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By C. Lurie

This final report describes the work performed by Gulton Battery Corporation under USBM Contract No. HO-112033, entitled "Research and Development on Lithium-Nickel Fluoride Batteries For Mint Life Support Equipment". The lithium-nickel fluoride couple was chosen For this investigation because of its high theoretical energy density (626 Wh/lb), its ability to operate at ambient temperatures and the fact that it showed promise as a secondary system. The theoretical energy density of the lithium-nickel fluoride couple is ten times greater than that of the widely used lead-acid battery and three times greater than the silver-zinc battery which has the highest theoretical energy density of the commercially available secondary systems. The experimental program first evaluated the cell components individually. The results of these studies then formed the basis for investigations of cell performance using experimental three-plate cells. These cells consisted of one nickel-fluoride and two lithium electrodes. All work was performed in a glove box under an argon atmosphere which was sufficiently pure to maintain the shiny appearance on freshly prepared lithium surfaces. The major portion of the work effort was concerned with the nickel fluoride electrode. Binder, conductive diluent, fabrication technique, as well as the nickel fluoride active material itself, were considered. Criteria for binder materials were established and six classes of materials encompassing thirteen binders were evaluated. The candidate materials were initially screened for appropriate chemical and physical properties and finally evaluated in three.-plate cells, Two epoxy powders emerged as the most promising binders. Two types of conductive diluent were evaluated. The first is a carbon black of low bulk density and high surface area. This material is a good conductive diluent; however, electrodes fabricated with it lacked good mechanical strength. It was hypothesized that a uni¬form, small particle size, low specific surface area would improve the mechanical properties of the electrodes. Therefore, two samples of graphicic materials, milled to uniform powders in the one-to-ten micron range were evaluated. Electrodes prepared with the graphitic materials had superior mechanical properties, However, their electrical performance was significantly poorer and voltage losses of 0.2 to 0.3 volts were observed. Several electrolyte solutions were evaluated. N-Methyl-2-Pyrrolidone was tested but found to be incompatible in the presence of lithium. Lithium perchlorate, lithium hexafluoroarsenate, and lithium bromide were tested as two-component electrolytes in propylene carbonate solvent and their performance compared with that of the single electrolyte solutions, Lithium perchlorate gave the best performance. Lithium hexafluoroarsenate was also evaluated in methyl formate and appears to give equivalent performance. The lithium perchlorate-propylene carbonate system is preferred as it is easier to handle and less expensive.

Jan 1, 1973

By Lloyd L. Farnham

This paper is one of a series describing the mineral resources of the Nation, including location, history, production, ownership, geologic setting, and mining methods for most of the known manganese deposits in New Mexico, With few exceptions these descriptions are the result of field examinations by the writer. Of 32 counties, the 12 which occupy the western half of the State contain all the known manganese deposits, These counties are Catron, Dona Ana, Grant, Hidalgo, Luna, Rio Arriba, Sandoval, Santa Fe, Sierra, Socorro, San Juan, and Taos. (See fig. 1.)

Jan 1, 1961

By Sidney Katell

This report, covering the period January 1968 through December 1968, is a continuation of a series that began with the publication of Information Circular 7516 in October 1949. It is the tenth in a series of reports prepared in cooperation with the American Association of Cost Engineers. The abstracted articles are concerned with all phases of cost of engineering in the field of chemical and petroleum plants and related subjects. They are from the following sources: 1. American Association of Cost Engineers Bulletin. 2. Bureau of Lines Information Circulars. 3. Bureau of Mines Reports of Investigations. 4. Chemical Engineering. 5. Chemical Engineering Progress s 6. Chemical Week. 7. Coal Age. 8. Coal Mining and Processing. 9. Cost Engineering. 10. European Chemical News. 3 11. Hydrocarbon Processing. 12. Industrial and Engineering Chemistry 13. Oil and Gas Journal. 14. Petroleum Engineer. 15. World Oil.

Jan 1, 1969

By Irvin G. Burough

Andros Analyzers Incorporated has designed and built two prototype continuous methane monitors capable of being mounted on a mining machine'. These instruments were designed for in-mine safety use. The monitors incorporated an NDIR optical/electronic analyzer design in which the response to the sample gas (methane in air) was achieved by synchronous detection and measurement of the amplitude oscillations of the trasmitted energy from an infrared source caused by the pressure modulation of the sample gas within the optical cell. Zero and span stability were to be achieved by the amplitude modulating of the infra-red source and using detected signal to correct for optical/electronic system variation. This design effort was to simplify and reduce the cost of the major components while eliminating the need for daily calibration. This report is the final report on this effort.

Jan 1, 1981

By E. A. Magill

This report is one of a series prepared by the Bureau of Mines on manganese deposits of the Northwestern States. It describes properties on the Olympic Peninsula, Wash. Exploration by the Federal Bureau of Mines in 1939-40 and 1954-55 on several typical deposits is summarized, and examination data are presented for other manganese deposits on the peninsula. An attempt was made to list all known occurrences; however, some properties are abandoned, and their exact location is unknown.

Jan 1, 1960

By L. D. Schmidt

Now that the war is over, there is a great revival in popular demand to decrease pollution of the atmosphere in our cities. Great cities, such as Pittsburgh, are starting to enforce laws against violators of smoke ordinances. The substitution of low-temperature coke for bituminous coal in household heating is a most promising field for helping to eliminate the smoke nuisance. This Information Circular is written to assist in the very worth-while effort to reduce atmospheric pollution. Herein are de- scribed recent German developments in the production of low-temperature coke. Operating and cost data are given on German commercial-scale low- temperature carbonization plants.

Feb 1, 1947

As a result of early experiments in underground mine illumination, the Bureau of Hines recognized the need for additional experience with the underground lighting of coal mines having low seam thicknesses. There was already experience with tile illumination of coal mines having higher coal seams, and this contract with Ocean Energy Inc. (OEI) was undertaken to contribute to the "low coal" experience. For the purpose of this contract, a "low coal? mine is defined as one having less than 45 inches of overall headroom in the working places. As a practical limit, 26 inches was the minimum coal seam thickness to be encountered in this program. In one instance, the maximum coal seam thickness was eight to ten feet, however, this particular work was at the direction of the Technical Project Officer (TPO) by virtue of the unique type of lighting arrangement that was to be evaluated which would be useful for low coal. At the outset of the contract, three major tasks were established. The first two tasks involved the installation of permissible fluorescent lighting equipment at two low coal mines. The intention was to illuminate mining sections in each case consisting of one or more machines. The third task was to illuminate a variety or mining equipment including a longwall. For the purpose of this report, the fol-owing identifies the particular installations associated with each task.

Jan 1, 1976

By V. H. Gottschalk, John Grodd, R. S. Dean

"Elemantary ConsiderationsAlthough magnetiem was first discovered in and derives its name from an oxide of iron found in magnesia and called lodestone its pracical uses date from the discoveries of Faraday concerning its relation to the electric current. We may therefore start our discussion of magnetic properties with Faraday's law for relation between induced electromotive force and the change in a magnetic where e is the electromotive force induced in an electric circuit by a unit rate of change of magnetic flux N, H is the intensity of the magnetic field, S is the area enclosed by the circuit, and i an angle between H and the normal to dS. In the simplest case we could use this law to measure the strength of a magnetic field by passing it at a measured rate through a coil of copper wire and determining the,electromotive force. As a matter of practical convenience, it will be simpler to nee the total quantity of electricity produced by a change of magnetic field. For this purpose we may let i denote the strength of the electric current induced by the change of magnetic field in time in a circuit of area a and resistance R. Then the total electric quantity. Q is given. by"

Mar 1, 1934

By Richard L. Ash

Introduction The blasting capabilities of commercial explosives are often rated according to their loading densities and detonation velocities. Both the density and velocity are relatively easily measured, the values of which can be used for determining the approximate detonation pressure developed by an explosive during any given set of blasting conditions (1-5). Knowledge of the actual rate of detonation attained at all points along a charger's length also is considered to give a good indication of how well the explosive is functioning. Many factors affect the density and velocity and have been thoroughly discussed by various authors (4, 6-12). For recording velocities several methods are available, but the resistance-wire, or probe, continuously recording technique has the distinct advantage of providing a record of the complete progress of an explosive reaction from the time it first initiates. Figure 1 is a copy of a typical record obtained by the procedure with certain significant information indicated. The theory and applications of the method are extensively covered in the literature so need not be reviewed for this report (13-18). Only the specific equipment and procedure employed for this investigation are presented.

Jan 1, 1973

By James L. Hendrix

The applicability of a rotating drum with an attached trommel as a flocculation dewatering device of Florida phosphatic claywastes was studied. Several experiments were conducted in order to determine the important fabrication and operating parameters. Results from the experiments indicated flint the dosage of polyethylene oxide required to form a satisfactory product cake could be reduced by using the rotary drum, which introduces less shear stress into the fluid than a constant stirred tank mixer. It was found that the length of the mixer was the most important parameter. Increased length increased the retention time the flocs stayed in the mixer without dewatering. Such increased time decreased the stability of the flocs. Through analysis of residence time distribution data it was found that the longer mixers approached plug flow characteristics. Other important parameters were trommel length and rotational speed. Mixers from 10 cm diameter to 35.6 cm diameter were tested with good results.

Jan 1, 1982

By Wils L. Cooley

The report covers tests and criteria for the establishment of safe grounding systems for coal mines. The work deals primarily with under-ground coal mines, but much is applicable to surface mines as well. Included is an extensive guide to grounding and bonding procedures for mine surface substations. Xit-Rods are evaluated and shown to deviate from manufacturer's claims. An analysis shows that very long cables are difficult to monitor using audio frequency ground-check techniques. A method is developed to detect failing cable splices without removing the cable from service. Simulation and measurement are compared for a technique to detect bad rail bonds, and an assessment is made of grounding techniques for dc face equipment.

Jan 1, 1979

By A. C. Fieldner

Much activity is called for in the present period of hightened national effort, and wise direction of such a program must always be conditioned by positive knowledge gained in years of slow and painstaking study and development. Research and technologic investigations on coal by the Bureau of Mines have been described in a series of annual

Jan 1, 1941

In attempting the predict coal cleat orientation in the subsurface for effective methane degasification of the coal beds in the Warrior coal field of Alabama, approximately 150 rock joint orientations and 45 coal cleat orientations were measured in each of 37 7 ½ minute quadrangles in Tuscaloosa, Walker, Jefferson, Fayette, Winston, Blount, and Bibb Counties. Data from these surface locations, and coal cleat data from eight underground mines was corrected for magnetic declination and titled beds rotated to the horizontal where necessary and plotted on rose diagrams for comparative analysis. Data collected on each joint and cleat consisted of attitude, quality, type, spacing, persistence, lithology, bedding thickness, surface texture, and filling. File data and published and unpublished reports from the State Survey and the State Mine Inspector's Office were re-viewed. Twenty-seven mining companies, most of which supplied information pertinant to the project were also contacted. The information obtained consisted of crop line information structure, and underground mine outlines, all of which were put on 7 ½ -minute topographic quadrangles. LANDSAT-1 imagery and Skylab photography were compared to dominant joint and cleat trends in the study area. Detailed results can be found in an open-file report entitled "Fracture Analyses in a Selected Area of the Warrior Coal Field, Alabama." A master's thesis entitled "The Relationship Between Surface Joints and Subsurface Structure in a Selected Area of the Warrior Coal Field" is being prepared to illustrate the relation-ship of the fracture system to the structure in the Warrior coal field. A proposal has been submitted for research on a project entitled "Rock Fracture Systems and Their Affects on the Extraction of Fossil Fuels in the Warrior Basin, Alabama"

Jan 1, 1976

By John G. Palmer

Continued development of an especially impregnated silica gel capable of reversible chemical detection of carbon monoxide (CO) was reported. The affects of changes in mine-related ambient conditions on the detection catalyst's response were explored. Temperature, humidity, and several interfering gases were found to affect the detection catalyst. The interferents include hydrogen sulfide, nitrogen dioxide, acetylene (and methylacetylene), and ammonia. High humidity decreased the detection catalyst's sensitivity to carbon monoxide for some formulations. Increasing temperature generally decreased the reaction time of the detection catalyst with carbon monoxide. Badges and carriers for the visual presentation of the detection catalyst were constructed. Several variations of these devices included provisions for absorbants and filtering agents which help protect the detection catalyst from gaseous interferents. A variety of catalyst support agents were tested in an effort to find the most suitable. Included were alumina, magnesium oxide, magnesium silicate, and several forms of silica gel. In addi tion to free-flowing forms of these sorbents, thin layer chromatography plates coated with cellulose, alumina, and silica gel and newly developed PTFE entrained silica gels were examined. A limited physical, chemical, and mechanistic characterization of the detection catalyst and the materials used to prepare it has been carried out. Metal component ratio studies, spectral, analytical, pH, and rate measurements were done.

Jan 1, 1982

By R. H. Thompson

Preliminary safe distances for blasting wiring from typical electromagnetic sources are presented. The distances are for underground coal mines and electromagnetic sources in the frequency range below 10 MHz. The distances are based on measurements performed at 3 locations in each of 3 coal mines. The measurement apparatus, measurement procedure, measurement results and the rationale used in the calculation of the safe distances are all described. The safe distances presented are dependent on the measurement results and their interpretation. More measurements are clearly necessary to establish the validity of the suggested distances.

Jan 1, 1985

By Thomas J. Peters

Tungsten, silver, lead, zinc, and placer gold occur in the Cucamonga B RARE II area (no. B5174). A strata-bound, scheelite-bearing zone at the Blue Diamond prospect (fig. 1, no. 1) contains an estimated 16,000 tons (15,000 t) of identified, subeconomic resources averaging 0.16 percent tungsten trioxide (W03). There is a high potential for discovering additional tungsten resources at this property. The California-Hercules prospect (fig. 1, no. 5) ha; a mineral occurrence which contains an estimated 1,000 tons (900 t) of tactite averaging 1.3 oz silver per ton (45 g/t), 0.75 percent lead, and 0.72 percent zinc. Another occurrence, at the Blew Jordam Prospect (fig. 1, no. 4) has an estimated 100 tons (90 t) of tactite averaging 10 oz silver per ton (340 ,/t), 3.75 percent zinc, and 2.3 percent lead. There is a moderate potential for discovering silver, lead, and zinc resources at these prospects, which are in metamorphic pendants. There are a few lode gold prospects in the area (fig. 1, nos. 3, 11, 14) are on geologic structures which parallel the San Andreas Fault, northeast of the area. These deposits are not well exposed and have been historically unproductive. Placer gold in area B occurs locally in the beds of intermittent tributaries to Lytle Creek (fig. 1, nos. 10, 12, 13) in concentrations as high as $1.17 per cu yd ($1.53/cu m, at a gold price of $450 per troy oz). The deposits have no significant volume, but could be utilized for recreational panning and suction dredging. In the Cucamonga C RARE II area (No. C5174) placer gold occurrences locally contain as much as $1.23 per cu yd ($1.61/cu m). However, gravel containing the gold appears to be limited to stream beds, and does not occur in sufficient quantity to constitute resources. Recreational panning and dredging also may occur in this area.

Jan 1, 1983

By W. R. Hardwick

This paper describing the mining methods of the Inspiration Consolidated Copper Co. is one of a series being prepared by the Bureau of Mines on mining methods and costs in various mining districts of the United States. The story of mining at Inspiration is of particular interest because, after 127,812,000 tons of low-grade copper ore were successfully mined, the mining method was changed from block caving to open-pit. As the open pit became deeper, many features of the former block-caving operation that were exposed elucidated concepts of the mechanics of caving that previously had been assumed but not observed. The conversion to open-pit mining was accomplished by unique combinations of equipment and the introduction of ingenious engineering and operating practices that have extended the expected life of the mine for many years.

Jan 1, 1963

By Donald R. Johnson

Apparatus providing simultaneous differential thermal analysis, thermo-gravimetry, and evolved gas analysis, has been developed by the Bureau of Mines specifically for thermal study of oil shale and other solid, natural fuels. The apparatus is described in detail, and simultaneous analyses on a single sample of an oil shale mineral, nahcolite, and a thermal analysis demonstration compound, calcium oxalate monohydrate, are presented to demonstrate the instrument's capabilities.

Jan 1, 1970

By Tyler Blake

This report describes a study designed to evaluate a pro-posed modification in the cap lamp battery cord intented to reduce the incidence of snagging and catching of the cord. A three phase evaluation was performed comparing a prototype with the standard, currently available cord. First, a ?pull test? equipment was run. The second evaluation was a body conformity study. The third evaluation involved subjects performing common tasks in a low seam coal mine simulator. The results of these evaluations clearly demonstrated significant safety advantages of incorporating coiled cord into the design of the cap cord. The coil cord presented less of a snagging hazard, allowed the wearer more time to respond to a snag, and transmitted lower levels of force to the helmet when snagged. The research team recommended that cap lamp cords be commercially developed which incorporate coiled cord at the battery and helmet.

Jan 1, 1980

By John C. LaScola

The Bureau of Mines investigated coal storage silos to determine how gassy coal must be for methane accumulations in a silo to become hazardous and where such accumulations are likely to occur. Methane concentrations were measured in the open space above the stored coal pile, in the pile, and in the reclaiming area. No methane layering was found in closed-top silos. Reclaiming areas were as gassy as the top part of the silos. Coal samples were collected from the conveyors entering the silos in order to assess the gassiness of the coal. No simple correlation was found between the gassiness of the coal stored and the measured methane concentrations. However, at mines where the average 24-hour gas emission from the conveyor belt samples was 14 ft3/ton or more, fans or open tops were used. It appears that a large fraction of the methane released during storage remains in the void space between the coal particles.

Jan 1, 1980