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By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

Accurate hematite solubility data are required to construct predictive solution chemistry models for complex hydrometallurgical solutions. These data are useful in understanding Fe(III) speciation and precipitation in a variety of hydrometallurgical processes. Hematite solubility data were generated in 10 to 70 g/L H2SO4 solutions and at temperatures from 130 to 270°C, using specially modified titanium autoclaves. These measurements represent an improvement over previous experimental data because of better in-situ filtration of the sample aliquots, the approach to equilibrium via hematite dissolution, and the inhibition of Fe(III) reduction on titanium surfaces. Fe(III) reduction was particularly studied to evaluate the inflationary effect of Fe(II) on hematite solubility measurements. Chromate was found to reliably inhibit Fe(III) reduction on titanium. Finally, the generated hematite solubility data were used to construct a solution chemistry model using the OLI software.

Jan 1, 2006

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By Dale A. Walters

The thermal recovery of bitumen reservoirs by steam assisted gravity drainage (SAGD) is often designed to maximize the operating pressure. In general, the benefits of higher operating pressures are higher steam temperatures that maximize the reduction of oil viscosity, potential permeability enhancement associated with lower effective stress and shear dilation, and a larger pressure window to allow flexible control of the producer. This is especially important for shallow reservoirs where the pressure window for injection and production is smaller. Higher operating pressure can reduce thermal efficiency (due to heat losses), but the other benefits usually compensate. The limitation of the maximum operating pressure is then based on maintaining caprock integrity. Thus, shear and tensile failure mechanisms must be quantified and managed. This paper presents a geomechanical analysis of caprock integrity for SAGD operation. Both analytical and numerical approaches are used to investigate the modes of caprock failure. Main factors in the analysis are the knowledge of the initial stress state and proper representation of the complexity of the geomaterials. Typical initial stress states for northern Alberta are presented showing the potential for low initial minimum total stress and elevated initial shear stress levels. The stress-strain behavior for the sand and caprock materials is discussed focusing on the potential for shear dilation in the sand and shear strength behavior in the caprock. Elasto-plastic constitutive models used to represent the sand and caprock are presented and compared using numerical analysis. The increase in pressure and temperature alter the stress state and disturb the soil matrix. This disturbance results in shear dilation of the sand matrix creating regions of enhanced permeability and porosity. Also, the transfer of stress and strain to the caprock causes dynamic stress changes and, therefore, dynamic behavior of shear and tensile failure conditions. Calculations are presented showing the stress paths associated with SAGD operations, suggesting better design of lab testing programs and the implications for shear dilation in the sand and shear failure in the caprock.

Jun 1, 2012

By Richard Simon

This paper presents an ongoing study on the use of borehole breakouts to estimate in situ stresses at depth in a Canadian underground mine. Breakouts were identified using an acoustic televiewer (ATV) probe. Rock samples were tested in a laboratory to determine their failure curve. Breakout analyses were performed using a 2D failure criterion and a multiaxial failure criterion. Analyses were carried out using both short-term (peak) and long-term strengths (the latter considered here as being represented by the damage initiation threshold DIT). The analyses have shown that the use of the longterm strength and a multiaxial failure criterion leads to results that are more consistent with stress measurements performed in the field, in the vicinity of the mine.

Jun 1, 2012

By Lizelle Glaner

An investigation was carried out by Mintek to investigate the influence of additions of gold to ?Fecraloy?, alloys based on Fe-Cr-Al. The aim was to try and improve the oxidation resistance of the ?Fecraloy? alloys at elevated temperatures over extended periods of time. The ?Fecraloy? alloys are very oxidation resistant alloys already employed in industry as substrates for metallic catalysts in auto-catalyst systems for high performance cars. Since their life and durability is limited by the slow, but steady, oxidation of the substrates, any change in the growth or stability of the oxides could be an improvement.

Oct 1, 2003

By Emmanuel Henry

Hanging wall deformation monitoring at the Kiruna Mine is a major concern for Luossavaara- Kiirunavaara AB (LKAB) since underground production is deepening towards the Kiruna Town. In the quest for more effective monitoring techniques, LKAB decided to evaluate satellite-borne Synthetic Aperture Radar (SAR) interferometry?s ability to monitor ground subsidence by generating continuous deformation maps from satellite radar images. While adopted by other geoscience-related industries, SAR interferometry is still relatively untested in the Mining industry. This paper describes how subsidence is actually monitored on the Kiruna Mine?s hanging wall and gives an insight on SAR interferometry?s principle. The encouraging results are discussed as well as the technique?s benefits (continuous deformation mapping, low cost, fast, etc) and limitations (sensitivity to snow and vegetation cover).

May 1, 2003

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By P. Langlois, G. Labonté, J. J. Barrett, J. Holmes

"The Voisey’s Bay mill processes a high-grade pentlandite and chalcopyrite ore in a largely pyrrhotite/troilite matrix. From 1994 to 1997, circuit development focused on making a 14% nickel concentrate. When flowsheet development resumed in 2001, the target grade was raised to 20% ni. initially triethylene tetramine and sulfite pyrrhotite depressants were used in a lime circuit, but by recycling process water and the contained thiosalts, the required nickel grade was made without depressants. construction of the mill was fast-tracked, with start-up in september 2005. ramp-up was faster than other recent nickel installations, with tonnage being limited by concentrate dewatering due to higher-thanexpected ore grades.RÉSUMÉ l’usine de traitement de Voisey’s Bay traite un minerai à teneur élevée en pentlandite et chalcopyrite dans une matrice formée surtout de pyrrhotite/troïlite. De 1994 à 1997, le développement du circuit ciblait la production d’un concentré à 14 % de nickel. lorsque le développement du schéma de traitement a été repris en 2001, la teneur cible a été élevée à 20 % de ni. initialement les déprimants triéthylènetétramine et sulfite de la pyrrhotite étaient utilisés dans un circuit à la chaux; cependant, en recyclant l’eau du procédé et les sulfosels qui y sont contenus, la teneur en nickel a été atteinte sans utilisation de déprimants. la construction de l’usine de traitement a été accélérée et elle a démarré en septembre 2005. la mise en opération a été plus rapide que pour d’autres installations récentes de nickel; le tonnage traité étant limité par le séchage du concentré en raison des teneurs de minerai plus élevées que prévu."

Jan 1, 2017

By J. Locat, G. Parker, D. Turmel

ABSTRACT Since 1964, the Iron Ore Company of Canada has deposited iron ore tailings into Wabush Lake in western Labrador, Canada. From 1999 to 2008, the authors completed multibeam bathymetric and sampling surveys and an airborne LiDAR survey. These data were integrated to study the evolution of the tailings delta shoreline and lakebed elevation. Subaqueous channels evolved between surveys, influencing the tailings depositional pattern. With this analysis it is possible to evaluate the effect of disposal strategies on the delta topset and tailings accumulation. This project uniquely couples marine and terrestrial techniques to follow the fate of tailings in a dispersal system.

Jan 1, 2014

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai."

Jan 1, 2017

By Andrew Matyas

"During the summer of 1968, the author was employed in the Research Department of Dominion Foundries and Steel, Limited, Hamilton, Ontario. Over the years, Dofasco has been conducting a program for developing more efficient control of its basic oxygen steelmaking process. The author was thus able to obtain a variety of viewpoints from both research engineers and furnace operators. He also had access to extensive literature dealing with BOF control schemes underway at other major steel producers. This paper describes the present state of developments in BOF steelmaking control.The necessity for efficient BOF control is pointed out. To appreciate the variables to be controlled, a brief outline of process fundamentals is included. Technical aspects of present methods of practical control are examined in detail; the relative merits of dynamic over static control models are emphasized. Finally, it is shown how an effective dymic-optimizing control scheme serves as the basis for closed-loop computer control of the process."

Jan 1, 1970

By Donald A. Cranstone

"This paper provides a bird&apos;s eye view of the pattern of gold discoveries since 1823, the year of Canada&apos;s first gold find, up to 1983. Within this 160-year period, more gold was discovered in Canada during the last ten-year period (1973-1982) than during any previous decade. The record suggests that the potential for further major gold discoveries is high, which bodes welt f or the future of Canadian gold mining.IntroductionCanada has an impressive history as a gold producer. Since 1921 we have occupied second or third place among the world &apos;s gold producing nations, after South Africa and most of the time the U.S.S.R. Canadian gold production over the last hundred years has added up to some 6 per cent of all-time world production.The sharp rise in the price of gold in the 1970s led to a surge of gold exploration, which in turn resulted in the discovery of significant quantities of gold in Canada. How do these recent discoveries rate in comparison with those of the more distant past? For example, are the quantities of gold in notable discoveries of recent year s, such as Hemlo and Detour, in the same league with the amounts of gold discovered around 1910 in the Porcupine and Kirkland Lake district s of Ontario? Can the combined gold content of the recent discoveries be likened to that o f the almost 40 major Canadian gold deposits, along with numerous smaller ones, discovered in Canada during the 1920s and 1930s? What are the implications of the more recent gold discovery record for future rate s of gold discovery in Canada?This paper attempts to glean answers to such questions from an overview of the period that begins in 1823, the year of Canada&apos;s first gold discovery. Gold deposits come in two major types: placer deposits and lode deposits in solid rock . Placer gold is distributed in sand and gravel. Gold in solid rock occur s mostly in gold ore filling fissures."

Jan 1, 1985

By W. Swidzinski

"Zelazny Most" post-flotation copper mine tailings pond is the only place to of storeing wastes for KGHM POLSKA MI EDZ S.A. The flotation tailings is are the main waste stream in copper mining in Poland. Sufficient storage capacity for tailings is crucial for , thus uninterrupted production of copper is crucially related to the possibility of storing wastes in the pond. The pond covers a Its over 14 km2 arca, almost 50 m high dams making this dame this construction one of the largest in the world. The risk assessment of potential damage due to un stable ility loss of dams or environmental contamination, as well as safely constructing damsincrease of dams within the design criteriaprocess, require quick access to a large amount of the monitoring data , which in vast amount have to be monitored, that needs to be analyzed and processed and reported, every day. This In the paper describes the numerical information system "SyZeM" , used for designated to the "Zelazny Most" pond, baseding on the Oracle database and Geographical Information System , to manage the graphical and descriptive data in coherent way., is presented. The main structure of the system, as well as the methodology of storing, processing and reporting the geological, geotechnical, hydrogeological, geophysical, chemical and survey data are shown. The aspects of Optimizing optimal and risk mitigation and safe management of copper wastes and risk mitigation with the help of "SyZeM" are discussed.

Jan 1, 2007

By X. T. Feng, Y. H. Hatzor, Y. Tal, G. Yagoda-Biran

"When studying jointed rock mass deformation around underground openings it is of great importance to model correctly the excavation sequence during the numerical simulation. This is because for effective arching mechanism to develop in the roof minute block displacements must take place and some of the available discontinuities shear strength must be mobilized. If from the beginning of the simulation the underground opening already exists in the numerical model, block displacements into the excavation space will initiate and develop from time zero, before the initial stresses in the model have attained their actual initial level in the field. These initial block displacements are therefore artificial and exist only in the numerical model, not in the physical reality, and may lead to erroneous assessment of the stability of the designed structure, typically on the conservative side. We have introduced sequence excavation capabilities both in the numerical manifold (NMM) and the discontinuous deformation analysis (DDA) methods and show here the advantages of this modification using three different case studies, each illuminating a different aspect of this enhancement.We begin with the 25 meter deep 2000 year old underground Zedekiah limestone quarry below the old city of Jerusalem, Israel, which is still standing today unsupported with a free span of 40 m. We show that when the opening exists from the beginning of the numerical simulation the required friction angle for roof stability is 25 degrees, whereas when the opening is removed after all stresses and displacements in the model have been stabilized the required friction angle for stability is only 15 degrees.We then model the excavation sequence of a tunnel model representing a 2500 meter deep research tunnel in the Jinping hydroelectric project, China, in order to determine the in situ stress field at this depth by a grid search inversion of displacement data obtained using the sliding micrometer technology in the course of tunnel excavation. Thus we are able to constrain the in situ stress field at these depths where standard in situ stress measurement procedures are extremely difficult to execute properly.Finally, we use sequence excavation modeling capability to find the total height of the expected loosening zone around tunnels excavated through columnar jointed basalts which pose a great engineering challenge because of the characteristic dense network of slender prismatic blocks that transect the opening at a steep inclination. We use MPBX data obtained during excavation of a deep tunnel through such a rock mass to validate our numerical results and show that application of standard empirical guidelines for dimensioning rock bolt reinforcement in such rock masses may in fact result in very un-conservative design because existing empirical approaches typically ignore the anisotropic nature of the structure of such rock masses which, as we show, plays a very significant role in determination of the extent, shape, and geometry of the loosening zone around the opening."

Jan 1, 2015

By Christopher Andreae

Years before iron and steel works were established at Sydney, several thriving although short-lived iron works operated in Nova Scotia. These furnaces reflected the general nineteenth-century North American experience with iron works. At the beginning of the century, small furnaces struggled to supply local needs. Charcoal was the principal fuel and water powered most furnace equipment. By the end of the century, a few huge primary iron and steel works dominated production for Nova Scotia and the rest of Canada. Two sites achieved prominence in the nineteenthcentury Nova Scotia iron industry: Londonderry and Ferrona (Fig. 1). Londonderry, the larger and longerlasting of the two sites, is today a small village on the south flank of the Cobequid Mountains, about 30 km west of Truro. Prior to the establishment of an iron works in 1849, no community existed. At the peak of operation in the 1880s, however, over 2600 people were located there. The second site, Ferrona, today is a mere crossroads on the map, about 10 km south of New Glasgow. Following the construction of a blast furnace there in 1892, a small village grew up around the furnace. But once the furnace was blown out in 1904, the population gradually drifted away.

Jan 1, 1999

By V. V. Zubkov

The systems of geophysical monitoring have been already put into operation at coal mines and ore mines. Since at present it is rather difficult to conduct mine experiments; it is necessary to start a new step in joining of geomechanics and seismic. The linking geomechanical and geophysical monitoring at coal mines and ore mines today became possible due to progress in development of numerical methods of modeling of stress state and technology for processing of seismic information. This paper describes one potential step in linking geomechanical and seismic monitoring at coal mines and ore mines.

Aug 1, 2013