Search Documents

In this paper, the use of electrochemical AC impedance spectroscopy (EIS) for in-situ diagnosis of high temperature PEM fuel cells is described. EIS was performed on single cell hardware, built in-house, using a fuel cell test station modified to operate up to 120°C and 30 psig. Electrode kinetics, membrane resistance, porous-layer and mass transport impedance of MEAs, assembled in-house, were measured at various current densities for the purpose of validating the test station and cell hardware, and for optimizing MEA and flow-field designs. The effect of temperature and humidity on the various impedances was investigated. Impedances obtained at lower and higher temperatures were compared to obtain insight into the issue of water management in operating fuel cells.

Jan 1, 2005

By Mario A. Morin

The last few years have seen considerable consolidation of the mining software industry and a trend towards greater planning and production control system integration, particularly for surface mines. The mining industry is starting to realize the benefits of system integration and will continue to drive the evolutions of these systems. Several trends can now be observed. The trends include application and system integration, data portability, ?intelligent? systems for support of decision-making activities, mine process-control and automation. While many planning systems are moving in this direction, there is room for considerable improvements. This paper will discuss these trends, examine the current state-of-the-art in mine design software, and identify areas where improvements should be made and why.

May 1, 2004

By Arne Renström

A fleet management system such as Minestar with CAES and Aquila could basically be defined as a tool for production control and distribution of drill and load maps, but should also be considered as continuous improvements and a never ending production study. The objective of production studies is to establish facts to be used for production improvements. In a mine operation there are many issues to improve and they spread from achieving productions plans, drilling precision, improved spotting while loading to equipment utilisation. This gives that there is not one single key value to present; we need to manage information presented on maps, as trends, graphs, tables and pre-calculated data for ?free-use? normally in spread-sheets to be able to turn data into useful information.

May 1, 2003

By Michel Aubertin

Using mine wastes as backfilling material for underground stopes has been a common practice for more than 60 years. Waste rock and tailings are used as filling materials because they are available at a reasonable cost to support the rock walls. Backfilling is also very advantageous because it reduces the amount of mine waste disposal on the surface. In underground mines, the backfill must first ensure stability of the opening, while increasing recovery of ore and minimising dilution. It is thus critical to accurately evaluate the pressures exerted on the walls and on the barricades placed near the base of the stope. In this presentation, existing solutions for evaluating the stresses on stope walls and barricades are briefly reviewed. The authors then present recently developed analytical solutions that take into account the stress transfer from the backfill to the walls in the stope and access drift. The stress state solution, which is based on arching theory, considers the influence of the stope geometry and barricade position within the drift. The method gives the pressure generated by partly or fully submerged backfill. The solutions apply shortly after backfill deposition, when the effect of pore water pressure cannot be neglected, and also for long term conditions under a fully drained state. Experimental testing and numerical modelling results are used to validate the proposed equations. Both numerical and analytical results show that the total pressure on barricades can be significantly increased by water pressure, while the effective stress is decreased (compared to dry or drained conditions). A discussion follows on the implications of the results for backfill applications.

Nov 1, 2008

By R. Harris

The vacuum thermal route for magnesium production today accounts for roughly 80% of the global production of magnesium despite significant investment in the competing electrolytic technologies, This is up from 30% of the global production 10 years ago and is all the more significant because global magnesium production has more than doubled in the same time, A review of the sophisticated anhydrous magnesium chloride production technologies provides some explanation for this sea change in technology usage, However, an examination of the economic factors provides compelling reasons, The present review outlines some of the salient strengths and weaknesses of the competing technologies, It also offers suggestion as to where future R and D and economic effort needs to be vested to improve the sustainability of the world magnesium market in terms of its value and impact.

Jan 1, 2006

By M. A. Kelly

Pit Optimisation using the Lerchs Grossman algorithm has been successfully applied in many deposits. Pit shells often form the basis for scheduling. Pre-assigned costs may not accurately reflect the costs that strategic scheduling decisions are based on. This can affect all mines, but is particularly true for commodities requiring blending. Adoption of Maximiser technology addresses these cost based scheduling and blending challenges.

May 1, 2007

By P. W. Ware

The majority of all refined copper is consumed to produce electrical conductors. Most copper conductors are drawn into wire from 8 mm ETP copper rod produced from high purity copper cathodes. Southwire Company has more than 40 years experience using, designing, fabricating and marketing a process for continuously producing ETP copper wire rod. This process is called the SCR® (Southwire Continuous Rod) process. Today, approximately half the copper wire rod produced in the world, or more than one third of all refined copper consumed, is produced using the SCR process. Southwire has sold 75 SCR copper rod mills to metal producers and wire manufacturers around the world. Southwire is North America's largest electrical wire and cable producer. Southwire operates a 48 metric ton per hour SCR® copper rod system in Carrollton, Georgia. This allows Southwire to provide technical support for existing SCR® system customers based on first-hand knowledge. Rod fabricators and their wire customers are always striving for copper rod that improves productivity. They are looking for improved surface quality, finer wire sizes and fewer wire breaks per ton of rod drawn. This paper will present a brief history of the SCR® process, a description and recent process developments.

Jan 1, 2007

By U. Martin

Advanced copper materials for conducting applications require an optimal combination of high mechanical strength at ambient and moderately elevated temperatures together with superior electrical and thermal conductivity. Mechanical alloying under repeated cooling of the milling vials in liquid nitrogen has been applied to produce ultra-fine grained (UFG) oxide dispersion strengthened (ODS) copper with a high yield strength at ambient temperature. In the present study ODS copper was manufactured by mechanical alloying of copper powder and 3% by volume of incoherent oxide dispersoids. During the high-energy milling a homogeneous distribution of fine dispersoid particles (diameter nearly 100 nm) can be achieved in the powder. Samples with a density of more then 97% of theoretical value were produced by uniaxial hot pressing under 650 MPa at 600°C for 20 minutes. The high yield strength at ambient temperature can be described by a linear superposition of the Orowan stress for particle hardening and of ultra-fine grain strengthening according to the Hall-Petch mechanism. Simultaneously, a best value of 75% IACS could be obtained for the electrical conductivity. The creep behaviour of ODS copper in the temperature range from 500°C to 700°C is described within the frame of diffusional creep deformation.

Jan 1, 2007

By M. Sabau

The Electrowinning Plant at INCO's Copper Cliff Nickel Refinery is a precious metals upgrading plant. The feed to the plant contains copper, nickel, cobalt, iron, significant amounts of precious metals and some impurities. Copper is the most abundant element in the feed. This paper describes the major equipment and process changes over the last twenty years, geared to improve the tankhouse operation, workroom environment and recovery of copper from the acidic solution. Copper is plated on to titanium blanks using explosion-bonded crossrods, animal glue as a levelling agent, and an organic surfactant for mist control. The installation of the stripping machine in 2001 required a number of changes: cathode and anode contacts were redesigned, flat bus bars were replaced with dog-bone type, spacer boards for cathodes and anodes were installed, longer anodes started to be used, and the plating cycle was extended from seven to fourteen days. A number of initiatives for improvement are being carried out. Explosion-bonded crossrods are being replaced with titanium-clad crossrods. The plan for the near future is to increase copper production by increasing current efficiency and current density. The possibility of lowering the iron concentration in electrolyte and changing the acid mist control method is being investigated.

Jan 1, 2007

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007

By Wataru Inagaki, Kozo Kawano, Tetsuya Ando

Cu–Ni–P alloys are the typical precipitation-hardening material. Thus, Cu–Ni–P alloys is expected to apply alternative materials for heat-exchanger tubes. Therefore, it was investigated that the effect of the heat-treatment simulated brazing on mechanical properties of Cu–Ni–P alloy in this study. The hardness of specimen as heat-treatment simulated brazing after solution heat treated (sht) was shown approximately 105 HV. The peak hardness and tensile strength of the specimen as performed aged at 498 K for 43.2 ks following the heat-treatment simulated brazing achieved at approximately 140 HV and 260 MPa, respectively. From these results, it is expected the application to higher-strength tube for heat-exchanger after brazing in a furnace. INTRODUCTION Copper prices have increased dramatically with high in recent years. At the same time, manufacturing industries are required to reduce the environment load by reducing the wall thickness of the copper tubes used in heat exchangers. High-strength copper alloys are developed for reducing the wall thickness, while achieving high strength, of the copper tubes. Moreover, excellent workability and corrosive durability are also required by these copper tubes. Furthermore, the brazing, which are carried out at about 1050 K during the assembly process of heat exchangers, leads to grain growth and re-solving of additive elements. Nomura et al. achieved a tensile strength and Vickers hardness of approximately 260 MPa and 110 HV, respectively, after aging at 723 K for approximately 36 ks. Tamagawa et al. studied that the strength of Cu–Ni–P alloy rapidly increased at about 125 HV during the cooling process after the heat brazing due to the Ni2P precipitates sized 5–10 nm. Furthermore, Inagaki et al. achieved a Vickers hardness of approximately 130 HV by aging at 498 K for 10.8 ks. In the present study, we focused on the lowest aging temperature of 498 K in the previous study, and investigating the effect of heat-treatment simulated brazing on the mechanical properties of the Cu–0.93 mass%Ni–0.24 mass%P alloy.

Jan 1, 2019

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By K. D. Peaslee, J. M. Soto, IéDé Smith, A. D. Saikia

Spinel-forming refractories reduce penetration of metal and slags through a tightening of the lining resulting from the volume expansion associated with spinel formation. Sintered spinel is often added to reduce the overall volume increase that results. Tests were carried out to evaluate the difference between performance in spinel¬forming and spinel-containing refractory mixes. Eight refractory linings, one (1) pure magnesia, three (3) magnesia-base spinel-forming and four (4) alumina-base spinel- containing dry vibratable mixes, were tested for four hours in contact with a low-carbon, low-manganese steel in a coreless induction furnace at temperatures in excess of 1600°C. Afterwards, sample were cut, and wear and penetration were measured. For magnesia-based mixes wear was minimized using 20-30wt. spinel formation although further experiments are required to determine the optimal value. For alumina-based mixes, there seemed to be an optimal ratio of spinel added to spinel formed that minimized penetration and wear at the slag line. Sidewall accretion occurred and the accretion was the highest for the mix with the ratio of spinel formed to spinel added near the optimum value. Therefore to design an optimum refractory mix the benefits of higher ratios of spinel added to reduce penetration and wear at the slag line will need to be balanced with the tendency to form accretions on the sidewalls of the furnace.

Jan 1, 2004

By Bob Butler

Brunswick Mine has been involved in a comprehensive research program investigating site specific aspects of thiosalt management to eliminate its adverse environmental effects. Minimum annual reagent cost estimates for thiosalt treatment using hydrogen peroxide and sodium hypochlorite are $400K and $1.5 million respectively. Also, minimum costs for the use of bicarbonate to buffer the pH depression associated with thiosalt oxidation in the receiving environment is in the order of $400K annually. A design of experiment (DOE) research program identified that natural UV radiation, temperature, DO and water chemistry are key factors influencing the natural oxidation rate of thiosalts within Brunswick?s water management system. A DOE surface response model was used to describe the thiosalt oxidation kinetics, which were then used to develop a predictive oxidation model for thiosalt and pH control of the mill?s reclaim water system.

Nov 1, 2002

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By D. D. Rodier

The mining and metals indusrty's approach to Sustainable Development has dramatically evolved in response to growing concerns for the future ability of the industry to continue as a vital contributor to the sustainability of society. This paper will review recent trends,including the overriding global issues impacting the sustainability of society and what the Global responses to these issues have been. This will be followed by the response of the mining and metals industry to better contribute to sustainable development, starting with the landmark independent study the MMSD Study and the creation of a global policy voice for the industry, the Intrenational Council for Mining and Metals (ICMM). The tenants of the ICMM's Sustainability Framework guide this organization's work with the overall themes of performance improvement, leadership and leverage through partnerships. The paper will then conclude with a brief description of an example of what, an individual company, a service provider to the industry, is doing to assist in the industry's efforts.

Jan 1, 2007

By N. Ntakaburimvo, C. Allaire

This paper presents an innovative experimental set-up which simulates refractory degradation by separate and simultaneous action of abrasion, erosion and partially or totally immersion corrosion whether dynamic or static. It also presents abrasion testing results obtained from five commercial aluminosilicate refractories used in aluminium melting and holding furnaces. Abrasion wear was quantified by measuring the weight loss and the depth of wear, as well as by determining materials properties degradation, such as the residual rupture force and the residual modulus of rupture. Results were correlated to as- fired materials properties, such as rupture force, flexural strength, elastic modulus, toughness, and apparent porosity; in order to establish which property could be used for refractory abrasion wear prediction. They were also related to the critical length of pre-existing defects and to those generated by the abrasion process. Positive correlation was established between abrasion resistance and mechanical properties, particularly for refractory castables. For similar mechanical strength, the castables tested offered less abrasion resistance than the brick sample.

Jan 1, 2004

By C. J. Cattarello

"The Langmuir Mine is located seventeen miles south-east of South Porcupine in Langmuir Township.The property was developed as a Joint Venture between Noranda Mines Limited and the International Nickel Company of Canada with Noranda responsible for the operation of the property.The Mine came into production in June 1973 at a rate of 700 tons per day of nickel ore.MINING The mining method selected for the Langmuir Project was a sub-level retreat method. This consisted of driving sub-levels longitudinally in the ore body at 35 foot, intervals with the sub-levels being connected by a ramp from each main level for the use of trackless mining equipment.GENERAL GEOLOGY OF THE LANGMUIR MINE The deposit is situated about 1,000 feet west of the shore of Carmen Bay at the south of Nighthawk Lake in Langmuir Township. The area is underlain by andesite and rhyolite flows with iron formations which are intruded by gabbro, diorite, peridotite and late precambrian diabase dikes."

Jan 1, 1975

By Pierre Boulanger

This paper describes a generic technology for modeling in real time the various operations of surface mines. Based on various sensor fusion techniques and high-speed network, a virtual reality model of a mine capable of representing not only static infrastructures but also mobile equipment such as trucks and excavators is created. The modeling technique deal with a wide range of sensors such as survey data, satellite pictures, ore concentration, machine condition indicators, video, sound, real-time GPS locator, range sensor, etc. The model created allows for every piece of information to be displayed in context allowing for a better temporal and spatial correlation of events by mine operators, planners, and supervisors. Syncrude, a Canadian mining company located in northern Alberta, is planning to use this technology, not only to understand oil sands mining processes better, but also to give decision-makers better access to the timely, accurate information from the field that they need to make informed decisions.

May 1, 2001