulfate is added. When addition of potassium iodide fails to produce a local blue color, reduction of selenious acid is complete, and the excess thiosulfate is then back-titrated with standard Iodine solution. The number of equivalents involved in the reduction of selenious acid by either thiosulfate or iodide is the same, and therefore no correction need be made for the potassium iodide. This procedure is much better than the original Norris-Fay titration, but acidity and time would stilt be rather critical factors subject to variation with individual technique. Also, the method still requires the lose of two standard solutions, a rather undesirable factor from the standpoint of routine application.]

Jan 1, 1954

By Thomas J. Blalock

The volumetric determination of uranium according to the method of Sill and Peterson (6),3/ which uses cerate oxidimetry after the separation of interferences such as sulfides and cupferrates, has been used for some time by the Bureau of Mines and gives satisfactory results for many of the samples tested. However, in those instances where the uranium content did not exceed a few tenths of 1 percent and iron was present in the range of 10 to 40 percent (as Fe203),4/ the method was cumbersome and unreliable. The need for a more accurate procedure for the determination of small amounts of uranium in the presence of large amounts of iron, such as in shale or black sands, prompted this investigation. The Bureau desired that materials containing as little as 60 p.p.m. of uranium be assayed within reasonable limits of accuracy. One of the primary aims of this work has been to eliminate, as far as possible, the necessity for repeated cup ferron extractions.

Jan 1, 1960

By T. T. Campbell

Although secondary recovery of lead and lead-tin alloys has been common practice in the United States during recent years, there is little published in-formation concerning recovery techniques. Available information does not cover metal recovery from wet dross skimmings. This investigation by the Bureau of Mines was undertaken to develop techniques that would allow lead-tin alloys to be recovered from wet dross skimmings containing large amounts of zinc chloride. A process was developed, on a laboratory scale, for recovering lead-tin alloys from wet solder dross skimmings. Straight water leaching, either with or without a second leaching operation carried out with a Na2C03 addition for removing chloride, produced a dross that could be smelted without further treatment. Overall recoveries averaging 92 percent of the metal values in the dross were obtained in the form of lead-tin alloys, which had an average tin content of 16 percent and lead content of 84 percent. The recovered alloy contained less than 0.02 percent zinc, as determined by both chemical and spectrographic analyses.

Jan 1, 1956

By Paul T. Allsman

This paper describes metal- mining practices at the Harrington -Hickory lead - silver - zinc mine at Milford , Beaver County , Utah . The operations of the Harrington-Hickory incorporate a number of features that should prove of interest and value to other operators of small mines . These features include employee participation in profits , a well- laid -out electrical system, adequate financing , a well - balanced equipment and supply inventory , a well - organized system of bookkeeping , adequate roads , and good management . As crude ore is shipped directly to smelters and mills in the Salt Lake Valley , close attention is paid to see that the ore is segregated by classes and treated where it can bring the greatest not return . A combination of these features has resulted in maintaining relatively low costs, considering the grade and size of ore shoots at a time , during and following the war , when equipment , supplies , and labor were costly and difficult to obtain . The period covered in this report includes two war years and two years following , from April 1, 1944 to June 30 , 1947 .

Apr 1, 1949

By J. W. Eckerd, W. S. Sanner, P. L. Woolf, R. E. McKeever

The Bureau of Mines experimental blast furnace was operated successfully with anthracite metallurgical briquets . Tuyère pressures were higher and more erratic than for operations using coke , and furnace " hangs " occurred more frequently . Higher hot - blast temperatures were required to maintain the quality of the metal . By using higher hot blast temperatures , the fuel and production rates and slag volumes were comparable to those obtained for all - coke operation . The anthracite metallurgical briquets exhibited excellent mechanical strength and descended through the shaft of the furnace with little breakage or reduction in size .

Jan 1, 1964

By H. Kenworthy

A zinc-pyrite ore from the Gray deposit in Jo Daviess County, Ill., was successfully concentrated on a laboratory scale. Initially, drill cuttings were submitted for separation of zinc and iron concentrates. Subsequent to mine development, a large sample of coarse ore was submitted to ascertain its amenability to sink-float treatment to produce a low-grade zinc-iron concentrate and discard a clean tailing. The samples of ore were submitted to the Rolla Metallurgical Branch by the Mining Division of the Federal-Bureau-of Mines. They were obtained during the recent war as a part of the extensive government program to increase metal production through exploration for new mineral deposits and investigation of old mineralized areas. The first sample consisted of about 3,000 pounds of drill cuttings collected, during the Bureau?s churn and diamond- drilling program. The second sample was taken at a later date, after Tri-State Zinc, Inc., had opened the deposit and commenced milling the ore. This sample consisted of a ?ton-of mill feed crushed through 2 inches and collected over a period of 3 days.

Jan 1, 1949

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By Constantine C. Popoff

During 1946 several limestone deposits near Fortson, Snohomish County, Wash., were examined by the Bureau of Mines. These examinations were part of a long-range investigative program of regional mineral supplies required by the anticipated industrial development of the Pacific Northwest. The .study outlined in the following paper was specifically undertaken to disclose new sources of high-purity limestone and to appraise, their economic aspects. The deposits examined -namely the Galbraith, Climax, and Hi, Hi -are somewhat similar in physical features and geologic environment. They are lenticular and belong to the same formation of metamorphosed sediments that underlies the prominent Whitehorse Ridge.

Jan 1, 1949

By G. H. Cobb, J. L. Johnson, H. H. Heady

An infrared absorbance technique is described for analyzing anodic gases produced during the electrowinning of uranium , thorium , and rare - earth metals in molten fluorides . Typical components determined qualitatively in a gas sample are CO , CO₂ , CF4 , C₂ Fe , C3F8 , COS , CS₂ , and SiF4 . About 20 minutes are required to record and interpret the spectrogram , and report quantitative results for CO, CO₂ , CF4 , and SiF . The procedure is used for control during electrolysis .

Jan 1, 1964

By Webster S. Anderson

The design, development, and testing of hydraulic props to provide a lightweight, high strength, recoverable unit is described. Modifications in design incorporating threaded components resulted in the development of a lightweight hydraulic prop fabricated from aluminum alloy tubing. This new design facilitates interchange and replacement of component parts, and the physical properties of the material are not changed as they are when welding is required. The new prop is 65,000 pounds and has a maximum load capacity of a lower weight-to-load capacity ratio than the hydraulic props now available.

Jan 1, 1967

By James A. Whelan

The Bureau of Mines sponsored research studies of variables in rotary drilling, done in the Department of Mineral Engineering, University of Minnesota. By studying carefully controlled drilling with good instrumentation, it was hoped to obtain a better understanding of rock failure during drilling and of the stresses in drill bits during drilling. Experimental procedures and equipment are described. From these studies it was concluded that 1. Thrust requirements, other things being equal, are proportional to the total length of cutting edge in the bit. 2. Data from penetrating a wedge into rock under thrust only are not directly applicable to rotary drilling. 3, In rotary drilling the initial wear on a bit greatly decreases penetration rate under any given set of conditions; however, after initial wear the effect of wear on penetration rate is reduced. 4. An increase in rotary speed increases the overall penetration rate but decreases the penetration per revolution. 5. An increase in thrust increases the overall penetration rate and the penetration per revolution. 6, Torque on a drill bit is proportional to both penetration rate and bit diameter. 7. For small-diameter holes full-hole drilling will save both drilling time and energy compared with pilot drilling followed by reaming; for large-diameter holes pilot drilling-reaming is advantageous in both respects,

Jan 1, 1962

By Jeffrey H. Welsh

This report presents a study on the use of computerized, continuous remote monitoring systems for fire and explosive atmosphere safety in underground coal mines. The effects of these systems on the safety level in mines are investigated, and the relationship between mine safety regulations and computerized, continuous, remote monitoring is analyzed.

Jan 1, 1982

By H. G. Iverson

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and sampled three properties in the vicinity of Winnemucca, Nev. As the ores were too low grade for direct production of ferromanganese, they were tested for their amenability to concentration by ore-dressing methods. Two samples of ore were procured by examining engineers of the Bureau of Mines from several outcrops in the Pollard Canyon area, Pershing County, about 30 miles southeast of Winnemucca. The manganese occurs in relatively small lenticular bodies as secondary replacement deposits in chert and quartzite. The first sample represented average run -of -mine ore as exposed in the Pollard Canyon deposits. Sample 2 was composed of hand-sorted, high-grade ore.

Jan 1, 1954

By E. C. Perkins

Preliminary experiments are reported utilizing bacteria to leach manganese from a variety of domestic low grade manganiferous materials. In two large leaches manganese extraction ranged from 71.7 to 92.5 percent, and the products analyzed over 48 percent manganese. Nutrient requirements and leaching time experiments were made. The mechanism of leaching is not understood, but is different than the mechanism encountered in the microorganism accelerated leaching of copper in the presence of sulfide minerals.

Jan 1, 1962

By Thomas C. Atchison

The experimental work described in this report is part of a continuing study by the Federal Bureau of Mines of the fundamental physical processes involved in breaking rock with explosives. Six explosives were tested for their strain-producing abilities in a dolomitic marble. The explosives selected for testing had a tenfold variation in detonation pressure and a fivefold variation in characteristic impedance (product of loading density and rate of detonation). Strain pulses produced by the detonation of small charges of the explosives were recorded at distances of 5 to 130 feet. Peak strain, ?, was found to decrease with distance, R, in accordance with an exponential propagation law previously determined for other rock types, namely ? = (K/R)e ?aR The absorption constant, a, did not vary significantly with the explosive and was of the same order of magnitude as that for other rock types. The different explosives produced a fivefold variation in the value of the intercept constant, K.

Jan 1, 1961

By R. V. Ramani, R. Bhaskar

"The National Academy of Sciences (1) recognized the importance of studying the spatial and temporal characteristics of respirable coal mine dust atmospheres. In this paper, the progress to date of a research project on dust transportation and deposition in mine airways is presented. A mathematical model is proposed for studying the transport of dust. A source representative of dust generation in underground coal mining is defined. The influence and applicability of surface roughness, dispersivities, coagulation and reentrainment to vine dust flow arc examined. A convective-diffusion model is proposed for the transport and deposition of dust in mine airways. Using the model, the spatial and temporal characteristics can be evaluated in terms of dust concentrations in the mine atmospheres.INTRODUCTIONThe prediction of the behavior of fine particles Is Important in many fields of science and engi¬neering including physics, chemistry, mining, mineral processing, and atmospheric science. In mining from the health point of view, fine coal dust is associated with the appearance of pneumoconiosis in miners exposed to the dust. Also, in addition to being a nuisance factor obscuring visibility and general mobility of miners, it can lead to sudden catastrophic incidences of explosions. This paper outlines the progress to date of a research project on dust transportation and deposition in mine airways. A mathematical model is proposed for studying the transport of dust for the various mechanisms. The dust dispersion is defined in terms of a dispersion term determined from experimental data by Skubunov (23). Coagulation is considered as one of the mechanisms that can lead to changes in the particle size distribution. Reentrainment as a possible secondary source of dust was examined during model development but was not included in the final model."

Jan 1, 1988

By J. W. Town

As part of the Federal Bureau of Mines titanium resources examination program, samples from seven deposits in the Pacific Northwest were tested for amenability to various beneficiation techniques. The samples obtained by the Bureau's Office of Mineral Resources at Spokane, Washington represent a large potential source of titanium. This report summarizes the results of tests at the Bureau's Metallurgy Research Center, Albany, Oregon. Recoveries from tabling placer samples were about 50 percent at grades of 30 percent titanium dioxide. Flotation was the most effective method for concentrating the fine ilmenite in clay samples; recoveries of approximately 50 30 percent titanium dioxide. Flotation was the most effective method for concentrating the fine ilmenite in clay samples; recoveries of approximately 50

Jan 1, 1961

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining and crushing methods and costs at various operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might, in many instances, cause embarrassment to the individual operator as well as to the industry as a whole. On the other hand, operating costs are essential to a technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations may ensue. The author wishes to acknowledge the assistance of the following persons: L. W. Camp, general manager; S. Cooper, plant superintendent; and W. R. Riel, office manager.

Jan 1, 1936

By L. L. Oden

The purpose of this research was to develop a method to remove copper and tin from the magnetic fraction of incinerated municipal refuse, as recovered by the Bureau of Mines pilot plant in College Park, Md. Copper, present in the scrap in a metallic form bonded to ferrous objects, was amenable to leaching in cupric ammonium carbonate solution. Copper levels in small 5-to 10-lb lots of treated scrap were reduced from the initial level, 0.5 to 0.6 pct, to 0.1 to 0.2 pct. Larger lots of scrap (100 lb) were treated less effectively because of poor contact of solution and scrap. Oxidation in the air or in aerated aqueous solution was applied to liberate tin from the dilute solid solution present on the surface of incinerated tinplate. Shredding of air-oxidized scrap or caustic leaching of scrap oxidized in solution reduced tin levels from the initial 0.25-pct level to about 0.1 pct.

Jan 1, 1973