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By A. L. Holloway, N. M. Soonawala, L. S. Collett

"Since the late 1970s, a major R&D program has been under way in Canada to assess the concept of disposing of nuclear fuel wastes in deep plutonic rock. Atomic Energy of Canada Ltd . (AECL), a federally-owned corporation, has been given the responsibility of directing this research (Rummery et al., 1983).The Underground Research Laboratory (URL), constructed in a granite pluton 15 km east of Lac du Bonnet, Manitoba (Fig. 1) is a major component of the Canadian Nuclear Fuel Waste Management Program. A diverse geotechnical experimental program is being carried out during both the construction and operating phases of the URL. This program involves detailed geological mapping, rock mechanics and hydrogeology studies, and geophysical surveying, to characterize the rock mass surrounding the shaft, and it has been described by Simmons et al. (1983). As part of the construction-phase program, ground-penetrating radar (GPR) surveys are being carried out during excavation, in an attempt to delineate fractures both ahead of the excavation and behind the walls of the excavation. This paper presents the results of surveys performed during shaft excavation and describes a procedure for plotting the data.Ulricksen (1982) cites examples of radar surveys to evaluate surficial deposits, such as peat, sands and gravels, and cavity detection in subsurface hard rock. Fowler (1981) used radar for fracture and clay vein detection in coal seams.In Canada, pioneering work in GPR has been done by Annan and Davis since the mid-seventies (Annan and Davies, 1976). Their work concentrated on problems relating to permafrost in the Arctic ."

Jan 1, 1986

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O'fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By J. X. Guo, A. Pindred, J. Moore

"Two modified centrifugal flotation cells (CFC), Q2 and Q3 models, have been developed for froth flotation. The operating mechanism of Q2 uses a rotating bowl to create a centrifugal force on the feeding slurry. Froth concentrate is collected on the central top of the cell and tailing is discharged along the top edge of the rotating bowl. The Q3 utilizes a vertical rotating feed pipe to introduce the feed slurry into a stationary flotation column cell. A centrifugal force is also created by a rotating pipe for the feeding slurry. Froth concentrate floats over the cell and tailing discharges through the bottom of the cell. The centrifugal force causes the flotation recovery of fine particles from CFC to be higher than from the conventional cell. The major operating variables of CFC are the rotating speed, air flow rate into feed slurry, and slurry feeding rate etc. Flotation tests have been carried out on synthetic mixtures of galena-silica and chalcopyrite-silica, as well as some natural base metal ore samples. Parallel tests were also conducted on a conventional flotation cell. The comparative test results demonstrated that both Q2 and Q3 have the advantage of higher recovery of finer than 10 µm mineral particles, which are very difficult for the conventional non-centrifugal flotation cell to recover. The grade-recovery curves produced from CFC are equivalent to or better than the conventional flotation cell. There is a potential in the future for the CFC to be employed in slime flotation.1. IntroductionA centrifugal flotation cell (CFC) was originally developed by Clean Earth Technologies [I] to separate oil from water and was subsequently applied in froth flotation. Figure 1 illustrates the design of the original CFC, in which a vertical feeding pipe is attached to the center part of a rotating drum and a stationary shell encloses it to direct the float froth and tailing discharge. The slurry flows down to the bottom of the spinning drum, gets in touch with a screen of air bubbles and then migrates outwards under the effect of centrifugal force. After the mineralized froth enters the rotating cell, it is pushed back to the inner surface. The overflowing froth is collected in the froth launder while the tailing slurry is discharged through orifices along the outer rim of the drum."

Jan 1, 1998

By Vern Evans

Saskatchewan has historically been recognized for farming, but in 1943 while drilling for oil, potash was discovered. The initial attempt to gain access to the potash beds was unsuccessful, however, subsequent attempts were successful and today there are ten operating potash mines in Saskatchewan. In this paper we will provide a brief overview of the historical and current Potash industry in Saskatchewan.

May 1, 2011

By M. A. Sobhi, L. Li

With the continuous reduction of mineral resources at shallow depth, more and more mines have to go deeper beneath the earth's surface to reach the ore zones. This increase in mine depth leads to a natural stress increase, which also raises the stresses around mine openings. This may result in ground instability, including the risk of rock bursts or exceedingly large opening closure. Stope backfilling is a well known solution to improve the ground stability condition. It also has the advantage of reducing the mining wastes disposed on surface, thus helping to reduce the environment impact from the industry. However, most available solutions for backfill design were developed for an isolated stope without taking into account the influence of mine depth, except for a few numerical analyses performed recently by Falaknaz and coworkers for the case of multiple backfilled stopes laying in the same level. In this paper, a numerical study is carried out to evaluate the stresses in backfilled stopes overlying a sill mat. The mine depth and the excavation of the underlying stope below the sill mat are both taken into consideration. Compared to the case of a single isolated backfilled stope, the obtained numerical results show that the stress magnitudes in the overlying backfill are considerably increased due to the excavation of the underlying stope. In general, the stresses increase with mine depth and backfill stiffness, but decrease with an increase in the surrounding rock mass stiffness. These results indicate that the barricade and sill mat backfill design should take into account the excavation of the underlying stope and the mine depth.

Jan 1, 2015

By Hani S. Mitri

Strainbursts in brittle rock are common to deep underground mines. The state of stress at the boundary of mine openings is dictated by a biaxial stress/loading condition. This paper reports the results of a series of biaxial compression tests carried out on 100 mm cubic samples of norite rock, under different horizontal-to-vertical stress ratios. The results indicate that the biaxial compressive strength is considerably higher than the uniaxial one. It is found that the norite sample behaviour under biaxial loading mirrors field behaviour where shearing and progressive spalling of the opening boundary are observed prior to strainbursting. Sample failure is initiated by rock spalling at the sample free faces, i.e. in the plane of biaxial loading. Finally, it?s the out-of-plane shear failure mechanism that causes the sample to collapse. Shear failure takes place violently and abruptly and is accompanied with considerable audible noise.

Apr 1, 2005

By E. L. Day

"In the early 1930s during the course of test work with a simple gold ore, it was evident that the time required to dissolve the gold by cyanidation was very much longer than should have been needed theoretically for the maximum size gold particles in the ore, A similar conclusion appeared to be valid for other gold ores. In a cyanidation system there are many factors which can influence the dissolution rate of gold, and a decision was made to investigate the more obvious variables, because a literature survey at the time showed that with the exception of the work of Yamazarki on the dissolution of silver in cyanide solution, virtually no attention had been given to this subject, Our work was not reported because the intention was to do this on completion of the Study, but owing to the demands on the Section's personnel for other work the investigation was never completed. Although other investigators have since studied the problem, the methods which we adopted and some of the conclusions may be of interest to metallurgists concerned with gold ore treatment.Form of GoldExperiments with gold ores were not possible because of the number of uncontrollable variables present in a gold ore-cyanidation system, therefore pure metal and reagents were used. Initially some experiments were carried out with gold leaf, but it was soon apparent that metal in this form was unsuitable because the uneven thickness of the leaf caused it to break up into pieces and. there was difficulty in determining precisely when complete dissolution had taken place, Numerous factors both expected and unexpected were found to influence considerably the results and much experimental work was necessary to establish the procedures which were finally adopted, Experiments were carried out with gold in the form of foil, wire, rings and sols. Finally, gold foil in the form of cylinders was adopted for most of the experiments although some work with gold in the sol form was included in the programme. Also some experin1ents were carried out with a gold ore to see if effects which were obtained with sodium chloride on gold sols were applicable to gold ores."

Jan 1, 1967

By G. W. Toop

"The Cominco smeller in Trail, British Columbia, is a large integrated lead-zinc production facility. In the plant description, emphasis is given to the pyrometallurgical operations including zinc concentrate roasting, lead singer-blast furnace processing and silver refining. Production figures for the main metal products - zinc, lead, silver and gold - are provided.IntroductionIncorporated in 1906, Cominco Ltd. is an integrated natural resource company with principal activities in mining, smelting and refining, mineral exploration, fertilizer production and electrical power generation.Cominco is one of the world's largest producers of zinc and lead, accoW1ting for about 10070 of mine production in the western world. The company also produces and sells copper concentrate, copper sulphate, copper arsenate, sodium antirnonate, silver, gold, cadmium, bismuth, indium, and germanium dioxide and a range of fertilizers and sulphur products.Zinc OperationsRoastingThe roasters currently treat about 1400 t/d of zinc concentrates. Over half of the total concentrate treated originates from the Red Dog Mine in Alaska. During the summer, concentrate is shipped from Alaska to Vancouver where it is loaded into rail cars and hauled inland, transferred to trucks and delivered to Trail. The remainder of the roaster feed is made up of Sullivan concentrate and various custom concentrates. These arrive either by train or by truck.There are three roasters available for roasting the concentrate. The two major roasters are Lurgi fluid bed units. Each Lurgi roaster can process concentrate at about 1:7 tonnes per hour (tlb). A smaller Cominco suspension roaster with a capacity of 10 tlb is also used. The flowsheet for the high temperature section of the fluid bed circuit is shown in Figure 1.Concentrates fed to fluid bed roasting are conditioned with 7 1/min water to give 8% moisture in feed. Two slinger belts throw the mixture into the fluidized bed. The fluid bed roasters are 10.4 m in diameter with a bed depth of 1 m. Grate area is 84 m2• Normal operating conditions include bed temperatures of 930°C to 950°C, fluidizing air at 750 Nm3/min and a wind box pressure of 2000 mm H2O."

Jan 1, 1994

By Daniel Gendron, Luc Morin

"Concentrate sampling is a growing concern in the world's mining and smelting industry. The main modes of transportation for concentrate to the smelter are by truck or rail car in a bulk form, thereby limiting access to sample extraction equipment. In many cases, concentrate is shipped to a smelter by several suppliers therefore requiring individual manipulation of different customer samples in a safe and reliable manner. The Heath & Sherwood Bulk Product Sampler offers this feature as well as an economical and effortless way of obtaining samples in rail cars or truck boxes.In 1994, Noranda Metallurgie in Rouyn-Noranda, Québec purchased a self contained Bulk Product Sampler to extract samples directly from inside rail cars before unloading the concentrate. After testing and comparing the results with the conventional sampling method, the bulk product sampler proved to be a practical and advantageous solution for concentrate sampling both for the customer and smelter. Since its installation at the Horne smelter in Rouyn-Noranda, the Bulk Product Sampler has been steadily used on rail cars which contain concentrates from around the world."

Jan 1, 1996

By L. Tang

A seismic monitoring system was installed in 2005 at Dongguashan Copper Mine, the deepest metal mine in China. Based on the seismic events monitored in situ, the possibility of rockburst prediction and prevention is investigated in this paper. The characteristics of space-timeintensity of mining-induced seismicity and the seismic response to mining are studied in detail using the seismic data in Dongguashan Mine. A conceptual model and a criterion of assessment of hazard seismic nucleation are proposed for Dongguashan Mine. In this model, the mine seismic stiffness method is adopted for rockburst prediction within the framework of the unstable failure theory. To analyze rock failure cases in Donggauashan Mine, the rate of the ratio of stiffness of rock in nucleation area to its surrounding area is proposed as a criterion for rockburst prediction.

May 1, 2009

By G. R. Guillet

Important resources of kaolin, refractory clay and lignite, not found elsewhere in Ontario, occur with quartz sand of glassgrade quality in unconsolidated Mesozoic sediments of the Moose River Basin in northeastern Ontario. These materials comprise the Mattagami Formation of Lower Cretaceous age, which overlie in some places a thin Jurassic unit and a thick Paleozoic section, and underlie as much as JOO m or more of glacial and marine sediments and a uniform capping of muskeg. The Mallagami Formation is known from deep boreholes to exceed 100 m in thickness and to consist of two phases: an earlier Type A unit of dark-coloured carbonaceous clays and lignite, and a later light-coloured (Type B) unit of kaolin-bearing quartz sands and bright-coloured refractory clays. Remoteness, poor access, and difficult physical environment have inhibited the exploration and development of these resources.

Jan 1, 1984

By Grant L. Anderson, Richard C. Rice, Richard L. Jentgen

"Data for underground mine-hoist ropes determined in the Ontario Special Rope Tests were obtained, encoded and analyzed statistically. Prior 10 refined statistical analyses, these data were subjected la characterization studies and preliminary analyses to allow trends to emerge that could be used to guide and facilitate the refined analysis. The data were characterized by determining distribution s for a wide range of variables including remaining strength, service life in terms of lime and hoisting cycles, outer-wire torsion values, elongation during tensile testing, diameter reduction, location of strength loss and the strength lasses associated with corrosion rating and lubrication rating , This paper describes the more important relationships between remaining strength (or, conversely, strength loss) as the dependent variable and some of the principal independent variables mentioned above.IntroductionBoth productivity and safety in underground mines could be improved if mine-heist rope Iife and reliability could be predicted more accurately . As a result, hoist-rope failure processes and their effects on rope life and remaining strength need to be quantified and related in such a way that improved retirement criteria can be developed. This is true whether the failure is incipient or actual or whether the failure mode is by corrosion , wear, fatigue or a combination of these factors."

Jan 1, 1984

By J. E. Hawley

"The property of Francoeur Gold Mines, Limited, lies directly west of the Armfield mine in Beauchastel township, Abitibi district, and 12 miles west and slightly south of Noranda. The gold deposits are of particular interest because of their replacement character and close association with fault zones. The property was originally staked in 1923 following the discovery oi a mineralized zone near the eastern boundary. This became No. 1 orebody. Later discoveries in 1936 of No. 2 and No. 3 orebodies led to underground development and actual mining in July, 1938. A fourth orebody, No. 8, was found in 1939.The following is the production record up to December 31st, 1947:Beginning in September, 1944, ore was shipped to Noranda as siliceous flux, but late in 1946 milling of low-silica ore from No. 1 orebody was undertaken until operations were temporarily suspended in 1947.The four main ore deposits, Nos. 1, 2, 3, and 8, consist of siliceous ferrocarbonate and albite replacement bodies mineralized with fine pyrite and specularite in schistose fault zones in Keewatin volcanics. Barren to low grade quartz veins though present in some are uncommon, but small stringers of quartz are usually present wherever here and there visible gold is found. Nos. 1, 2, and 3 deposits lie in a major fault zone that extends completely across the property from west to east (over 7,000 feet) and dips N.40° to 50°, and are separated by intervals of 1,800 to 2,000 feet respectively. The fourth lies in a smaller fault zone striking east and dipping on the average 65°S.No. 1 orebody has been explored by mining to a depth of 500 feet, No. 2 to 400 feet, and No. 3 to slightly less than 300 feet . The greater part of No. 8 lies above a depth of 200 feet, but a raise has recently .been driven through from the west end of the 5th level of No. 1 to the 2nd level on No. 8 zone. Most of the ore of No. 8 zone above the 2nd level and of Nos. 2 and 3 above the 3rd levels has been removed."

Jan 1, 1954

By J. H. Nantel, J. F. Archibald

"The presence of radon from uranium-bearing ores, waste and from backfill material introduced underground to provide ground support, work platform and waste disposal functions, requires that ventilation controls be established to maintain safe working level concentrations. One approach has been developed at Queen's University to quantify radon and radon daughter source level s and to estimate ventilation requirements necessary to maintain these safe levels.Knowledge concerning the sources of radioactive contaminants and their production quantities is of value for planning and design stages of ventilation control systems. For any given mine layout, radiation level estimates may be forecast and modified by ventilation network design where excessive production quantities may exist.Behaviour of Radon Gas in MinesRadon gas, produced from the decay of Ra-226 in a host medium, will diffuse through porous media. In areas adjacent to mine workings, radon will be liberated into the mine atmosphere. The rate of radon emanation is proportional to the rate at which radon is produced within the host material (a function of the ore grade of U308) , to the radon concentration gradient in the host pores and to the diffusion properties of the material.The radon source concentration is determined by the rate at which Rn-222 is produced by the decay of Ra-226, and by the emanating coefficient (E), or fraction of the radon which escapes from the source matrix and is free to diffuse through the pore spaces."

Jan 1, 1984

By P. E. Auger, J. E. Gill

"The zinc deposits to be described are in Lemieux township a few miles south of the Tabletop mountains, in the central part of Gaspe peninsula, Quebec. Although they have not been worked, they constitute a potential source of zinc and lead and structurally are of considerable interest.GENERAL CHARACTER OF THE OCCURRENCEThe deposits are in sharp-walled quartz-carbonate veins and breccia zones carrying locally, and in varying amounts, sphalerite, galena, pyrite, marcasite, chalcopyrite, and specularite. Those so far investigated strike generally north-south, have steep dips, and cut through sediments of Lower Devonian age, mostly calcareous argillites or siltstones. Wall-rock alteration is negligible.BROADER STRUCTURAL FEATURESThe principal known occurrences are in the south-central part of a dome structure measuring 6 by 5 miles. The argillaceous sediments are overlain, on the flanks of the dome, by sandstones and lavas. These have been stripped from the central part of the dome, revealing the veins in the argillites beneath. The veins formed after the volcanics, but the fractures and breccia zones in which the deposits formed are confined mainly to the argillite series, presumably because of the greater strength of the lavas.The argillite series is cut by dykes, sills, and small stocks of diorite and acidic 'porphyries' that are older than the veins.THE FEDERAL HILL AREAThe distribution of known veins is shown in Fig. 1. The characteristic features of the veins are well illustrated by the Federal Hill area shown in Figs. 2, 3, and 4, and described below."

Jan 1, 1954

By M. Kaya, A. R. Laplante

"Since the beginning of eighties the use of flotation columns has surged in Canada and abroad; the metallurgical superiority of columns over mechanical cells is in great part due to froth washing, which ensures higher gangue rejection and selectivity. Can wash water, which has proven so beneficial, be used in mechanical cells? Although froth washing technology was widely implemented in Soviet plants for bi tuminuous coal, and alusite, powellite, scheelite, molybdenite, etc. more than 25 years, it has been neglected in the western world. Published data suggest 10 to 15~ increases in grade and/or recovery with wash water in mechanical cells (Klassen and Mokrousov, 1963). There are at least three wash water plant applications in Zaire, Chile, and Canada, but little, if any, published information is available. This research work, which is the first extensive fundamental study related to froth washing in mechanical cells, attempts to answer the questions of how, how much, and where should wash water be added.This project was undertaken in three stages:1. Bench-scale laboratory tests with a 6.5 L Denver cell at McGill using a silica flour and a slime reject from Niobec (St.Honor6).2. Pilot-plant scale tests with a 65 L Denver cell at McGill using the silica flour and a complex Cu-Ni sulphide ore from the Strathcona mill of Falconbridge.3. Plant-scale tests with a bank of 2800 L Denver cells at Falconbridge Ltd. for complex Cu-Ni sulphide ore and Eastmaque Gold Mines Ltd. for Au tailing reclaimation."

Jan 1, 1989

By B. McFadzean, J. Taguta

In order to recover minerals by flotation, the sub-processes of collector adsorption onto the valuable minerals followed by bubble-particle attachment should occur efficiently. This paper investigates both of these sub-processes for various thiol collectors and their mixtures onto base metal sulfide minerals. The aim of the work was to investigate whether there is a correlation between the strength of the collector interaction with the mineral and the subsequent bubble-particle attachment. The collector-mineral affinity was measured experimentally using an isothermal titration calorimeter in order to determine the molar enthalpy of adsorption for each collector-mineral system. The bubble-particle attachment was measured using a microflotation device which essentially determines the hydrophobicity of the mineral. Sodium ethyl xanthate (SEX) and sodium diethyl dithiocarbamate (DTC) and mixtures thereof were used as collectors with either single minerals or binary mixtures of pyrite and chalcopyrite, respectively. The adsorption enthalpies of the collectors were interpreted with reference to the chemical structure of the collector molecule and showed that the greater the positive inductive effect of the collector, which may be qualitatively related to their pKa, the greater their affinity for the mineral surface. In the microflotation studies, recoveries were strongly related to the alkyl chain length but there was no correlation between the enthalpies of adsorption and the flotation recoveries. When mixtures of collectors were used there was clear evidence of synergistic effects and in the case of DTC/xanthate mixtures it is possible that this synergism is related to a DTC promoted oxidation of xanthate to dixanthogen. When mixtures of pyrite and chalcopyrite were used the flotation recovery and enthalpy of adsorption of SEX onto the individual pyrite particles in the mixture increased substantially compared to the case of pyrite alone. Mechanisms are proposed to interpret these important observations.

Jan 1, 2016

By Lorne Roberts

"This paper describes: how Falconbridge's fire protection system meets the needs of the Lockerby Mine; why the system was chosen over other alternatives; how it is unique, but can be applied to any underground situation; details of the system; how it was installed; the role of a fire protection company; and general considerations when choosing afire-suppresant system.IntroductionIn May 1981, after about three years of searching for the best fire protection system for the re-opened Lockerby nickel mine at Whitefish, near Sudbury, Ontario, Falconbridge Nickel Mines Ltd. installed an AFFF type of fire suppression system. It was designed and supplied by the Fire Protection Systems Division of Levitt -Safety Ltd.The system protects against loss of life, equipment and/or production, and it complies with legislation should fire occur in a fuel storage area and/or scooptram garage and service bay at any or all of the three levels near Shaft No.2.About 18 months after Levitt-Safety began working with Falconbridge, the system was designed and installed at a cost considerably less than that which would be incurred if fire damage caused the loss of two days of production.The fire protection system, which overcomes a limited water supply, is a self-contained balanced pressure proportioning system. It senses the flow and automatically determines the correct concentration of foam to water. It is triggered by a release mechanism which operates a bank of nitrogen cylinders, which in turn pressurize a pressure vessel to expel the foam concentrate and water from the tanks. This solution is piped to sprinkler heads in the specific area."

Jan 1, 1982

By Y. P. Wu

Steeply dipping seam refers to the coal seam with dipping angle in the range of 35?55°, which is well recognized to be very hard to mine by the mining industry all the world. In the last two decades, some fundamental researches were focused on the strata behavior of long-wall panel, complicated rock mass breaking process of the steeply dipping seam, overburden stress field developing and evolution, rock strata breaking and moving process, rock structure stability mechanism and control. Results show that it?s presenting macro stress arch-shell (MSAS) of the stress distribution of the overlying rock in steeply dipping seam. The MSAS is the spatial distribution of intensity envelope line under the strength criterion and has the geometry shape asymmetry as well as the stress distribution heterogeneity. The arch- shell base will forward as the working face mine forward and the shell roof will extend to higher overlying strata above the gob. In this paper, the stress arch-shell analysis model and coordinate system were established and analyzed the inclined masonry structure at different zone. Analysis results show that the rock damage at the key part of the arch-shell is the main factor which causes whole overlying rock structure failure. The rock structure instability modes have tension instability of the shell roof, compression-shear instability of the shell shoulder and composite instability of the shell base, meantime, instability coefficient is proposed to determine instability condition. The above research results enrich the complex coal seams mining theory and provide a theoretical basis for mining safely and efficiently in steeply dipping seam.

Aug 1, 2013

By M. Hashemzadeh

The efficiency of water use is a top priority for the global minerals industry, especially in regions with limited freshwater supplies. In these areas, the freshwater shortage has prompted mining companies to search for alternatives to freshwater sources. Seawater has been proven to be a potential water source for mineral beneficiation and metal extraction processes. This study compares chalcocite leaching behavior with ferric chloride to that with cupric chloride. We carried out leaching tests with a highly pure chalcocite sample in jacketed reactors under fully controlled pH and solution potential. The effect of chloride concentration, oxidant concentration, and temperature on copper extraction was quantified in both cupric and ferric chloride systems. In the ferric chloride system, increasing ferric concentration showed a positive effect on the first stage of chalcocite leaching. In the second stage, increasing temperature markedly enhanced copper extraction. In the cupric chloride system, chloride concentration presented a considerable effect on both the first and second stages of leaching, while temperature had a remarkable effect only on the second stage. The findings of this study would be beneficial to mine operations aiming to replace fresh water with seawater for heap leaching of chalcocite. INTRODUCTION Mineral processing operations/plants are normally operated adjacent to mines which are often located in remote and arid area, such as northern Chile, southern Peru and Australia with limited access to fresh water (Liu, Moran, & Vink, 2011, 2013). Water scarcity in these areas has prompted mining companies to invest in sustainable technologies to reduce the water use and/or increase the water use efficiency. One of the current sustainable approaches in mineral processing operations is to replace fresh water with seawater. Seawater is now being increasingly used for mineral beneficiation and metal extraction processes (Hernández et al., 2015). Another application of seawater could be for heap leaching of copper secondary sulfides, mainly chalcocite. However, the high concentration of chloride ion in seawater may significantly affect leaching kinetics of copper sulfide concentrates and ores (Watling et al., 2014). Therefore, it is essential to develop a fundamental understanding of the leaching of chalcocite in chloride media.

Jan 1, 2019