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By N Kojola, A Vickerfält, J Huss

The possibility of using an acidic autogenous hydrogen direct reduced iron (H-DRI) slag as a basis for vanadium extraction is investigated. For a raw material to be suitable for producing high-quality FeV, the vanadium oxide content should be sufficiently high and the phosphorus oxide content in a tolerable range. Therefore, the feasibility for vanadium extraction relies on fulfilling two demands: the predominate partitioning of phosphorus to the metal and vanadium to the slag. Correspondingly, the behaviours of phosphorus and vanadium in the Al2O3-SiO2-FeOx-VyOz-P2O5-Fe system were studied experimentally. Slag, 10 g, was put in contact with liquid iron, 30 g, for different durations (2–24 hrs) in closed alumina crucibles at 1873 K. The slag composition was varied between 33.1– 49.3 wt per cent Al2O3, 27.1–46.7 wt per cent SiO2, 16.6–30.1 wt per cent FeOx, and 2.5– 8.8 wt per cent V2O3. The equilibrium phosphorus distribution was 0.42, while the vanadium distribution ranged from 7.6 to 43.4, increasing with the Al2O3- and the FeOx-content.

Jun 19, 2024

By Maloszewski J, Kidybinski A, Sawka B

A forecast of mining conditions in Upper Silesia collieries for the beginning of the 21st century has special focus on average depth of mining, energy of seismic tremors induced by mining and energy of dynamic loads on roadway supports. A method of dynamic loads calculation is based on volume of failed rock surrounding an opening and the seismic energy of tremors anticipated. New types of yielding steel arch supports have been designed to resist massive static and dynamic loads and a system of supports has been tested both on 1 : 10 scale models and in natural size. The support sections used are 29, 36 and 44 kg/m.

Jan 1, 1988

By J L. Mauk

The Favona adularia-sericite epithermal Au-Ag deposit is located at the southern end of the Hauraki Goldfield, about one kilometre southeast of the world-class Martha deposit. The deposit occurs in Late Miocene andesitic lava flows and local dacitic tuffs of the Waipupu Formation. In some places, post-mineralisation ash fall and ignimbrite, up to 50 m thick, cover mineralised rocks and andesite. We collected soils samples from 110 sites along eight traverses over Favona, and from three regional lines: two south of Favona, and one north of Favona.   Analyses of soils identify prominent enhanced concentrations of Au, Ag, and Hg, and lower enrichments of Sb and As. At Favona, Au and Ag appear to be highly anomalous in areas over mineralisation with Au concentrations greater than 100 ppb and Ag concentrations greater than 1000 ppb, whereas background concentrations are approximately 5 ppb and 50 ppb respectively. The background concentrations of Hg in soils are approximately 100 - 200 ppb, but in mineralised areas, Hg generally exceeds 200 ppb, and some soils contain greater than 600 ppb. Antimony shows enrichments, although weak, above known veins and As locally shows some enrichment above areas of known mineralisation. Therefore, soil sampling at Favona defines geochemical anomalies that correlate with the position of known mineralisation at depth. Thus, there is strong empirical support for the use of Au, Ag and Hg, and possibly Sb and As geochemistry to identify mineralised trends associated with buried deposits at other epithermal prospects.

Jan 1, 2007

By Wooltorton B

Highwall failures in surface coal mines in Queensland occur as circular slips through weak and weathered material, or as bilinear slides on sub-horizontal surfaces and steeply dipping joints. Weak horizontal planes occur in the Permian-Tertiary unconformity or on bedding surfaces within the Permian Coal Measures. Sub-vertical movements occur along rock joints and tension cracks induced by stress relaxation after excavation. Blasting also introduces new fractures and causes movement along existing rock discontinuities. Critical factors for stability include the dip direction of potential failure surfaces, shear strength of the rocks, damage due to blasting prior to highwall excavation, groundwater conditions, the type and performance of clays on shear surfaces, and pit geometry.

Jan 1, 1981

By G M. Evans, C M. Phan

This paper presents an analysis on the dynamic adsorption of frothers and collectors onto air bubbles in flotation. The analysis was carried out using the theory on the surfactant transfer by diffusion and adsorption. The bubble size was considered when solving the diffusion equation for the dynamic surface excess. The adsorption kinetics was modelled employing the Langmuir adsorption isotherm and its extension with the inclusion of the lateral interaction of the adsorbed molecules (the Frumkin adsorption isotherm). The numerical computation was applied to solve the governing equations. The dynamic adsorption of the surfactants was measured in terms of the dynamic surface tension for sodium dodecylbenzene sulfonate (SDBS) and Dowfroth 250, using pendant bubble tensiometry. The results show that for air bubbles with diameter of the order of 1 mm, the bubble size effect on the dynamic surface tension is small and the solution of the diffusion equation for a planar gas-liquid surface can be used to describe the dynamic adsorption onto the air bubbles. The experimental data obtained with SDBS were well described by the Frumkin adsorption isotherm and the molecular diffusion. The model description for the experimental data obtained with Dowfroth 250 required the kinetic equations. The paper is relevant for further analysis of the role of the adsorbed surfactants in the particle collection.

Jan 1, 2005

By S H. Sie, R Seetharam, K Naito, T Takagi

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medicallhigh-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnS2), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995

The phenomenon of Instantaneous Outbursts, although not new to Australia, was sharply drawn to the attention of the local coal-mining industry by two isolated fatal occurrences on widely separated fields, both late in 1954. An outburst is the eruption of apparently solid coal from the face, aided by vast quantities of gas released from the coal, as the coal fails under mining stresses additional to its natural stressing.The gases involved are principally methane and carbon dioxide. The various factors which combine to produce outburst conditions range from external factors such as stresses arising from depth of cover and other causes, to inherent factors such as strength of coal,and its capacity to retain gases (sorption). Of the localities where instantaneous outbursts occur the Gard Basin in Southern France has had the greatest number and the most serious occurrences. By contrast, local outbursts have been minor.Experimental work into some influencing factors has been carried out by various overseas authorities and some research has been accomplished in Australia. Practices used in some overseas areas to improve safety of working are largely empirical, as are the local rules and recommendations for work in affected areas.The appearance of further outburst areas is anticipated as mining becomes more extensive and deeper.INTRODUCTION"Instantaneous Outbursts" can be described as violent eruptions of coal from the solid accompanied by considerable gas evolution. The projected coal is usually of small size, and a high proportion is pulverized, and may be carried and deposited over great distances by the gases, liberated from the outburst. This outburst coal is of bituminous to anthracitic rank, and the gas involved is essentially methane or carbon dioxide, or a mixture of both. Outbursts involving carbon dioxide are usually more violent and dangerous. The phenomenon is relatively unusual, being confined to probably sixteen known areas in the entire world, these areas comprising only portion of the coalfields in which they occur. Usually only one or two mines on each field are affected.

Jan 1, 1958

By M Bond, R R. Hargreaves, G W. Booth

There are numerous causes of speculative mineral resource and reserve inflation. Traditionally, these are linked to issues of data accuracy or misinterpretation, the use of overly optimistic estimation parameters or assumptions, an absence of independent expert verification, or the simple pressure to increase company value, covert or otherwise. Owing to its subjective nature, classification of resources and reserves remains an opaque process. Of necessity, Competent Persons rely on personal heuristic interpretations, ideally underpinned by appropriate estimation and classification experience across commodity and deposit types. Whereas independent verification of individual resource and reserve statements remains impractical, publicly available data can be interrogated for potential category inflation, particularly when viewed with exploration expenditure statistics included in annual company reports. Abrupt changes in category tonnages and market capitalisation without concomitant expenditure can aid in outlier detection. Consequently, a comparison of common exploration and resource reporting parameters offers a basis for risk assessing classification robustness, over time. In this introductory study, an analysis of globally listed companies was undertaken over a multi-year period, examining base and precious metal projects in both preproduction and operational asset classes. From these, a series of exploratory decision tree trigger points were generated against which target companies were anonymously identified and risk-ranked.

May 24, 2023

Sizing is fundamental technology for each step of ironmaking process. The progress of sizing technology has greatly contributed to the development of ironmaking technology. As the purposes of ironmaking operations diversified particularly since the oil crisis of 1973, the sizing technology made new advance- ment, as represented by pulverization of ser- pentine, dezincification and classification of secondary blast furnace dust, pulverized coal injection, size-segregated sinter charging and a coal preparation control process. These techniques are mostly characterized by the fine grinding of a given type of mineral or coal to heighten the degree of reaction con- trol. This trend is expected to continue Further.

Jan 1, 1984

By Carter A. J, Miller D. M, Holder N. H M, Van Aswegen P C

The Harbour Lights Mine situated at Leonora in Western Australia, mines a refractory sulphidic gold ore. The main sulphide minerals are pyrite and arsenopyrite. Due to the association of gold with the pyrite and arsenopyrite, gold recovery is not amenable to the normal cyanidation process.A pyrite/arsenopyrite flotation concentrate is produced at Harbour Lights. This concentrate has been stockpiled for the past two years.A bio-oxidation process (BIOX«)* to treat refractory gold flotation concentrates has been developed by GENMIN in South Africa. Harbour Lights acquired the technology from CRL BIOX« Pty Limited in Brisbane, to treat the refractory gold concentrates.

Jan 1, 1992

Research cruises dedicated to seafloor hydrothermal activity along the Kermadec arc first began with the Sonne-135 expedition in 1998. This was followed by the worldÆs first systematic survey for venting along an arc during the 1999 NZAPLUME I expedition. Since then, cruises dedicated to mapping plumes along the Kermadec arc include NZAPLUME II (2002), NZAPLUME III (2004) and ROVARK (2007). In addition, the manned submersible cruises SWEEP Vents (2004) and NZASRoF (2005) utilised the Shinaki 6500 and Pisces V, respectively, to sample in detail select hydrothermalsystems for mineralised samples, rocks and vent fluids. The ROVARK (2007) cruise was the first to deploy an autonomous underwater vehicle (ABE) along the arc which surveyed Brothers volcano at a far greater resolution than had been done previously by ships on the sea surface. While these expeditions have largely been led by GNS Science, together with its collaborators from National Oceanic and Atmospheric Administration, Pacific Marine Environmental Laboratory (NOAA/PMEL), significant contributions have been made by other groups from various nations, exemplifying the global interest in seafloor hydrothermal activity associated with intraoceanic arcs. This is an ASTRACT only. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Larsen D. F

Minor iron formation related base metal sulphide mineralization occurs in granulite facies metamorphic rocks of the early Proterozoic Willyama Complex. Rock sequences hosting three iron formation related Cu, Zn, Pb prospects from the Thackaringa Group (Suite 3) are described. A caparison of host rock sequences, style of mineralization and facies of iron formations suggests major differences in terms of the overall depositional environment. However, significant similarities are present with respect to the nature and distribution of iron formation facies and the occurrence of chlorite 'alteration' zones in close proximity to mineralization in all cases. The chlorite within these zones occurs in a number of diverse forms in a range of rock types. A comparison of the prospects shows that there is no evidence to indicate that the chlorite in the zones is a retrograde alteration product of former higher grade prograde mineralogies - the chlorite appears to have survived granulite facies metamorphism. The mode of occurence of the chlorite in the 'alteration' zones together with the fact that the association quartz + chlorite + magnetite + pyrite + base metals is cx rmn to all areas suggests that the chlorite is specifically related to the processes which deposited the stratiform iron formations and related sulphides. It is considered that the chlorite precursor was a prenetanorphic alteration product or chemical sediment closely related to submarine hot spring activity which was also the source for chemical sediment precursors of the iron formations, associated lode rocks and Sulphides.

Jan 1, 1983

By D E. G Connelly, K Y. Wong

Gold at the Harbour Lights Mine (HLM), WA occurs principally in pyrite (Py) and arsenopyrite (AsPy) minerals rendering it inaccessible to direct cyanidation. Froth flotation produces a concentrate with low mass recovery and with high recoveries of sulfides. After investigating several alternatives, a novel flotation process has been developed to separate the concentrate into pyrite and arsenopyrite rich fractions. The pyrite fraction is finely ground and cyanide leached, while the arsenopyrite is treated off-site. This paper describes the separation process from laboratory bench scale through to commercial operation at the HLM gold plant.

Jan 1, 2005

By Palmer C. G, Rowe P. G

Ore handling improvements at Mount Isa Mines Limited were necessary to keep abreast of technological advances in all phases of sublevel stoping practice.In the early 1930s an efficient ore handling system was in operation.However in 1936 excessive water encountered in deepening the hoisting shaft necessitated the sinking of a second hoisting shaft. Financial difficulties prevented abandoning the original shaft and surface ore handling and crushing facilities, so ore was transferred underground and underground crushing deferred. It was not until 1951 Jhat multilevel crushing permitted increased efficiency in the handling of ore from stopes. Ore was then hoisted in one shaft and transferred on the surface by conveyor belt to a new crushing plant.In 1956 a planned production increase from 5,000 to 11,000 tons per mining day made possible further improvements in ore handling. Larger equipment was installed and existing equipment modified to capacitate the handling of larger sized ore at increased daily tonnages.INTRODUCTIONThe intensive exploratory programme commenced in 1954 disclosed large reserves of both lead and copper ores and in 1956 an expansion programme was initiated to increase production from 5,000 to 11,000 tons per mining day. The increased tonnage would result in decreased costs per ton and further cost reductions would result from increased mechanisation underground. The combined effect would permit larger tonnages of lower grade ores to be included in ore reserves. To achieve both cost reduction and the scheduled production increase, improvement in ore handling was of vital importance.For efficient and low cost sublevel stoping it is necessary to maintain an economic balance between...

Jan 1, 1961

By Whittaker B. N, Reddish D. J

The rockbolting method of support is employed widely in several countries in different of mines. Hard rock mines use this method extensively. Soft rock mines, such as coal mines, have employed standing supports (steel sets) as the main method, although some countries such as the U.S.A. and Australia have preferred rockbolting. There is increasing interest in extending the rockbolting method in coal mines. The application of rockbolting techniques in an industry which traditionally has not applied such techniques, has required the development of a systematic design approach. This design approach uses extensive monitoring, to asses the viability of the support system in differing conditions. Currently at a number of new and existing mine developments in the U.K., rockbolting is being successfully applied. Although, inevitably some localised geotechnical problems have been encountered and have needed to be taken into account. The effect of faulting on roadway conditions is discussed in this paper and a design approach has been applied using a numerical analysis method, namely the Finite Element Method. The results presented in the paper serve as a useful guide to roadway support designers, and in particular the role played by different bolts in a range of conditions.

Jan 1, 1992

By Bodnaras G. E, Sceresini P. A

The Filblast Cyanidation Process incorporates the advantages of intense high shear mixing, high dissolved oxygen concentration and high pressure to achieve extremely rapid gold dissolution rates. This is made possible by the unique design of the Filblast gas shear reactor. The reactor is a rugged and compact in-line device. The outer casing is protected by a polyurethane coating and the internal parts are of wear resistant polymer. The largest unit built to-date has overall dimensions of 1200 mm length by 300 mm diameter and has a capacity of 150 dry tonnes per hour at 40 - 45 per cent solids. Service life at this throughput is at least three months. The process may further be applied to high temperature leaching of refractory gold ores or other metals. Wear resistant metal or ceramic materials would be employed for this duty. Four mines are currently employing the Filblast Process for treating a variety of ore types ranging from highly reactive, almost impossible to treat, pyrrhotite/arsenopyrite to deeply weathered clay ore which forms a highly viscous pulp. The effect of shear thinning has resulted in improved adsorption kinetics resulting in higher carbon loading and reduced soluble gold loss. Total tonnage treated is approximately four million. Operating costs which include leasing and maintenance charges for the Filblast and pump power costs are about 16 cents per tonne. This is equivalent to about ten per cent of savings. Laboratory scale units having capacities up to 30 litres/min are available for test work but laboratory testing techniques so far developed do not accurately reflect the oxygen and cyanide savings which have been achieved in the plant.

Jan 1, 1994

By J H. Park, R R. Kim, H S. Park, H J. Kim

This study focuses on the recovery of valuable metals, specifically silver (Ag) and palladium (Pd), from copper-containing sludge (with copper content less than 20 per cent) generated during PCB processing and from spent petrochemical catalysts used in vapour decomposition during oil refining processes. The present results indicate that an increase in the mixing ratio of alumina-based spent catalyst leads to a decrease in the recovery rate of Ag and Pd. The recovery rates for Ag and Pd range from 84 per cent to 96 per cent and 80 per cent to 98 per cent, respectively. This trend is attributed to the increased emulsification of copper droplets containing Ag and Pd in the slag. The emulsification is caused by the decrease in the settling velocity of the copper droplets due to the increased viscosity of the slag as well as by the decrease in the slag-metal interfacial tension due to an increase in sulfur content at higher mixing ratio of spent catalyst.

Jun 19, 2024

By I Jabou, D G. Blazak, L C. S Hogarth

The R70 test is a good indicator of coal reactivity to oxygen and is commonly used to provide a rating of propensity for self-heating. Tests performed by The University of Queensland Spontaneous Combustion Testing Laboratory have resulted in the development of a large database that shows the impact of coal quality on this parameter. From these results it is possible to infer an R70 value, which can be used to gain an appreciation of the intrinsic coal reactivity before it is even tested. However, any interpretation of R70 values must consider the influences of coal rank, mineral matter and moisture content to provide a better understanding of the spontaneous combustion risk of a particular coal.

Jan 1, 2005

By Cliff D, Harrison P. Hester C

During 1997 two different types of coal mine inertisation equipment were trialed in separate underground coal mines in Queensland.In April 1997 tests of the Polish developed GAG-3A inert gas generator were carried out at the Collinsville No 2 Coal Mine. These demonstrations indicated that the GAG-3A device was applicable in underground coal mines and that with respect to inertisation rate the device outperformed all other currently available techniques. The unit was assembled rapidly and operated safely during surface and underground trials and no mechanical problems were encountered with the device. The GAG-3A is not suitable for every fire scenario particularly if large volumes of fresh air are being drawn into the mine(where multiple units may be required), but with respect to the selection criteria developed by the Moura Implementation Process Task Group 5 criteria, the unit performed up to the specifications required.

Jan 1, 1998

By B Wu, B W. Lei, B J. Duan

When a coalmine fire occurs, it is crucial to judge the developing trends inside the fire area by analysing the changes of gas concentration in order to formulate the proper rescue measures. At present, few researchers have focused on the relationship between the changing trend of gas product and basic characteristics of fire in the coal fire extinguishing process. To study the relationship of basic characteristics of coalmine fire during the extinguishing process, an experimental platform for coal combustion in a confined space was built, and gas production, flame image and coal temperature during the extinguishing process were monitored and analysed by an online continuous gas analysis instrument, camera and thermocouple. Research shows that during the burning phase of the coal sample in the confined space, the flame zone decreases gradually due to insufficient gas supply. The size of the flame zone fluctuates and shares a positive correlation with CO concentration, while sharing a negative correlation with O2 and CO2 concentrations. Then, in the extinguishing phase, the increasing rate of CO2 concentration and the decreasing rate of O2 concentration both decrease gradually, but CO concentration would rise for a period before it eventually decreases. Coal temperature continues to rise in the open flame stage and does not go down until the flame is extinguished.CITATION:Lei, B W, Wu, B and Duan, B J, 2015. Experimental study on extinguishing characteristics of coal fire in confined space, in Proceedings The Australian Mine Ventilation Conference, pp 279–284 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015