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By Yusuke Yamamoto, Mineo Asano

"The present study investigated the texture transition during secondary recrystallization in the AA5182 sheet. During the initial stage of annealing, the texture showed a weak Cube orientation as the primary recrystallization texture. During the secondary recrystallization with abnormal grain growth, the area ratio of the {hkl} <011> orientations increased by consuming the other orientations. The texture transition was calculated by the 2-D Monte Carlo simulation with the misorientation dependency. When the higher grain boundary mobility was set in the specific range of the high angle misorientation, the orientation preferential growth of the RW {100} <011> orientation was reproduced. However, other {hkl} <110> orientations could not be well reproduced by the misorientation dependency.INTRODUCTION Crystal orientation and texture are important factors for aluminum sheet products from the standpoint of mechanical property, formability and isotropy. The recrystallization texture results from the orientation preferential growth from the rolling deformation microstructure and the texture (Alvi, Cheong, Suni, Weiland, & Rollett, 2008). Texture development has been a topic of intense research for decades with advances in analysis methods, e.g., orientation mapping (OIM) and computer simulations (Fjeldberg & Marthinsen, 2010; Ivasishin, Shevchenko, Vasiliev, & Semiatin, 2006). The grain boundary characteristic is considered to be a key for the orientation preferential growth. In the case of the recrystallization from the deformed microstructure, not only the grain boundary characteristic, but also the dislocation density and the subgrain size affect the nucleation and the grain growth (Engler, Löchte, & Hirsch, 2007). On the other hand, in the case of secondary recrystallization, the dislocation density and the subgrain size can be ignored and the effect of the grain boundary characteristic can play a significant role in the grain growth. There is intense research about the texture development during secondary recrystallization in aluminum alloys and it was reported that coarse {hkl} <011> grains were formed during the secondary recrystallization (Suk, Shin, & Huh, 2006; Rios, & Gottstein, 2001). However, the mechanism of forming the {hkl} <011> grains has not been fully clarified. In the present study, the effect of the grain boundary characteristic on the orientation preferential growth was investigated by EBSD analysis and Monte-Carlo (MC) simulation."

Jan 1, 2018

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By T. C. WEBB

In New Brunswick, significant potash deposits are intimately associated with rocks of the Lower Carboniferous Windsor Group. To date, two deposits high in sylvinite, up to 20 m thick, have been confirmed at depths between 490 and 1,035 m below surface near Plumweseep and Salt Springs. These areas are currently under development by the Potash Company of America and the Denison-Potacan Potash Company respectively. A third area, near Lower Millstream, is also known to contain potash-bearing evaporites and is now being explored by BP Exploration Canada Ltd. All three areas are situated in the western half of the Moncion Subbasin and are within 25 km of Sussex. Numerous similarities in stratigraphy, thickness, mineralogy and structure suggest that deposition of evaporites throughout much of southern New Brunswick was contemporaneous and extended over a considerable area. Future opportunities for potash exploration in the province thus seem excellent. A number of large unexplored areas remain in the Moncion and Cumberland Subbasins and in parts

Jan 1, 1984

By José J. Suárez

As pressure grows for commodity pricing, new mines are more difficult to develop, the stock markets demand better financial returns from mining companies, resources for the developing and operations are scarce, and developing countries in Asia, and Africa demand more metals, it is important that mining companies effect better utilization of capital to develop capital projects. In the last few years, the costs for Capital projects have been impacted by the following factors:

May 1, 2013

By J. A. Espinosa-Guillen, J. A. Lopez-Molina, S. García, J. A. Valencia-Quintanar

"The design and implementation of grouting treatments in rock masses are procedures that require continuous adjustment of parameters and criteria to optimize the results. In this proposal we describe a set of tools that enhance decision-making for this type of jobs particularly in dam projects. The methodology is focused on hydrogeological zoning of the site and its constant update combining engineer’s experience with artificial intelligence techniques to integrate the site knowledge; as well as the evaluation of grouting results for different scrutiny scales, with special attention on the relationship between water absorption and grout consumption. INTRODUCTIONSeveral methodologies for design, implementation and evaluation for grouting rock masses have been developed for the solution of specific problems and tested in diverse geological conditions. Each of these methodologies is focused on results evaluation for different scrutiny scales (Table 1) and is employed to assist decision-making before or during the grouting process.Some methods define specifications for grouting each stage of the borehole, making theoretical, semi empirical or experience-based considerations to define basic parameters as maximum pressure, maximum volume, grouting time, flow rate, etc. Ultimately each approach aim to optimize the injection process, adjusting volumes or the grouting time required to obtain satisfactory results, reducing risk of creating new flow paths or unnecessary grout travels, and enhancing the mixture properties to achieve adequate penetrability and long-term behaviour. Some of these criteria have been widely used in dam projects, for example the concept of Grouting Based on Facts to define the maximum pressure and volume (Ewert, 1997), the GIN method (Lombardi & Deere, 1993; El Tani, 2012), or the North American standards based on Apparent Lugeon measures (Naudts, 1995; Bruce 2011); on the other hand, there are relatively new criteria that have shown good results for dam grouting as the Aperture Control Method (Bonin et al., 2012; Carter et al., 2012) or the Real Time Grouting Control Method (Stille et al., 2012)."

Jan 1, 2015

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

To produce high quality castings, one must monitor the melt quality by evaluating such parameters as the grain refinement and silicon inoculation and modification during the production of the commercial casting. Thermal analysis is a tool one can use for both monitoring and providing input to the process control of the operation. The current technique of performing thermal analysis in commercial foundries is to pour a relatively small quantity of the molten aluminum alloy into a sampling cup and to then acquire the cooling curve. This approach is somewhat simplistic in that one has limited control of the cooling rate and hence the solidification rate of the sample. Moreover, this process requires a fair amount of user intervention and effort. In the past, studies have been conducted in an attempt to develop a system for conducting thermal analysis in-situ. In a study at McGill University, an alkali based heat pipe system was developed for conducting thermal analysis in-situ. While the concept was deemed as very desirable, the complexity of the equipment and procedure was a substantial negative component. In order to improve the technique of accomplishing real-time thermal analysis with an in-situ probe, a new method that is based on McGill heat pipe technology was developed. In the new system, a controllable and flexible water based heat pipe probe is used to solidify a small quantity of metal while residing in the melt. The solidified aluminum is remelted after completing the thermal analysis. This is a key feature of the probe. It resides permanently in the melt yet it is able to both solidify a sample of the melt and then to subsequently remelt it. Various solidification rates encountered in commercial castings are attainable by adjusting the heat extraction rate of the unit.

Jan 1, 2004

By J. W. Jefferies

"Plant availability up 13%, production output up 40%, tons per employee up 15% and labor turnover down 52%. One mine manager states these were direct spin offs from the work being done to qualify for a safety award in the program known as the ""IMSRS 11 over a three-year period of time. ""Of Course"", stated this manager, ""these were in addition to an 87% reduction in our disabling injusry frequency rate.”Officially known as the International Mine Safety Rating System or the Five Star Mine Safety Rating, a new approach to mine safety is being used with enthusiasm by a significant number of mines in Canada, the U.S., Australia, Chile, Indonesia, the Philippines and South Africa. Significant results are coming into the International Loos Control Institute from over 125 mines from these countries.The program is built around a mine safety audit system that gives positive recognition to a mine at 5-step intervals along the way, (a star with each step attained). The Institute has licensed auditors in locations in Canada and the U.S. available to audit.It is believed the success of this program is the result of the premise upon which the program is based. The results being achieved are due to the concept that a modern, well-managed mine safety program maintains the basic foundation of a complete management system. When properly implemented, it reinforces those factors common to production, quality and safety. (Attitude - skill - knowledge - fitness - structure - machine - equipment - materials and processes). The IMSRS contains elements that reinforce all these factors. It uniquely treats safety as part of the ""right way"" to do the job and not just the ""safe way"" as a distinctly separate entity. Mines using this program now recognize that many of the older safety techniques were not necessarily the right way or the most efficient way to do things. It appears that this new approach to mine safety is a new avenue for the attainment of management's real goals for being in business, and at the same time achieves optimum support for the important target of safety and health for the mine worker."

Jan 1, 1983

By Roger St. C. Smart, Paul Weber, Joan E. Thomas, William M. Skinner, Warwick Stewart, Stuart Miller

For mine sites affected by acid rock drainage (ARD) or with a potential future ARD issue, the prime consideration is not only the classification of different waste rock as potentially acid forming or non acid forming but also the peak acid (and metal) release rates and expected ARD duration during which effective ARD management and acid neutralisation capacity (ANC) are required. Methods for assessment of this ANC (e.g., Sobek tests) are already available but can be unreliable in ARD containing significant proportions of framboidal pyrite or iron carbonates. The measurement of negative ANC values and the release of S to solution showed that significant sulfide oxidation may occur prior to and during testing in samples containing reactive (particularly framboidal) pyrite resulting in serious underestimation of the original ANC. A simple methodology with dissolution in Ar-purged water before ANC testing, removing ferrous salts, and sulfate assay after ANC testing corrects these effects. Results also showed that a significant lag period (up to 432 h) may be needed for complete hydrolysis of Fe associated with the standard Sobek ANC testing of, for instance, siderite. Hence, the ANC of iron carbonates is usually significantly overestimated. By filtering and the addition of H202 until there was no subsequent pH drop (due to Fe hydrolysis reactions), followed by back titration to pH 7.0, the ANC for siderite was similar to the ANC determined after 432 h lag by the Modified Sobek ANC test and to the mineralogical carbonate ANCcarb determined by calculation based on electron probe micro-analysis. A chemical ANC calculation, based on neutralising cations released to solution, has provided a method to quantify the short-term ANC of carbonates and silicates in simple mixed mineral assemblages and waste rock samples. Results showed that silicate ANC can be more important in short-term neutralisation than carbonate ANC in low carbonate samples. In the longer-term, decreasing sulfate and metal loads with increasing pH values suggests that eventually sulfide acidity generation rates will match the longer-term inherent acid neutralisation rates of the sample derived from silicates. A kinetic ANC measurement for silicates, after steady state dissolution is reached, that indicates the number of hydrogen ions neutralised/m2/yr has been developed. These values can be used in estimates of the net acid production profile from wastes with low (and decreasing) pyrite content after the short-term ANC is exhausted.

Jan 1, 2004

By B. Dubreuil, J. -M. Lalancette, D. Lemieux

Arsenical bearing deposits are posing an increasing challenge for the mining industry. In particular, mineral processing of arsenical sulfidic ores for base and precious metals recovery tend to produce problematic arsenical tailings. This arsenic being present as sulphide or oxide, tends to dissolve, contaminating surface and underground waters. To meet the environmental regulations, it is often required to stabilize the arsenic in a more insoluble form. Dundee Sustainable Technologies has developed a new patented technology using vitrification of the arsenic oxide in an economical way, giving a stable solid, well below the environmental regulations upon leaching. This technology involves oxidation of As (III) to As (V), by using a low cost natural oxidizer and transformation of the produced arsenic oxide into calcium arsenate, which is not volatile at the melting temperature of the glass. This technology would be advantageously applied on most cases around the world where sulphide concentrates are oxidized in a fluidized bed or smelted.

Jan 1, 2014

By R. Abel

During the last eight years, the Ventanas electrolytic refinery has been improving its results by applying a series of new operational practices, such as the reduction of electrode spacing from 115 mm to 105 mm., raising the current density to 305 A/m2, modification in the operators shifts to about 70% of the workers, reducing the pulling cycles by two hours, and the erection of a new anode preparation machine. These improvements allowed an increase in the refinery capacity from 323,000 to 382,000 metric tons of electrolytic copper per year. In the same period it has obtained certification under the ISO 9001:2000 and ISO 14001:2004 standards. All of these developments have been achieved using conventional technology with copper starting sheets. The continuous improvement that is covered in this paper has allowed Ventanas to optimize its production, costs, and operational results. For the next years, it is planned to follow the same tendency, bringing the productivity of the plant to higher levels.

Jan 1, 2007

By B. Dubreuil

Arsenical bearing deposits are posing an increasing challenge for the mining industry. In particular, mineral processing of arsenical sulfidic ores for base and precious metals recovery tend to produce problematic arsenical tailings. This arsenic being present as sulphide or oxide, tends to dissolve, contaminating surface and underground waters. To meet the environmental regulations, it is often required to stabilize the arsenic in a more insoluble form. Nichromet has developed a new patented technology using vitrification of the arsenic oxide in an economical way, giving a stable solid, well below the environmental regulations upon leaching. This technology involves oxidation of As (III) to As (V), by using a low cost natural oxidizer and transformation of the produced arsenic oxide into calcium arsenate, which is not volatile at the melting temperature of the glass. This technology would be advantageously applied on most cases around the world where sulphide concentrates are oxidized in a fluidized bed or smelted.

Aug 1, 2013

By P. Coulombe, J-F. Riverin, A. Gaboury

Cavity cleaning during anode change generates a material that consists of anode cover material and cryolite melts. This material is scooped and placed in bins for transport and further processing and recycling as fresh anode cover material. Typical processing methods in use involve cooling of the hot cavity bath in bins, with or without emission treatment systems, until it is adequate to be processed and grinded to the required particle size distribution. Handling of the hot and cooled cavity bath material can be labour intensive. It also generates significant air emissions which contain particulate and gaseous fluorides. With the advent of the Aluminerie Alouette smelter Phase II expansion, the hot cavity bath tonnage to be processed increased to 700 t/day and maintaining existing practices was not satisfactory. This article presents a novel process implemented at the Alouette smelter where cavity bath is processed as a hot material directly from the potlines ( 600-800°C range), sized, cooled and then processed in the existing cold bath treatment plant. The system is designed to process 36 t/h, is fully automated and requires limited monitoring from operations. Implementing this new system in a Browrifield environment imposed numerous constraints for space, interfaces with existing operations, commissioning and ramp-up. It is presently operating at approximately 80% availability and is easily meeting the requirements of the potlines. This system has significantly improved the workplace environment in the bath treatment area and reduced the overall particulate and gaseous fluorides emissions at Alouette. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By Christina Graf

A synthesis of colloidal gold shell particles with a silica core is described. Small gold nanoclusters were attached to the functionalized surface of colloidal silica particles. Reductive growth and coalescence of these clusters lead to the formation of a closed gold layer. By variation of the thickness of this gold layer and the radius of the shell it is possible to adjust the plasmon resonance of the gold shell particles over the whole visible and infrared region of the spectrum. The optical properties of the particles made are in good agreement with theoretical calculations for coreshell particles. Due to their low polydispersity these gold shell particles form in solution large crystals with submicron lattice constants. It is also possible to produce hollow gold shells by dissolution of the silica core. A new method to coat the silica core gold shell particles with an additional outer silica shell is also presented. This allows due to a reduction in the Van-der-Waals forces to make more permanent dried crystals and facilitates functionalization of the particles for use in various photonic applications.

Oct 1, 2003

By Alan L. Sangster

Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The 0348 values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate sourCe for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-colurnn. Published ? 13C and ? 18() values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992

By B. P. Verma, K. N. Sinha, N. M. Raju, B. Singh

The paper describes a new method of grouting bolts developed at the Central Mining Research Station at Dhanbad in India. This method makes use of wire-mesh sleeve instead of the expensive metal tube to insert the cement mortar into the drill hole. The field trials confirmed that the method is cheap and an effective system of support.

Jan 1, 1972

By M. L. Free

Laboratory scale extraction of metals from heterogeneous materials such as copper ores is often performed using fine material to increase kinetics and reduce sample size requirements and costs. In contrast, commercial extraction is usually accomplished using much larger material sizes than are used in laboratory settings. The large size difference between laboratory testing and commercial application materials makes it difficult to use laboratory test data to accurately predict performance for commercial material. One solution adopted widely in industry is the use of large test columns. Large test columns cost considerably more to set up and run and take much longer periods of time to evaluate than laboratory scale tests with small particles. Consequently, from a cost and data collection efficiency perspective, the development of accurate scale up methods offers significant potential for saving both time and money. This paper provides details for a new approach to correct for scale-up phenomena in heterogeneous material processing.

Jan 1, 2007

By M. Côté, H. Pépin, Y. Richer, C. Gingras

Rolls-Royce Canada has been nominated as a Rolls-Royce Center of Excellence for repair of fan blades in 2003. One of the challenges of the Rolls-Royce Canada Component Repair Center of Excellence team is to reduce cost and time of inspection while ensuring trace ability and quality of the inspection performed on the fan blades. In the context of the dimensional control process optimization, and following the positive conclusions of initial trials carried out in 2003, the technical authorities at RRC have selected the SPG data 3D(TM) technology as a development base for dimensional control programs. The main goal of this development initiative is to develop and support an inspection system to perform the dimensional control and inspection of different components at the Montreal Fan Blade Repair Center of Excellence. The final objective of the program is to build a server platform capable to support different inspection sites within the Montreal facility for the future. This paper presents the certification process of the technology according to the VDI-VDE 2633 certification standards and some results of the fan blade inspection program of the BR 710, BR 715 and TAY according to the JES 195 engineering standards specification.

Jan 1, 2006

By J. E. Marshall

"The concept of employing a project management team to coordinate all aspects of the construction of a new resource development has gained wide acceptance. This team can be formed from within the staff of large mining companies or contracted from major engineering firms and consultants. The mandate of the project managers usually terminates on successful startup of the operation. For frontier mineral developments in the Canadian Arctic or in the developing countries, startup and the initial year of operation represents the period in which the project is most vulnerable to technical, political and managerial problems. A complete change of the management team or the retention of the construction project managers and the resulting cost combined with the breakdown of organizational accountability within the operating staff .are unnecessary management problems.Independent project management services provide the commitment necessary to sustain the continuity of management through all project phases. Efficiency and the ability to make decisions quickly are characteristics of the many successful small mining companies. These qualities are necessary in the project management group, which will be responsible for up to 90% of the preproduction costs.Continuous project management in the construction and operational phases of a mineral development are common in the iron ore industry, but remain anomalous in the base metal, energy mineral and industrial mineral fields.The Nanisivik project on Baffin Island in the Canadian Arctic is used to illustrate the advantages of total project management through construction and operation.Total project management has further potential for foreign interests and financial and utility organizations desirous of participating in the Canadian mining industry, but with no direct involvement in the construction or operating management. Participation agreements in the operating phase of a project can be negotiated to have management fees related to both the production and the profits of the enterprise."

Jan 1, 1980

By M. D. Quinn

THE sand and gravel used for backfilling at the Hollinger mine is obtained from deposits in a low range of hills some three miles north of the mine, where the Company owns a number of claims. The material is transported to the mine by aerial tram. Shipments from these deposits to the Hollinger mine commenced in June, 1927, and since May, 1936, sand has been supplied also to the McIntyre mine. During 1942, Hollinger requirements were 1,700 tons per day, and 900 tons per day was delivered to McIntyre. For the past seven years production has averaged 900,000 tons annually, and total deliveries to the end of 1942 were 13,129,022 tons, of which 11,075,339 tons went to Hollinger and 2,053,683 tons to McIntyre. Some years ago, when the original pit was approaching exhaustion, new workings were opened on claims east and south of the tramway terminal. It soon became apparent that the sand varies considerably in character from place to place. The weight per cubic foot was found to range from 85 to 130 lb., and the water percolation rate from 2 to 50 inches per hour. As the mine requirement is a sand with percolation rate of 6 inches or better per hour, it was evident that in certain parts of the deposits the material was not suitable for use as backfill. As a consequence, it was decided to carry out a programme of systematic sampling of the claims in order to select the areas containing suitable material for back-fill and at the same time estimate the tonnage available.

Jan 1, 1944