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By W. J. Whiten, D. W. Grinsberg

Most cluster analysis techniques are not well suited to the analysis of engineering data as they have been designed for more qualitative data that tend to produce compact clusters. A clustering technique is described which develops and uses local cluster shapes to build clusters that are suitable for use in engineering applications. The technique is finding application in the analysis of many types of data, particularly where multiple trends and outlying points occur in multiple dimensions. Applications of particular interest are the calibration of on-stream analytical equipment and the analysis of data on plant performance. In both cases the multidimensional nature of the data renders manual analysis very difficult

Dec 1, 1991

By E. A. Brocchi, D. H. Gameiro, P. K. Jena

Carbon tetrachloride was found to be a very efficient chlorinating agent for anatase concentrate, even at the low temperatures that were investigated (250-400 degrees C). For example, at 400 degrees C about 90% of the anatase concentrate was found to have been chlorinated within 60 minutes

Jun 13, 1905

By C. A. Pickles, S. J. Splinter, J. Cameron

The addition of copper oxide to a borosilicate slag resulted in the breakdown of the silicate network and a dramatic decrease in viscosity. With increasing borax to silica ratio the viscosity was reduced by two mechanisms. First, rising sodium oxide content promoted cleavage of the Si-O bonds. Second, increasing boric oxide (B2O3) content increased the number of trigonal borate units that were converted to tetrahedral borate units by sodium oxide and copper oxide. The BO4(4-) tetrahedra decreased the local silicate symmetry, thus disrupting the silicate network and lowering the viscosity. The activation energy decreased with increasing temperature and increasing copper oxide content

Jun 13, 1905

By A. W. Fletcher

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J, Cahalan President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, December, 1970, pp. C247-52, and contributed remarks. Contributions are included from: Cahalan M.J., giving figures related to leaching Cu from pyrite at Rio Tinto 1880-1910; Noakes F.D.L.; Embling P.M.K.; Bradshaw A.V.; Le Roux N.W.; Kelly D.P.; and Tuovinen O.H. Questions were raised regarding impurity removal, effects of light and ultraviolet light on the bacteria, the economics of solvent extraction and the possibilities for other organisms or other metals

Dec 1, 1971

By I. R. Stevenson, J. G. Dunn, T. N. Smith, L. C. Mackey

An experimental flash reactor has been developed to simulate the operation of an industrial flash-smelter reaction shaft. Four concentrate materials of differing mineralogical compositions were characterised and then oxidised in the reaction shaft. The products were examined by chemical analysis to determine the extent of oxidation and by electron-probe microanalysis to determine the fate of individual particles. This programme of work enabled the influence of mineralogical composition and particle size on the extent of oxidation to be assessed

Jul 1, 1991

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

By Evans E. C.

Discussion of the paper presented at the Manchester Geological and Mining Society' general meeting held in Manchester, March 14th , 1916, with Leonard R. Fletcher, President, in the Chair included contributions by Fletcher L.R., Paton J.D., Orchard A.J.A., Ross A., Gerrard J. and Stephenson H., with the author's responses

Dec 1, 1916

By E. H. W. Hornbrook, P. W. B. Friske

Paper presented at the 28th International Geological Congress, Washington DC, July 1989 (International geochemical mapping sessions). The objective of the programme is to establish and maintain a nationally consistent geochemical drainage database. Towards this end systematic surveys have been conducted since 1973. To date more than 200 surveys have been completed to the required standards, representing 180 000 sites and covering about 2 100 000 km2 throughout Canada

Jun 13, 1905

By W. Doherty, P. C. Lightfoot, V. A. Fedorenko, N. S. Gorbachev, V. I. Kunilov, A. J. Naldrett, Z. Johan

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. A model is presented which regards the Lower Talnakh- and Talnakh-type intrusions as part of the plumbing system for the overlying lavas. As magma ascended along the Noril'sk-Kharayelakh fault it was forced to spread out within sedimentary strata immediately beneath the obstruction of the accumulated volcanic sequence. Here it was severely depleted in chalcophile elements by sulphides, which were then trapped by their high density and remained behind in the main arteries to form the central, elongated zone of maximum thickness. Subsequent magma also lost Ni, Cu and PGE to the sulphides as it flowed through. The Lower Talnakh-type intrusions represent part of the plumbing system that became blocked at an early stage, before the influx of much mokulaevsky-type magma rich in chalcophile elements. The model accounts for the high metal content of the ores in comparison with the size of their associated intrusions, the extensive metamorphic aureoles, the chalcophile depletion of some overlying volcanic suites, the presence of the ore in near-surface intrusions rather than deep magma chambers, and the sulphur isotopic composition of the ore

Apr 1, 1995

By D. J. Esdale, D. F. Pridmore, F. W. Lindman, J. H. Coggon

Almost all the presently viable nickel reserves in the Yilgarn Block contain nickel in a sulphide phase. Both volcanic peridotite- associated (VPA) deposits and intrusive dunite-associated (IDA) deposits are characterized by massive, matrix and disseminated sulphides (typically, pyrrhotite, pentlandite, pyrite, chalcopyrite, magnetite and other spinels), though in the IDA deposits the volume of disseminated sulphides is far greater than that in the VPA deposits. Potentially all geophysical techniques have application in the direct detection of these deposits'gravity for the detection of the dense massive and matrix ore; magnetics for the detection of magnetite and pyrrhotite in the ores; electromagnetics for the detection of the massive and matrix ore; and induced polarization for the detection of disseminated and to some extent matrix and massive ore. In practice the application of geophysical techniques is limited to a varying extent by (1) the relatively small size of an economic accumulation of sulphides, particularly the VPA deposits, (2) the extreme depth of weathering and lack of outcrop on the Yilgarn Block and (3) the abundance of geological noise or anomalous responses caused by sources other than economic mineralization.

Jan 1, 1984

By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By Winmill T. F.

(Paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916.) The conclusions reached in this paper may be summarized briefly as follows: (1) The method of estimating moisture in coal by determining the loss in weight of a sample heated to 105°-110° Cent, in an air-bath for an hour is untrustworthy, the results so obtained being too low. (2) Dried coal has a very considerable power of absorbing moisture, and a sample, after being dried, must be protected instantly if it is to remain free from moisture. (3) A fairly accurate estimation may be made by heating the coal in a current of dry air at 105° to 110° Cent., and collecting the moisture evolved. (4) In cases in which it is proposed to use the dried coal for any further experiments, the drying must be done in the absence of oxygen, and this can be done simply and quickly by the vacuum method now described

Dec 1, 1916

By I. Garba

The Bin Yauri deposit in the Zuru schist belt of northwestern Nigeria is a vein-type quartz-sulphide-carbonate gold mineralisation hosted by a brittle fault zone. The occurrence of the mineralisation in a contact zone of a Pan-African granitoid was believed to be sufficient evidence of deposition from magmatic fluids. However, studies may now indicate a metamorphic source for the mineralising fluids. A study of rare earth element geochemsitry was used to investigate the nature of the fluid-rock processes involved and identify the sources of the auriferous mineralising fluids.

Jan 12, 1992

By Hirsch H. H.

The paper, presented at the North of England Institute of Mining Engineers' general meeting held in Newcastle-upon-Tyne on 12th February 1916, gives a short description of the Hirsch lamp, which, though largely used in the United States of America, has not yet been adopted in Great Britain. The lamps, which consist of (1) the watchman's lamp and (2) the miner's lamp, are portable, and have been designed to provide a safe and reliable light for use by watchmen, and in mines, rescue-work, powder-works, oil-refineries, and other places where special precautions become necessary on account of the presence of explosive materials or gases. The lamps are in each in­stance operated by a storage-battery contained within a casing, and this supplies the current necessary for a miniature incandescent lamp. Each safety-lamp forms a complete unit and can be carried from place to place or held in any position. Appendices give details of battery cleaning, test results and safety reports

Dec 1, 1916

By A. L. W. Lips, T. J. R. Barclay, E. Rothery, S. H. White

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994 (originally entitled: The Broken Hill base metal deposit - a tectonically transported and modified basinal deposit within the Proterozoic Willyama fold and thrust belt). A regional structural study was undertaken which incorporated the role of shears. Their positions were identified from earlier mapping, from regional aeromagnetic data and by additional field work. Kinematic studies determined movement histories and petrological studies of the fault rocks formed within the shears identified the relationship between the movements and regional metamorphism. It was found that the shears formed a part of an earlier, major thrust event with transport from NW to SE and a later, minor one in the reverse direction. Neither had any significant effect on the mineralisation apart from local displacement, but the shuffling of the basin stratigraphy adds to the difficulty of recognising the original volcanic and sedimentary protoliths of the metamorphosed sequence. The mineralisation at Broken Hill mine is confined to a single recognisable thrust slice within a shear corridor. It is stratabound with locally transgressive remobilisation due to the high-temperature thrusting and some metasomatic alteration as a result of the retrograde shearing. This variation accounts for the different genetic models applied to the deposits in the past

Jun 17, 1905

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

Jan 1, 1984

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By Fearnsides W. G.

Discussion at the The Midland Institute of Mining, Civil and Mechanical Engineers' general meeting held in Doncaster on 27th May 1916, on the paper published in Trans. I.Min.E., vol.LI, 1916, p.409-448, included oral contributions by Lupton A. on the mechanisms of subsidence and water egress and by Kendall P.F. on the validity and accuracy of the contour extrapolation technique and the effect of major faults, together with the author's response

Dec 1, 1916