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By S N. Nyoni, K C. Corin, C T. O’Connor

Considering future water scenarios, as influenced by the increasing scarcity of water and the move towards sustainable process engineering etc, the closed water circuit becomes an important point of study in metallurgical operations, such as in milling and flotation. However, a deterrent in the use of recycled process water is often a lack of understanding of the effects of the accumulation of dissolved ions and other process chemicals. Recovery of the valuable minerals may be impacted by the concomitant complex mineral-pulp chemistry interactions. Literature indicates that these interactions are not necessarily antagonistic to process outcomes. Wet milling using steel media results in the dissolution of Fe from the media, the rate of which is dependent, inter alia, on the type of media and the chemical conditions of the aqueous environment in the mill. The pulp-phase interactions of dissolved ions with sulfide minerals may result in significant changes to the chemical conditions in the mill, which may subsequently impact negatively on the flotation recoveries. To understand the effect of these interactions in the context of the processing of sulfide minerals, this study seeks to consider the effect of three factors, viz mineral type – pyrite (Py) and galena (Gn) -, milling media of different compositions – forged steel (FS), 21 per cent high chrome and ceramic media -, and water chemistry, viz, deionised water (DI) and synthetic plant water (SPW). Ceramic media and galena are used for the respective control cases where the milling media and sulfide mineral contribute no Fe species. Using DI as a control case, a high ionic strength case is used to mimic the changes in water chemistry for a closed water circuit. Batch flotation tests are used as a diagnostic tool to determine the effects of these media-water-mineral interactions to investigate correlations between the chemical reactions occurring and chemical species present during the milling process and the ultimate flotation performance.

Aug 24, 2022

By E Rubio, N Morales

Currently, mine plans are optimised by using several criteria as objective functions, like profit, life-of-mine, concentration of some pollutants, mining costs, confidence level or ore resources, with consideration of constraints related to production rates, plant capacities and grades. Whilst this approach is successful in terms of producing high value production schedules, it uses a static opening sequence of the drawpoints and therefore the optimisation is made within the level of freedom left by the original opening schedule, and as a result it is far from the true optimal value of the project. This paper presents a model to optimise the sequence of drawpoint opening over a given time horizon. The emphasis is in the precedence constraints that are required to produce meaningful operational sequences considering the exploitation method (panel or block caving), physics considerations and logical rules. Further on, while it applies the standard approach of maximising net present value (NPV), it considers other targets for optimisation, like the robustness and constructability of the plans. Finally, it applies the model to real data to obtain feasible plans by means of this model. The first tests were done varying the production capacity of the mine.

Sep 26, 2011

By J Krnmmelbein, T Raab

In Lusatia, lignite mining causes major disturbances on the landscape scale. Reclamation procedures are applied to recover the reconstructed landscape for different land use options. In this study we investigate soil physical properties of an agricultural reclamation/recultivation site directly after site restoration and the development of selected parameters within the first years after site restoration depending on varying recultivation strategies.The sandy substrates used for recultivation stem from depths of several meters. They are unstructured, free of recent organic matter and have high contents of calcium carbonate. During reconstruction and most of all during surface levelling with heavy crawlers, the substrate?undergoes high mechanical stresses. This leads to partly severe soil or substrate compaction, depending amongst others on substrate water content and mechanical stresses during site construction. We investigate the effect of different organic soil amendments, different crop rotations and partly subsoiling on the development of soil structure. We compare results of laboratory measurements directly after site construction before any reclamation measures had been applied to results we gained after three and four years of recultivation. The results show that after the earthworks are completed, the site is strongly heterogeneous in relation to mechanical stability, permeability for air and water, pore volume and bulk density. The results after three and four years show that the heterogeneity of soil physical parameters decreases. The selection of suitable crop rotations superimposes the affects of other reclamation measures, eg varying organic fertilisers or deep loosening.CITATION:Krnmmelbein, J and Raab, T, 2012. Reclaimed lignite mining areas A73 in Lusatia - Development of soil physical parameters of an agricultural site within the first years after site reconstruction, in Proceedings Life-of-Mine 2012 , pp 117-122 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By P Bethune

Back Creek is a tributary of the Condamine River. It flows in a northerly direction across the existing Commodore coal reserves. The diversion of Back Creek was proposed to minimise sterilisation of the reserves. The approval process required a Waterworks Licence application, under the Water Resources Act 1989 (Qld), for the construction of a stream diversion channel and floodway. The diversion was designed using the æreference reachÆ approach, which mimicked existing properties of Back Creek. The following design standards were developed for the diversion: the diversion corridor width was 500 m; the diversion geometry was specified for both the low-flow channel, and the floodplain; material properties were specified for both the low-flow channel lining and the diversion bund; compaction standards for both the low-flow channel and floodplain were set; and the diversion rehabilitation included a riparian corridor and pasture land with clumps of native trees and shrubs. The following performance criteria were developed for the diversion: velocity regimes were replicated for the design events considered, in an attempt to avoid increasing the diversion flow velocities in comparison with the existing creek flow velocities; sediment transport calculations indicated that no significant change in sediment transport was expected within the diversion; overburden settlement estimates for the spoil placed in the corridor were summarised, and will be monitored throughout the construction process; geotechnical stability of the proposed Eastern Pit Buttress and the diversion bund configurations was confirmed; and groundwater impacts were assessed. Construction techniques, monitoring and further investigations are also discussed in this paper.

Jan 1, 2003

By S Basu, P M. Midhun

Electro-Slag Remelting (ESR) is a process capable of producing ingots with much lower centre-line segregation and better internal soundness than conventional ingot casting processes, as well as lower inclusion and sulfur concentrations. This process is commonly used for alloyed steels intended for critical applications like components of marine turbines, supercritical powerplants and rocket motor casings. It involves melting a metal electrode using electrical resistive heating in a slag pool and re-solidification of the resulting metal droplets beneath the slag layer, forming an ingot. Conventional ESR fluxes consist primarily of CaF2, Al2O3 and CaO, along with minor concentrations of SiO2, MgO etc. The emission of fluoride vapour from the molten slag causes several environmental and health problems, triggering a need to develop and reduce the fluoride content in the ESR flux. The present study aims to develop low-CaF2 alternatives to commercial ESR fluxes without compromising on productivity and the surface quality of the refined ingot. Thus, the modification in chemical composition needs to satisfy properties like electrical resistivity, viscosity and liquidus temperature, essential for efficient ESR operation. Since electrical resistivity and viscosity are highly dependent on the ionic structure of the molten slag, it is important to understand the effect of compositional modification on the structure of the flux. The present study employs Fourier-transform infrared spectroscopy (FT-IR) and Raman spectroscopy to investigate the structural variations in the modified fluxes, especially the effect of changing SiO2 concentration, in comparison with conventional CaF2-rich fluxes. Additionally, thermal analysis (Differential Thermal Analysis (DTA) and Thermogravimetric Analysis (TGA)) has been carried out to characterise the melting behaviour of the fluxes. The findings are compared with simulations carried out using the FactSage™ software, ver 8.3 (GTT Technologies, Aachen, Germany). Simultaneous analysis of liquidus temperature and the structure is expected to help in identifying the practical suitability of modified ESR flux compositions for industrial implementation.

Jun 19, 2024

By C M. Côte, P Bolz, R Chrystal

The design of final landforms is an integral part of mine closure plans in Queensland and aims to ensure the rehabilitated land is safe, stable and non-polluting. Landform stability in this context is commonly assessed using Landscape Evolutions Models (LEM) which are physical models simulating sediment erosion and deposition around individual landforms over long timespans (up to thousands of years). The most used LEM for assessment of rehabilitated landforms in Queensland is SIBERIA (Willgoose, Bras and Rodriguez-Iturbe, 1991; Tucker and Hancock, 2010). SIBERIA models are complex, require very detailed input data and simulate erosion and deposition over time frames that extend decades beyond closure. They are not suitable to assess erosion risks during the operational phase of a mine and to support the development of erosion and sediment control plans. Other types of erosion models, such as the Revised Universal Soil Loss Equation (RUSLE, Wischmeier and Smith, 1978) or Water Erosion Prediction Project (WEPP, Nearing et al, 1989) calculate soil loss on a monthly or yearly basis and are much better suited to erosion management during the operational phase. They are simpler to implement and can support the design of control measures. For instance, designing a sediment basin requires quantification of sediment loads, which can be produced by these models. In Queensland, the legislation around sediment and erosion control for open cut mines is currently tightening. Soil erosion remains a major concern due to potential impacts on the receiving environment. It requires management during operation and for closure consideration alike and it is critical that erosion and sediment control plans are developed with the most appropriate tools. Globally, RUSLE is the most widely used soil loss model (Borrelli et al, 2021). This is because it is an empirical model with relatively simple input requirements: biophysical data such as soil properties, vegetation cover, topography and rainfall variability, which can be directly measured or derived from regional or national databases and/or spatial data sets that are available in most parts of the world. The second most used model is WEPP (Borrelli et al, 2021) but compared to RUSLE, there is a large drop in the frequency of its use. This is because WEPP is physically-based and has more complex data requirements. WEPP integrates hydrology, hydraulics, erosion mechanics and land cover to predict soil erosion and sediment transport on hill slope profiles and small watersheds (Stolpe, 2005). It requires some biophysical parameters in formats different from those of RUSLE, as well as detailed hydrologic and catchment data. Nevertheless, it has been used in landform design for mines across Australia to determine final landform stability (eg Howard and Roddy, 2012; Costin, 2020). In this study, we assess which tool would be the most appropriate to support development of erosion and sediment control plans from operation to closure. We use RUSLE and WEPP to predict soil loss from a mine site, compare the results from both models and outline the advantages of each method.

Aug 2, 2023

By M I. Pownceby, N Karimian, A Frierdich

These may be found with goethite through mechanisms including direct substitution or coprecipitation of nanocrystalline phases. Understanding P incorporation in goethite has significant implications for Australia’s iron ore industry as it lowers their commodity value. The current study tests a novel low-temperature technique to extract P impurities from synthetic goethite phases under O2-free ambient conditions by utilising Fe(II)-catalysed recrystallisation. The objective of this study was to examine the effect of the Fe(II)-catalysed recrystallisation of goethite on the geochemical behaviour (mobility and speciation) of co-associated P. To achieve this, we tracked changes in labile P (aqueous and 1M NaOH extractable) concentrations over time in goethite suspensions which were reacted with Fe(II)aq for 14 days under circumneutral pH conditions and room temperature conditions. Temporal changes in Fe mineralogy were investigated via synchrotron-based X-ray absorption spectroscopy. Iron K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy confirmed goethite as the only mineral phase in P-free treatments while goethite (~86 per cent) and feroxyhyte (~14 per cent) were the main phases in 1.0 per cent P-containing treatments after a 14- day reaction with Fe(II)aq. According to our findings, the treatment of P-goethite with Fe(II) for a duration of 7–14 days, followed by a 24-hour extraction of the reacted solids using 1M NaOH, results in the removal of approximately 79.5 per cent of the initial P content. This removal encompasses both the aqueous fraction (~4.5 per cent) and the surface adsorbed fraction (~75 per cent) from the 1 per cent P-bearing mineral phase. Notably, this approach demonstrates an improvement in P extractability, with approximately a 10 per cent increase compared to the 1 per cent P-goethite sample that was not reacted with Fe(II).

Sep 18, 2023

This paper describes the MillMapper technology developed for condition monitoring of liners and other operational parameters in grinding mills used for mineral comminution, by presenting a case study of its application. MillMapper provides maintenance engineers, operations managers and process and plant metallurgists with quantitative, accurate and reliable condition monitoring data for informed decision making regarding the maintenance and metallurgical aspects of such mills. MillMapper uses calibrated laser scanners for the capture of three-dimensional surface representations inside a mill during a shutdown so as to determine shell, feed and discharge liner thickness at a resolution of several million data points, a procedure that nominally takes five minutes to complete. Once several data sets over time have been collected inside a mill, MillMapper can be used for liner wear, liner wear zone, liner weight, ball charge volume, ball charge weight and intelligent profile tracking over time. Liner tracking in combination with site defined reline and failure criteria and with throughput tonnage data is utilised for change out prediction of each separate liner segment type.

Jan 1, 2008

By Riley S. J

Ranger Uranium Mine is located within the Alligator Rivers Region of the Northern Territory of Australia and surrounded by the World Heritage listed Kakadu National Park (Figure 1). The mining operation is currently producing about 1500 tonnes of uranium oxide annually, as well as considerable volumes of waste rock, low grade ore and tailings. The rehabilitation of the project should ensure that the radioactive mill tailings and other contaminants remain contained for at least 200 years, as required by the existing guidelines (Commonwealth of Australia, 1987). The present uranium mining operation is regulated by the Northern Territory Department of Mines and Energy who must refer to the Environmental Requirements when considering regulatory options. These Environmental Requirements were agreed by the

Jan 1, 1994

By R E. Gerald II, B Zhang, T Sander, J D. Smith, J Huang, R J. O’Malley, H Tekle

In the steelmaking process, mold fluxes are essential for ensuring thermal insulation, refining, and the efficiency of continuous casting. Real-time understanding of the in-service composition of slags and fluxes are crucial for optimising the steel production process and improving the quality of the final product. An in situ fibre-optic Raman probe that enables the study of the structure, composition, and viscosity of molten slags and fluxes at steelmaking temperatures has been developed and demonstrated both in the lab and in foundry scale experiments. The focus of this study is on the structural, compositional, and property analysis of molten fluxes in a laboratory setting, with the aim of applying this technology for in situ monitoring during industrial production. Raman spectra were successfully collected at various temperatures from 1000°C to 1400°C in real-time and analysed using a deconvolution algorithm to isolate and quantify peaks in the spectra associated with the specific structures of molecular components in molten and solidifying flux. The research successfully combines in situ Raman spectroscopy with high-temperature viscosity data, specifically targeting CaO-CaF-SiO2-Al2O3 based mould flux systems. Specified ratios of the deconvoluted Raman peaks, such as Al-O-Al/Si-O-Si ratio, shows good correlation with the flux chemistry, while the Q3/Q0 peak ratio shows good correlation with viscosity. A ruggedised Raman probe system was also developed and demonstrated in an 80 kg induction furnace. Ultimately, the goal of this work is to demonstrate in situ slag and mould flux analysis in industrial processes, such as in the continuous caster or electric arc furnace (EAF).

Aug 21, 2024

By M-E Boucher

While the haematite concentrates produced in Eastern Canada and the magnetite concentrates that Australia will soon be producing are different feed materials, the pellets they produce have similar physical and metallurgical properties. This paper will examine the similarities and differences in the evolution of pellet microstructure for pellets produced from magnetite and haematite. The molten slag phase generated at high temperatures has a lower melting point when in contact with magnetite compared with haematite due to the higher divalent iron content. The presence of some slag is beneficial for bonding but too much can inhibit oxidation of magnetite, although slag generation at lower temperatures reduces energy usage. In pellets produced from haematite, magnetite is generated artificially from the combustion of the carbon particles added to the pellet feed as a source of energy. Maintaining the optimum production level and mineralogy of such æsecondaryÆ magnetite, allowing for its subsequent reoxidation, is important for the quality of haematite pellets. In both magnetite and haematite pellets, balancing the slag formation and oxidation (re-oxidation for haematite pellets) of the magnetite (secondary magnetite for haematite pellets) is necessary.

Jan 1, 2007

By T C. Souza Pinto, M Safari, F S. Hoseinian, D Deglon, L Leal Filhoc

In this study, the effect of hydrodynamic parameters on the iron ore reverse was investigated in a mechanical flotation cell. The work carries out using the case study of Iron ore from Vale in Brazil. The influence of hydrodynamic factors such as froth height, impeller speed, superficial gas velocity and solids percentage were evaluated on the quartz flotation. The results showed that the hydrodynamic conditions have a great effect on the flotation performance, especially on the fine and coarse quartz. The size-by-size analysis of the froth products showed that froth height, impeller speed, superficial gas velocity and solids percentage have a significant effect on true flotation quartz particles. The increase in the froth height decreased the recovery of quartz particles. The increase in the impeller speed increases the recovery of quartz particles to an optimum. The increase in the superficial gas velocity improved the flotation of coarse quartz particles. The increase in the solids percentage increases the recovery of quartz particles.

Sep 18, 2023

Incremental sampling is defined as a solution to fight segregation, the theory is demonstrated and theoretical and practical aspects are discussed. The number of increments necessary for successful sampling is discussed. As an application, riffle splitter division is reviewed.

Mar 1, 2010

The project is undertaken by Elgas Pty Ltd, a 50 per cent joint venture between AGL and BOC, to store 65 000 t of LPG in underground storage at Port Botany, NSW. The contractor, Concrete Constructions Pty Ltd, elected to use drilling and blasting techniques. The project specification called for the following works to be excavated: Access Shaft:122 m (out of 140 m total depth), 6.0 m diameter (selected by the contractor),Operation Shaft:125 m (out of 150 m total depth), 4.0 m diameter,Water Curtain Gallery:500 m (Later extended by additional 270 m), 4.0 m wide and 3.5 m high,Storage Caverns:910 m, 14.0 m wide, 11.0 m high,Top Heading:14.0 m wide, 5.5 m high,Bench:14.0 m wide, 5.5 m high,Connection Galleries:250 m, 5.5 m wide, 5.5 m high.A total of 156 000 cubm of rock to be excavated.

Jan 1, 1999

By L B. Sukla, V N. Misra

Microbial desulfurisation of coal has significant advantages over physicochemical desulfurisation processes since the former process selectively removes the inorganic sulfur compounds and heavy metals without significant carbon loss. The purpose of this study was to improve the desulfurisation yield of a coal sample from northeastern coalfields, Assam, India using microbial technique. The coal sample contained 2.13 per cent of total sulfur and 2.59 per cent of ash. Stirred tank reactors of 40 L capacity were operated in batch mode. Initially, the reactor was fed with 40 L of slurry containing ten per cent (w/v) coal, ten per cent (v/v) inoculum of mixed culture of mesophilic acidophiles, native to coal itself and the requisite amounts of constituents for 9K medium without added ferrous sulfate. The percolate of the reactor was then used to seed the medium for the next experiment. The purpose was to obtain a better adapted and more active biomass which would give a better desulfurisation yield for coal. Further studies were conducted in the bioreactor, fed with 40 L of slurry containing ten per cent (w/v) pulp density of coal, ten per cent inoculum (derived from previous studies) and the medium, supplemented with ferrous sulfate. Results showed an increased total desulfurisation yield of 43 per cent in the latter treatment in comparison to the previous one, where the desulfurisation yield was only 23 per cent. The findings also demonstrated the convenience of using inocula derived from coal, where 50 - 60 per cent of pyritic sulfur was removed, while chemical desulfurisation is of little significance with the majority of coal types. The ash content was also reduced to 1.74 per cent as the low pH of the process caused dissolution of a number of common minerals present in the coal.

Jan 1, 2004

By Y-B Kang, J H. Park, J Park

In order to understand the effect of oxygen injection into the molten metal on the valuable metals (VM) recovery and interfacial phenomena, several high-temperature experiments were conducted using a high-frequency induction furnace with a quartz tube as the reaction chamber at 1673 K. Copper-based waste printed circuit board (PCB) that contains some impurities was selected as the end-of-life resource. CaO-SiO2 based pre-fused slag and oxygen gas were used in present works. The composition change and microstructure of the samples were analysed. As oxygen was injected into the system, impurities were rapidly removed. After the removal of impurities, continuously injected oxygen lowered interfacial tension between liquid slag and liquid metal. Lowered interfacial tension induced Cu loss into the slag.

Aug 21, 2024

By S Hapugoda, A Edenton, M Adam, R J. Holmes, J R. Manuel, R Smyth

Lump ore is one of the key ferrous feeds used in the blast furnace ironmaking process, normally accounting for ten to 20 per cent of the blast furnace burden. Like other feeds, the characteristics of lump ore have an important impact on the stable operation and productivity of the blast furnace. Lump ore is usually assessed chemically, physically and mineralogically to establish its likely blast furnace performance. The physical characteristics of lump ore are strongly related to the chemistry, mineralogy and texture of the ore involved. In this paper, the blast furnace ironmaking process is reviewed, with particular emphasis on the key quality requirements for the ferrous burden material. A variety of key physical characteristics of lump ore measured using standard and non-standard methods are then described and subsequently correlated with the chemical and mineralogical characteristics of the ore wherever possible. Finally, the impact of these physical characteristics on blast furnace operation is assessed.

Jan 1, 2009

By D K, S Freij, A Rossiter, X Han, B Feng

In mining operations, the removal of overburden to expose the ores is achieved by rock blasting using ammonium nitrate based explosives, eg ammonium nitrate-fuel oil mixtures, commonly known as ANFO. However, ammonium nitrate can react with pyritic shales that are often found in many mines, leading to premature detonation or spontaneous explosion. In order to minimise the occurrence of spontaneous explosion, the reactivity of the shale in a mine must be assessed. This will provide a better understanding of blasting risks and thus will improve the safety and the cost efficiency of blasting through the selection of appropriate explosives. In this study, shale samples were collected from different locations in Western AustraliaÆs Mt Whaleback iron ore mine and geochemically characterised. The reactivity of the shale samples towards ammonium nitrate and ANFO was investigated using a combination of large-scale firing range tests and laboratory isothermal reactor tests. Results of the firing range tests show that the reactive ingredients of the shale are the limiting factor for the reactions between shale and ANFO. Based on the firing range test results, further isothermal reactor tests were conducted to investigate the reactivity of shale samples towards ammonium nitrate under controlled conditions. Analysis of the results from the firing range tests and the isothermal reactor tests shows that there are correlations between the reactivity of shale samples and several geochemical characteristics such as sulfate, sulfur, ferrous and zinc content.

Jan 1, 2005

By I F. Wood

Planning for flooding and assessment of flood impacts are important requirements for mining projects, as they are also for other types of development. With more intense development and concern from the community, supported by government regulatory requirements, assessment of flood concerns and impacts has become of increasing importance. To ensure that flooding issues are fully understood and results presented in an appropriate format, advanced hydraulic analysis procedures have been developed and are beginning to be applied. These procedures must be rigorous in an engineering context but the results must also be readily understood by the community and government agencies. Advanced two-dimensional hydraulic modelling is becoming accepted as an important means of assessing flooding issues for mining projects. With presentation of results from hydraulic models with Geographic Information Systems (GIS), flood impacts can be analysed rigorously and presented clearly. This paper discusses the application of advanced hydraulic modelling in the planning and impact assessment of a major mining project located on a floodplain where there is extensive inundation. The analysis provides for both input to the planning of the project and for detailed assessment of potential impacts. This case study illustrates some important aspects of the application of hydraulic modelling using a two-dimensional modelling to a critical flood design.

Jan 1, 2003

By B G. Lottermoser

Phosphate induced stabilisation has been used to create passive iron phosphate coatings on pyrite and pyrrhotite. The formation of solid phosphate coatings on sulfide grains thereby inhibits sulfide oxidation. The aims of the study were to determine whether phosphate induced stabilisation could control sulfide oxidation and metal mobility in partly oxidised, polymineralic, sulfidic mine wastes. Waste materials were obtained from the acid mine drainage generating, abandoned Montalbion silver mine site, far north Queensland, Australia. The waste consists of quartz, kaolinite/illite, sulfide minerals (galena, chalcopyrite, tetrahedrite, sphalerite, pyrite, arsenopyrite), and pre- and post-mining oxidation products (hydrated Fe, Cu, Pb and alkali mineral salts). SEM observations of waste material treated with potassium orthophosphate showed that metal, metal-alkali and alkali phosphate coatings developed on all sulfides (with the exception of tetrahedrite). The abundance of phosphate phases was dependant on the availability of cations in solution for complexation with the phosphate anion. In turn, the release of cations was dependent on sulfide oxidation or the dissolution of efflorescent mineral salts. Experiments aiming to dissolve these phosphate coatings û using a strongly oxidising solution û showed that the phosphate coatings remained stable, preventing acid generation and metal release. The results of this study demonstrate that liquid phosphate stabilisers can suppress sulfide oxidation and immobilise metals in partly oxidised, polymineralic mine wastes.

Jan 1, 2003