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By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012

By H. R. Stockford

"A pyroxenite-carbonatite complex containing extensive pyrochlore mineralization was discovered during January, 1966, within an exploratory license area held by Consolidated Morrison Explorations Limited. Located 32 miles south of Moosonee, Ontario, the deposit was found under 100 feet of glacial till and Paleozoic sedimentary cover using airborne and ground magnetometer surveys. Exploratory and detailed drilling, totalling 47,625 feet in 85 holes, was completed in outlining the deposit to a maximum depth of 900 feet. Pyrochlore reserves are estimated at 62,000,000 tons averaging 0.52 per cent Cb,05 to a depth of 825 feet. Included in this tonnage is a high-grade section containing 10,000 tons per vertical foot grading 0.82 per cent Cb20 5• The deposit is still open at depth and the intrusive complex has by no means been fully explored.The columbium (niobium) mineralization occurs in a lineated calcite-dolomite host rock which has been intruded along a fault zone within a northeast-trending granulite belt. Potassium-argon dating indicates an age of 1655 million years.Preliminary studies suggest that the complex was intruded in a series of pulses in the form of a partially crystallized mush. The James Bay intrusive is unusual in that it is linear in form and contains only two main rock types - p•yroxenite and carbonatite. Nepheline-bearing syenites and associated rocks are notably absent. Moreover, the pyrochlore is essentially non-radioactive and free from many of the impurities generally associated with other pyrochlores. A test shaft to investigate soil conditions and to provide a 250-ton bulk sample was completed during 1968. Subsequent pilot-plant operations indicate that good quality pyrochlore concelttrates can be produced from this deposit."

Jan 1, 1972

By Michael Klichowicz, Holger Lieberwirth

"For a detailed prognosis of mineral comminution processes, simulation tools like DEM still pose various challenges. Less realistic mineral structures can affect the results of simulation models such as bonded-particle models (BPM). Hence, in order to design mineral processes with these models as tools, representative mineral input data should be used. The article shows, how realistic 2D-structures can be modelled by taking advantage of the parameters identified by the Quantitative Mineralogical Analysis (QMA). Important quantitative parameters can be derived by analyzing three orthogonal thin or polished sections. For this reason point, line, and area analysis are applied. The mentioned parameters precisely describe the texture and structure of minerals. The newly developed software is able for the first time to semi-automatically analyze images of mineral structures using QMA. Moreover, statistically equivalent structures of minerals can be modelled using the QMA- parameters. Generating synthetic, but equivalent mineral structures opens the door for more reliable BPM based simulations. Within future research, the procedure will be adopted to generate 3D-structures. Therefore, QMA-based routines that already have been applied to generate 2D-models shall be utilized as basis. The aim of this procedure is to synthesize realistic microstructures based on certain statistical figures in order to improve comminution simulations.INTRODUCTION Due to its increasing capability, the use of computer technology is permanently intensifying in the design of mineral processes. The recent past has impressively shown that computer models can enhance the understanding of mineral processing. There is in fact a rising number of research activities, which are using simulation approaches to study various aspects of it. Weerasekara et al. (2013) give a comprehensive overview over the application of discrete element modelling (DEM) in the science of comminution.Nonetheless, using simulation tools such as DEM in general still poses a challenge. For a detailed simulation of a mineral comminution process with DEM, bonded particle models (BPM) appeared suitable in the past. The following issues, however, affect an appropriate prediction when modelling with BPM:• Simulations with high numbers of particles may need a lot of time for computation. • Internal modeling parameters like the spring and damper constants in DEM have to be adjusted by comparing its specific crushing behavior in the simulation to reality.• In order to use DEM for prediction of mineral processing, it is essential to validate the correctness of the models and assumptions, which is sometimes difficult. As Weerasekara et al. (2013) have stated it is crucial that the DEM method as well as the DEM code work properly.• It is challenging to implement the complex geometric structures of real minerals into the model."

Jan 1, 2016

By G. W. H. Norman

"The La Corne molybdenite-bearing veins, discovered in 1915, lie halfway between Amos and Val d'Or near the southwest corner of La Corne township, Abitibi county, Quebec. The Molybdenite Reduction Company, which carried on operations during 1927 to 1930, sank a 200-foot inclined shaft to develop the property and produced about 22 tons of concentrntes from a 30-ton mill during 1929. Hollinger Consolidated Gold Mines, Limited, carried on further underground exploration in 1930. The Molybdenite Corporation of Canada drilled a part of the property in 1938 to 1939 and produced 1 ton of concentrates in 1938. Wartime Metals operated the property from 1942 to July 15, 1945. At this time the mill was enlarged to treat 200 tons daily. Molybdenite Corporation of Canada since July 15th, 1945, have continued the operation of this property and have revised the mill flow-sheet in order to produce both a bismuth and a molybdenite concentrate.The production for the period 1942-1946 is as follows:Total molybdenite production from the mine in the 1942 to 1946 period was about 4,127,400 lb.The La Corne deposit occurs at the northwest contact of a small mass of biotite granite with biotite schist. The form and extent of the biotite granite mass is concealed by a wide sand plain that extends northwest and west from the deposit and overlies bed-rock except in four small outcrop areas. These are spaced 1,000 and 2,000 feet apart along a narrow strip extending 5,000 feet south from the mine. The outcrops suggest that the granite must be at least 1,500 feet wide and 3,000 feet long northeastward. Where exposed in the mine workings the contact dips 70°N.W., but is not a sharply defineable feature due to the presence of numerous granite dykes and tongues in a zone of biotite schist 100 feet wide along the margin of the granite. The biotite schist in the few outcrops that flank the north and south sides of the granite strikes northeast and dips 60° to 70° S.E."

Jan 1, 1954

By Stephan Day

Comments on Robust M3 to Protect Water Quality ?Regulatory and philosophical thinking have tended to evolve at decade scale since 1970s. ?Mines typically last more than a decade. ?Robustness is defined by the ability to adapt to new realities. Managing Water Quality in BC ?1973 ?BC Pollution Control Objectives ?1977 ?Federal Metal Mine Liquid Effluent Regulation (Fisheries Act) ?Late 1980s ?Philosophy of ?Designing for Closure? ?1990s ?Designing for Acid Rock Drainage Management ?2000s ?Awareness of need for water quality management in general, regardless of acidity

May 1, 2010

By Huan-Qiang Zhang, Gang-Hai Huang, Yu-Yong Jiao, Fei Zheng, Zhang. Xiu-Li

An efficient and accurate three-dimensional (3-D) contact detection algorithm is of vital importance in large-scale computing of discontinuous deformation analysis. The contact detection algorithm takes up a large proportion of the whole calculation time because of the increasing calculation number in three-dimensional case. For block systems which consist of convex polyhedrons, the efficiency and accuracy of the contact detection algorithm is a great challenge. The presented contact detection algorithm in discontinuous deformation analysis (DDA) method is carried out in three phases: the global neighbour searching, the local contact type searching and the contact transferring. A contact detection algorithm for 3-D DDA is presented with some improvements on the three phases. A grid-based global neighbour searching algorithm is used to eliminate unnecessary neighbour blocks to the exact number. The local contact type searching includes two steps. In the first step, the common plane method is used to determine the contact type between convex polyhedrons. In the second step, the contact pairs detected by the common plane method are divided into four basic types. In the third phase, the four contact types are transferred into two basic contact types, vertex-to-face contact type and edge-to-edge contact type, which are managed in a uniform procedure. Three verification examples are calculated, the results show that the proposed algorithm based on the three contact detection phases is robust and efficient.

Jan 1, 2015

By A. Dahi Taleghani, A. Shojaei

Continuum damage mechanics (CDM) of rocks is studied together with their elastic and plastic behaviors to develop simulation tools for hydraulic fracturing jobs in naturally fractured formations. The model is constituted based upon pressure sensitive inelastic deformation of porous rocks and their damage mechanisms in the cases of drained and undrained conditions. The CDM model is formulated within Fracture mechanics framework. The performance of the developed elastoplastic and CDM models are compared with the available test data of a specific shale play. The hydraulic fractures growth in the reservoir scale is then simulated; in which the effect of fluid viscosity, natural fractures characteristics and differential stresses on induced fracture network is studied. The simulation results are compared with the available solutions in the literature. The developed CDM model outperforms the traditional fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures without any essential need for remeshing.

Jan 1, 2015

By G. T. Lapidus, J. Trejo-Gallardo

A phenomenological model is presented for leaching silver from silver sulfide contained in mineral particles with ammoniacal thiosulfate solutions of copper in stirred reactors. Experimental results were used to adjust the kinetic parameters of the model, such as the reaction order and velocity. The incorporation of the cuprous sulfide-silver sulfide equilibrium at the reaction interface allowed the prediction of the conversion limits for different reagent concentrations. The information obtained from the reactor model was later integrated into a heap leaching simulation, whose results adequately describe tendencies observed in column tests, with respect to variations in copper and thiosulfate concentrations. Comp

Jan 1, 2005

By H. G. Harper, R. C. Hart

"The Mississagi quartzite is the basal formation of the Quirke Lake trough. As it is traced around the rim, a gradual change in dip is observed, as follows:Northwest corner 50 degrees south.Algom Quirke mine 34 degrees south.Quirke Lake 25 degrees south.Whiskey Lake 22 degrees west.Pecors Lake 25 degrees north.Algom Nordic mine 18 degrees north.Elliot Lake 11 degrees north.Pistol Lake 5-7 degrees west.Thus the apparent synclinal axis is a curving east-west line lying closer to the north limb than to the south. The axis appears to plunge west at about 5 degrees.The Huronian sediments lie on a basement of granites, gabbros, and volcanics. Diamond drill evidence indicates that this basement has a surface of peneplanation, and that the areas of soft basic rock have a smoother topography than the granite. For the most part the orebodies at the Quirke and Nordic mines overlie a basement of soft basic rock.The Mississagi formation is the host rock of the deposits, and its primary structures are suggestive of the conditions under which the conglomerate beds were deposited. Cross-bedding is common, although normal bedding varies from thick to thin to essentially lacking. Grain gradation is not common. Where coarse and fine grains occur together, the coarse tend to be more rounded than the fine. These features are characteristic of shallow-water deposits, laid down above the lower limit of wave action. Therefore, the quartz-pebble conglomerates probably represent ancient water courses, bays, beaches, and bars.The causes governing the creation of the trough can only be conjectured, but there is evidence that both subsidence and compressive stresses played active roles. Drag-folds in argillite beds near Whiskey Lake indicate compressive stress. On the other hand, gentle crumpling in thin-bedded limestones on Quirke Lake is probably due to pre-induration slumping and folding. If strong compression had been widespread within the trough, one would expect drag-folding and shearing of the incompetent beds to be more general. Two large-scale, fold-like structures were mapped by Collins, but their axes do not parallel the trough axis, and they are therefore not related to the major structure."

Jan 1, 1949

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020

By A. Vervoort

The concepts of geostatistics are commonly difficult to understand for students, even for those with a strong mathematical background. A main problem is certainly the link between the variation of the parameter value in space or time, and the calculated experimental semivariogram as a function of the interdistance, but over the entire area. Another problem is to differentiate between directional and omnidirectional semivariograms and the way they have to be interpreted. Furthermore first time users of geostatistics often do not want to struggle through different books with the whole geostatistical background before using it. Too often this leads to using geostatistics as a black box with all the risks linked to it. That is the main reason that we developed some interactive tools based on the free public domain software R. We aim by developing three different modules to assist individual first time users, but also regular students and teachers to get a feeling of the importance of the various aspects in conducting a good geostatistical study. The modules show directly e.g. the impact of deleting, moving or adding data points, of changing parameters of the semivariogram model and of the geometrical parameters during kriging. The first module allows making the link between the variation of the parameter values in one direction and the calculated experimental semivariogram, and this for different given datasets. The second module covers two dimensional datasets and apart from calculating the semivariogram values, models can be fitted to the calculated data. A distinction can be made between omni-directional and directional semivariograms, including the effect of the tolerance on the angle and lag-distance. The third module focuses on ordinary kriging of point values in two dimensions. The aim of the interactive tools developed is limited to educational purposes only, i.e. to visualize some basic concepts for different pre-selected types of spatial variation. They do not intend to do a geostatistical study on a certain dataset (for this purpose there exists already a broad spectrum of good software packages). The original intention of developing the three modules was aimed at users with no or a limited amount of geostatistical experience. However, these modules seem also very useful to remain critical for experienced users. One should never forget that in a real application one does not have a complete view of the phenomenon studied. The geostatistical interactive modules can be accessed through: www.bwk.kuleuven.be/geostatistics . We compiled a manual to facilitate the use of the modules and to guide the user we formulated several questions to be solved for each module.

Aug 1, 2013

By J. R. Fisher

"Uranium may be leached to some extent in situ from the Blind River conglomerate uranium ores by using the products of bacterial activity from the bacterium Thio-bacillus ferrooxidans his paper describes some of the laboratory techniques used to investigate the characteristics of the bacteria, and to utilize their properties in uranium leaching. The application of some of the laboratory results underground at the Milliken mine of Rio Algom Mines Limited are de-scribed, along with the method of uranium recovery from the mine waters."

Jan 1, 1966

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014

By T. Kawai

Japan Oil, Gas and Metals National Corporation (JOGMEC) has started an exploration program for Seafloor Massive Sulfides (SMS) in the EEZ of Japan, and launched an investigation program for mining, processing and environmental impact on SMS development. With regard to the mining aspect, the mining system consists of three units: a mining unit on the sea floor, an ore lift-up unit to surface, and a mining support vessel unit which has an ore unloading system that unloads onto a shuttle ship. Regarding the mining unit, JOGMEC and certain Japanese mining and machinery companies developed two types of state of the art mining testing tools. Excavation tests on the actual SMS site in the Okinawa Trough, south-west of Japan, were conducted in 2012. In these tests, the functions of the testing tools, such as cutting ore, moving on the seafloor and climbing up slopes having steeper than a 25 degree gradient, were confirmed. The physical characteristics of the ore, which are key parameters for establishing a mining system, are yet to be fully understood as the exploration program has been undertaken simultaneously. Hence, those examinations have been carried out by ground cutting experiments, analysis of drilling core data, and the like. This paper describes the outline of a proposed mining system, mining testing tools and results of the on-site mining testing.

Aug 1, 2013

By M. Jarvis, D. B. Dreisinger, T. Hitchins

Mineral carbonation (MC) has been extensively researched all over the world since it was found as a natural exothermic process to permanently and safely sequester CO2. In order to accelerate the natural process, various methods for carbonation of Mg-/Ca-silicate minerals and other industrial wastes have been studied. It has been found that the MC efficiency will increase with an increase of CO2 pressure, retention time, temperature, mass ratio of Mg or Ca to Si in minerals, specific surface area, and the slurry concentration in a specific range, and with the introduction of an effective catalysts, for example, 1M NaCl and 0.64M NaHCO3 or carbonic anhydrase. However, there still is not a successful industrial application because of high economic cost and slow reaction rate. It is not economic to exploit Mg- and Ca-silicate minerals deposits or tailings to sequester CO2 by MC, due to the cost of grinding and heat pre-treatment and in some cases the whole sequestration process may result in more CO2 emissions than the amount of CO2 sequestered, due to the requirements of energy inputs. The process however, may be profitable as a whole (with carbon credits). It is suggested to combine MC with recovery of valuable metals from ore deposits in order to reduce the cost for MC by cost sharing for mineral recovery.

Jan 1, 2017

By G. R. Cope, C. D. Spence

"The Mac porphyry molybdenum prospect is located 100 km east of Smithers in central British Columbia. The identification of anomalous levels of molybdenum, copper, and silver in three adjacent lakes, sampled during a regional lake sediment survey, lead to the discovery of molybdenite mineralization in float. Subsequent magnetic and soil geochemistry surveys, together with prospecting and mapping, located the source of the float. Mineralization is hosted by a leucocratic granite stock of the Upper Jurassic to Lower Cretaceous Francois Lake Intrusions which has intruded Carboniferous and Permian Cache Creek Group volcanic and sedimentary rocks. The stock measures 500 m by 300m at surface and is mineralized throughout. Sulphide mineralogy is simple and consists of molybdenite with minor pyrite and local chalcopyrite. Molybdenite occurs within fractures and as selvages along quartz stockwork veins and is best developed near the margins of the stock.Known mineralization is coincident with distinct soil geochemistry and magnetic anomalies. Two additional areas of the property display similar features and these remain to be tested.IntroductionThe Mac property is situated in the Babine Lake area of central British Columbia on NTS map sheet 93K/13E, approximately 100 km east of the town of Smithers (Fig. 1). The property lies on the western margin of the Hogem Range at the northern tip of the Nechako Plateau. The centre of the claim block lies at 54°51 ' 30""N and 125 °34 '30""W.Topographically, the claims are characterized by gently rolling hills ranging in elevation from 900 m to 1500 m. Slopes are forested with tall conifers and underbrush is minimal. Flat-lying areas are swampy with tall grasses and scrub brush.Presently, the property is only accessible by helicopter from bases located in Smithers and Fort St. James. Recent road construction by the British Columbia Forest Service has brought road access from Burns Lake to within 5 km due south of the property. It is expected that in the near future, roads will be advanced into the claim area to facilitate logging of mature timber."

Jan 1, 1995

By O. Engler, J. Friis, S. J. Andersen, C. D. Marioara, Y. Aruga

"This work investigates the early stages of precipitation in Al-Mg-Si alloys using a combination of high angle annular dark field scanning transmission electron microscopy (HAADF-STEM), selected area electron diffraction (SAED) and density functional theory (DFT) calculations. Quenching from a high temperature (solution) treatment leaves an alloy in a high-energy unstable state, with solute and vacancies in supersaturation. Thus, already at room temperature (RT) a large driving force exists for solute atoms to cluster and order on the Al matrix positions. DFT calculations indicate that strain alleviation is important at this stage. We observe larger regions of Mg-dominated L10 ordering together with a Si-dominated ordering of smaller clusters in a particular geometry connected to the Si-network found in all the precipitates. In addition, building blocks of the main hardening phase ?'', stabilized by vacancies, are observed at higher, typical pre-aging temperatures.INTRODUCTION Al-Mg-Si (6xxx) alloys are widely used in industry due to a combination of favorable properties such as strength, ductility, corrosion resistance and lightweight. They undergo a complex production route, usually consisting of the following thermo-mechanical steps: casting, homogenization, extrusion or rolling, solution heat treatment (SHT) and artificial aging (AA). The SHT takes place at temperatures above the solvus line in the phase diagram, usually between 500°C and 570°C, followed by a rapid cooling to RT. This ensures that high amounts of solute atoms, uniformly distributed on the cubic face-centered (FCC) Al lattice, together with a large amount of vacancies, are quenched-in. The material is therefore in a super-saturated and unstable state. During the subsequent AA, at temperatures usually between 150°C and 220°C, the solute atoms diffuse and cluster, forming metastable precipitates with needle/ lath/ rod morphologies having the main growth direction along <100>Al. With a maximum alloy solute level (Mg + Si) of only 2%, these precipitates increase material strength up to three times that of pure Al, and are essential for the final material properties. To understand and make better use of this phenomenon, it is imperative to research the nature of the precipitates (such as their atomic structure), measure their key parameters (number density, size, volume fraction) and connect it to material properties (Marioara, Andersen, Zandbergen & Holmestad, 2005; Marioara et al., 2014). The following precipitation sequence is given for the Al-Mg-Si system:"

Jan 1, 2018

By Gilles Bonin

Structures and serpentinization patterns in the Thetford Mines peridotites are important characteristics indicating the necessary geological conditions which led to the development of chrysotile orebodies in Early Ordovician limes. These structures and serpentinization patterns are reviewed in this paper using the geology of LAB Chrysotile orebodies as a model. Structural aspects include parallel and transverse faults, parallel and transverse granite slabs, and orebodies, some of which trend clearly north-westward parallel to the accretionarymovement. Serpentinization patterns in the peridotite belt, particularly in the harzburgite, include primary pervasive mass serpentinization and secondary complete serpentinization. Listwaenites layers appeared along some faults and along some granite slabs as a result of hydrothermal alteration of the serpentine, following the emplacement of the devonian plutons to the south. These plutons as we/1 as other important lineaments, align with the structural pattern of Thetford Mines ophiolites. It is believed that these plutons are part of a heavy magma tic corridor resembling the Pilote-Mont-Louis corridor in the Gaspe (Doyon and Berger, 1997), and the Buchans' structure in Newfoundland (Hutchinson, 1984), both intersecting the Brompton-Baie Verte line.

Jan 1, 2001

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005