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By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

This paper presents the water management plan of the Mae Moh Project in the North of Thailand, which includes a large lignite opencast mine and thermal power plants. Lignite production will increase from the present 5.5 million tons per annum to approximately 20 million tons per annum by 1995 when the pit area will be about 20 sq.km. and the depth at over 300 meters. Seven power plants are proposed of which two are under construction. The total capacity to be installed is 2,925 MW. The principles considered for water management are firstly flood protection, including drainage of the mining pit and diversion of the Mae Moh stream away from proposed future mining areas; and secondly, a plan to meet the water requirement of the thermal power plants, while maintaining downstream supplies for irrigation and other purposes. The limited annual run-off of Mae Moh and Mae Chang watershed basins are inadequate for the proposed power plants. A study has been prepared to compare two approaches, namely conveying water from remote watersheds to meet the water requirement of the power plants up to total installed capacity; or by limiting future total generation, at the existing site, to only 2025 MV.

Jan 1, 1988

This paper will describe the exploration project which led to the discovery of the La Escondida porphyry copper deposit in northern Chile and will serve as companion paper to the description of the geology of Escondida being presented by J M Ojeda. The author would like to express his appreciation to Robert Hickman, Chairman of Minera Escondida, for permission to present this paper.In July 1978, a proposal was made by J D Lowell to Robert Wheaton, then Exploration Manager of Utah International, that Utah fund a "grass roots" program exploring for porphyry copper deposits in northern Chile. Wheaton expressed interest, and it was agreed that Getty Oil Co also be invited to participate. A joint venture agreement for the Atacama Exploration Project was signed January 1, 1979, between Utah, Getty and Lowell. The project was managed by Lowell who reported to a management committee which through most of the project consisted of Lowell, Francisco Ortiz, Robert Wheaton, Maurice Young, Sigfried Muessig and Louis Rove. Oliver Warin and Jim Bratt participated in the committee in the last phase of the contract. Special thanks are due Louis Rove of Getty and Maurice Young of Utah who made contributions throughout the course of the project. Francisco Ortiz was resident manager through most of the project.

Jan 1, 1990

Future hard rock mining will gradually move towards complete mechanisation which lends itself to remote control and ultimately to robotic mining. This will require different technical inputs into mining engineering and one of these is in the area of rock'mechanics. Traditional hard rock mining has had little rock mechanics input. Problems arising from high stresses and poor ground conditions have in most cases be remedied after they occurred, in the worst case by abandoning a particular stope or area and starting elsewhere. In a fully mechanised remote or robotic mining situation the financial penalty for such an approach could be severe, as a major part of the production costs will be in the development and the equipment. It is therefore imperative that a complete rock mechanics feasibility study is undertaken before an area is set up for robot mining and that a continuous stability monitoring system is installed that will predict rock behaviour well in advance of mining, such that the necessary ground control measures can be implemented without impeding the continuity of mining. This system will utilise already existing instrumentation such as extensometers and stress cells, and possibly additional improved instrumentation which has to be developed for this particular Application.

Jan 1, 1986

International tenders for contract mining opportunities require the Contractor to make an assessment of risk for an operation with a life span of up to twenty-five years usually based on data made available by the Client. This paper seeks to address how the Contractor assesses the data and quantifies the risks associated with the project. The areas of risk are common to most projects, but in the--Lontractor's case, risk assessment is carried out on the Client's data base and within a compressed time frame of usually less than six months. Incorporation of that risk assessment into the contract documentation is also discussed. Practical examples are given in a number of areas.

Jan 1, 1986

This paper will provide an overview of the coal mining industry operating in the Wollongong area, covering: the history and heritage of mining in the Illawarra region;unique features affecting mining in the region û opportunities and threats;current mining operations in the area;challenges facing coal mining in the region, including managing environmental impacts and seeking community support for mining approvals; andthe future for coal mining in the region. The paper aims to showcase the size and history of the coal mining industry around Wollongong and to emphasise the specific benefits and challenges that are faced by companies operating coal mines in such close proximity to urban and environmentally sensitive areas.

Jan 1, 2008

By Gluch KD

The current Mining Act has been the mechanism for administering and encouraging the State's mining industry through the 1970's up to the present. Although it has been subjected to considerable amendment there continues to be judicial challenge as well as criticism in relation to ambiguity of interpretation. Expansion of the mining industry and pressures placed upon "it by the ever increasing interaction with other land users have highlighted deficiencies in the current legislation and the need for a strong and progressive Act covering the rights and obligations of miners and their relationships with those outside the industry. - It is considered that the most positive results can be achieved by a complete redrafting of Queensland's mining administrative legislation.

Jan 1, 1987

The optimisation of human resources provides the path to improving productivity. British Coal has the goal of competitiveness with a quality product in ensured supply. High class skilled professional management teams will analyse job definition and selection procedures for posts, as well as objectives for and delivery of effective management training.Some fundamental changes in attitudes towards training as a means of achievement may be by managers at all levels self-examining their abilities to improve their styles, and by moving training more into the world of high technology techniques. The resulting improvements to management and training with attendant cost benefits will be enjoyed by the companies responding most effectively to these challenges.

Jan 1, 1991

By R A. Bearman

Recent demand pressures for iron ore should not distract from the longer term view that intense competition in the industry has demanded technological innovation of a high order. There is a long track record of successful innovation underpinned by a solid base of scientific research and knowledge. By comment on recent developments in trucks, comminution and direct smelting, this paper suggests that innovation is still a key attribute of the industry. The spending of the minerals industry on underlying science, however, is not particularly high. By looking at other industries we can ascertain that for step change technologies, it is particularly advantageous to have a solid base of science and technology underpinning developments.

Jan 1, 2005

By Ellis CG

The N.S.W. Department of Mineral Resources commissioned its first Mobile Gas Laboratory in 1973.Although originally intended for diesel exhaust analysis, it has been progress- ively made more suitable for mine air analysis. Currently there are two upgraded units in operation. These laboratories have been used at the scenes of four mine fires, two mine explosions and three recovery operations. The authors' experience jointly covers all of these incidents. In this paper they recount the role of the Mobile Laboratory in each incident - including the difficulties encountered - and trace the development of these units to their present state. Future improvements are foreshadowed, and some comments offered concerning the likely future role of these vehicles in mine Emergencies.

Jan 1, 1981

Thermo Fisher Scientific is a supplier of samplers, instruments, analysers and consumables to the mining industry under the Thermo Scientific brand. The critical need to provide a representative sample to the analyser has played a pivotal role in product development. Products discussed are the Analysis and Sampling Station (AnStat) for mineral slurries, the Coal Quality Manager (CQM) and the prototype Bore Hole Analyser (BHX) with optional drill chip recovery system. Analytical techniques used in the above products are XRF, PGNAA and LIBS respectively. The company also designs and supplies conventional mechanical sampling equipment and complete sampling systems for bulk material applications (historical Ramsey brand). These products and application of them are presented.

Jan 1, 2008

The low grade Mount Charlotte orebody was first mined with minimum capital expenditure by mechanised cut and fill stoping. The lower block was prepared simultaneously for open stoping by shaft sinking and installing another crusher and services. Similar development for the third block was discouraged by economic factors and reduced tonnage. Decline develop- ment required less capital and opened up ore reserves commensurate with advance, providing flexibility to stop operations without commit- ment: A 1 in 7 decline measuring 4.25m x 5.5m to accommodate standard Euclid 25 tonne dump trucks was developed south of the orebody. A fleet of four trucks average 12 loads each per shift over a haul distance of 700m.

Jan 1, 1973

The writer had the pleasure of several months' laboratory tests on a metallurgical process for copper ores devised by Mr. W. H. Corbould, Consulting Engineer, North Queensland. Mr. Corbould's research work in this direction commenced somesix years ago, and he eventually succeeded in obtaining a good extraction of copper and a resulting solution practically free from iron and other impurities. The commercial operation of the process was investigated and special machines with novel features were designed. OUTLINE OF THE PROCESS.The process described in detail in the following pages, required for successful application that the ores contain at least the minimum ratio of sulphur to copper, consistent with the production of sulphadising roasting conditions.

Jan 1, 1921

By Duncan B

Shortwall continuous mining as first introduced at Burwood colliery, and currently being used at John Darling, Lambton, and Corrimal collieries, is a method of coal winning which was pioneered in the Newcastle district. The system uses individual hydraulic self-advancing chocks for roof support and the coal winning operation is by continuous miners and shuttle cars. Where physical conditions are suitable the system provides a safe, efficient and economically viable basis for pillar extraction. Shortwall operations have been conducted successfully in the Victoria and Dudley seam, near the coastal fringe of the Newcastle district and are now being tried out in the more difficult conditions of the Bulli seam in the Illawarra district.

Jan 1, 1972

By Hikosaka A, Chiba A

In a fundamental study of the physical chemistry of steelmaking slag, equilibra bet- ween hydrogen-water vapour gas mixtures and liquid slags contained in solid iron crucibles have been measured for four binary slags, FetO-CaO, FetO-Si02, FetO-TiO2 and FetO-Al203 at 14000C. From the data, the activity of iron oxide and the ratio of ferrous and ferric ions (A = Fe3+/Fe2+) were calculated for the slag composition. The best ionic model is found to be that based on regular solution of cations. The oxygen distribution between slag and metal is quantitatively expressed by this model over a wide range of slag composition.

Jan 1, 1980

By Mandzic E. H

The Dome Mine of Timmins Mining company is located in South Porcupine, N.W. Ontario. The orebody being mined partially lies in the No. 3 shaft pillar. Stability analysis has been carried out to establish the influence of nearby mining on ground movement in the shaft vicinity. Mathematical modelling of shaft displacement has been done for stope layout at depths from 180-210 m and distances of 10-50 m from the shaft. Analysis indicated that ground displacement around the shaft is below 1 mm/m and one third less for cut and fill than in the case of open stope mining. The result of the investigation was later confirmed by cut and fill mining of this orebody.

Jan 1, 1986

By Pathan AG

This research work is concerned with an investigation of the fracture toughness of sandstone, siltstone, and coal. Tensile failure trades have been examined with three different specimen geonetries, i.e; rectangular bar, round bar (in three point bending), and diametral compression discs. The Stress intensity approach, and J-integral methods were used to evaluate fracture toughness. Results from both approaches are discussed. True crack length was determined after pre-cracking, using the compliance calibration technique. Fracture toughness results of sandstone are independent of crack length and the size of the specimen. Fracture toughness may hence be regarded as a material property for sandstone. In cxnntrast fracture toughness values for !siltstone and coal are dependent on crack Length.

Jan 1, 1986

The recent installation of top gas temperature probes in blast furnaces at Australian Iron & Steel Pty. Ltd. - Port Kembla, has provided the means for studying radial gas flow distribution in blast furnace shafts. This paper describes the top gas temperature probes and outlines their development and results of initial studies aimed at obtaining a suitable relationships between temperature profiles and furnace parameters. The effects of various combinations of burden materials have been outlined by the results reported. The use of probes has also helped to clarify the effect of casting cycles on furnace operation leading to increased emphasis on the reduction of the interval between gun-up and drill-out. Areas for future studies are also broadly Outlined.

Jan 1, 1975

By Y Wan, L Liao

Organo-montmorillonites were synthesised by intercalating different amounts of dodecyl trimethylammonium bromide, cetyl trimethyl- ammonium bromide and stear trimethylammonium bromide into montmorillonite layers, and were used for the adsorption of 17b-estradiol in aqueous solution. The adsorption kinetics and thermodynamic of 17b-estradiol onto organo-montmorillonites and the effect of pH on the adsorption capacity of organo-montmorillonites for 17b-estradiol were studied. The adsorption isotherms at 20¦C, 35¦C and 50¦C were measured. Results show that organo-montmorillonite has a high affinity for 17b-estradiol. More 17b-estradiol can be adsorbed on to organo-montmorillonite and the adsorption is more rapid at a lower temperature. The montmorillonite intercalated with cetyltrimethyl- ammonium bromide with the amount equivalent to one times of its CEC has the highest adsorption capacity. For all organo-montmorillonites synthesised in this study, an optimum pH (around nine) for the adsorption of 17b-estradiol exists. Before this pH 17b-estradiol uptake increased with increasing pH. After that the 17b-estradiol uptake decreased with increasing pH. Simulation of the isotherms indicated that the adsorption of 17b-estradiol onto organo-montmorillonites is a spontaneous and exothermic process. Endocrine-disrupting chemicals (EDCs) are the focus of current environmental concern, as they can cause adverse health effects in an intact organism, or its progeny, subsequent to endocrine function. Most EDCs are man-made organic chemicals (industrial chemicals, crop protection products, antifouling compounds, pharmaceuticals and personal care products). In addition, EDCs can be naturally occurring in the environment (eg the natural female hormones estrone and 17b-estradiol). Therefore EDCs, especially estrone and 17b-estradiol, are ubiquitous in the aquatic environment receiving sewage inputs. Estrogen and 17b-estradiol are among the most potent of all EDCs and are sufficiently stable to survive present sewage treatment processes and are reactivated during those processes through deconjugation (Clara, Strenn and Saracevic, 2004; Zhang and Zhou, 2005; Fukuhara et al, 2006; Butler and Guilbault, 2006; Volpe et al, 2006; Ren et al, 2007; Zeng and Li, 2007). In comparison to traditional contaminants such as pesticides, the concentrations of the most potent EDCs are low, generally within ng/one range. The current sewage treatment processes have limited capacity in removing certain EDCs (eg 17b-estradiol, C18H24O2) It is therefore essential to install additional treatment processes to remove them from wastewater before discharge (Zhang and Zhou, 2005; Fukuhara et al, 2006; Lee, Jung and Kim, 2006). Adsorption is considered to be a possible way to remove EDCs from aqueous solution. Various adsorbents have been studied, including chitin, chitosan, ion-exchange resin, activated sludge, activated carbon (Clara, Strenn and Saracevic, 2004; Yoona and Westerhoffa, 2003; Zhang and Zhou, 2005; Fukuhara et al, 2006; Ren et al, 2007). Studies have shown that organo-montmorillonite has a high affinity for organic pollutants (Li, 1997; Zhu et al, 1998; Han et al, 2001). The aim of this work is to investigate the feasibility of removing 17b-estradiol from aqueous solution by adsorption onto organo-montmorillonite.

Jan 1, 2008

By J Lane, D J. Barker, B Pei

Queensland Alumina Limited (QAL) is the worldÆs largest producer of smelter grade alumina, located in Gladstone, Queensland, Australia. The plant employs evaporative cooling towers for waste heat rejection. Process water requirements include red mud residue disposal, steam venting to the atmosphere and Calcination feed moisture. Raw (untreated) water consumption in 2001 was 37 700 m3/d or 3.8 m3 per tonne of production. The Gladstone region experienced a water shortage in the period 2001 to 2003, resulting in progressive water restrictions. Industry operated under a ten per cent restriction from April 2002 and in November 2002 a 25 per cent restriction came in force. The maximum restriction level of 50 per cent was anticipated for the middle of 2003. Water restrictions of these magnitudes have the potential to result in significant production limitations, which would have major economic consequences for QALÆs owners, customers, suppliers and employees. Therefore it was imperative that measures be found to mitigate the impact of these restrictions. Furthermore, as one of the largest water users in the Gladstone region, QAL had an obligation to the community to minimise water usage as much as possible. A thorough analysis of water usage on site was conducted, focussing on all water streams leaving the plant. The philosophy used was that by minimising water outputs, the inputs would follow suit. Where possible, preference was given to solutions that provided lasting water savings. This occurs when the value of the water saving justifies the project cost, irrespective of water restrictions. By June 2002 an average water saving of 19 per cent was achieved, almost double the required saving. By end November 2002 further projects had increased the total water saving to 29 per cent, mainly through the re-use of GladstoneÆs municipal treated effluent as wash water. Further measures to reach the target of 50 per cent reduction were investigated. The evaporative cooling system was to be replaced with seawater cooling, using cooling towers to minimise the seawater pumping cost. Another benefit of this concept was the ability to dispose of the cooling tower bleed stream with the existing system for neutralised red mud disposal. This would avoid the need for an additional environmental outfall from the plant. In February 2003 the Gladstone region received over 500 mm of rain, which boosted water reserves to five years supply at forecast usage rates. This led to the lifting of all water restriction. As most of the implemented water savings measures are economically viable in the absence of water restrictions, raw water usage at QAL is still less than 75 per cent of pre-2002 levels.

Jan 1, 2003