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By Gary Hawthorn

"Laboratory testing, by Lakefield Research determined that, in spite of the relatively high pyrite content of the Golden Rose (GR) orebody, it would respond well to gravity concentration followed by either direct cyanidation or cyanidation of a flotation concentrate.Economics favoured the former choice which became the adopted process flowsheet.During the latter stage of the feasibility study, the Dekalb 500 tpd copper flotation mill became available in the Highland Valley of British Columbia. This plant was purchased by Emerald Lake Resources, and was moved to the Golden Rose minesite.The crushing and grinding circuit were retained and the original flotation circuit was replaced with a 400 mtd gravity plus cyanidation circuit. The plant commissioning commenced in August 1987, and by early September was processing 300 tpd.HistoryThe Golden Rose Mine was operated by Cominco during the period 1935 to 1941 processing 146000 tons grading DAD oz/t Au at a rate of 110 tpd .The process flowsheet consisted of gravity plus amalgamation followed by cyanidation.Metallurgical TestingThe underground mining areas were below the level of Emerald Lake, and had flooded on abandonment in 1942.Samples for metallurgical testing were collected from exposed faces underground once the mine had been dewateredin 1984.In spite of the anticipated high pyrite content of the ore samples, it was apparent from the success of the previous operation that the pyrite did not interfere with the gold recovery.Laboratory testing, at Lakefield, determined that, from a technical perspective, two metallurgical options existed, as shown in Tables I and 2.Note that the very high pyrite content of the ore precluded the possible direct marketing of concentrate. The process flowsheet, therefore, had to contain a cyanidation circuit for the operation to succeed financially.Although the anticipated metallurgy was excellent with either option, the 2.1 % increase in gold recovery with the gravity plus cyanidation option made this the clear choice."

Jan 1, 1989

By J. I. Carroll, J. A. Walker

"Abstract - Camelback is a small (=200 000 tonnes), moderate grade (5%-7% Zn+Pb), volcanogenic massive sulfide deposit, which occurs within the Nepisiguit Falls Formation of the Ordovician Tetagouche Group. The host rocks are tuffaceous sedimentary rocks (Little Falls member) that overlie quartz-feldspar porphyritic tufflavas (Grand Falls member). The hanging-wall sequence comprises rhyolite of the Flat Landing Brook Formation, overlain by the Forty Mile Brook tholeiitic basalt. A dike of unaltered andesite was intersected beneath the massive sulfides, but was not found in the hanging-wall sequence in the vicinity of the deposit. The stratiform part of the deposit is made up of two, steeply south dipping, subparallel massive lenses that average approximately 4 m in thickness. Each lens is zoned, with an upper part consisting mainly of a pyrite and a basal part containing pyrite, sphalerite, and galena, with Ag values. The Au content in the massive sulfides is low (average = 52 ppb for 271 samples), but tends to be enriched in the massive pyrite near the top of each lens. Oxide facies iron formation is spatially associated with the massive sulfides, and has been traced up to 1800 m along strike. Footwall hydrothermal alteration is typical of VMS systems, and is characterized by depletion in K2O and Na2O, and enrichment in MgO and Fe2O3T with proximity to massive sulfides. The massive lenses are underlain by intensely chloritic, fine-grained, tuffaceous sedimentary rocks containing locally significant sulfide (chalcopyrite > pyrite > pyrrhotite) veins, which are interpreted to represent feeder zone mineralization. Unlike many VMS deposits, there is no evidence of silicification beneath the massive sulfides at the top of the feeder zone. The oxygen isotopic compositions (d18O = -1.5‰ to -0.3‰) of hydrothermal chlorite coupled with sulfur isotopic compositions (d34S ˜ 12‰) of the massive sulfides suggest that seawater was the dominant fluid in the hydrothermal system. Normalized rare earth element diagrams show flat Ce profiles and positive Eu anomalies, indicating that modified seawater was involved in ore formation; i.e., high-temperature (=350ºC), acidic, and reduced prior to entrainment into the hydrothermal cell. Although, seawater was the dominant fluid in the sulfide-forming system, d34S values of stringer zone sulfides (8.5‰) coupled with elevated Sn (400 ppm) in one massive sulfide sample indicate that there was at least some magmatic component in the hydrothermal cell."

Jan 1, 2006

By E. Ghali

For engineering applications, magnesium is usually alloyed with one or more elements which include aluminium, manganese, rare earth metals, lithium, zinc, and zirconium. Under normal environmental conditions, the corrosion resistance of magnesium alloys is comparable or better than that of mild steel. The oxide film thickness on pure magnesium after exposure for only ?10 seconds at ambient temperature is 2.2 ± 0.3 nm. Exposure to humid air or to water leads to the formation of a thick hydrated amorphous film that has an oxidation rate less than 0.01 pm/ y. E-pH diagram and high temperature corrosion are discussed. The pH values between 8.5 and 11.5 correspond to a relatively protective oxide or hydroxide film that is more stable at higher pH. Structural applications of magnesium alloys are limited by creep strength rather than by oxidation. Active and active-passive behaviours of magnesium alloys are discussed. The pilling Bedworth Ratio values of oxide and hydroxide are 0.79 and 1.77 respectively and so the formation of Mg(OH)2 inside the oxide film could lead to the development of cracks. Microbiologically influenced corrosion and rational biodegradation of magnesium alloys are discussed because of their interest for medical care.

Jan 1, 2006

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By Turgut Yalcin

"In this study, potential benefits of focculant usage were explored in the processing of mill tailings by hydrocyclones. Tests conducted on copper-nickel mill tailings have demonstrated that, under suitable conditions, flocculation could significantly enhance solid-liquid separation in hydrocyclones. For example, at a feed pulp density of approximately 9%, focculant-assisted hydrocyclone produced an underflow with over 98% solids recovery, compared to a recovery of less than 53% with conventional hydrocyclone. However, feed pulp density was found to be a critical factor, and tailings with pulp densities of greater than about 15%required a two-stage hydrocyclone operation where the focculant-assisted hydrocyclone was employed at the second stage to process the overfow of a conventional hydrocyclone.The underflow and overflow products obtained from the focculant-assisted hydrocy-clone may be discharged into tailings dams in the same manner as those produced by gravity thickeners. The focculant-assisted hydrocy-clone would, however, provide a higher throughput."

Jan 1, 1996

By I. Filzwieser, M. B. Hanel, A. Filzwieser

The paper describes the current density increase within the last 150 years. From the beginning in 1885 at 30 A/m² up to the highest used current densities nowadays at 420 A/m² towards future pathways were even 1000 A/m² can be achievable. A short tour through history will highlight the milestones of the process of electrolytic refining of copper. Besides the improvement of the existing technology, the biggest changes leading to higher possible current densities are linked to the introduction of the ISA stainless steel plates and the introduction of the parallel flow principle. Furthermore, the parameters influencing the limitations regarding current density and therefore the practical used current density as well as the influence from the chemical composition of the electrolyte is discussed. Finally, the possibility of further increasing the current densities by enhancing the relative movement between electrolyte and electrode will give an outlook about the future of the copper electrolysis process. INTRODUCTION The current density is the most important characteristic to describe the productivity of a copper refining electrolysis besides the characteristic number for the electrical efficiency. Over the last 150 years, current density has risen from a few amperes per square meter to over 400 A/m² without any significant change in the principle of electrolytic refining. This increase in current density is documented exemplary by the electrolysis of Montanwerke Brixlegg in Austria (Brixlegg, 1963, 2013). The very beginning of the technology of electrolytic refining of copper was first patented in England by James Elkington in 1865 and the first electrolytic copper refinery was built in Newark, New Jersey, in 1883 (Armstrong, 1999). The secondary smelter Montanwerke Brixlegg, Austria, has been operating an electrolysis plant since 1884. In 1988, the third "Mount Isa" electrolysis plant worldwide and the first in Europe was put into operation in Brixlegg. Since 2010, the so-called high-current electrolysis (parallel flow METTOP-BRX Technology) with a current density of approx. 400 A/m² has been operated in half of the electrolysis process.

Jan 1, 2019

By Gregg W. Morrison

"The Craigmont copper-iron skarn deposit is adjacent to the southern margin of the late Triassic Guichon Creek batholith in south-central British Columbia. Host to the ore are sedimentary and volcanic rocks of the western calc-alkaline belt of the Upper TriassicNicola Group. In the mine area, the Nicola Group rocks are a stratigraphically complex sequence, at least 1800 feet thick, which have been subdivided into Basalt, Rhyolite, Carbonate and Clastic Sediment units. All the units strike and dip parallel to the margin of the Guichon Creek batholith and are within the batholith contact aureole. However, only the Clastic Sediment unit is in contact with the batholith.Most of the skarn and ore is within the Carbonate unit and more specifically within an Interbedded facies that consists of lime sandstone, lime siltstone, quartzo-feldspathic siltstone and argillite. The Interbedded facies and the adjacent barren Massive Limestonefacies are interpreted aspart ofa carbonate reef complex. The distribution of skarn and ore within the Interbedded facies suggests that the facies boundary was a physical and chemical barrier that resulted in concentration of metals adjacent to the Massive Limestone facies.Two stages of skarn formation have been recognized at Craigmont. In Stage I, ore-bearing magnetite-rich and actinolite-epidote-magnetite skarns developed both in basaltic rocks and in Fe-bearing siltstone and argillite of the Interbedded facies, while barren grossular garnet-epidote-calcite-pyrite skarns developed in Fe-poor rhyolitic bands within the Interbedded and Massive Limestone facies . In Stage ll, massive, barren grandite garnet skarn replaced mineralized Stage I skarns in the vicinity of diorite plugs. and specularite ore formed in brecciated Stage I skarn and clastic rocks away from the plugs. Theformation of Stage I skarns required no addition of material, only redistribution and concentration of elements already present within the Interbedded facies. However, the concentration of Cu in Stage lore requires a mechanism for more efficient leaching of Cu from the host rocks, an anomalous concentration of Cu at the site of the Stage I orebody or an additional input of Cu from an external source. The formation of Stage II skarn and ore requires only remobilization and recrystallization of Stage I skarn and ore.Copper and iron are the only elements in economic concentrations in the ore and chalcopyrite is the only significant copper-bearing mineral. Chalcopyrite is disseminated and interstitial to magnetite in Stage I mineralized skarns and is interstitial to specularite in the matrix of Stage II breccia ores. Chalcopyrite also occurs with pyrite as stringer ore in bleached • sediments and rhyolite tuffs in the stratigraphic footwall of the main orebodies.The Craigmont deposit has more features in common with Cu-Fe deposits hosted in metavolcanic and metasedimentary rocks than it has with typical skarn deposits associated with porphyry copper deposits. The orebody is more likely a product of concentration of metal contained within the Nicola Group rocks than of the mineralizing event that produced the . Highland Valley Cu-Mo porphyry deposits in the central part of the Guichon Creek batholith ."

Jan 1, 1980

By R. W. Zeindler, D. A. Fawcett

"A summary is presented of the report completed by the Coal Mining Research Centre in 1980. This report was of a cross-pit conveyor system applied as an auxiliary mining complement to the major stripping unit, a dragline. The purpose of the CMRC report was to evaluate selective mining and replacement of the upper horizons of the strata as an aid in reclamation. These strata were the topsoil, subsoil and glacial till.Past utilization of cross-pit conveyor systems and related engineering studies were assessed. The parameters of the study were based on the mining and geological conditions of the Alberta prairie coal mines. The principal excavator for stripping was a dragline. Excavation of the upper horizons was done by a bucket-wheel excavator discharging onto the crosspit conveyor. Alternative equipment applications were economically compared. Four cases or geological sections were evaluated in detail. The economics of the alternative mining systems for each of the cases were determined. In all instances, the most economical solution was a tandem system utilizing a dragline with a bucket-wheel excavator/ cross-pit conveyor system."

Jan 1, 1981

By Floyd Smith

Based on underground observations made in .the coal mines of the Dominion Coal Company Ltd., this paper deals with the stress phenomena in the approach roads and headways and in the gob areas associated with the longwall method of total extraction. The deformation of roadways during development and the deformation of roadways during the total extraction period is delineated and presented in graphical form .. Conclusions are made as to the feasibility of the introduction of the retreat method of longwall extraction in one of the colhenes. The importance of future studies are enumerated, especially. those pertaining to the determination .of the opti.m.um sizes of protective pillars and to increasing the efficiency of the current methods of artificial roadway support.

Jan 1, 1967

By Umbreen Agha, Stephan L. Chryssoulis, A. Margaritis

"The deportment of gold in samples of the biooxidation feed and product from the Harbour Lights mine in Western Australia was determined using optical microscopy and microbeam techniques such as Secondary Ion Mass Spectrometry (SIMS), Time-of-Flight Laser Ionization Mass Spectrometry (TOF-LIMS), and Electron Probe Microanalysis (EPMA). The main objective was to determine the mechanisms by which acidophilic bacteria (Thiobacillus ferrooxidans) liberate refractory gold which is locked in a sulphide minerals host as visible gold inclusions (> 0.1 µm) and as submicroscopic or 'invisible' gold.Using the integrated mineralogical approach approximately 99% and 100% of the assayed gold in the biooxidation feed and biooxidation product was accounted for. The results were compared to and verified by chemical assays.The gold deportment study indicates that during biooxidation, locked visible and 'invisible' gold is rendered cyanidable by the direct action of Thiobacillus ferrooxidans as well as indirect chemical leaching. Visible gold which is enclosed in sulphide minerals is liberated or partially exposed and is therefore rendered cyanidable as the host mineral is oxidized and dissolved. 'Invisible' gold either coalesces on the surface of the host sulphide mineral as the particle is dissolved or is released into the liquid phase and immediately adsorbs onto the surface of other ore particles with a net negative charge.The shakeflask suspension indicates that direct bacterial oxidation pits and channels correspond to zones of 'invisible' gold and arsenic (in pyrite) enrichment in the host sulphide mineral."

Jan 1, 1996

By A. D. Dalvi

Economics, Resources, Environment and Technology are the major driving forces in the base metals industry. However, these factors are intertwined and together will propel the industry in the future. The demand for metals has grown with economic expansion, between 2 to 4 % p.a. The current growth cycle has been driven by economic expansion in China where the demand for base metals has risen from - 7 % of the world demand in the 90's to - 25 % of world demand today, and rising. Base metals are commodities and their demand and price are cyclical. Historically metal prices have declined in constant dollars, forcing the industry to reduce costs, increase productivity and increase the scale of operation for economies of scale. Due to resource depletion and capacity expansion the industry is driven to expand its reserve and resource base. However, in the case of sulphide deposits of copper and nickel it appears to be a losing battle. For nickel the laterites represent a vast source at this time. Their development requires development of new technologies to make these resources economic. Emission reduction is being increasingly mandated in most jurisdictions with all governments enacting progressively more stringent regulations. The industry has been responding with technological innovation. With the Kyoto protocol there is a push to reduce energy intensity in metal production. Technological innovation is driven by all the other factors and is leading to novel ways of doing exploration, mining and processing, that would maximize resource delineation and utilization, reduce costs, increase productivity, reduce energy consumption, maximize asset utilization and reduce environmental affects. Development of alternative technologies such as Pressure Acid Leach of laterite for nickel, bio-leaching, heap leaching, SX-EW etc are being adopted to achieve the aims of the industry.

Jan 1, 2005

By P. J. Le Roux

"Mining worldwide and definitely in South Africa, is constantly under pressure to reduce its cost structure so as to sustain profitability. In underground gold mines where an open stope mining method is employed, dilution often has a significant effect on the viability of sustaining profits. Target Mine practices Open Stope mining Method and it was found that in some open stopes dilution was in excess of 10%, which has a significant impact on the sustainability of the mine.Dilution in excess of 10% can result in the reduction of the recovered grade from 5,5 to 4,5 grams per ton (g/t). The reduction of 1 g/t in recovered grade results in a potential loss of about ZAR21 Million per month bases on a gold price of ZAR240 000 per kilogram. Based on Life of Mine projections the potential loss of income could be as much as ZAR3,3 Billion. A reduction in dilution would have the opposite effect. There are a number of factors which affect dilution of which falls of ground in open stopes is a major contributor. The falls of ground can be attributed to a number of factors such as beam failure as a result of a larger than normal expected roof area (hydraulic radius too large), poor ground conditions, and poor blasting. The cost of damage to or loss of trackless equipment as a direct result of the falls of ground in open stopes, is very significant. The review of financial figures has indicated that this could be as high as ZAR491 million. This combined with the added cost of transport, hoisting, secondary blasting, milling and plant treatment costs of ZAR293 results in an estimated opportunity loss of ZAR784 million.Currently there is a significant amount of data available in the mining industry which could be effectively used to develop suitable back analysis techniques but to date this has not been used effectively. If dilution can have such an impact on current and future mining ventures then the optimization of back analyses for the prediction of dilution in open stoping could assist significantly in the reduction of dilution in massive open stopes. Rockmass classifications, geotechnical information, blast techniques, blast design, the stress strain environment and hydraulic radius all have an effect on, or play a role in the evaluation of dilution. Each of these factors will be taken into consideration to ultimately determine a measurable or calculated percentage of dilution in massive open stopes.The amount of overbreak in an open stope can be determined by subtracting the planned stope volume in m3 from the actual measured final stope volume in m3, which is obtained from the CMS (cavity monitoring system). This is in turn divided by the planned stope volume in m3 to determine the percentage overbreak. The CMS wireframe is imported into the geological model and its grade re-evaluated. From this the actual percentage dilution for this open stope can be determined. The dilution obtained can result in a major reduction of recovered grade for the open stope, but can also increase the recovered grade. The latter is normally the exception rather than the rule.When analysing data from Target mine the following was achieved:• Using 11 years of data a method of measuring and predicting the percentage dilution in open stoping was developed. This took into account rock mass quality, stress-strain state, and the hangingwall hydraulic radius (size of stope hangingwall exposed).• Implementation of this prediction method resulted in a reduction in falls of ground in open stopes. The benefit of this was a reduction in the damage to mechanised equipment resulting from less falls of ground which had a positive effect on the profit margins of the mine. As a direct result the recovered grade from the open stopes increased due to the reduction in the amount of dilution.• A design criterion, Dilution Stress-Strain Index (DSSI), was developed which allows the user to calculate, with certainty, the stability of the open stope and determine if m"

Jan 1, 2015

By P. Su

Friction stir spot welding of a range of Mg-alloys is investigated (AZ91, AZ31, AM50 and AM60). The peak temperatures during friction stir spot welding of all Mg-alloys are close to their solidus temperatures. Also, the apparent material viscosity of Mg-alloy sheet is lower than that when Al-alloy sheet material is spot welded. This is important since it means that the widths of the stir zones forming during spot welding of Mg-alloy sheet are smaller than those when Al-alloy sheet is welded (when identical welding parameter settings are applied). These lower apparent viscosity values must be taken into account during numerical modeling of the Mg-alloy spot welding process. The efficiency of energy utilization is very low when Mg-alloy sheet is spot welded and is of the same order as that when fabricating Al-alloy sheet. The energy generation contributions of the rotating pin and the tool shoulder are investigated. When the spot welding operation is carried out without the application of a dwell period, the contribution made by the rotating pin vis-à-vis energy generation is around 66%. The contribution made by the tool shoulder increases to about 65% when a dwell period of four seconds is incorporated during the spot welding operation. This increase results from a longer contact time between the tool shoulder and material within the stir zone, The failure load during overlap shear testing increases when the bonded area and the energy input increase during spot welding. Sample failure initiates from unbonded regions and from discontinuities at the edge of the stir zone. The formation tendency of discontinuities is increased when Mg-Alloy sheet is spot welded because of the limited deformation characteristics of the base material at lower temperatures.

Jan 1, 2006

By A. R. Hekmat

Hypereutectic Al-Si alloys are used in applications that require high resistance to wear and corrosion, hardness and low coefficient of thermal expansion, To maximize the properties of these alloys, semi-solid processing can be utilized to modify the solidification structure of the primary silicon crystals as well as to reduce microsegregation and porosity, The transformation and spheroidization of primary Si crystals by shearing in the semi-solid state are not fully understood as they precipitate in the presence of other alloy phases, The objective of the present work is the determination the rheological characteristics of A390 (Al-17%Si-4,5%Cu-0.5%Mg) alloy using a Couette type (Haake RV12) viscometer and examining the microstructural evolution during continuous cooling and isothermal shear rate experiments, The effect of shear rate, solid fraction (temperature) and morphological evolution of the silicon crystals are investigated.

Jan 1, 2005

By A. R. Naji Meidani, A. Cameron, A. Richardson, M. Isac, R. I. L. Guthrie

The supersonic core of shrouded jets remain coherent over longer distances vs conventional supersonic jets. This phenomenon should allow for greater penetration of oxygen into slag/steel reactor systems. As such, they hold the promise for faster slag/metal mixing in BOF type metallurgical reactor systems, possibly creating greater surface area/volume ratios of reacting phases, and thereby faster kinetics, as compared to conventional supersonic jet systems. In order to assess the potential of shrouded supersonic jets versus their conventional counterparts, an experimental investigation of impinging shrouded supersonic jets into a water model of a simplified BOF system was carried out in the MMPC's water modelling laboratory. The experimental results for three different designs of a shrouded supersonic jet nozzle have been compared in terms of greater penetration depths and reduced mixing times. Based on a novel dimensional analysis, the depth of penetration of a gas jet into a liquid bath is shown to depend on the nozzle-bath distance, the liquid's Froude, Reynolds and Weber numbers, reflecting the ratios of gravity, viscous and surface tension forces to the jet's inertial, or momentum, forces. Good agreement between the mathematical model and experiment was obtained in terms of predicted and observed depths of penetration. Further efforts have been made to study jet penetration into liquid metals. The effects of mean liquid density of slag/metal mixtures and a wide range of gas flow rates on the penetration depth were investigated theoretically. The results show that the penetration depth can be increased with increasing gas flow rate and decreased bath density.

Jan 1, 2004

By W. Griffith

"While oxalic acid precipitation practices are commonly applied on purified rare earth elements (REEs) pregnant leaching solutions (PLS), few efforts have been reported using oxalic acid (OXA) to recover REEs directly from untreated PLS. High oxalic acid demand is the most significant issue in all these direct oxalic precipitation (DOP) practices. Preliminary research on DOP of REE from a dilute PLS originating from an acid bake followed by water leaching was conducted. At 75°C, the oxalic acid demand was between 12 and 18 times the stoichiometric requirement for complete REE precipitation. Conducting DOP at 25°C had superior REE recovery but the product purity and filterability declined. Between 75°C and 100°C, REE recovery increased with increasing temperature. When sodium hydroxide was used to adjust the pH during DOP, in the range of 0.5 to 1.5, higher pH benefited REE recovery. Using ammonium hydroxide in place of sodium hydroxide, the REE recovery was reduced by close to 5%. Sodium chloride addition to the PLS was also investigated and the results showed that at both 75°C and 25°C, the REE recovery was enhanced substantially. At 25°C, when the oxalic acid addition was controlled at 4.7 times the stoichiometric requirement, the overall REE recovery reached 95% with the addition of 240 g/L NaCl. Other reagents such as KCl, NH4Cl also showed significant enhanced REE recovery at the same oxalic acid addition. The addition of sodium sulphate appeared to largely enhance the precipitation of LREE but inhibited the formation of HREE oxalate. All results indicate the formation of rare earth double salts may play an important role in REE DOP sulphate media.INTRODUCTIONThe conventional routes for recovering rare earth elements (REEs) from a sulphuric acid pregnant leaching solution (PLS) involves an initial purification step for removal of iron, aluminium for example by precipitation through neutralization, followed by precipitation of REEs as hydroxide, oxalate or carbonate salts, or by bulk solvent extraction for REE recovery (Xia, 2013). Another route was used by Bayan Obo in their historical flowsheet, where the PLS was first subjected to double sulphate precipitation, then the remaining REEs, mostly heavy rare earth elements (HREE), were recovered by oxalate precipitation (Li, 2011)."

Jan 1, 2016

By A. V. Tarasov

There are still a number of copper smelters in the world using the roasting and smelting process flow diagram for treating sulphide raw materials. The technical, economic and environmental performance indicators of such operations are inferior to the respective indicators of advanced processes. First of all with respect to copper and sulphur recovery: 95% and 75% as compared with 98% and over 90%, respectively. Based on the studies of the single-stage smelting process to produce white metal and blister copper conducted during recent years an analysis of the feasibility of roastingsmelting technology improvement was carried out in the Gintsvetmet Institute to substantially increase the copper and sulphur recoveries. On the basis of this analysis, it was proposed to modernize the technology and equipment within the framework of the existing process flow-sheet. The proposed modernization implies an increase in the roasting temperature; higher desulphurization degree in the process of roasting; a number of modifications in the roaster design depending on the particular conditions of a given operation; addition of lime flux to the feed charge to roasting; and transition to combined calcium-silicate smelting slags. The metallurgical and energy computations made have indicated that the proposed modifications of the technology will improve the copper and sulphur recovery up to 98% and 90%, respectively. The required capital investments have been estimated using as an example a particular copper smelter, the payback period determined taking into consideration additional output, fuel saving and a reduction in fines for sulphur emissions. For comparison, the capital cost of a smelter modernization is given for change-over to basically new autogenous Ausmelt, Outokumpu and V anyukov smelting technologies.

Jan 1, 2007

By G. A. Fenton, A. Vervoort, M. Alvarez Grima

"High-risk underwater mining operations necessitate characterizing spatial heterogeneity and resource uncertainty. Local average subdivision is a method of simulating spatial deposit variability inside a cell through a sequence of discretization stages, during which a cell is further subdivided into four or eight cells. New developments are presented to validate simulated deposit models and deal with point measurements of geotechnical and ore-grade properties. This paper illustrates the relevance of translating spatial deposit variability into financial or operational performance indicators during underwater resource exploitation. Two synthetic case studies highlight the challenges of underwater mining in relation to production plans and equipment selection.RÉSUMÉ Les opérations d’extraction minière subaquatique à risque élevé exigent une caractérisation de l’hétérogénéité spatiale et de l’incertitude de la ressource. La moyenne locale de subdivision est une méthode de simuler la variabilité spatiale du gisement dans une cellule par une séquence d’étapes de discrétisation durant lesquelles une cellule est subdivisée en quatre ou huit cellules. De nouveaux développements sont présentés afin de valider les modèles de simulation des gisements et de traiter des mesures ponctuelles des propriétés géotechniques et de teneur du minerai. Le présent article illustre la pertinence de traduire la variabilité spatiale du gisement en indicateurs de rendement financier ou opérationnel durant l’exploitation subaquatique de la ressource. Deux cas synthétiques soulignent les défis de l’exploitation minière subaquatique par rapport aux plans de production et de choix des équipements."

Jan 1, 2015

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005