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By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By R. A. Lunceford, K. C. Shaver

Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km

Jan 1, 1998

By J. E. McMenamin, R. B. Hall

"With the emphasis in the past decade on larger and more efficient equipment for open-pit operations, the Normandie mine of the Asbestos Corporation has followed the trend, switching from the smaller type of percussion drills to down-the-hole rigs. One 5 Y2 -in. percussion drill is still in use, but is limited to a ""smooth blasting"" role or to the control of the slope on final benches.In keeping with the times, an attempt was made to eliminate, as much as possible, the use of high explosives and to maximize the percentage of ammonium nitrate -fuel oil mixture. As the concentration of ground water increased with increased mining depths, small pumps were initially employed for the dewatering of boreholes. This proved unsuccessful, and a hole-blowing rig was built and a conversion to plastic liners made. The acquisition of a bulk-mix AN-FO truck has permitted the changeover from an AN premix to an ammonium nitrate prill -fuel oil combination at the borehole."

Jan 1, 1966

By J. A. H. Church

My paper entitled "Spontaneous Combustion of Coal in Mines;" read some time ago before this Branch, consisted chiefly of extracts from the British Blue Book dealing with the same subject. Fallowing my article, Mr. de Hart submitted a paper dealing with the application of existing methods of working in Alberta to the conditions obtaining in our bituminous mines. I must confess that the perusal of his paper did not enlighten me either as to what might be a method preferable to those in vogue or even to Mr. de Hart's ideas on the subject, nor did the ensuing discussion of Mr. de Hart's paper afford any great clarification of the problem. The outstanding idea, supplied by Mr. Dick, seemed to be that a retreating system could not be employed, as no operator would feel justified in risking the capital necessary to driving to the boundary when the whole might be jeopardized by a fire breaking out in the waste. That a fire would break out in the waste of any adit-level working seemed to be conceded by all, and with that I agree; that an ignited waste could not be safely sealed off by means of stoppings in a coal barrier-pillar appeared to be the contention of Mr. Dick, or perhaps he attributed this idea to the Mines Branch-anyhow, it seemed to loom over the discussion like a miasma. With this aspect I do not agree, as ? reliance is placed wholly on stoppings in the thick seams of South Staffordshire, even in fiery mines. In the thick coal at Exhall colliery, or elsewhere in Warwickshire (34 feet 4 inches) containing hard and soft coal in layers, a fire assuming serious proportions is sealed off. By the way, retreating long-wall methods are employed. In Fifeshire, sealing off fire in the Dysart mine has been accomplished successfully. The seam averages about 20 feet thick.

Jan 1, 1924

By Sadough vanini Ali

The silicon anisotropic wet chemical etching technique is widely employed for fabricating various microelectromechanical system (MEMS) structures for advantages such as simple etching equipment and its capability to fabricate special microstructures. In this paper, we consider a complete theoretical derivation of the analytical solution based on geometrical and kinetic aspects of step flow on any surface and with a mathematical method we derive new equation for calculating the microscopic etch rates of surface atoms for a new range of concentrations and temperatures. Furthermore, a novel equation is presented for the calculation of the microscopic activation energies for some typical surface atoms and a new comparison of activation energies between some atoms is made that divides atoms into three categories. The results demonstrate agreement with the experimental results.

Oct 1, 2011

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005

By Henry Lepp

Introduction A shaft sinking operation carried out at the Viking Yellowknife mine in the spring of 1947 presents certain features, especially as regards speed of sinking and low cost, that may be of interest to Institute members, and especially to those who are not familiar with conditions and costs in the Northwest Territories. After collaring, the inclined, two-compartment shaft was sunk 130 feet by four miners in twenty-eight days at a direct cost of only $53.19 per foot. All things considered, this is a remarkable performance, even if it does not actually establish a record. The property is at Morris lake, some forty-five miles north of Yellowknife. Formerly owned by Athona Mines (1937), Limited, it was acquired by the then newly incorporated Viking Yellowknife Gold Mines, Limited, in 1947. Surface work and diamond drilling in 1946 disclosed a number of veins and masses of quartz in a sill of diorite which lies conformably within sedimentary rocks. The sill strikes N.30°E. and dips at 70° to 85° southeast, and has a mean width of 40 feet over its explored length of 3,000 feet . Both the quartz and the diorite carry gold and are mineralized with pyrrhotite and lesser amounts of galena, sphalerite, chalcopyrite, and arsenopyrite. Of thirty-five holes drilled in the mineralized zone, the core from twenty showed visible gold. Sampling of drill cores indicated several ore shoots in the north and central parts of the sill. Assays, however, were somewhat erratic, possibly due to the fairly widespread presence of visible gold, and it was decided that the deposit could best be explored by underground sampling. Accordingly, late in 1946, plans were laid for the sinking of a shaft.

Jan 1, 1948

By T L. Horsley

This paper deals with the drilling and blasting methods employed at the Cassiar mine, which is located just south of the B.C.-Yukon border. It covers both the "pit" and "peak" mining operations. Specific problems, such as working in frozen ground, are discussed, and the breaking characteristics of the various rock formations are outlined. The paper concludes with a brief mention of the equipment used in the operation, as "~ell as an outline of the breaking costs. Introduction T HE Cassiar asbestos mine is located just south of the British Columbia -Yukon border high on a spur of McDame mountain. Chrysotile asbestos fibre occurs in a faulted enlargement of a serpentine sill lying conformably be-tween a series of sedimentary beds and volcanic flows which dip at 45 degrees into the mountain. One end of the orebody is eroded by a cirque in which a layer of permanently frozen ore and waste talus lies at the end of the mining benches. The topography at the mine is steep, with no flat areas. Roads, dumps, and areas for crushing,

Jan 1, 1965

By Daniel Torres Espinoza, Jose Pinedo

"Ventilation is a vital service in underground mines, required to provide fresh air to the work force and dilute diesel equipment gases (CO, NOx) and diesel particulate matters (DPM). At a Mexican precious metal mine in the state of Chihuahua there is a VOD system implemented using Howden’s control and monitoring system and a state of the art tagging and tracking technology. The JM zone of the mine is ventilated using a push and pull system, using automated regulators on each level to control the air going in and out of the levels. The implementation of advanced control strategies using Howden’s VentSim™CONTROL allows the mine to generate significant savings and increase health and safety of the workers.INTRODUCTIONIn underground mines, ventilation is a requirement in order to maintain the fresh air needed for personnel and equipment. Ventilation regulations dictate the amount of air required underground to carry out day to day operations by limiting the exposure that workers have to toxic gases and other pollutants. Regulations for required airflow in underground operations for diesel pollutants are generally provided on vehicle rated brake horsepower, in Mexico the requirement is 75 cfm/bhp. In underground mines, ventilation services can account to up to 75% of the mine’s energy consumption, and it is very common for fans to operate all the time because of a lack of control infrastructure for the ventilation system. By the implementation of a Ventilation On Demand (VOD) system a mine can reduce this consumption with different control strategies. The main infrastructure required to implement this system consists of remote control of ventilation infrastructure (fans and regulators), a communication network between throughout the mine with the surface and a tracking system for personnel and diesel equipment. Software is required to determine fresh air requirements based on the tracking system data and then send the control commands to the different ventilation infrastructure. In 2015, San Julian Mine acquired Howden’s VentSim™CONTROL (formally SmartEXEC) and the hardware solution to deploy a VOD system at their operation. The VOD system and Fresnillo plc’s San Julian Mine in Chihuahua, Mexico, consists of control of 10 surface exhaust fans, 2 surface intake fans, and 12 underground automated regulators. It also includes the monitoring of 46 flow sensors, 28 CO sensors, 28 NO?? sensors and 42 temperature and humidity sensors, approximately 500 personnel tags, approximately 220 vehicle tracking tags with diesel status (ON or OFF) and approximately 250 tracking zones. This paper discusses the control strategies that have been implemented at San Julian Mine since the system was commissioned and the next steps that will be taken at the mine with the system as they test different level on VOD."

Jan 1, 2019

By John S. Stevenson

Zeballos mining camp is on the west coast of Vancouver island; 195 nautical miles northwest from Victoria.; The spectacularly rich gold-bearing veins that made Zeballos an important; gold camp were found early in 1934. Small pockets of very coarse; gold had been found earlier under large boulders at the mouth of Spud; creek; and in the autumn of 1933 rich gold-quartz float was found near the; mouth of the creek. The rocky beds of the steep creeks entering Spud creek; were searched for its source and as a result the veins on the White Star property; were found. The Goldfield vein on the Spud Valley property was discovered; in 1935; and the No. 1 vein on the Privateer in 1936. In the general; prospecting activity that quickly followed; other veins were found; not; only in Spud creek but in other creeks draining into Zeballos river.

Jan 1, 1954

By A. D. Akerman, D. D. Young, G. R. Baiden

The development and maintenance of underground roadways are increasingly important aspects of the modern mining process. With the trend toward automation and track-less mining, roadbeds capable of with standing increased wheel loading have proven necessary to maintain high vehicle speed and reduced maintenance costs. Concrete has been used successfully on some roadways in order to obtain the required characteristics. However, this solution usually involves unacceptable expense. The objective of the Road Router project was to create a drift floor profiling machine capable of cutting a smooth surface out of the existing rock floor of development drifts and ramps. This surface would provide a durable, high strength, low rolling resistance roadbed that would allow for reduced operating cycle times and lower maintenance costs of scoops and haulage trucks. The Road Router has the potential to offer an alternative to concrete with substantial cost savings.

Jan 1, 1997

By H. J. Handewith

"After having performed qualitative and quantitative tests on nearly 550 rock specimens from tunnel projects throughout the world and comparing the results with actual boring in eight distinctly different rock types which varied in compressive strength from 12,000 to over 34,000 psi, it has been concluded that any rock -andesite, granite and even taconite -can be machine-bored. The question is -can it be bored economically? The intent of this paper is to delineate the investigative needs to accurately and reliably answer this question. A piece of NX core in the hand represents less than 50 per cent of the worthwhile geologic information that could have been obtained from a given core hole. A thorough site investigation by competent personnel can gene-rally foretell to what extent, if any, varying geologic conditions will hinder machine progress.A laboratory testing technique has been developed that has been correlated well (80 to 120 per cent) with actual boring results. This technique will be discussed in detail. Rock cutter life is a function of the penetration rate and the forces required to sustain that rate. Cutters are now, and will be for .some time to come, the single, most expensive consumable item involved in continuous tunneling in hard rock. It is by strict attention to predicting these rates and forces that tunneling costs can be optimized."

Jan 1, 1970

By T. Yalcin

"This paper describes the development of a process flowsheet designed to provide high dewatering rates and to bring about savings in tailing disposal costs. The flowsheet comprises a hydrocyclone, a settling cone and a thickener arranged in closed circuit. The mill tailing, after pulp density adjustment, is fed to the hydrocyclone which yields two products. The underflow product is sent to the settling cone for further dewatering. The overflow product, together with the settling cone overflow, goes to the thickener which, with the aid of flocculants, gives a clear effluent and a relatively dilute underflow. The latter combines with the original mill tailing to form the hydrocyclone feed. Solids finally leave the system in the settling cone underflow which can reach pulp densities of up to 78%, making it suitable for direct disposal or for use as mine backfill.Some discussion is included for the selection and sizing of equipment required for this process. INTRODUCTIONDewatering is an essential process for the disposal of mill tailings which forms an added burden in milling practice, often with little or no return. It is, therefore, desirable to conduct this process as economically as possible. One way of reducing costs would be to increase the rate of dewatering so that savings can be made in the size of dewatering unit s which would lead to lower capital and operating expenditures.A common method of dewatering mill tailings is gravity sedimentation which is frequently carried out with the aid of flocculation. In most cases, flocculation greatly enhances the sedimentation process, but only until a pulp density of 50% to 55% is reached in the settled material.Centrifugal sedimentation in hydrocyclones can provide high pulp densities rapidly, but does not result in a clear effluent.This paper outlines a suitable combination of gravity and centrifugal sedimentations that results in an over-all high rate of dewatering. The system developed produces a material of high pulp density while at the same time giving clear effluent."

Jan 1, 1989

By H. O. Olsen

"GeneralTHE IRON ORE at Marmora is a replacement deposit of Precambrian limestone and is overlain with Palaeozoic limestone. It is a low-grade magnetite deposit and the ore will require concentration be-fore it can be used economically for the production of iron and steel.Present plans estimate an annual production of 500,000 tons of concentrate in the form of pellets. This will require mining approximately two million tons of ore and\ waste annually. Shipment of pellets from Marmora to a ship-loading dock at Picton will be made by rail on a year-'round basis. Shipments from Picton to the Lackawanna plant of the Bethlehem Steel Company at Buffalo, N.Y., will be carried on during the Lake shipping season.LocationThe mine, located a mile southeast of Marmora village in Hastings county, Ontario, is 31 miles north of Belleville and 3•7 miles east of Peterborough. Marmora is 130 miles from Toronto and 150 miles from Ottawa. Highway No. 7 passes half a mile north of the mine and Highway No. 14 half a mile west of the mine. The Canadian National railways' branch line between Trenton and Bancroft passes through the property just east of the open pit.HistoryThe Ontario Department of Mines conducted an airborne magnetic survey of the district during 1948 and 1949. Maps of this survey were released to the public early in 1950. Bethlehem representatives carried out ground surveys in the Marmora area shortly thereafter and in June, 1950, commenced diamond drilling."

Jan 1, 1955

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers&apos; ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By W. D. Robbson

DR. G. W. RAMSEY (l): A study of our non-treatment silicosis autopsy material for the years 1940-43 inclusive, in addition to the common findings of fibrosis, nodules, and emphysema, shows marked thickening of the alveolar walls. This change is due to one or more of the following factors: congestion, edema, accumulation of both small and large monocuclear cells within the interstitial tissues and large monocuclear cells attached to the lining membrane of the alveolar sacs. This alteration in the alveolar walls, we believe, is one of the most important factors in producing impaired pulmonary function. Comparison of our first autopsy material of a case receiving twenty aluminium treatments beginning June, 1943, shows a striking change in the alveolar walls. In all areas free of silocotic nodules and fibrous tissue, the alveolar walls approach normal thickness and are free of cellular deposits. No change was noted in the old processes and none was expected. We believe that these changes in the alveolar walls were brought about by the aluminium therapy and that they constitute a major factor in the improved pulmonary ventilation noted in treatment cases.

Jan 1, 1945

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By A. E. Cameron

The theory of atomic distribution of the stranger atoms in the space lattice of the solvent metal has been well developed by Rosenhain. It has long been known that the addition of one metal to another to form a solid solution increases the strength and hardness of the solvent metal. This increase is practically proportional to the amount of added substance up to the limit of solid solubility. To account for this increase in hardness and strength, Rosenhain assumes that the stranger atoms occupy positions on the solvent metal space lattice. Atomic attractions about the stranger atoms will not be the same as in the case of the pure metal, and there will thus be a disturbance of the orderly arrangement of the atoms on the space lattice, or a distortion of the lattice. Such a disturbance would interfere with the ease of slip along the planes and would thus tend to promote strength and hardness. Rosenhain notes that not only may there be a local disturbance of the lattice about the stranger atom but there may well be also a measurable change in the dimensions of the lattice as a whole. The relative amounts of local and general distortion of the lattice will depend upon the nature of the lattice itself. As Rosenhain says, "If the lattice is comparatively soft and flexible the distortion is likely to be largely local. In a stiff lattice, however, local distortion will be resisted and there will be a correspondingly increased general distortion."

Jan 1, 1927