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By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By Edmond Chow

Shovel bucket blast fragmentation analysis is an alternate way to assess blast performance and its effects on downstream mining processes. A camera is installed on the boom of cable shovels, and the stick of hydraulic shovels. Images are captured automatically as the shovel digs, and are processed to acquire rock size information. The automatic data acquisition makes this method safe to use with minimal manual labour. It also allows for a large set of sample data to be captured from both the surface and the interior of a bench face. The system has been deployed in several mines to provide an objective assessment of blasting performance. Images are captured from their cable or hydraulic shovels. The images are grouped into sets based on the shovel location and time to match the fragmentation to specific blasts. Blast fragmentation reports are created for each blast after reviewing the results. Measuring blast fragmentation from the shovel bucket proves to be an effective alternative for blast performance assessment with unique advantages. The blast fragmentation information has been valuable to the mines, and the mines have begun adopting it into their operations.

May 1, 2011

By M. Honarmand, Z. Moezifar, H. Ranjbar

Abstract - The Sar Cheshmeh area covers an area of 640 km2, and is located in the southern part of the Iranian Volcanic-Sedimentary Belt. ETM+ images have been used for alteration mapping. The Crosta method was found useful for enhancing exposed areas containing hydroxyl and iron oxide minerals. However, field checking has shown that this method is not able to identify all the known areas of hydrothermal alteration. Many of these altered areas are also not clearly resolved in the geophysical data. In order to improve resolution of such areas, integration of remote sensing and geophysical data may be helpful. The Darrehzar Cu deposit was chosen as a control area. The data have been divided into two sets: explanatory and target variables. The explanatory data are Landsat hydroxyl and iron oxide images and airborne geophysical data (K, U, and Th total counts, and total magnetics). The target variables are rock geochemistry and ground geophysics. Data analysis and integration of geophysical and remote sensing data were performed using directed principal components. This technique is found to be useful for the delineation of hydrothermally altered areas with more confidence.

Jan 1, 2002

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By G. P. Holmes

"Bell Copper is situated (Latitude 55°0''N, Longitude 126°14W) on Newman Peninsula on the east side of Babine Lake at an altitude of 2,450 feet above sea level. The mine site is approximately 170 miles north west of Prince George and 40 miles east of Smithers. Access to the property is by way of 30 miles of paved road to the Village of Granisle on the west shore of Babine Lake and then a further 9 miles of unpaved road to Bell Copper's west dock. The two mile lake crossing is made using a tug and barge. A compressed air bubbler system maintains an ice free channel for the barge during the winter months.Temperatures range from summer maximums of around 32 °C to winter minimums in the region of minus 40°C. Long periods in winter may be spent with temperatures in the range of minus 15""C to minus 28°C. Freezing temperatures usually start in October and last for six months. The lake normally freezes over in mid December and the ice breaks up in mid May. Snow accounts for approximately two t11irds of the annual precipitation of twenty-one inches."

Jan 1, 1976

By Zainelabdin Khalid Zainelabdin Elfaki

The influence of partially replacing cement with marble waste on the workability and compressive strength of concrete bricks was investigated. Three replacement percentages, 10%, 20% and 30% weight marble waste, were used with different curing times of 7, 14 and 28 days. Two specimens were prepared for each percentage and curing time. For this study, marble powder from the Mining House Company in Saudi Arabia was used. It was observed that the replacement of cement in Concrete brick with marble waste enhanced the loading strength and the workability of the prepared concrete bricks. It was also observed that 20% replacement of cement with marble waste was the best replacement percentage compared to the other replacement percentages tested. Marble waste from manufacturing companies, either in powder, sludge or slab form, has negative impacts on the environment. In contrast, reusing marble waste has both economic benefits (i.e., selling the marble waste) and lessening the need for raw resources.

Jan 1, 2014

By T. R. Bieler

"Hot forming and superplasticity in powder metallurgy aluminum alloys and composites is reviewed. The effects of alloy composition, particulate composition, size, and size distribution is summarized. The role of climb distance for recovery is described in connection with the size of strengthening phases. In materials with fine strengthening phases on the order of one micron or less, high strain rate superplastic deformation processes are likely. However, the quality of superplastic deformation depends on the prior processing history, and these effects are reviewed. Very few data describing the effects of hot forming history on post-forming properties exist, but some results emerging in the literature are compared.IntroductionHot deformation in aluminum based materials is done for several technological purposes, such as thermomechanical processing to alter mechanical properties of simple forms, and/or final shaping operations to produce a complex shaped part by means of extrusion, forging, or superplastic forming. In the interest of improving the mechanical properties of aluminum based materials, two microstructural design strategies are commonly used, dispersion strengthening, and composite strengthening. The introduction of fine, stable dispersions is commonly done for high temperature strength, and the dispersions are typically ceramic particles in the range of 10 nm to 1000 nm in volume fractions around 5 vol.% (Higashi et al., 1990; 1991a; 1991b; 1992; Bieler and Mukherjee, 1990; Otsuka et al., 1987; Bieler et al., 1991; Oliver and Nix, 1982). Alternatively, composite strengthening strategies using 10-40 v% of 3 µm to 40 µm ceramic particles provide high modulus and high strength aluminum based materials (Midling and Grong, 1995; Lloyd, 1994; Subramanian et al., 1995)."

Jan 1, 1997

By P. W. A. Walker

"The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.216% W03 and 0.020070 Mo. The deposit is uneconomic at current tungsten prices. IntroductionDuring the 19705, Union Carbide Corporation was a major producer, processor and supplier of tungsten and derivative products to end-user manufacturing industries. The corporation owned and operated two tungsten mines in the United States, and one in Brazil, and operated a plant in the United States which produced ammonium paratungstate (APT) which is an intermediate product in the production of tungsten wire and tungsten carbide for cutting tool insets and hard facings. In 1975 the three mines were ageing with short-life reserves and high production costs. The world market for tungsten was buoyant and prices, in constant dollar terms, had risen steadily over the past 15 years (Fig. 1).It was against this background that a decision was made to explore for tungsten in North America, South Mrica, Australia and Brazil."

Jan 1, 1994

By Mike D. Riley, Alan V. Bell, Ernest K. Yanful

Acid mine drainage (AMD) research under the MEND program has been ongoing since 1988 at the Heath Steele Mines waste rock piles including sulphide material, outside Newcastle, NB. In 1989 approximately 10,000 mt of waste rock was placed on a prepared sand base with an underlying impermeable membrane. The waste rock pile was heavily instrumented for measuring oxygen concentrations and temperatures. In September 1991, a composite soil cover designed for the Heath Steele climatic conditions, using local soils, was placed over the pile, creating a totally enclosed system. Moisture content and oxygen probes were installed within the composite soil cover to monitor changes within the soils over time, while two large-size lysimeters were installed below the cover to monitor the hydraulic conductivity of the cover. The waste rock site has been monitored on a monthly basis since installation of the cover, for performance of both cover and waste rock. The monitoring shows very clearly that the placement of the composite soil cover has had a major impact on the generation of AMD. Major reductions in temperature and oxygen concentrations within the waste rock pile indicate that the cover has significantly inhibited the oxidation reaction that generates the AMD. Performance data have shown that the cover has maintained its integrity under the climatic conditions of the area.

Jan 1, 1995

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By George Dogbe

Open pit optimization forms the basis of mine design, production planning and construction of mine facilities. The negative effects of this phase may include substantial reductions in ore recoveries, relocation of waste dumps and surface infrastructure, extraction of unwanted waste, with a cumulative effect on mine value reductions. As a result, this area has received significant research focus using linear and dynamic programming, heuristic, genetic and stimulation algorithms and the graph theory. These algorithms are derived from rigorous mathematical models, but they are built on the assumption that all the periodic production capacities are extracted at the time of analysis. This assumption weakens the models because mining occurs over significant time period. In order to develop a comprehensive model that accounts for the timing of material extraction, the current models, which are built on the economic block value (EBV) concept, must be modified to account for time. In this paper, the authors develop a model of the optimization problem using the 2-D Lerchs-Grossmann?s optimization algorithm. This model is used to investigate the effect of periodic discounting on the optimal pit layout design by designing an integrated pit optimiser (IPO) that incorporates ?production scheduling?. IPO uses the ensuing discounted economic block value (DEBV) as a basis for the pit optimisation process. The time-dependent model is compared with a time-independent model. The results show that discounting has no effect on the optimal pit contour although the reported pit value is overstated if the EBVs are used instead of the DEBV. The authors, however, believe that this conclusion may not be general and could have been influenced by the nature of ore body geometry and the proposed mining strategy.

May 1, 2004

By A. J. Sinclair

Abstract-Exploratory data evaluation is an essential part of every high quality, mineral inventory estimate. Efficient analysis involves a thorough organization of available quantitative data that are the basis of the estimate and perhaps the formation of composite grades. Data organization and evaluation can involve more than 50% of the time necessary to conduct a mineral inventory estimation. The principal purpose of exploratory data evaluation in mineral inventory work is to improve the quality of estimation by providing insight into characteristics of the variables under investigation. Specific aims include: (1) to recognize and eliminate errors; (2) to provide a comprehensive knowledge of the statistical characteristics of all variables of interest for resource/reserve estimation; (3) to document and understand the interrelationships among the variables of interest; (4) to recognize systematic spatial variation of variables such as grade and thickness of mineralized zones; (5) to recognize and define distinctive geological domains that require independent estimation of mineral inventory; (6) to identify and characterize outliers; and (7) to evaluate similarity/dissimilarity of various types of raw data, especially samples of different supports. These aims are not mutually exclusive but they can all have their own impact on resource/reserve estimation. Error must be minimized. Individual variables can have characteristics that lead to different decisions in the course of estimation. Similarly, interrelations of variables might contribute to the ease (or difficulty) with which estimates of several variables can be obtained. Trends can impose the need for two or more domains, each of which might be estimated independent of the others. Outliers, a perennial problem, require detailed evaluations because they impact on reserves much out of proportion to their abundance. Data, of widely different supports, generally must be standardized if all are to be used for purposes of estimation.

Jan 1, 1998

By M. J. Bennett

"The Quemont mill is primarily a differential flotation plant in which copper, zinc ·and pyrite concentrates are recovered. Native gold and silver are associated in the form of very small particles with all the minerals contained in the ore: chalcopyrite, sphalerite, pyrite, pyrrhotite and even with the gangue rock.The proportion of the precious metals associated with chalcopyrite is such that the best recoveries we can obtain in our copper flotation concentrate are about 68 percent of the gold and 51 percent of the silver in the ore. In order to improve the total recoveries of precious metals it is necessary for us to float a pyrite concentrate and treat it by cyanidation for the extraction of whatever gold and silver we can obtain in this manner. In spite of the fact that we regrind this concentrate to 75 percent minus 325 mesh, it is difficult to extract much more than half of the gold and silver present in the pyrite concentrate by cyanidation, due to the extremely fine association of the precious metals with the pyrite.In 1963 we produced 86, 853 ounces of gold by flotation alone, and 14, 581 ounces by cyanidation. These amounts are equivalent to 67. 74 percent and 11. 37 percent respectively of the total gold in the mill heads. Comparable figures for silver are 325, 598 ounces by flotation and 99, 448 ounces by cyanidation; and 51.37 percent and 15.69 percent respectively.The total annual value of these metals (ie. $4, 000, 000) qualifies Quemont as a precious metal producer of some note. On the other hand, it is evident that by far the greater proportion of our gold and silver production is contained in copper flotation concentrates. When the income from our copper and zinc values is also considered, the much greater importance of flotation compared with cyanidation in our operation may be appreciated. This explains why most of our work on controls has been carried out in our flotation mill, rather than in our cyanide plant. Some of the controls installed there could, of course, be employed in either type of operation."

Jan 1, 1964

By Chunlin Chen

Published data on thermodynamics of tin in liquid copper, matte and slag have been reviewed, assessed and used in development of thermodynamic solution models of melts. The developed model/database was applied in modelling the Sn deportment in primary copper smelting and e-waste melting processes. The results show that Sn can be removed from the matte through evaporation of various volatile Sn species (with SnS the most volatile) and slagging during copper smelting. The Sn removal increased with increasing matte grade due to the increased gas and slag volume. In the e-waste smelting process, fluxing strategy was developed for smelting e waste to produce a slag with reasonable liquidus and viscosity. Modelling results show that very low amounts of Sn reported to the gas phase due to low S, hence low SnS partial pressure in the system. The black copper produced could contain a few percent of Sn depending on the oxygen potential. The Sn in the black copper could be removed to the slag phase during anode refining. INTRODUCTION Tin is an impurity element commonly found in copper ores, which will be dispersed into various solid, liquid, and gaseous streams during the pyrometallurgical processing of copper. Tin alloy is widely used in electronic soldering due to its low melting point. The growth in treatment of recycled e-waste through primary and secondary copper smelting has led to an increased tin input to the smelting system. Therefore, the deportment of tin between phases is of great interest to the operators of modern smelters. Multi-Phase Equilibrium (MPE) is a thermodynamic package developed by CSIRO for simulating reactions between phases in multi-component and multi-phase systems (Zhang et al., 2002). Over the years the capability of the MPE model has been extended to cover the behavior of a large number of elements in high temperature system (Chen, Zhang, Wright, & Jahanshahi, 2006). In the present paper, the thermodynamic data on tin in liquid copper, matte and slag have been reviewed, assessed and used in the development of a database for Sn slag, alloy and matte phases. The model/database was applied in modelling the tin deportment in primary copper smelting and e-waste smelting processes. The aim of this study is to provide a better understanding of the chemical behaviours of tin in high-temperature copper processing and e-waste smelting.

Jan 1, 2019

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N'- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By Paul MacLean

MAC TSM ?Mining and Biodiversity Conservation 1.Corporate biodiversity conservation policy, accountability and communications 2.Facility-Level biodiversity conservation planning and implementation 3.Biodiversity conservation reporting ?Activities indicative of level AA -AAA (formerly 4-5) performance: ?Independent verification ?Integration into broader business strategy and planning processes ?Engagement with communities of interest ?Commitment to actively partner with other organisations for biodiversity conservation

May 1, 2011

By Juan Pablo Vielma

In this work we study how to incorporate risk control to the generation of ultimate pits when orebodies are modeled through a finite number of conditional simulations. To control risk we consider a chance constraint on the value of the ultimate pit. We incorporate this measure into the generation of ultimate pits by solving a stochastic programming version of the ultimate pit problem. We compare this stochastic programming problem to previous approaches such as generating the ultimate pit for each simulation and the hybrid pit approach introduced by Whittle and Bozorgebrahimi. We also study the effect of using different number of simulations in the generation and evaluation of ultimate pits.

Oct 1, 2009

By Michael Samis

NOFLEX valuation results ? CF deviations and net CF risk discount factors ??Cash flow deviations indicate average cash flow variability. ??Net cash flow riskdiscount factors (NCFRDFs) indicate the size of the risk adjustment applied to a cash flow. NCFRDFs profile should change with variations in cash flow uncertainty since the risk adjustments applied to the project cash flow reflect investor sensitivity to uncertainty.?DCF and RO will often produce different NCFRDFs for the same project since they use different methods of risk-adjustment.

May 1, 2006

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By Chih-Huey Lin

The Au/?-Al2O3 catalyst prepared by AuCl3 impregnation is subjected to the influence of residual chlorine after an oven drying. A post-impregnation NH4OH treatment was able to eliminate chlorine, and to reduce the cluster size of Au moiety. However, the CO oxidation activity was not increased by this post-impregnation NH4OH treatment. This suggests that certain metal-support interaction (MSI) is the determining factor for the activity of Au catalysts. Thermal treatment under H2, O2 or He was attempted to increase MSI of the prepared catalyst with or without the post-impregnation NH4OH treatment. No significant activity enhancement was found but the TPD analysis suggests that a H2 treatment has a higher chance to induce MSI.

Oct 1, 2003