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By Kurt Aasly, Przemyslaw B. Kowalczuk, Rolf Arne Kleiv

Seafloor massive sulphides (SMS) can serve as a potential resource of metals such as Cu, Zn, Au and Ag. SMS rock samples from the Loki’s Castle area at the Arctic Mid-Ocean Ridge are comprised of sulphide bearing minerals such as pyrite, chalcopyrite, isocubanite, galena, sphalerite, whereas the gangue consists mainly of barite and silica. Sphalerite, chalcopyrite and isocubanite show complex intergrowth textures on the nano- to microscale. Various mineral processing tests were conducted in order to recover copper, zinc and silver. It was shown that sensor-based sorting can be efficiently used for preconcentration of SMS rock samples. A significant amount of waste (i.e. barite and silica) was removed in the preconcentration stage with very low losses of copper and zinc to the waste fraction. The upgraded samples were sent to the next processing stages. The results showed that the complex mineralogy of the SMS material provided challenges to conventional mineral processing methods. Hydrometallurgical processing was applied as an alternative method for extraction of metals from SMS. Leaching experiments were conducted using solutions of different lixiviants, and it was shown that leaching of SMS together with manganese nodules would facilitate efficient recovery of metals from these resources.

Jan 1, 2018

By Ian Selby

Recent offshore diamond exploration has been concentrated in the SW Joseph Bonaparte Gulf. I`IW Australia. Extensive high resolution seismic and sampling surveys have been carried out in Cambridge Gulf, offshore of the mouth of the OR River and other rivers of the region. Surface-tow boomer surveys have been correlated with sampling data from vibracores and a wide diameter (1m) airlift system, providing a geological framework for the area. Although large-scale bulk sampling has not been undertaken, there has been no reported recovery of diamonds since 1993. The geology and prospectivity of a range of potential diamond traps in high energy, fluvial and transgressive depositional settings has been assessed. Potentially diamondiferous targets include (i) a shoreline apron. (ii) fluvial/estuarine channel infills and terraces and (iii) ravinement surfaces.. Although there is evidence for a long history of fluvial development and sea level changes, the majority of the investigated traps represent the result of erosion and sedimentation during and following the last interglacial. Significant volumes of unconsolidated gravels and coarse-grained sands with occasional indurated layers are present, and are locally exposed at sea beet In place s thick successions (>5m) of fine-grained overburden overlie the coarse-grained sediments.

Jan 1, 1998

By R. W. Nesbitt

The TAG and Broken Spur hydrothermal mounds are located on the Mid Atlantic Ridge (MAR) at 260N and 290N (respectively). Both were initially discovered by exploratory work from surface vessels and both have since been investigated by submersibles. The discovery of TAG resulted from a NOAA Trans-Atlantic Geotraverse (Rona et al. 1975) which fortuitously sampled low temperature materials on the east wall of the MAR rift valley and follow up operations (Rona et al. 1986) located the high temperature (365°C) mound some 5km to the west. In 1994, ODP deep sea drilling (Leg 158) at over 3,500 metres of water recovered core to a depth of 150 m below surface (Herzig et al. 1998) and for the first time allowed a geological interpretation of an active mound. The Broken Spur mound was accidentally discovered in 1993 when sulphide fragments were observed on a deep-sea towed camera system (Murton 1993). Later that year, exploratory submersible dives by Alvin located the hydrothermal field and the area was again explored by submersible in 1994 and 1997. Despite the amount of work carried out, our geological understanding of the MAR mounds is limited. Much effort has gone into measuring fluid chemistry whilst practical difficulties have inhibited good geological mapping of the sulphide areas. It is clear from both TAG and Broken Spur that the mounds are not necessarily located in the areas of highest heat potential. Indeed, TAG is some 2 km from the rift valley axis and has been operational for several tens of thousands of years. Hence, heat availability is not a major consideration and the most obvious control is a structural one. Mapping on Broken Spur indicates a series of isolated vent-sulphide areas, concentrated around a minor graben. Their distribution, size and nature all indicate that they are residual parts of a much larger sulphide body which was at least the size of the present TAG field. The evidence is for a cyclical pattern of mound growth -mass wasting? rejuvenation and the Broken Spur mound appears to be in the rejuvenation stage of the cycle. Mound cyclicity must be related to the supply of hot water which itself is a function of the connectivity of fracture systems. Hence, we return to the theme that the major controls in mound development are structural ones.

Jan 1, 1998

By Brian D. Bornhold

A comprehensive multi-disciplinary marine geological survey of northwestern Graham Island, Queen Charlotte Islands, British Columbia, Canada was conducted by Offshore Survey and Positioning Services Ltd. of Vancouver, B.C. on behalf of the Geological Survey of Canada; Energy, Mines & Resources Canada, Pacific Geoscience Centre, Sidney, B.C. Canada during October 1984 and July 1985. The aim of the survey was to map both the surficial geology and geomorphology in order to identify and evaluate the nature of the nearshore sedimentation and recent tectonics including stability (slumps and scarps) seafloor faults (frequency and displacements) and both the classification and consistency of soil type boundaries and properties. Data was acquired by utilizing conventional indirect applied marine geophysical techniques including side scan sonar, precision echo sounding and complimentary soil sampling. During October 1984 a total of 320 line kilometres of data including 180 soil samples were acquired. During July 1985 a total of 300 line kilometres of data were acquired including 150 soil samples.

Jan 1, 1985

By James C. Barker

Concern over the availability of domestic critical and strategic mineral supplies has led the Bureau of Mines to evaluate the reserve development potential of alternative sources in Alaska. Near the village of Platinum, on the southwest Alaska coast, the Red Mountain concentrically zoned ultramafic complex is a source of onshore alluvial placers containing platinum-group-metals (PGM). It has long been suggested that valuable placers may also underlie the shallow coastal waters of the Bering Sea. A direct correlation of placer PGM and chromium to ultramafic rocks in the area was studied by the Bureau and the extent of the complex was mapped. Magnetometer and gravity data and geological studies suggest the complex is a large lensoidal body trending several kilometers offshore to the southwest with a probable steep southeasterly dip. Multiple Pleistocene glaciations and marine transgressions have eroded the western and southwestern portion of the complex. Sediments containing PGM, chromium, and associated gold (largely derived from glacial till) have been transported northward along the advancing coastline by littoral currents. Beyond the breaker zone, these sediments are generally buried by recently winnowed sand and gravel transported by strong longshore tidal currents. There is also evidence that paleoplacer channels underlie the marine sediments.

Jan 1, 1986

By David S. Cronan

Submarine hydrothermal mineralization occurs in at least three locations along the Hellenic Volcanic Arc in the Eastern Mediterranean Sea. Weak hydrothermal discharges occur off Kos and Nisseros at the eastern end of the arc and off Milos at the western end. In both cases the hydrothermal solutions are rich in iron and manganese and are precipitating iron oxides variably enriched in minor elements. This points to the likely presence of sulphide minerals at shallow depth below the sea floor at these locations. By contrast, at Santorini, in the centre of the arc, the hydrothermal discharges are much stronger and rate of deposition of the hydrothermal minerals much greater. Indeed, in one of the two hydrothermally active embayments off Santorini (Nea Kameni) hydrothermal deposits are accumulating up to five times as fast as in the Atlantis II Deep of the Red Sea. Radiocarbon dating indicates that these deposits have been accumulating for about 100 years. In the other embayment off Santorini (Palaea Kameni), hydrothermal deposition has taken place over a longer period (more than 1,000 years) but the deposits are not so hydrothermally enriched due to the simultaneous deposition of biogenic silica and detrital mineral with the hydrothermal deposits. The observed pattern of increasing intensity of submarine hydrother¬mal activity from the extremities of the arc towards its centre argues for additional hydrothermal mineralization on poorly explored areas of the sea floor between Milos and Santorini and between Kos and Santorini.

Jan 1, 1994

By Hunsoo Choi, Sung Rock Lee, Ian J. Graham, Ian C. Wright

This is a part of the joint KIGAM-GNS-NIWA 3-year study of ferromanganese modules in the Campbell Nodule Field, east of Campbell Plateau to determine age distribution, growth rates and geochemical evolution in relation to geographic setting. The petrography, chemistry, inferred genesis, and 10Be/9Be dating of the nodules were described in the science report of GNS (Chang et al., 2003a, 2003b; Graham et al., 2003a) and presented at UMI (Chang et al., 2003c; Graham et al., 2003b). The morphology and distribution of ferromanganese nodules were also published in detail (Wright et al., 2005). This presentation is only concentrated on the mineralogy and chemistry of the nodules.

Aug 24, 2006

By Geir Johnsen

Hyperspectral remote sensing has been used extensively on land to identify minerals for the mining industries. An underwater hyperspectral imager (UHI) has been developed at the Norwegian University of Science and Technology. It captures optical fingerprints within the spectral range of 400-700 nanometers, with 1 nm resolution. The UHI has been tested on nodules and SMS deposits in the laboratory and on the sea floor to establish if this technology can be used to identify marine mineral deposits, to determine type of deposit and distribution.

Jan 1, 2010

By Jonguk Kim

The North Fiji Basin (NFB) is a mature intraoceanic back arc basin with an age of ~12 Ma. Recent volcanism and spreading activity are focused along the Central Spreading Ridge (CSR), A ridge segment more than 800 km long, composed of four main segments, the N160°, N15°, north-south (N-S), and southernmost segments from north to south. The dominant volcanic rock in the entire central spreading ridge is normal mid-ocean ridge basalt (N-MORB), very similar to those emplaced along mid-oceanic ridges. Conversely, influence of an oceanic island basalt (OIB) source increases northward from 18°20'S. Several basalts which show a significant subduction-related component are also observed in the southern part of the NFB. Hydrothermal activity along the spreading centers of the North Fiji Basin was investigated by several previous works, especially by the STARMER project in 1989 and 1991. Both extinct and active hydrothermal vents are found on the N15° and N-S segments. In contrast, only traces of hydrothermal activity have been found on the N160° segment. Although high temperature activity and related massive sulfide deposit on the N15° segment was further investigated by several follow-up studies, no systematic survey for other hydrothermal sites was conducted after their discovery. In 2012 and 2013, KIOST performed two hydrothermal expeditions aboard the R/V Onnuri in the three targeted areas of hydrothermal activity along the CSR of North Fiji Basin. All targeted areas include sites for hydrothermal activity reported in previous works. Occurrence and distribution of hydrothermal plume were investigated by combined

Sep 14, 2011

By James R. Hein

Methane and hydrogen sulfide vent from a cold seep above a shallowly buried methane hydrate in a mud volcano located 24 km offshore of Los Angeles, California in 800 m water. Bivalves, authigenic calcite, and methane hydrate were recovered in a 2.1 m piston core. Aragonite shells of two bivalve species are unusually depleted in 13C (to -19? d13C), the most 13C-depleted shells of marine macrofauna yet discovered. Carbon isotopes for both living and dead specimens indicate that they used in part carbon derived from anaerobically oxidized methane (AOM) to construct their shells. Although the?d13C values are highly variable among specimens, most fall within the range -12 to -19?. This variability may be diagnostic for identifying cold-seep/hydrate systems in the geologic record. Authigenic calcite is abundant in the cores down to about 1.5 m subbottom, the methane hydrate horizon. The calcite is strongly depleted in 13C d13C = -46 to -58?) indicating that AOM was the main carbon source. Three sources of methane are likely: a geologic hydrocarbon reservoir, and biogenic and thermogenic degradation of organic matter in basin sediments. Oxygen isotopes indicate that most calcite formed out of isotopic equilibrium with ambient bottom-water, under the influence of gas hydrate dissociation and strong methane flux. High concentrations of Ag, Hg, Cd, Tl, and other elements in mud volcano sediment reflect leaching of basement rocks by fluids circulating along an underlying fault. Fossil (geologic) methane was likely transported with these fluids.

Jan 1, 2005

By Hyun Sub Kim

Subsea mineral deposit exploration aboard the R/V Onnuri was performed along the northern Central Indian Ridge (CIR) between 8°S and 17°S in December 2009 ~ January 2010 (09IR Leg01 and 09IR Leg02) and December 2010~ January 2011 (10IR Leg01, 10IR Leg02, and 10IR Leg03). Final goal of the expedition for the first Korean research cruise on mid ocean ridge system is to define seafloor massive sulfide ore bodies through searching the active hydrothermal vents nearby spreading centers as well as to elucidate the nature of spreading segments of the northern CIR area where no systematic survey have been operated before by mapping and sampling of volcanic rocks. The preliminary result of topographical interpretations of bathymetry clearly display ocean core complex between 10°S and 11°S. The ocean core complex is featured by topographic-high area with corrugated surface. Lineaments of corrugations of the ocean core complex are clearly perpendicular to abyssal hill direction which is triggered by symmetric-normal faults. Ocean core complex are favor for hydrothermal fluid path because of the long-lived faults. In further exploration, more detailed examination, including systematic CTD casting and tows, need to narrow down actual venting site around ocean core complex. Magnetic field survey is able to estimate the location of hydrothermal vents with the properties that high temperature of hydrothermal fluids over Curie-point can cause thermal demagnetization. In magnetization intensity map, most of low magnetization zones are located at the nodal point over the ridge axis and the ocean core complex.

Jan 1, 2011

By Daisuke Monoe, Kisaburo Nakata, Rika Takeuchi, Tetsuo Yamazaki, Tomoaki Oomi, Tomohiko Fukushima

There are generally two methane passes in conjunction with the seafloor natural cold seepages, as is schematically shown in Fig. 1. The first pass consists of the coupled anaerobic oxidation of methane and anaerobic sulfate reduction, as well as sulfur oxidation in the bacterial mats and immobilization thereafter in the sediment layer and on the seafloor. Through the first pass, calcium and organic carbonates are formed in biological and chemical processes from the methane (Luff and Wallmann, 2003; Luff et al., 2004). The detailed structure of the seafloor methane consumption process unit and its biological and chemical processes were introduced in Yamazaki et al. (2005). The other pass consists of direct bubbling into the water column. Through this pass, organic carbonate is formed with biological oxidation, and a small amount of the methane escapes into the atmosphere. Methane flux is supplied to these two passes through the sediment layer from the deeper structures. The structure of the methane supply process unit was introduced in Yamazaki et al. (2006).

Sep 24, 2006

By Robert R. Tarver

A long history of gold production at Nome, Alaska has resulted in long term interest in the nearshore environment as a production target. Mining by Western Gold Exploration and Mining Company offshore of Nome yielded approximately 100,000 troy ounces of gold in the period 1986 through 1990. This study was designed to determine the relationship between heavy minerals, sediments, and gold concentrations which occur in the upper meter of sediment offshore of Nome. Standard procedures were implemented for grain size analysis, heavy mineral separations, and heavy mineral frequency determination.

Jan 1, 1991

By Samantha Whisman, James R. Hein

Hydrothermal marine manganese-oxide deposits (HMMD) are cemented and variously replaced volcaniclastic and biogenic sediments that were mineralized by distal, low- temperature, hydrothermal fluids. HMMD predominantly form below the seabed as sediment-hosted statabound deposits but can also form on the seabed. These deposits form at oceanic and back-arc basin spreading centers, volcanic arcs, and mid-place hotspot volcanoes. HMMD have traditionally not been considered to have an economic potential because they were considered to be devoid of economically valuable critical elements. This contrasts with their non-hydrothermal counterparts, ferromanganese crusts and nodules, which are enriched in many critical elements. However, manganese is now one of the critical metals and HMMD have the highest manganese contents (up to 55% Mn, so- called battery-grade Mn) of all the types of deep-ocean mineral deposits. There is a growing demand for this critical metal and an upward trend exists in the price of manganese on the global market. Also, other critical elements can occur in high concentrations in some HMMD and their economic potential has not been considered, especially for lithium (up to 0.17%) and molybdenum (up to 0.24%), but also vanadium (to 820 ppm), chromium (to 346 ppm), and nickel (to 0.45%), among others. Which of these critical elements are enriched and their concentrations depend on the types of rocks leached at depth by the hydrothermal fluids, the composition of hydrothermal minerals precipitated in the higher temperature parts of the circulation system, and the types of sediments mineralized by the manganese oxides. For example, mineralization of a carbonate sediment resulted in the highest lithium contents, whereas leaching of ultramafic rocks at depth as a rule results in the highest chromium and nickel contents in the HMMD. These deposits are known to be widespread, especially in volcanic arcs, but their lateral and vertical extents and consequently size, tonnage, and grade have not been determined. Most samples of hydrothermal deposits have been collected by dredging and therefore the in situ relationships often are not known. One sample from the Mariana volcanic arc, west Pacific, was collected by ROV at 1274 m water depth from a layered outcrop 6.6 m thick that may be a sequence of pervasively mineralized volcaniclastic layers and offers the first clue as to the potential vertical extent that these deposits may attain. However, only the top ~0.4 m-thick layer was sampled, so it is not known whether the mineralization extents throughout the outcrop. Although large manganese deposits of various origins occur on the continents, they consist of manganese carbonates, silicates, or complex mixtures of manganese minerals. In contrast, marine hydrothermal HMMD exhibit relatively simple mineralogy that would make processing of this potential ore much simpler.

Jan 1, 2018

By ?. V. Kabanov

n considered operation hydraulic and kinematic circuits of deep-water installation for sampling a ground from a sea-bottom are submitted. Control by setters is made remotely from a service station with the help of a system of telemechanics. Migration of apparatus along a bottom is ensured with the help of force of a response of a jet and Archimedean force. The mathematical exposition of the device composed and computer simulation is Design parameters are defined and static performances are obtained. Operation is in a stage of manufacture of working drawings. There are patents of Russia.

Jan 1, 2005

The chemical composition of the nodules varies with the type of manganese minerals and the size and characteristics of their nucleus, but those who have an economic interest have the following composition: Mn 29%, Fe 6% Si 5%, Al 3%, Ni 1.4%, Cu 1.3%, Co 0.25%, Na 1.5%, Ca 1.5%, Mg 0.5%, K 0.5%, Ti 0.2 0.2% and Ba 0.2% (Morgan, 2000; ISA, 2002). The Pacific Rim is an area of abundant occurrence of polymetallic nodules (Glasby et al., 1980; Morgan, 2000). According to these authors, the Pacific sea floor of the Clarion-Clipperton Zone (CCZ) is one of the most interesting areas in regard to the genesis of polymetallic nodules. Their abundance in the ocean floor is very variable, as there are places where they cover more than 70% of the ocean floor. The nodules can be found at any depth, but the highest concentrations are between 4000 and 6000m (Morgan et al., 1993). In studies conducted in the EEZ of the Mexican Pacific are those made within the project "Research on the origin, process and distribution of minerals in the Pacific ocean floor in the Exclusive Economic Zone of Mexico". Within this project Rosales (1989) conducted studies on the origin, process and distribution of polymetallic nodules, finding that a number of processes give origin to nodules, being diagenesis one of the main mechanisms of elements that contribute to the nodules. Besides hydrothermal processes that are carried near the East Pacific Rise at 21° N, inputs are contributing to the nodules metallic elements and sediments, especially in regions close to the dorsal, as a greater influence hydrogenetic processes occurs westward (Rosales and Carranza, 1990). In 1993, after cruise MIMAR II, Carranza and Rosales refer that metals such as Cu, Co, Ni, Sn, Fe, Mg, Pb, Zn and Ba may have a relationship with the East Pacific hydrothermal activity and sea currents carry these metals in solution to the Clarion-Clipperton fracture area, where there are hydrogenic metals sources (Al, Fe and Mn).

Jan 1, 2011

By Kira Mizell, James R. Hein

Ferromanganese (FeMn) crusts form by precipitation of iron and manganese oxides from seawater onto a rock substrate and are therefore considered hydrogenetic in origin. Diagenesis does occur however, through the process of phosphatization. During phosphatization, abundant dissolved phosphate in seawater replaces carbonate in the detrital fraction as well as directly precipitates within the FeMn matrix as carbonate fluorapatite (CFA). This process is likely accompanied by the partial dissolution or replacement of the oxide phases [1]. As a result of these diagenetic processes, trace elements adsorbed on the oxides are released and can either be depleted or enriched in the phosphatized FeMn crust layers. Pb, for example, has been shown in sequential leaching experiments to associate with the iron oxyhydroxide (FeOOH) phase in purely hydrogenetic layers, while >95% of Pb in phosphatized crust layers is found in the CFA fraction [2, 3]. However, previous sequential leaching studies analyzed bulk layers of phosphatized crusts and only a few crusts, from the Pacific Ocean. Here we present concentration data for Pb and other trace elements in the CFA fraction leached from thin stratigraphic intervals of the phosphatized portion of FeMn crusts from the Pacific and Atlantic oceans to confirm consistency of trace metal association with CFA both throughout the phosphatized section and in two ocean basins. The Pb and trace element concentration data from this study will also be compared with data from non-phosphatized crusts from the global ocean. We can then determine the effect of phosphatization on the concentration of Pb and other elements of greater economic interest in FeMn crusts, specifically whether there is overall enrichment, depletion, or possibly even phase transfer of each metal in the phosphatized layers.

Jan 1, 2018

By P. C. Hollick

Two marine diamond deposits on concession 2b off Namaqualand along the South African Coast, have been systematically mined over the past year by the mv Moonstar. The two deposits, Smith?s Ulcer and Wedge Point Basin, are comparable in morphology, straddled the same water depths and have similar geology yet have given very different recoveries when compared to their respective grade models. These differences are best ascribed to the different style of mineralisation observed within the two deposits which has been directly controlled by the bedrock morphology. The smith?s Ulcer deposit has been formed in a metagreywacke bedrock displaying a strong north-south trending foliation which dips steeply to the west. Consequently the mineralisation is confined to narrow north-south linear trends with limited lateral extent (less than 5m) making extraction extremely difficult and somewhat variable. RE factors (recovered grade versus estimated grade) for this deposit range from 0.5 to 1.1. The Wedge Point Basin deposit is formed in a micaceous metaquartzite with a conjugate southwest northwest joint set, the southwest lineation being the more prominent, and structural foliation dipping gently to the west. The resultant style of mineralisation is confined to basinal features defined by topographical lows and is fairly lateral in extent (in order of 50m). Extraction of the mineralisation from this deposit is less arduous with recoveries more uniform, RE factors are frequently in the range 2 - 3. This style of mineralisation is more in line with what is to be expected from marine alluvial deposits, the nugget effect of diamond concentration being responsible for the high RE factor. The long narrow linear trends observed in Smith?s Ulcer demonstrably require a specialised approach in successfully sampling, modeling and ultimately mining.

Jan 1, 1998

By T. Semkova, G. Cherkashov, V. Rashidov, L. Anikeeva, G. Gavrilenko, G. Glasby

The Kurile Arc consists of at least 100 submarine volcanoes and 5 submarine calderas located mainly in the rear arc (Figure 1). The arc is seismically very active, particularly in the south, and is characterized by extensive volcanism and hydrothermal activity. At least one subaerial volcano on the arc (Medvezhy located on Iturup island) has an extremely shallow magma chamber and is intensely active.

By G. A. Tret’yakov, V. A. Simonov, I. Yu. Melekestseva, V. V. Zaykov, N. N. Ankusheva

The Kyzyl-Tashtyg massive sulfide polymetallic deposit is situated 120 km north-east of Kyzyl (the capital of Tuva Republic, Russia). It is located in the Ulug-O volcanic zone which is interpreted as the northern segment of the Kaa-Khem rift in Sayano-Tuva marginal sea, one of the Paleoasian Ocean margin (Fig. 1) [Zaykov, 2006]. Since its discovery in 1946 the deposit has been studied by many researchers. Significant information was published by Kuzebny et al. [2001] and Zaykov [2006] who proposed volcanogenic-sedimentary genesis. A single reference in English about Kyzyl-Tashtyg is available [Herrington et al., 1999].