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By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

By A. Zangooi

Frothers play major roles in flotation through interaction at the air/water interface. A method of determining frother adsorption density (coverage), i.e., the number of molecules per unit of interfacial area of bubble surface, is introduced. The technique is based on mass balancing the frother around a continuously operated bubble column. The mass balance requires collection of bubbles before they burst. The column design and operating procedure is reviewed, and some preliminary results discussed. Keywords: flotation, colorimetric frother analysis technique, frother mass balance, coverage

Sep 1, 2012

By A. S. Choudhary

Most of the coal reserves in India are of drift origin and have very poor washability characteristics and a high level of near gravity materials. At least 30 new coal wash plants are expected to be set up in the next 5years.In such a scenario, adequate sampling followed by sink float test work for washability analysis becomes very critical for designing these new plants. For coal sampling purpose, stipulations of different standards are sometimes formidable and on the border of ?impracticality?; sometimes are self contradictory in terms of gross sample weight vis-a-vis minimum number of particles required in each size fraction and in each relative density fraction and also the minimum mass in the latter. Validation of the generated data is another important aspect of washability analysis. These issues can easily be addressed by using straight forward mathematical relationships, well known RR plots and by using simple MS Excel tool, etc.

Sep 1, 2012

By M. V. Sowmya

Batch biosorption experiments were carried out for the bio-remediation of Cr (VI) ions from aqueous solutions using Serratia marcescens, a Gram negative, heterotroph and Gram positive bacterial isolates from a chromite mine. The influence of various experimental parameters such as contact time, pH, concentration of Cr (VI) ions and amount of biomass was evaluated with respect to the uptake of Cr (VI). The bio-sorption of Cr (VI) was found to be quite rapid and the percentage biosortion was found to increase with increase in the equilibrium chromium concentration. The free energy of biosorption of Cr (VI) was estimated to be in the range of -23 to -25 kJ/mol for the chosen bacteria. The uptake of chromium by the bacteria was confirmed by EDX and FTIR spectroscopy. As a follow up of this study, bacterial strains resistant to hexavalent chromium were isolated from a chromite mine in Karnataka, India and identified as Arthrobacter sp., Micrococcus sp. and Exiguobacterium sp. using 16s rRNA sequencing. The efficacy of the bacterial isolates for Cr (VI) uptake was assessed and over 90% bioremoval could be achieved for Serratia marcescens and Micrococcus sp. isolate. Possible mechanisms of chromium uptake by the microorganism are discussed. Keywords: bioremediation, hexavalent chromium, biosorption, bioreduction

Sep 1, 2012

By E. Alldén Öberg

In 2004, LKAB decided to start a basic engineering study in expanding its existing production lines at the Malmberget mine site. It was expected that some of the production lines would become bottlenecks with reference to capacity. In this study, the sorting plant is examined and the results show that several unit operations will be limiting under current operating conditions. An additional purpose with the study was to investigate how replacement of some machines would influence performance and if production plans for the coming years might be achieved. Steady-state simulations using the software Modsim? were extensively used to study process performance for different operating conditions, such as iron content and size distribution in run-of-mine ore. Model parameters were derived from pilot plant data and when possible from ex-isting circuits. A complication for the simulations was the lack of relevant data and therefore some of the initial results were only indicative. The result shows that installation of new screens would give a much better operation, but also new crushers would be an improvement. This, since they can be run with full crusher chamber and tighter CSS. During 2007, most of the proposed remedies were implemented and the result is that the bottle-necks are gone, and the grades and material balances are even better than what was envisioned from the simulations.

Jan 1, 2014

By F. M. Isik

Due to not to being our own sources, some energy sources such as oil and natural gas which are used frequently, are not reliable energy sources for our country. Coal is an important energy source that Turkey also has a certain reserve as many countries have. To be able to use for many years the reserves of this source that comes from fossils, there is a great need to make more investigation and development activities on it. On behalf of using more productively the current sources, briquetting facility is represented that commenced production in The Aegean Lignite Establishment in 2005 which is in Manisa, Soma. This facility is a part of General Directorate of Turkish Coal. This facility is run by Soma Coal Establishment that works in return for royalty in a licensed field that belongs to TKI. As the demand of market for 0.5 mm dust coal diminishes, we had to accumulate and stock unmerchantable dust coal. Besides, we have intermixed 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal obtained as a result of washing in coal washer with thermic coal with low price as we could not find a client in the market. In this study, the production stages of briquette coal with high quality produced as a result of pressing by mixing 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal with molasse and lime, quality control, and data?s obtained about calories and solidity of products were presented. By briquetting of 0.5- 1 mm powder coal and 0.1 ? 0.5 mm fine powder coal washed in coal washer, it became possible to sell these coals on a high unit price and by providing the demand of coal of the market, we contributed to productivity of our firm. Keywords: briquette coal, briquetting, producing stage

Sep 1, 2012

By U. M. J. Boin, W. L. Dalmijn, T. P. R. de Jong

"This paper explores the complex interrelationship between the resource cycle, recycling and metal production as a function of economics, environmental legislation, and product design. It is argued that central to optimising this resource cycle lies the control in particular of physical separation plants by the application of advanced sensor technology and sorting equipment, as well as suitable control and sampling algorithms supported by optimising mass balance models.Metals are produced through a long chain of processes. For primary resources, metals production goes through mining, mineral processing, ore smelting, conversion and refining steps or via low temperature hydrometallurgical processes, or a combination of both pyro- and hydrometallurgical operations. For the recycling of resources, metals are separated and recovered from metal scrap, which plays an increasingly important role in the world. Metals after being produced, either from primary or recycling resources, have to be further refined or manufactured into various types of alloys and finally shaped into different products for the end-users. Since the end-user discards products the contained materials find their way back into the resource cycle as scrap. Therefore, controlling the metallurgical reactors also controls, in a much broader sense, the material quality in the complete metals cycle, from the production phase, to the end-use phase, up to the recycling phase (Reuter et al., 2003). The recycling phase includes separation of materials into saleable intermediate products, which are reintroduced into the production phase as a recycling resource. Therefore, the metallurgical processes in each unit operation in the metals production and processing chain have to be controlled, so as to achieve optimal performance of high product quality, low energy and materials consumption, and low environmental impact."

Jan 1, 2003

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

Separation performance of a Floatex Density Separator (FDS) has been studied both experimentally and theoretically. Experimental results reveal that at a lower bed pressure the FDS acts like a classifier. Higher bed pressure is required to attain the concentration effect as proper development of suspension density occurs under these conditions. It is seen that the size or density alone is not able to describe the partition fully. The terminal settling velocity, which includes both the size as well as the density of the particle can be a useful descriptor of separation in a FDS. While a narrowly distributed feed offers better performance of a FDS, a wide size distribution of feed results in large scatter in the terminal settling velocity distribution and renders the separation difficult. The closely sized feed enhances the density effect in concentration. A higher teeter water flow rate also helps in carrying larger-lighter particles to the overflow by increasing the cut off terminal settling velocity as it increases the net upward force. A detailed description of separation performance in a Floatex Density Separator has also been established from theoretical considerations. Separation performance of the separator is described using a simple slip velocity model. The model has been validated com-paring the predicted FDS performance results with those experimentally measured under widely different operating conditions.

Jan 1, 2014

By Auhin Kumar Maparu

Metal oxide nano-particles are used as additives in various industrial applications such as pigments in paints, additives in adhesives, plastics, cosmetics, functional coatings, personal care and health care products, for antibacterial applications and more recently in heat transfer applications. In most of these applications, usually dry nano-particle powders are added to the formulations. However, often it becomes difficult to achieve a uniform and stable dispersion of nano-particles in the given formulation. Thus, a scalable and commercially viable process for in-situ production of stable nano-particles suspensions in the desired medium will certainly be more beneficial. Ultra-fine grinding in high energy mills (planetary mill, stirred media mill) has been used to produce fine particles (sub-micron size). However, in order to obtain nano-particles (particle size <100 nm), the choice of appropriate dispersant and solvent is crucial, since freshly generated nano-particles tend to agglomerate due to their high surface reactivity. We have employed molecular modeling (MM) based selection methodology to arrive at the most suitable solvent?dispersant combination for preparation of the given metal oxide nano-particles. Molecular modeling techniques are employed to compute the interaction energy of a given dispersant with surface of the metal oxide particles in the presence of the dispersion medium. The interaction energy helps identify a dispersant that has strong affinity for the metal oxide surfaces allowing for strong dispersant adsorption and hence a more stable dispersion. For example, in case of aqueous nano-titania suspensions, poly-carboxylic acids like citric acid provide better dispersion than mono-carboxylic acids like lauric acid, mysristic acid, and oleic acid. While in non-aqueous medium like ethanol, p-hydroxybenzoic acid and glycerol trioleate perform better. The suspension is produced in-situ by ultra-fine grinding of the metal oxide powder in the presence of the selected dispersant and dispersion medium in a planetary ball mill. By careful selection of various process parameters such as percent loading of powder, jar filling, grinding media to powder ratio, time and amount of dispersant addition, both aqueous and non-aqueous suspensions of metal oxide nano-particles with average particle size less than 100 nm are produced. The aqueous suspensions of alumina and titania produced in presence of citric acid dispersant exhibit median particle size of 83 and 62 nm, respectively. These suspensions have been found to be stable for nearly 3 years. The nano-particles thus produced are used in the preparation of nano-fluids?advance heat transfer liquids, which show enhanced heat transfer capabilities and unaltered stability and performance even after several heating-cooling cycles. The nano-particles are also utilized for making efficient photo catalysts, which are found to be highly effective under sunlight. Keywords: stability, nano-fluid, milling, grinding, thermal conductivity, nanocoolant, photocatalyst

Sep 1, 2012

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Diego Mesa, Willy Kracht

Frothers may be classified as weak or strong depending on their ability to produce stable froths, which is related to the amount of water that they transfer from the pulp to the froth. They can also have an effect on the non-selective mechanism of recovery by entrainment, implying that both selectivity and froth stability are, at least to some extent, frother dependent. Solids, on the other hand, also have an effect on froth behaviour. Clays, which are characterized by their small particle size, laminar shape, and high specific surface, tend to report to the froth phase and have an enormous impact on both froth stability and the overall performance of the flotation process. The purpose of this work is to shed light on the effect that different frothers have on the froth behaviour when clays are present. In order to do that, two sets of experiments were conducted using frothers from the families of alcohols and polyglycols. For each test, the equilibrium froth height was measured at different frother concentrations in an agitated machine with an acrylic square-base cell that was 11 cm wide and 25 cm high. The cell was designed in such a way that froth was able to grow without concentrate discharge. In the first set of tests, pure clays such as kaolinite and montmorillonite were used. In the second set, an actual copper sulphide ore with a high content of clays was used as solid phase. The results, expressed as curves of equilibrium froth height against frother dosage, showed a coupled effect of frother-clay on froth behaviour for both sets of experiments. In some cases, the froth grew up until the border of the cell with only a few parts per million of frother. In other cases, the equilibrium froth height varied smoothly with frother dosage. The results suggest that choosing the right frother can be of use for controlling the froth behaviour when dealing with clay-rich froths, using frother dosage as the control variable. The application of these findings at industrial scale are discussed and some recommendations are given.

Jan 1, 2018

By Yosep Han

Mechanically-induced chemical reactions between natural beach ilmenite (FeTiO3) and silicon (Si) have been examined by a combination of X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analyses. The effect of various milling time on the phase transformation, crystallite size, and lattice strain of a beach sand ilmenite with silicon, and on their leaching behavior in hydrochloric acid (HCl) has been investigated. For mechanically activated FeTiO3, the crystallite size decreased and lattice strain increased monotonically with time of milling. However, the mechanochemically synthesized ilmenite with silicon showed a relatively smaller crystallite size and greater lattice strain compared with the mechanically activated ilmenite under the same milling condition. In accordance with the elapse of milling time, the intensity of both pure FeTiO3 and mechanically activated FeTiO3 gradually decreased. However, in case of the mechanochemically synthesized ilmenitereduction of FeTiO3 by silicon resulted in formation of rutile TiO2 at the milling time of 20 h and afterwards. Additional leaching experiments were carried out at an HCl/ilmenite (wt%) ratio of 20:1. The concentration of HCl was 3 M and the reaction temperature ranged from 70 to 90 oC. Mechanical activation was observed to significantly enhance the dissolution rates of both iron (Fe) and titanium (Ti) in HCl. Particularly, effects of both milling time and silicon addition on the dissolution rates of titanium and iron were significant, while those of temperature were relatively minor under the conditions investigated in this study. Keywords: mechanochemical treatment, natural beach ilmenite, silicon, leaching behavior

Sep 1, 2012

By Gu Guohua

The alteration of surface properties of chalcopyrite after biological conditioning with Leptospirillum ferriphilum was studied by adsorption, zeta-potential, contact angle and bioleaching tests. The strains of L. ferriphilum cultured using different energy sources (either soluble ferrous ion or chalcopyrite) were used. The adhesion of bacteria to the chalcopyrite surface was a fast process. Additionally, the adsorption of substrate-grown bacteria was greater and faster than that of liquid-grown ones. The isoelectric point (IEP) of chalcopyrite moved toward that of pure L. ferriphilum after conditioning with bacteria. The chalcopyrite contact angle curves motioned diversely in the 9K culture with and without chalcopyrite powders. The results of X-ray diffraction patterns (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analysis indicated that in the bioleaching process by L. ferriphilum, the surface of chalcopyrite was covered with sulfur and jarosite. Furthermore, iron phase dissolved preferentially from chalcopyrite surface during bioleaching from EDS detection. The copper extraction was low resulting from the formation of a passivation layer. The major component of the passivation layer that blocked continuous copper extraction was sulfur, not jarosite.

Sep 1, 2012

By M. D. Kaizer

PETROBRAS started its Oil Shale process development in 1953, the PETROSIX process which was developed and tailored to Irati Oil Shale formation. Since 1991, the industrial plant called MI (Industrial Module) has been operating, producing more than 20 million barrels of oil. In order to continue the oil shale exploration, a new shale mine is been opening. This article reports the planed measures taking in order to limit the environmental impacts and to return the land as close as possible to the original condition, as well as with the disposition of the process waste and the city garbage. It shows that the remediation process starts during the mining activities and continues after the mine exploration. Another characteristic of the Petrosix process, the pyrolysis of tires will be focused.

Jan 1, 2014

By Z. L. Huang

A new porous apatite product was prepared using phosphorite from Yichang China by a tem-plate-directed method in self-made reaction equipment under constant temperature and pressure. The product was characterized by XRD, FT-IR and SEM. The results showed that the product was a kind of micrometer porous sphere three-dimensionally structured by apatite nanoflakes, that the average thickness of nanoflakes was about 50 nm, that the average pore size was about 1.2 µm and that the particle average size was about 20 µm. Great amounts of Ca2+channel, high special surface area and regular spherical shape show the potential promising applications of this special porous apatite product in the fields of catalyst, medication, chemical engineering and environment engineering

Jan 1, 2014

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018

By Tamal K. Ghosh

In this study, the QEMSCAN technology is used to acquire quantitative modal, textural, mineral association and liberation data on different products generated from with or without washing, fractionation by size and density using screens and heavy liquids/panning, which has provided significant information on the quality and beneficiability of four categories of low Grade iron ores from Jharkhand-Orissa region. The deposit of low Grade iron ore has been categorized into four categories viz. Grade-I with <45% Fe(t) a) containing shale rich type and b) BHJ rich type; Grade-II with 45-55% Fe(t) and Grade-III with >55% Fe(t) containing conventional flaky, hard, kanga, lateritic, shale and BHJ litho/ore types in varied proportions. Mineralogy is similar across all samples being hematite, martite, goethite, kaolinite and gibbsite. Banded Hematite Jasper has difficult liberation characteristics due to highly compact banded mode of silica mineral occurrence with hematite. In all categories, the grade dilution is by the presence of 1) ?Discrete gangue rich litho types? at lump size and 2) ?Within ore types?. The second type of grade dilution contains coating of gangue phases around the iron ore minerals and different degree of locking of gangue phases within iron ore minerals. Further characterization and beneficiation assessment details are discussed in this paper.

Sep 1, 2012

By W. Yao, M. L. Li, R. Cui

"The purpose of this research is providing a flotation process for recovery of lead in lead silver residues from a zinc smelting plant with a new hydroximic acid collector (HOC). The collecting ability and reaction mechanisms of HOC were investigated based on pure mineral flotation tests and analysis of zeta potential. The pure anglesite flotation tests showed that HOC has a good collecting ability for anglesite. Zeta potential measurements proved that HOC adsorbed on anglesite surface physically and chemically. The lead-silver residues in a zinc smelting plant with lead grade about 17.5% was used as raw material for flotation tests. The results showed that under the conditions of pH adjusting agent lime 500g/t, inhibitors sodium silicate 2000g/t, collector HOC 1500g/t, frother alcohol oil 75g/t, the grade of the lead concentrate can be reach 47.18% and the recovery was 76.39% by one roughing-one scavenging-three cleaning and middles back to the flow-sheet in turn after the lead-silver residues were washed by two stages of cleaning-filtration.INTRODUCTION Nowadays, with the increasing exploitation of natural mineral resources, more and more secondary resources should be researched and used for the valuable metals. Hydrometallurgical zinc leaching residues, which contain a considerable amount of zinc, lead, silver and other minor valuable constituents, is a typical and abundant secondary resources (Zhang et al., 2011). A huge quantity of zinc leaching residues (ZLR) had been produced per year (Jiang et al., 2017).This residues not only occupy precious land but also threaten the environment because of the dissolved heavy metals especially in rainy days (Han et al., 2014). Consequently, it is urgent to develop an effective and clean method to dispose this residues which can benefit not only in economical but also in environmental (Jha et al., 2001)."

Jan 1, 2018

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012