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By Bernard Tougas, Franco Chiesa, David Levasseur, Bernard Duchesne

"In the present paper, the optimization of a tilt poured permanent mold will be carried out using filling and solidification modeling. This exercise resulted in 3 modifications of the initial mold design which was based on the foundry experience. The optimization provided a 20% improvement in the yield while increasing the output from 10 to 15 castings per hour.In a subsequent study, the value of the critical fraction solid of AlSi7Mg (A356) alloy was verified by radiographic analysis of the castings produced in the first 5 cycles of a run, which are necessary to bring the mold to a dynamic thermal equilibrium."

Jan 1, 2014

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By A. S. H. Kabir, I-H. Jung, J. Su, S. Yue, M. Sanjari

The final mechanical properties of wrought magnesium alloys are mostly controlled by microstructure and crystallographic orientation or texture. In common magnesium alloys, grain coarsening occurs during annealing process and formation of undesirable basal texture cannot be changed markedly. The aim of this work is to investigate the effect of static precipitation on microstructure and texture evolution during annealing at 250 °C after warm rolling of Mg-Al-Sn alloy. Mg-3Al-3Sn (wt. %) alloy has been designed using thermodynamic modeling software, FactSageTM, based on forming target stable and incoherent Mg2Sn precipitate within the industrial deformation temperature range. Microstructures and precipitation were investigated by optical and scanning electron microscopes and macro-texture was measured by X-ray diffraction (XRD) techniques. It was found that static precipitates form in a large scale at the recrystallized grain boundaries and retards the grain growth during annealing. Slight weakening in basal texture was also observed during annealing.

Jan 1, 2014

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By Xuanxue Mo, Kaihui Yang

"The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Early Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry. The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affInities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental microplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820/0 Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 glt) and recoverable amounts of Au, n, Gd, Ga, Ge, In. A massive sulfide zone, in which lenticular and stratiform orebodies are localized in a sulfide-<:arbonate-silica shale unit or sulfidic tuffIte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulfide zone developed in a subvolcanic intrusion or volcanic sequence. The sulfIde mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite - chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerals occur rarely in the massive ores. The massive ores are generally fme-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and displacement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two distinctive alteration zones have been identifIed: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, tremolite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive model of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By M. Hall

"SomarioEl circuito de molienda a Selbaie consta de molino semiaut6geno en un circuito cerrado y molino de balas en un circuito cerrado. El amperaje del motor de se usa controlar el tonelaje el molino. Este sistema estabiliza el circuito pero no mejora activamente el rendirniento del circuito. Se desarroll6 auxiliar el rendimiento del circuito un sistema experto en manipular las objetivos de existir control proporcional-integral. Se ejecut6 el sistema con el Comdale /C conjunto del sistema experto y ha side funcional hace tiempo el mayo de 1992. El sistema experto ha resultado en un aumento en tonelaje de 7tph y una disminuci6n de $210,000 en el caste anual de media de molienda. Se describe el desarrollo del sistema y los provechos derivar se presenta.AbstractThe grinding circuit at Selbaie consists of SAG mill and ball mill closed circuit grinding. The SAG mill motor current is used to control throughput. This system stabilizes the circuit but does not actively optimize circuit performance. An expert system was developed to aid the optimization of the circuit by manipulating the set-points of existing PI control loops. The system was implemented with the Comdale /C expert system package and has been on line since May 1992. The expert system has resulted in a net increase in tonnage of 7tph and a decrease in annual grinding media costs of $210,000. The system development is described and the benefits derived are presented."

Jan 1, 1994

By B. R. Maas

Processing material at a consistent rate through the continuous countercurrent decantation (CCD) thickeners presented a major bottle neck to unlocking additional value from one of the post-flotation streams at the Kansanshi processing plant. The manual operation of the thickeners making up the CCD train resulted in frequent imbalances and process upsets across units. The automation of CCD trains is notoriously tricky as the available manipulated variables are outnumbered by the parameters requiring regulation. The implementation of an advanced, auction-based, control philosophy to manage the movement of both slurry and solution inventory through the train addressed this parameter imbalance and lead to the stabilisation of the circuit. Since the commissioning of this control strategy: an additional 7 200 dmt/day (+36% throughput) of material can reliably be processed through the train, the number of monthly downtime events has reduced, and a saving of $354 000/month in reagent cost has been achieved. INTRODUCTION CCD operation Agitated leaching is a common method used in hydrometallurgy to extract a metal from its host ore. The host ore is initially finely ground to liberate the surfaces of the valued minerals and improve the kinetics of the leaching process. The ore is then contacted in an agitated tank with a lixiviant to dissolve the desired metal into the aqueous phase. The resultant slurry from the leaching process comprises of a solution pregnant in the metal salt and a barren ore. The first purification step taken after leaching is to wash the pregnant liquor solution (PLS) from the depleted ore. On the industrial scale, a set of between two to ten thickeners arranged in a countercurrent configuration is often used to carry out this separation (Perry & Chilton, 1973). The slurry is introduced at the head of the train and a wash solution at the tail. The two streams are pumped through each thickener countercurrent to one other. At each stage the residual PLS in the slurry is mixed and diluted down with the countercurrent overflow solution from the downstream thickener. The diluted slurry is fed into the thickener where the solids separate out through gravity sedimentation. The settled solids are channelled towards the underflow of the thickener by a rake mechanism and pumped downstream to the next thickener in the train. The outcome is the recovery of a PLS from the overflow of the lead thickener and a slurry of washed solids from the underflow of the tails thickener.

Jan 1, 2019

By D. W. I. Griffiths, J. C. Bélanger

"La Division Matagami de Minéraux Noranda inc. a profité de la construction de sa nouvelle mine (Isle-Dieu) pour continuer sa modernisation.L&apos;utilisation d&apos;automates programmables (PLC) s&apos;est intensifiée pour contrôler et automatiser de plus en plus d&apos;équipement dans ses minessouterraines, au concentrateur, dans les atelierset bureaux.Tous les PLC comrnuniquent entre eux et les IBM PC sont utilisespour exterioriser l&apos;information et faire Ie lien entre Ie personnel et les automates. Le système Central IBM 36 emmagasine les donnees traitees par lesPLC (a travers les PC). Ces donnees sont transmisesau programme d&apos;entretien de chaque equipement et compile les heures, cycles, tonnes, etc., fait imprimer automatiquement les feuilles d&apos;entretien préventif &apos;, etc.Les principales realisations adate et en progrès pour la mine Isle-Dieu sont:• automation complète du système de remblayage du concentrateur ala mine Isle-Dieu situee a2 km de la mine principale;• automation du fonctionnnement des ventilateurs qui comprendra la position des portes de ventilation, Ie chauffage, Ie débit, etc.;• automation des pompes, surveillance des sous stat ions électriques, concentration des gas (CO, SO2) à chaque niveau en tout temps et du propane à l&apos;entree d&apos;air frais;• tonnage et cycles par Ie treuil; et• contrôle d&apos;autres équipernents à differénts niveaux. D&apos;autres travaux furent egalement effectues par les employes, tels que:• la conversion d&apos;un Scooptram ST5A de diesel à électrique;• I&apos;installation complete de systèmes de depoussierage a I&apos;eau (scrubber) pour le concassage secondaire;• I&apos;installation d&apos;un marteau hydraulique avant les concasseurs coniques;• la rénovation des cellules de flottation ; et• l&apos;installation d&apos;un système de gardiennage par caméra. D&apos;autres projets seront effectués ou étudiés:• automation d&apos;un Scooptram"";• automation d&apos;un marteau hydraulique;• récupération de Scooptrarn; téléguidé:• gestion de l&apos;énergie, contrôle de la demande, surveillance et contrôle de l&apos;équipernent de machines fixes(compresseurs, boulloires, pompes à vide, génératrices, débits et pression d&apos;air, eau pour diagnostiquer les problémes, analyser les coûts;• concasseur portatif pour fabriquer de la pierre concassée pour utiliser dans les chemins sous-terre, et• utilisation de micro-ondes pour transmettre les images captées par camera."

Jan 1, 1990

By Z. D. Hora

Of four main gypsum areas in the province, commercial production has only come from Falkland and the Kootenay and Columbia River valleys of southeast British Columbia. The Windermere deposit in southeast B.C. has been the major producer since /948. Gypsum and anhydrite from the Falkland deposit is used principally in cement-making at Kam/oops. GYPSUM deposits in British Columbia are known from four different areas: the southeast part of the province in the proximity of the Kootenay and Columbia River valleys; Forgetmenot Creek astride the British Columbia - Alberta boundary near Intersection Mountain; Falkland; and O'Connor River north of Haines . To date, commercial production has only come from Falkland and the southeast part of the province. Gypsum deposits of southeast British Columbia occur in the Burnais Formation of Devonian age. Outcrops of gypsum and numerous sinkholes indicating its presence are scattered over large areas of the Stanford Range. Several properties have been examined by industry in both the recent and more distant past. Significant production is reported from only two deposits. The Mayook deposit, active from 1926 to 1929 and from 1947 to 1954, produced approximately 95,000 tonnes of gypsum. The Windermere deposit, which has been active since 1948, is operated by Westrock Industries and has produced more than 6.8 million tonnes of gypsum. The Burnais Formation is composed principally of well bedded, finely 'laminated gypsum but also contains thin lenses of black fetid limestone and dolomite. Part of the Formation consists of breccia with angular carbonate clasts in massive, coarse grained gypsum. In several exposures, the Formation appears 10 be from 200 10 400 m thick, of which more than 75 Industrial Minerals in Canada per cent is gypsum . In the Stanford Range reserves mineable by quarry methods are estimated to be approximately 450 million tonnes.

Jan 1, 1984

By H. M. A. Rice

"The Ainsworth mining camp is on the west side of Kootenay lake; British Columbia; 14 miles south of the town of Kaslo. It is in one of the oldest mining districts in central British Columbia; for mining started there in 1888. Its principal production was between 1905 and 1920. Activity since then has been sporadic. According to available records; some 222; 000 tons of ore had been produced from the camp up to 1942.GENERAL GEOLOGY Bedrock in the district consists of a succession of quartzite, quartz-mica schist, hornblende schist, and limestone of Late Precambrian, Carboniferous, and Triassic age. Most of the hornblende schists are of volcanic origin but some formed from related intrusions. The Nelson granodiorite batholith of Jurassic age borders the camp on the west. There is also a series of basic dykes of much later age."

Jan 1, 1954

By M. X. Yao, C. D. Opris, P. C. Patnaik, R. Liu, X. J. Wu

Two cobalt-based superalloys, Stellite 694 and Stellite 712, were functionally graded with reinforcement of titanium-carbide particle for high-temperature wear/corrosion applications. The designed composite specimens were fabricated using powder metallurgy (P/M) technique, combined with hot isostatic pressing (HIP). Calorimetric effects of the alloy powders were investigated using the differential scanning calorimetry (DSC) technique, which provided the basis of the sintering cycles designed. The phases present in the microstructures of the materials were analyzed using SEM and X-ray diffraction. The wear resistance of the materials was evaluated on a pin-on-disc tribometer. It was demonstrated that adding titanium-carbide particles to the alloys has increased significantly their wear resistance. It was also found that the HIP process had improved the density of the sintered specimens and thus enhanced their wear resistance.

Jan 1, 2004

By Paul D. Young, Michael J. Allan

"The Con Mine has been producing gold continuously since 1938. In 1990 laboratory and pilot plant investigations began into the use of pressure oxidation for treatment of an arsenic trioxide waste product from two previous roaster operations on the property. This led to the construction in 1992 of a 96 ton/day plant to treat a mixture of arsenic waste and flotation concentrate from the existing mill. The plant was commissioned in the fall of 1992.This paper describes experience gained in the commissioning and initial operation of the plant. The unique aspects of treating a hazardous waste product are described including special operating procedures to satisfy environmental and employee safety concerns. The paper further describes modifications made to the process flowsheet, to operating procedures and to materials of construction in the early months of operation."

Jan 1, 1994

By J. L. Rodrigues Bravo

The aim of this paper is to show the results of the study that relate the variations of the bismuth content in the Caraíba Metais&apos; electrolytic copper with the main electrolysis&apos; process variables as electrolyte flow rate and temperature, anode&apos;s impurities content, electrolyte composition, current density, etc and their combinations and factors like cathode washing, blend of materials entering rod plant&apos;s furnace, analytical methods, shot-circuit inspection, etc. Also, the methodology considered arsenic, bismuth and antimony mass balance in the electrolysis and their electrolyte&apos;s molar ratio relations as well as bibliographic references of refineries that operate in similar conditions. The results showed the circumstances with the major probability of causing bismuth content increasing in the electrolytic copper and the main operating conditions that have to be fixed for having less bismuth variation and lower content in the electrolytic copper.

Jan 1, 2007

By F. Golestani-Fard, A. A. Nourbakhsh

In this paper microstructural development of nitride-Bonded SIC refractories is reported in presence of Al203, Mg() and Urea additives .The samples were prepared by mixing, shaping and firing at 1400-1500°c in a controlled atmosphere furnace. Phase analysis, microscopic observation and mechanical evaluation were taken for microstructural investigations. The strength of samples doped with Al203 was first increased and then decreased at higher amount of Al2O3 additions. The addition of MgO decreased the strength while the urea showed an improving effect on strength. These phenomena could be attributed to microstructural evolution and mainly to liquid phase formation and grain morphology. It was found that the additives such as Al203, MO and urea could modify the microstructure in terms of phase formation and texture modification, which in terms influences the mechanical behavior.

Jan 1, 2004

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004

By G. E. Agar, R. Stratton-Crawley

"The applicability of a hydrocyclone model to simulation of the cyclone banks in a multi-stage sandplant circuit producing mine back fill has been demonstrated. The model ha~; been used in conjunction with a modular computer program for circuit simulation in order to study the effect of changes in the operating conditions. It has been shown that weight recovery to sand fill increases as feed percent solids decreases, and, to a lesser extent as pressure drop across the banks increases. An increase in apex diameter also causes an increase in weight recovery. Increased weight recovery must, however, be balanced against sump an1l cyclone capacity and dilution of sand fill by fines. The predicted results from circuit simulation were in good agreement with plant data.The model has been found to be applicable to widely different ores."

Jan 1, 1979

By Neda Zangeneh

Production efficiency from low permeability gas shales require techniques to optimize hydraulic fracture completions. One completion strategy involves the simultaneous or near simultaneous hydraulic fracturing of multiple horizontal wells to maximize the fracture network area and stimulated reservoir volume. However, changes to the in-situ stress field caused by an earlier hydrofrac on subsequent hydraulic fractures are not accounted for in traditional hydrofrac design calculations. Presented here are the results from a set of transient, coupled hydro-mechanical simulations of a rock mass containing two wellbores using the discontinuum-based distinct-element method. The results demonstrate the influence of stress-shadows generated by a hydraulic fracture on the development of subsequent hydrofracs from an adjacent well. It is shown here that these interactions have the potential to change the size and effectiveness of the hydraulic fracture stimulation by changing the extent of the hydraulic fracture around the secondary well.

Jun 1, 2012

By Hans Lundberg

During the last few years, geophysical methods have been introduced to aid mining geologists and mining engineers in locating mineral deposits. These methods have been developed as the result of investigations of various physical characters of minerals and rocks. In prospecting for ore-bodies, electrical methods have proved most successful. These methods are based on the great differences in electrical properties, and especially in conductivity, between ore minerals and rock minerals. The electrical resistance of the common minerals, rocks, and ores in ohms per cubic céntimeter is given in the following table: [ ] The first attempts at electrical prospecting were based on observing currents of polarization around certain ore bodies, which currents it was possible to measure. This method has been developed by Prof. Schlumberger and has been utilized by him successfully. He is represented on this continent by Mr. Sherwin Kelly, who has successfully operated the method here.

Jan 1, 1926

By M. S. Moats

As smelter feeds become more complex, the impurities that ultimately report to electrorefineries are changing. Many of these impurities collect in the electrolyte and must be controlled. As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the interaction between electrolyte composition and anode passivation can cause operational difficulties. To improve the industry&apos;s understanding of the passivation phenomena, the role of electrolyte composition was evaluated using commercial electrorefining anode samples. The electrolyte composition variables examined were copper, acid, nickel, arsenic, chloride, thiourea and glue. Finally, the role of non-commercially utilized additives, such as bromide and polyethylene glycol were studied. From this investigation, electrolyte parameters that inhibit copper dissolution through copper sulfate precipitation, copper oxide stabilization and/or absorbed species lead to accelerated passivation. Species that prevent passivation have the ability to complex cuprous ions. Possible mechanisms for the role of each.

Jan 1, 2007