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By S. C. Rhoads

The Bureau of Mines is investigating low-chromium alloy substitutes for type 304 stainless steel (type 304 SS). The purpose of the research is to reduce the chromium content in austenitic stainless steels used for corrosion-resistant applications. Nine Fe-9Cr-12Ni alloys containing additions of 0 to 5 pct Mo, 0 to 2 pct V, and 0 to 2 pct Cu were selected for evaluation. All of the experimental alloys containing 5 pct Mo and an alloy containing 2Mo-2V-2Cu possessed structure and tensile strengths similar to those of type 304 SSe Alloys containing SMo-2V and SMo-2V-2Cu had ac-ceptable welding properties as measured by the Varestraint test. Alloys containing at least 2 pct Mo had cQrrosion resistance comparable to that of type 304 SS in solutions of nitric acid, phosphoric acid, acetic acid, and citric acid. In chlorides, all the experimental alloys were susceptible to localized corrosion and stress corrosion cracking similar to that of type 304 SSe The corrosion properties were established by weight-loss tests, electrochemical polarization tests, and stress-corrosion cracking tests. An Fe-9Cr-12Ni-SMo-2V alloy and an Fe-9Cr-12Ni-SMo-2V-2Cu alloy had a combination of welding properties, tensile properties, and corrosion resistances that were most comparable to those of 304 SS.

Jan 1, 1984

By H. N. Dunning

A comprehensive research program designed to aid development of new and improved methods for more complete production of petroleum from partly depleted reservoirs is being conducted at the Bureau of Mines Petroleum Experiment Station, Bartlesville, Okla. Water flooding has accounted for much of the petroleum produced by secondary-recovery methods; however, a considerable portion of the crude oil commonly remains in place after water flooding has been terminated. In recent years the possibility of increasing the efficiency of water flooding by using surface-active additives has received wide attention. In general, the results of laboratory research have shown that use of detergents as water-flooding additives will reduce the residual petroleum in porous media (1).3/ Some less extensive field tests have supported this conclusion but have not been entirely conclusive (2). Later studies (3, 4) have given conflicting evidence as to the relative worth of detergent additives for water floods in water-wet (hydrophilic) or oil-wet (hydrophobic or lipophilic) reservoir materials. The results of these studies emphasize the need for a more complete understanding of the fundamental principles involved in displacing petroleum from reservoir surfaces by injected fluids. Accordingly, a comprehensive research program was initiated to investigate the practical and fundamental aspects of detergency in petroleum production.

Jan 1, 1953

By Ernest L. Corp

Seepage forces computed by a finite-element flow program are combined with gravity forces in an elastic-plastic stress-analysis program to determine the stability of mine-waste slopes. Computer output provides a cross-sectional plot of the dam or embankment showing the safety factors for each element. The combined finite-element program called SEEP-SLOPE was used to analyze several trial embankments and the 1972 Buffalo Creek Dam failure Safety factors computed by the finite-element method (FEM) were compared with those computed by Bishop limiting-equilibrium method. For individual slip circles, there was little correlation between the factors of safety computed by the two methods. Both predict failure, but FEM shows a different mode of failure plus development of potential failure zones not indicated by conventional methods. Besides having a better theoretical basis than the Bishop method, FEM requires no assumptions regarding the location or geometry of the failure surface. As a result, the program will show progressive development of a failure zone, and areas can be pinpointed where remedial measures should be taken. In addition, nonhomogeneous cross sections can be analyzed, and zones of potential piping can be defined.

Jan 1, 1975

By W. W. Adams

"The present world-wide demand for increased production in all branches of essential industry involves a matter of vital concern t persons engaged in the mining industry, namely, the productive capacity of the individual mine employee. This applies particularly to coal-mining, upon which other industries so largely depend.The folded and faulted condition of the coal beds in some countries, as well as the thinness and depth of the seams, the adaptability to the beds of available mining machines and equipment are factors which cannot be overlooked in determining what increase in individual output may be looked for in any given country. This subject, while of fundamental importance, can only be referred to in a paper of this length, the primary object here being merely to present a comparative tatamant of individual output under prevailing conditions.The quantity of coal produced by a miner does not accurately indicate the miner's capacity as a workman, not only because of the natural conditions referred to above that limit his annual output, but also because of human factors which may possibly, however, be controlled, such as the demand for coal, the car supply, use of labor-saving machinery, number of days worked during the year, accidents in the mine, etc. It will, however, be an aid in answering the important question as to how and where the immediate need for coal throughout the world may best be surlier, if we examine the output of the miners in the important coal-producing countries over a period of years.Complete official information for recent years is, for several countries, jacking, particularly for France, Austria, and Prussia, but partial data from unofficial sources may be used to show the individual output of the miners in these countries."

Jul 1, 1920

By William Cochran

The mineral waste disposal system at the Grace Mine, Morgantown, Pa., was designed to minimize environmental effects while allowing much of the waste from the iron mine, mill, and concentrator to be utilized. Standard cost estimating procedures were used by the Bureau of Mines to determine waste disposal costs. Mill tailings and rock waste disposal costs were estimated at $0.151 and $0.276 per ton, respectively, for the 1965-67 production period. Total waste disposal cost was reduced about $0.015 per ton by utilizing part of the waste as aggregate. The net average cost for disposal of all mineral waste was $0.189 per ton.

Jan 1, 1969

In this U.S. Bureau of Mines report, two drill-split mechanical excavation mining system concepts are described, casted, and cost compared with conventional drill-blast mining systems. The concepts for the two drill-split mechanical excavation mining systems presented are (1) a method for steeply dipping narrow veins 0.6 to 1.2 m wide and (2) a longwall method for fiat-lying tabular ores. In the proposed systems, 70 to 80 pet of the ore is disposed of underground as backfill. For sortable ores, face area crushing, sorting, and direct stowage of run-of-mine waste and low-grade ores are proposed. The underground sorting and stowing of waste reduce materials handling, processing, and waste disposal costs by reducing the quality of ore transported to the surface by 70 to 80 pet (by volume). Because many of the tools and techniques proposed for use in these systems have little or no historical mining industry use, cost assignations are heavily influenced by engineering judgments and presented as prefeasibility-level cost estimates. These estimates, presented as discounted-cash-flow-rate-of-return (DCFROR) values, show the proposed systems to be at least as profitable as, and in some cases 50 pet more profitable than, conventional drill-blast mining.

Jan 1, 1994

By Mackenzie Burnett

Quick-Fix Blowout Stoppings were evaluated in several underground mines as an alternative to conventional ventilation control bulkheads. Blowout stoppings offer considerable savings in bulkhead construction and repair costs if the 0.1 inch H20 of differential pressure required to inflate them is available. The Quick-Fix Blowout Stoppings were utilized successfully in uranium mines in the Southwestern United States where savings in bulkhead construction and repairs to blast damaged bulkheads are estimated to equal $9,500 over the projected 2 year average life of a blowout stopping. Two types of material were evaluated. Five methods of anchoring the stoppings to drift walls were evaluated. Three methods of anchor attachment to the stopping material were evaluated. Blast pressure measurements were made in conjunction with the evaluation of the blowout stoppings.

Jan 1, 1978

By G. W. Weems

The specific objective of this investigation was to determine the compressibility factors for helium and carbon dioxide mixtures at -10° and -20° C and pressures to 1,000 psia. A Burnett apparatus was used. Data from the experiments were treated by the method of Barieau and Dalton. Tables of compressibility factors and approximations of the virial coefficients are presented for 10 binary mixtures as well as for helium and carbon dioxide. The results follow the same trend as data previously reported.

Jan 1, 1970

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By Gus Pantages, Bernard D. Blaustein, Charles Zahn, Irving Wender

Oils from coal hydrogenation have been examined at the Bureau of Mines to learn whether any centers of the optical activity reported in coal would survive catalytic hydrogenation at 450-525 ° C and about 8,000 psig pressure , and , if so , to obtain information about the nature of the active products . Oils from carbonization tars also were examined . Optical activity was found in the majority of the distillate fractions of the hydrogenation oils and in almost all distillates from the carbonization tars . No activity was observed in the tar - acid and tar - base fractions examined . Methods for isolating optically active concentrates included distillation through a packed column , liquid chromatography on silica gel , and adduction with urea . For the materials so processed , the optical activity segregated mainly in the paraffin - naphthenic and the hydroaromatic fractions . Although the specific compounds responsible for the optical activity were not isolated , experimental and spectrometric findings indicate that alkylsubstituted cycloalkane , cycloalkene , and hydroaromatic structures are most likely responsible for the optical activity of the concentrates . The optically active centers probably derived mainly from the steroids and terpenes in the biological materials that participated in the formation of coal .

Jan 1, 1964

By J. Hamilton Duffy

This is the first of, a series of papers describing dredging methods and costs in recovering sand and gravel from the beds of rivers throughout the United States and deals directly with the methods employed and costs obtained by the Ohio River Sand Co. near Louisville, Ky. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of J. R. Thoenen, mining engineer of the Bureau of Mines, in the collection of data and compilation of this report.

Jan 1, 1931

By R. Vernon Helm

Four tables listing values for the various physical properties of those sulfur compounds most likely to occur in petroleum and petroleum products are given herein. The data necessary to bring the first compilation2/ in this subject up to date are given in table I -Revised and Additional Data, which includes boiling points, refractive indices, densities, and freezing points. Tables 11-, III, and IV are published for the first time and include refractive indices for the F, C, and G' lines of hydrogen and the helium D:3 line; surface tensions and viscosities, and refractivity intercepts, specific dispersions, specific refractions, and parachors. The need for information concerning the sulfur compounds in petroleum is becoming-more urgent because of the necessity of refining larger quantities of high-sulfur crude oil to meet the rising demand for petroleum products. For a number of years the Bureau of Mines has been engaged in research to make available more information concerning the properties of the sulfur compounds in petroleum. The petroleum industry has recognized the value of such studies, and as a result the American Petroleum Institute has established Research Project 48A to study sulfur compounds. The investigations under this Project are to be done in Bureau of Mines laboratories as a cooperative project in connection with the work already started.

Jan 1, 1949

By Lewis M. McNay

Description of methods employed and cost data are given for surface-mined land reclamation in Moraine State Park, Butler County, Pa. This project was conducted under the authority of the Appalachian Regional Development Act; a total of 177 acres of land was rehabilitated for specific land use purposes. The use of large equipment expedited the project work, and similar results could be anticipated on similar reclamation programs.

Jan 1, 1970

By Ludwig Schmidt

The economic value of reducing the evaporation losses of crude oil and of gasoline is so well founded that the petroleum industry is constantly seeking new and improved storage tanks and methods of handling its products to further reduce these losses. A comparison of the methods and apparatus used in handling and storing crude oil and its products today with those in general use 10 years ago would show that an oil tank is no longer simply a container for holding liquid, but is now considered an important piece of equipment which if, subjected to constant inspection and care. In fact, the modern vapor-tight tank often requires as much care as a boiler or pump when one considers Its various component parts such as vapor-tight gage hatches and thief-hole covers, vacuum and pressure relief valves, swing line apparatus, vapor-recovery systems, insulation, cooling devices, and often automatic gaging devices. As an auxiliary to the physical equipment of the tank itself the subject of paints and paint colors is now given considerable attention. In addition to vapor-tight tanks and auxiliary equipment, other types of tanks for reducing, evaporation which are new to the industry have also been developed and placed on the market within the past few years. The development of the floating roof type was an innovation in tank construction, directed toward the reducing of evaporation losses. This type of roof rides on the surface of the oil and thus eliminates all vapor space. It is especially valuable for working tanks.3 A recent development in tank construction is a new type of tank roof known as the diaphragm or "breather roof," Which practically eliminates the movement of air-vapor mixture from a storage tank filled with oil. It is of especial value for use on tanks in which oil is stored over long periods.

Jan 1, 1930

By Alvin Kaufman

Increased exploration in Alaska has resulted in many requests to the Bureau of Mines for facts about the mineral resources and mining conditions in the Territory. This report presents information about the minerals of Southeastern Alaska and the factors that affect development of a mining industry in that area. Southeastern Alaska is a narrow coastal strip of rugged mountains and many islands. The climate is mild, with an average annual temperature of 40° and heavy rainfall. Geologically, the region is favorable for deposition of ore; geographic-ally, it is difficult to prospect and to develop, except along areas immediately adjacent to the coastline.

Jan 1, 1958

By R. A. Busch, R. R. Backer, R. W. McKibbin

The Bureau of Mines conducted laboratory tests to determine the slur- ry transport and deposition properties of coal waste. A 188.5-ft pipe test loop was constructed with instruments to measure density, flow, and power and discharge, suction, and differential pressures. A 20-ton sample of Western coal waste was crushed and screened to 100 pct minus 1/2 in. Eight loop tests using this graded waste were run at slurry densities ranging from 1.15 (25 wt-pct solids) to 1.46 (60 wt-pct sol- ids). The resultant friction-pressure gradients ranged from 0.06 to 0.24 ft of water per foot of 4-in standard steel pipe. Particle-size degradation was significant. In a typical loop test lasting 25 min, the minus 200-mesh fraction increased from 19 pct to 34 pct. Deposi- tion tests showed that without the use of a flocculant, the slurries would not dewater when left to stand for 1 week. With flocculant, ad- ditional water was released; however, the settled slurries remained thixotropic. Further testing is necessary to determine their suitabil- ity for use as backfill material in active mines.

Jan 1, 1965

By Jr. Frank Parrish

This report describes the performance of 17 selected water-injection projects producing from Pennsylvanian-and Permian-age reservoirs. Illustrations depict reservoir structure and thickness, and production and injection history. A selected bibliography of publications pertaining to area oil recovery and geology is included. Tabulations of field and reservoir data reveal marked differences in the projects. Increased oil recovery resulted from injecting water in most cases; however, seven projects recovered less oil than the operators anticipated. Oil recovery by water injection ranged from 0.2 to 262 bbl per acre ft, or 0.1 to 22.5 pct of the initial stock-tank oil in place. Major reasons suggested for poor performance include: (1) Adverse directional horizontal permeability, (2) channeling of injected water through fractures or zones of high permeability, and (3) lack of containment of injected water. One 330-foot-deep project is among the first successful shallow water-floods in north Texas. Another project is the first successful Canyon sand-stone waterflood reported in the area. Previous gas injection in two Cisco sandstone projects did not prevent the reservoirs from responding favorably to waterflooding.

Jan 1, 1965

By G. L. Humphrey

Although thermodynamic data for ferrous oxide are among the most important in extractive metallurgy, adequate values have not been available until quite recently. The older data suffered not only from the usual experimental difficulties but especially from lack of the knowledge that ferrous oxide of stoichiometrical composition does not exist as a single, thermodynamically stable crystalline phase under any circumstances. This paper reports new experimental data on the heat of formation of ferrous oxide by two methods (combustion calorimetry and solution calorimetry), employing material of unequivocal composition. The results are compared with values obtained from data for the hydrogen reduction, carbon monoxide reduction, and disproportionation reactions of ferrous oxide, and a best value is selected. A table of heat and free energy of formation values of ferrous oxide to 2,000°K is given. These values are combined with available data for water, carbon monoxide, and carbon dioxide to obtain theoretical heats and free energies of reduction corresponding to the selected heat of formation. Hydrogen and carbon monoxide reduction equilibria are compared, and the differences in trend with temperature and the percentage utilization of the reductants are considered.

Jan 1, 1952

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute, and the Bureau of Mines of the United States Department of the Interior. This paper is a continuation of a series made in cooperation with the Coordinating Fuel Research (CFR) Committee of the Coordinating Research Council (CRC), Inc. The first of this series of reports presented data on motor gasolines sold during the winter of 1935-36, and succeeding reports described motor gasolines sold during the summers and winters to and including the summer of 1941. No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942. However, starting with the winter of 1942-43, the semiannual reports were resumed

Jan 1, 1948

By D. E. Shanks

This U.S. Bureau of Mines (USBM) research simplified an earlier hydrogen chloride (HCI) leach-sparge process developed by the USBM to recover reduction-grade alumina from domestic kaolin clay. Improvements were made by decreasing the initial leaching acid concentration from 25 to 20 pet, decreasing the leaching time from 1 to 2 h to 15 to 30 min, eliminating the solvent extraction step for Fe removal, and eliminating the step to recover the AI content of the bleedstream circuit. A 10-cycle bench-scale experiment of the simplified process showed that the ferric chloride (FeC13) concentration built up to 9.3 g/L in the recycle stream. This did not interfere with any of the unit operations or final alumina product purity because Fe forms stable soluble chloride complexes when sparged with HCI and is easily washed from the large aluminum chloride hexahydrate (ACH) crystals. The reduced leaching time and acid concentration did not decrease Al extraction.

Jan 1, 2010