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By Williams Calderon, César Arredondo, Gonzalo Montes-Atenas

The quality of final concentrate in froth flotation circuits is largely dictated by the correct implementation of the froth washing operation in flotation cleaning stages, which are commonly installed in column flotation cells. In flotation plants, this aspect has been largely overlooked and the froth washing is restricted to the use of perforated piping through which process water flows producing a similar effect to that observed in "fountains": jet created with low energy crosses the froth phase washing out entrained particles as well as particles weakly attached to bubbles. The aim of this research study is to assess the efficiency of traditional froth washing systems theoretically and experimentally. A theoretical model was implemented using Fluent® software where a jet of variable speed was introduced in a continuous soft matter phase with physical properties similar to those observed in a froth phase in wet and dry conditions. In addition, a simple experimental protocol was designed to validate the model. It was found that the water process jet-like flow influences the behavior of 2 to 3 times the equivalent volume in the froth phase. Such influence zone is dramatically reduced as the froth phase becomes drier. These results were confirmed by the experimental findings indicating that a better froth washing technologies must be assessed and implemented. Some aspects of the ideal froth washing system are derived and discussed in details.

Jan 1, 2014

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using sodium dodecyl sulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).In order to investigate the effect of the initial concentration of Fe3+ on As removal, sets of experiments were performed with a concentration of Fe3+ in the proper range of pH (5,0 – 6,0) previously observed in the coprecipitation tests. As removal improves significantly as the concentration of the coprecipitant agent increases from 60 mg.L-1 (77,4%) to 80 mg.L-1 (99,7%). This is probably due to the higher concentration of ferric hydroxide (Fe(OH)3) which provides a larger surface area available for adsorption of As. From the initial coprecipitant concentration of 80 mg.L-1, As removal has shown to be rather high (? 99,7%), with the maximum being (99,9%) by using a Fe3+ concentration of 160 mg.L-1. Therefore, for a maximum As removal, under these test conditions, the optimum concentration of Fe3+ is 160mg.L-1.This paper also shows the effect of the initial concentration of Al3+ on As removal at a suitable range of pH (7,0 – 8,0). A very significant increase on As removal was found to occur as the initial concentration of coprecipitant was increased from 60 mg.L-1 (35,7%) to 80 mg.L-1 (97,7%) and a decrease in As floatability (43,7% - 54,5%) was found to occur from that Al3+ concentration amount. Based upon those results, the optimum Al3+ concentration so as to remove As under these test conditions is 80 mg.L-1."

Jan 1, 2003

By M. H. Moys, H. Dong

"Discrete Element Method (DEM) has become a standard tool to simulate grinding mills in order to gain information about load behaviour, power drawn, etc. However, parameters necessary to run a simulation are not always readily available. For example, the coefficient of restitution used in DEM simulation from the literature ranges from 0.1 to 0.9 due to lack of accurate values. The lack of correct input parameters results in the fact that some simulation parameters are adjusted to match the simulation prediction with the experimental results. It is inappropriate to tune one single parameter arbitrarily in order to fit the prediction with experimental results. The correct value of parameters for DEM simulation should be established, and rigorous validation on simulation results by DEM needs to be done.The objectives of the ongoing project are to measure the coefficient of restitution at conditions analogous to grinding practice. Equipment has been built to measure the coefficient of restitution. A typical case of impact test showing the vertical position of a ball as a function of time is presented in Figure 1. The coefficient of restitution between steel ball of different sizes and the targets including steel liner (e = 0.91), mild steel block (e = 0.57) and rubber liner (e = 0.7) have been measured. The coefficient of restitution reduces to 0.38-0.52 when there is a layer of coal particles (1-2 mm) on the steel liner. The effects of ball size, drop height on coefficient of restitution are investigated. Then a DEM code is developed of several contact models to simulate the impact process. This code can reveal details on velocities (translational and rotational) and forces (normal and tangential) during the brief impact interval. Figure 2 is a comparison of the rebound rotational velocity between experiment and prediction by different models. The results can be used as DEM input and to assess contact models."

Jan 1, 2003

By Olgac Kangal, Ali Guney, Gulay Bulut, Guven Onal, Ayhan A. Sirkeci

"This paper presents the results of pilot scale column flotation applications in the two different copper concentrators in Turkey. The Kure Copper Plant is located in the Black Sea Region of Turkey. There are four types of copper ore formations in the Küre region. The so called disseminated ore contains 60-70% siliceous minerals of which Cu content is around 0.5%. The remaining three ore types in the region are generally named “massive ores”. The massive ores may assay up to 15% Cu and the major gangue mineral is pyrite associated with relatively little amount of silica. The main copper mineral in all formations is chalcopyrite that is generally finely disseminated in pyrite therefore satisfactory liberation requires ultrafine grinding especially in the case of the massive ores.A blend of these ores, containing 1.7% Cu on average, is fed to the Küre Copper Concentrator whose capacity is 1.2 million tons of ore annually. Unfortunately, today the plant operates below its designed capacity treating around 550,000 tons of ore per year. The design of Küre Copper Plant was undertaken by the Outokumpu Company of Finland. The operation of the plant is almost automatically controlled and the feed, the concentrate and the tailings are assayed for copper by on-line XRF analysers. The particle size analysers are also connected to the grinding circuit. The feed material is ground almost below 50 µm and the flotation is conducted around pH 11.2 using Hostaflot X-231 (a trade mark of Hoechst) as the collector. Apart from the rougher cells, there are four cleaning stages after which the final concentrate is produced. A very fine grinding requirement for an adequate level of liberation makes successful flotation difficult and consequently the final concentrate can hardly assay above 16% Cu leading to copper losses around 20% in the tailings that contains 0.3% copper."

Jan 1, 2003

By J. Yvon, Inna V. Filippova

"The aim of this work is to seek the inhibitors of the meteoric and bacterial dissolution of sulphides and gangue minerals to stop the undesirable chemical reactions during conservation of the flotation wastes. The approach of passivation of surfaces by chemical treatment of the solid phase is applied for this objective.The samples taken from different depths of an old French waste dump revealed the capacity of the flotation tailings to produce acid waters (pH 1.8-2.4) and to release heavy metals. Mineralogical studies show not only the product of sulphide oxidation, i.e. sulphates, but also the complex transformations of aluminosilicates in acidic liquid phase. The detection by XRD of aluminium hydroxides (gibbsite, boehmite) allows supposing the recrystallisation phenomena during tailings conservation.Comparative tests of the passivation of the surface of sulphide minerals and waste of flotation with using of conventional reagents (CaO, NaOH, phosphates) and original reagents for this purpose (alkyl dithiocarbamates) allow to identify the optimal treatment conditions and the efficient chemicals.Leach tests were carried out in percolation columns during 68 weeks. The normalised leaching tests according to French legislation were run to confirm the selected treatment conditions. The results obtained show that a single treatment with carbamate inhibits the oxidation of the pyrite and the other sulphides, and totally prevents the formation of acid waters (the stabilised pH was 5.3-5.8). Treatment of in situ drainage water allows to obtaining a total precipitation of heavy metals: the residual concentrations of Fe, Cu and Zn are lower than 0,1 mg/l.The passivation of sulphides is the result of the formation with carbamate (studied by IR spectroscopy and XPS) of organometallic compounds, which are stable in acid medium. The presence of thiuramdisulphide (product of alkylcarbamate oxidation) at the mineral surface stabilises the mixed adsorption layer and leads to a considerable reduction in the hydratation rate of surface by avoiding the corrosion of the pyrite. No aluminium was detected in leach solution with this treatment."

Jan 1, 2003

By R. Peter King, Claudio L. Schneider, Reiner Neumann

Predicting the liberation spectra that is produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.

Jan 1, 2003

By O. N. Mohanty, S. Mohan Rao, N. D. Rao, T. Mukherjee, P. V. T. Rao

"Chromite ore is an indispensable raw material in the manufacture of ferro-chrome and charge-chrome, which are used for the production of stainless and other alloy steels. The demand for chromite ore is ever increasing because of increasing consumption of these steels. Keeping this in view, Tata Steel is keen to recover values from fines and wastes, and also to produce value added products from their captive chromite mines and its processing plants.Tata Steel has its captive chromite resources at Sukinda, Orissa. They contain two ore types, i.e. (i) Ferruginous and (ii) Siliceous. The generation of off-grade ores is an increasing trend and simultaneously customer quality requirements are becoming ever more stringent. The ferruginous type ore also contains a considerable quantity of in-situ fines (~20% particles below 0.5 mm) that compound the beneficiation problem.In many places, in India and abroad, mined non-marketable off-grade and low grade chromite ores are upgraded by using either simple classification techniques like screw classification, hydrosizing, hydrocycloning or conventional gravity concentration processes such as Heavy media separation, Jigging, Spiraling, Tabling etc.At Tata Steel, the ferruginous type ores are treated in Chrome Ore Beneficiation (COB) Plant that comprises: a crushing and grinding circuit; a classification circuit using hydrocyclones; and a beneficiation circuit using 4 stage spirals in the coarse circuit (-0.5+0.1 mm) and 3 stage spirals & tables in the fine circuit (-0.1+0.038 mm). In this process, 3 types of tailings are being generated and together analyses about 17 % Cr2O3, which is high. From the present operation the chromite recovery is around 70% and could not produce coarse concentrates (+0.5 mm size). Whereas the siliceous type ore is treated in the Lumpy Ore Processing (LOP) plant, consisting of crushing-washing & classification-hand sorting operations, to produce marketable grade lumpy ore and –10 mm de-slimed fines. These fines are intermittently treated in the COB plant. The higher silica content (greater than 1%) and low Cr/Fe ratio (less than 2.8) are the problems with these concentrates."

Jan 1, 2003

By Bertil I. Pålsson, Sture V. Persson, Kent T. Tano

"Autogenous (AG) and semi-autogenous (SAG) mills often operate in an unstable state because of the difficulty to balance the rate of replenishment of large ore particles from the feed with the consumption in the charge. This has led to an increased interest in obtaining an accurate and direct measurement of mill load and the behaviour of the mill charge. A problem in attempting to measure those parameters is getting a sensor that is both robust and sensitive enough for continuous on-line measurement.Techniques that measure the force acting on the lifter when it hits the charge inside the mill have got an increased interest recently because of the ability to combine it with DEM modeling. This paper presents a method for the measurement of the apparent filling level in a pilot ball mill equipped with the Metso Continuous Charge Measurement system (CCM). In this technique a strain gauge sensor is mounted on a flat steel spring which is fitted into a recess underneath a lifter bar. In addition, a conductivity probe, the Boliden Grinding Measurement System (GMS), is mounted in another lifter bar with the purpose of comparing the two measurements. To visualise the behaviour of the charge a 2D DEM modelling technique is used with Metso HFS software.The pilot mill is a grate-discharge mill, equipped with 12 rubber lifters of square size 0.1 m, face angle 45 degrees. Steel balls in the size range 10-30 mm and density 8000 kg/m3, are used in the experiments. Test material is a hematite pellet feed, d50 around 45um, chosen to get stable grinding conditions with respect to feed size variations.The experiment is meant as a first test of the equipment’s performance, and to study how the sensors respond to changes in some operating variables. To get an understanding of, and distinguish between correlation and causality, experiments are performed according to a full factorial design with two levels, and in addition two replicates of the experiments at a center-point in the charge level setting."

Jan 1, 2003

By S. S. Indi, D. Santhiya, S. Subramanian, K. A. Natarajan

"With the gradual depletion of the high-grade ores and finer dissemination of values in the leaner samples, it has become imperative to develop innovative approaches to process such complex ores. The beneficiation of complex sulphide ores containing copper, lead and zinc minerals, remains one of the most important challenges in base metals metallurgy. The advent of biotechnology in mineral processing has opened up immense possibilities to exploit such difficult-to-treat ores. Bioprocessing techniques thus hold promise as potential substitutes for the conventional technologies in vogue. Several types of autotrophic and heterotrophic bacteria, fungi, algae and yeasts are implicated in mineral beneficiation processes. Adopting a bioprocessing route to mineral beneficiation has attractive benefits, such as lower cost and energy requirements, environmental acceptability and operational flexibility.The interaction of sphalerite- and galena-adapted Bacillus polymyxa (B. polymyxa) cells with sphalerite and galena has been investigated through adsorption, electrokinetic and flotation studies. The amount of sphalerite-adapted cells adsorbed onto sphalerite and galena is found to decrease with increase in pH. On the other hand, the adsorption density of galena-adapted cells onto galena shows a feeble maximum around pH 8, and the amount adsorbed is marginally higher in the pH range of 8 – 11.5. In the case of sphalerite the amount adsorbed is higher in the pH range of 5 to 7. The adsorption density of both the adapted cells is higher for galena vis-à-vis sphalerite. Electrokinetic studies indicate significant surface chemical changes on the chosen sulphide minerals and the bacterial cells, consequent to microbemineral interactions. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite could be preferentially floated from galena, using galena-adapted cells, but not with the sphalerite-adapted cells. The cells adapted to galena assay a higher polysaccharide content and are more hydrophilic, while the sphalerite-adapted cells have a higher protein content and possess greater hydrophobicity. Transmission electron microscopic studies have provided evidence in support of the differences between the cell surface characteristics of sphalerite- and galenaadapted cells (Figure 1). Possible mechanisms of interaction between the minerals and the bacterial cells are discussed."

Jan 1, 2003

By Ming’an Wei, Chuanyao Sun, Yangge Zhu, Fayu He, Yanbo Shang, Xingrong Zhang

In order to discuss the separation mechanism of copper-molybdenum ore, surface electronic structures of chalcopyrite and molybdenite were studied in the paper, by using First Principles method of quantum chemistry. So, the separation mechanism of thioglycolic acid (TGA) with chalcopyrite and molybdenite was revealed better. The results showed that differences of the electronic structure of chalcopyrite and molybdenite could directly affect their interactions with TGA, such as band structure, density of states, Mulliken populations, and so on. And the frontier orbitals of chalcopyrite and molybdenite were also calculated by Dmol3 after the optimization by CASTEP, from which the interaction energies between minerals and TGA were obtained and compared. So, the essence of flotation separation of copper and molybdenum were well revealed.

Jan 1, 2014

By Markus A. Reuter, Antoinette van Schaik

"INTRODUCTIONGoods and products, such as passenger vehicles, are manufactured by using a wide spectrum of different raw materials to meet highest consumer requirements during use. Due to the time-varying composition and complexity of multi-component products such as cars, recycling is complicated. It involves a network of interconnected processes and material and energy flows. Improving the efficiency of the material cycle of the car to comply with the recycling targets as imposed by EU legislation, requires insight into all aspects influencing the closing of the material cycle (dynamics, technology, economy, legislation, etc.) and their mutual relation. In order to define the link between recycling end-of-life products, their changing composition and design a dynamic model was developed for the resource cycle of cars. The model integrates the optimisation of the material cycle with the dynamic behaviour of recycling systems."

Jan 1, 2003

By Javier Baladron, Mijail Villar, Brandt Henriksson

"In this presentation an overview will be given of what has been observed by the authors in the copper concentration industry, with a large diversity of tailing thickeners operating under different conditions, although many of them are located in the same neighborhood. A closer look will be taken at the reported performance from different sites and from different thickener designs, either conventional or high rate, including those that were retrofitted, regardless of the thickener brand. An analysis is also made of the generic correlation of the size of the thickener and the performance in terms of solids loading (or unit area) and % solids. The paper envisions a technology development route, makes a brief analysis of the economic impact of the suggested route and points out the need for development in technologies around tailings thickeners, such as automation, yield stress measurement, slurry pumping and construction methods."

Jan 1, 2014

By Raquel Franco de Souza Lima, Isao Matsuoka

"Microflotation studies and abstraction experiments were conducted with synthetic oxide spinels relating to chromite (MgCr2O4, FeCr2O4, FeFe2O4 and FeAl2O4), using sodium oleate as collector. An attempt was done to correlate this data with the speciation of oleate in the bulk solution and at the interface solid-water, to explain the floatability curves. The microflotation tests were conducted using a microflotation cell. The abstraction of sodium oleate was measured at 25°C, with one gram of synthetic spinel and the abstraction time was 30 minutes. After centrifuging, the residual oleate concentration in the supernatant was measured by using the spectrophotometric method described by Mizuniwa et al. (1977), that covers the range from 1.5 to 9 ppm. To cover the range from 0.2 to 1.5 ppm, the residual oleate concentration was measured using the spectrophotometric method described by Gregory (1966). The amount of oleate abstracted was calculated from the difference between initial and residual (equilibrium) concentrations.Figure 1 shows the floatability of FeCr2O4, FeAl2O4, FeFe2O4, MgCr2O4 as a function of pH and sodium oleate concentration of 1 x 10-5 M. The IEP of each sample is indicated in the figure by a vertical line in the horizontal axis. The chromium-bearing spinels FeCr2O4 and MgCr2O4 show the lowest isoelectric points (IEP), around pH 6, while in the case of FeFe2O4 and FeAl2O4, the isoelectric points lie at pH 6.5 and 7.3, respectively. It is seen that the flotation-pH curve for FeFe2O4 has a peak at the pH of the IEP, while flotation peak for FeCr2O4 appears at pH below the IEP and that of MgCr2O4 does at pH above the PZC. On the other hand, FeAl2O4 is floated at pH range between about 4 and 7,3 (IEP). This suggests that the pH value at which the maximum flotation occurs is dependent on the sort of spinel to be floated, though it appears in the vicinity of the respective IEP."

Jan 1, 2003

By Aubrey Mainza, Malcolm S. Powell

"A hydrocyclone with two vortex finders, named the three-product cyclone (3PC), has been successfully tested in the Platinum industry for dealing with the dense Chromite found in UG2 ores. This dense component preferentially reports to the cyclone underflow, resulting in an over-ground fine Chromite component in the final product. The dense media effect caused by a high concentration of this in the cyclone feed produces a coarsening of the cyclone overflow, which results in loss of recovery through over-size silica in the PGM carrying component material in the float feed. The fine barren particles of Chromite that report to the overflow are recovered through entrainment in the flotation process, resulting in detrimental contamination of the slag produced from the concentrate.Data from many industrial scale tests of the 3PC have shown that three distinct products are obtained when the inner vortex finder length (LIVF) is extended to the region either above (normal classification) or below (reverse classification) the transition zone (a region were the inner and outer overflow streams are identical). Due to wear problems arising from extending the IVF deep into the cone of the cyclone, it is advantageous to use the shorter IVF. Only the normal classification results are reported here, but similar outcomes (to opposite overflow streams) were obtained for the reverse classification. The results showed notable differences in the percentage split of the plus 100µm material in the product streams, confirming that three distinct products are discharged from the 3PC. About 12% of the plus 100µm material in the feed reports to the middlings stream, 1% reports to the final product, and the remainder to the cyclone underflow.Results of silica and chrome splits to the three distinct products namely, the inner overflow (INO), the outer overflow (OUO) and the underflow (U/F) are given in Table 1. These show that the 3PC can be used to recover coarse silica through screening the middlings product - which has a high silica content. When the vortex finder ratios (ratio’s of cross-sectional areas) are carefully selected, the split of plus 100µm silica to the middlings product ranged from 2.9 to 9.6%. Large amounts of oversize silica and chrome report to cyclone underflow, explaining their high percentages in the underflow stream."

Jan 1, 2003

By K. W. Stöckelhuber, A. Wenger, H. J. Schulze

"An important elementary step of the flotation process is the forming, drainage and rupture of a thin intervening liquid film between bubble and mineral particle.After the encounter of the bubble with the solid surface a wetting film is formed. The initial thinning of this film is driven by the capillary pressure inside the bubble. When the film has reached a certain thickness rupture can take place. There are two possible mechanisms describing this process:(a) Gas nucleation, caused by nano bubbles inside the film.(b) Growing fluctuation waves (spinodal dewetting) on fluid interfaces under the influence of any kind of attractive forces (electrostatic, van der Waals).Metastable wetting films on negatively charged, hydrophobic glass surfaces (gaseous phase methylated), or on hydrophilic, positively charged glass surfaces (with Al3+ ions), have been analysed by means of the kinetics of film thinning according to the Reynolds law. These experiments demonstrate that both mechanisms can be responsible for the rupture of a thin wetting film."

Jan 1, 2003

By João Queiroz, Cristian Marquez-Sarmiento, Luiz Teixeira

The removal of various metals from process waters and effluents is usually done by precipitation of the corresponding hydroxide. Manganese however is one metal that does not respond efficiently to that approach. It may be seen in its eH X pH diagram that the way of oxidation to Mn IV rather than hydrolytic precipitation of the Mn II ion as its hydroxide, is the way to efficient precipitation of Mn in the pH range 6 to 10. We studied the use of oxidants O2; NaClO; H2O2; Caro´s Acid (H2SO5) and the combinations of O2 or H2O2 with Na2S2O5, and H2O2 with NaClO, for the oxidative precipitation of Mn from synthetic solutions starting with 10 mg/L Mn, at 25 oC. In adequate conditions, which include pH > 8, it is possible to reach final [Mn] less than 0.1 mg/L in 60 minutes of reaction time.

Jan 1, 2014

By Sergey Gudkov, Yuri Yemelianov, Stanislav Balikov, Andrey Boldyrev, Andrey Bogorodsky

"The results of POX of refractory gold-bearing concentrates using halide-ion as a lixiviant for precious metals and activated carbon as an adsorbent are given. It was found that gold did not recover to the solution when halide was added during POX. Silver partially dissolved in the solution. When halide-based reagents and activated carbon were added during POX, gold dissolved and loaded onto the activated carbon. The degree of sulfides oxidation was 99.3-99.6%. The recovery of gold onto granulated carbon was 94.7-94.8% when using chlorine-bearing lixiviants: NaCL, CaCL and carnalite and 98-99% when using KJ and KBr. This treatment process of refractory gold-bearing concentrates combines sulfide oxidation, dissolution and adsorption of precious metals. The results of the metals recovery achieved using this process can be compared with the recovery during POX-cyanidation. In this case, sodium cyanide was not used. This allows the reduction of capital and operational costs due to the absence of cyanidation, CIL and detoxification of leaching tailings circuits."

Jan 1, 2014

By H. Pearce, A. E. Lewis, A. Ochieng

"Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. Hydrodynamic conditions influence phase mixing and mass transfer in a multiphase system, and these affect the overall performance of such a system. Detailed information on the effects of the hydrodynamics on the performance of agitated systems is still required for the design and optimal operation of hydrometallurgical systems, which are always multiphase. Computational fluid dynamics (CFD) techniques have been employed to study the hydrodynamics and mixing, most of which have focussed on the performance of axial and radial pumping impellers in agitated tanks. However, very little has been reported on the influence of a draft tube on the flow profile in such systems.CFD simulation of a stirred vessel centres on the way the impeller is modelled. Some of the most recent approaches to modelling an impeller are impeller boundary condition (IBC), snap shot, sliding grid (SG), multiple frame of reference (MFR) and inner outer (IO). The accuracy, with which these models predict experimental results and the corresponding computational demands, form the basis upon which the choice of an approach is made. Most of these approaches (IO, SG and MFR) address the key problem of the stirred tank modelling, namely, the simultaneous meshing of the rotating impellers and the stationary baffles. The MFR is computationally cheap and has been found to give predictions that compare well with experimental data.The CFD technique (code CFX4.4) has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the impellers have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor."

Jan 1, 2003

By James A. Finch, Linda Restrepo, Mitra Mirnezami, Amy Buchanan, Maryam Hashemi

Settling rate studies on slurries from Cu/Zn flotation plants occasionally reveals two aggregation maxima at pH 8-10 and 10-12 (Figure 1). From measurements on sphalerite and silica suspensions the double maxima could be replicated. These maxima correspond to the effects of Zn and Mg ions. The aggregation mechanism of both ions is related to the formation of the corresponding hydroxide precipitate. A combination of chemical and electrostatic bridging by the hydroxides is considered to be the aggregation mechanism.

Jan 1, 2003

By Nóra Schreithofer, Kari Heiskanen

"INTRODUCTIONThe knowledge of the adhesion forces between particles and bubbles is of key importance in the improvement of flotation models. The development of the Colloidal Interaction Force Measurement Apparatus (CIFMA) opened the possibility to quantify the adhesion forces between particles and bubbles. The aim of this study was to examine the effect of three main variables: the approach velocity, the loading force and the loading time on the adhesion force between an air bubble and a hydrophobized silica particle."

Jan 1, 2003