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PROF RICHARD ÅKERMAN Stockholm, Sweden DR FRANK DAWSON ADAMS Montreal, Canada ANDREW CARNEGIR New York, N.Y. PROF HATON DE LA GOUPILLIERE Paris, France SIR ROBERT A. HADFEILD London, England HERBERT C. HOOVER Leoben, Austria JAMES FURMAN KEMP New York, N.Y. PROF HENRI LOUIS LE CHATELIER Paris France EZEQUIEL ORDONEZ Mexico City, Mexico ALEXANDRE, POURCEL Paris, France PROF RICHARD H, RICHARDS Boston Mass. JOHN E. STEAD Middlesborugh, England PROF DIMITRY CONSTANTIN TSCHERNOFF St Petersburg, Russia PROF TSUNASHIRO WADA Tokyo, Japan CHARLES D WALCOT Washingtion D.C.

Jan 1, 1923

PROF RICHARD ÅKERMAN Stockholm, Sweden PROF RICHARD BECK Friberg, Germany ANDREW CARNEGIR New York, N.Y. DR. JAMES DOUGLAS New York, N.Y. PROF HATON DE LA GOUPILLIERE Paris, France SIR ROBERT A. HOFFER Leoben, Austria PROF HENRI LOUIS LE CHATELIER Paris France M FLORIS OSMOND Paris, France ALEXANDRE POURCEL Paris, France JOHN E. STEAD Middlesborugh, England DR. ING H. C. EMIL SCHROEDTER Dusseldorf, Germany JAMES M. SWANK (Associate) Philadelphia, Pa. PROF DIMITRY CONSTANTIN TSCHERNOFF St Petersburg, Russia CHARLES D WALCOT Washingtion D.C.

Jan 1, 1910

EXECUTIVE COMMITTEES OF LOCAL SECTIONS New York L. W, FRANCIS, Chairman, WILLARD S. MORSE, Vice-Chairman. THOMAS T. READ, Secretary, Woolworth Bldg., New York, N. Y. P. A. MOSMAN, Treasurer. LOUIS D. HUNTOON. Boston HENRY L. SMYTH, Chairman. ALFRED C. LANE, Vice-Chairman. AUGUSTUS H. EUSTIS, Secretary-Treasurer, 131 State St., Boston, Mass. TIMOTHY W. SPRAGUE, HENRY A. WENTWORTH. Columbia F. A. THOMSON, Chairman. GEORGE W..RODDEWIG, Vice-Chairman. LYNDON K, ARMSTRONG, Secretary-Treasurer, P. O. Drawer 2154, Spokane, Wash. R. S. McCAFFERY, S. H. RICHARDSON.

Jan 7, 1914

By Charles H. Jacoby

In 1774 a Swedish chemist, C. W. Schule, first recognized manganese as an element. That same year Schule's associate, J. G. Gahn, isolated the element manganese for the first time. In 1856 the Bessemer process of steelmaking gave birth to the economic importance of manganese. Later, in 1882, Robert Hadfield discovered high manganese steels. Although the primary use of manganese is in the ferroalloy industry, two additional important uses for manganese are making chemicals and dry cell batteries. Manganese is also vital to plant and animal life. Various chemical compounds of manganese are used in fertilizers, feeds, glass manufacture, paints, varnishes, and for numerous medicinal and chemical purposes. For the study of industrial minerals and rocks, only the chemical and battery grade material is of concern, but for the sake of comparison, metallurgical aspects are included in this presentation. Although currently the world's largest consumer of manganese, the United States is producing only minor amounts of ore at the present time. This is due primarily to the fact that although huge deposits of manganese occur within our borders, all are of such low grade as to be economically unfeasible to mine. For many years various government agencies and segments of private industry have devoted sizable sums of money and time in an attempt to upgrade ores from the various deposits, and also in an attempt to recover manganese from blast furnace slags. In view of current world prices, and the quantity of high grade material available, there is little likelihood that any of these approaches will be found to be economically feasible in the near future. Geology and Mineralogy Mineralogy There are over one hundred minerals that contain manganese. These minerals vary from those with compositions that are predominantly manganese to those having only minor percentages. [ ] Geology From a geological standpoint most manga¬nese deposits are complex. In general, it can be said that all primary deposits of manganese are carbonates or silicates. The most productive and profitable have been those of sedimentary origin and residual concentrations. Examples of these residual types of deposits are associated with the metamorphosed lodes of Madhya, Pradesh, India, and the lateritic deposits of Orissa and Bihar, India; nodules in the residual clays of the Philippine Islands, U.S. southern Appalachians and Arkansas, Ghana, and Brazil. Sedimentary manganese deposits are best exemplified by the Nikopol district of Russia and the Tchiatouri area of Georgia, USSR. Hydrothermal replacements are characterized by the rhodochrosite deposits of Butte and Phillipsburg, Mont. In general, the hydrothermal type deposit has not resulted in any large tonnages being produced, but may have given

Jan 1, 1975

By W. C. Hagel

Previous inuestigators have repovted unusually low H* and Do values for self-dzf@szon in certazn bcc metals, e.g., chromium nnd y -uvanium. It has been postulated that this is nn experimental crl -tetion for the existpnce of a four -atom ring meclzanzsm, mid there could be. zmpovtant theoretrcal Implicatlons. By utilizing a precise sectioning technique with Cr51 as the tracer, self-dzffi-lsion measurements in large grains of 99.99-pct Cr were extended from 1200° fo 1600"C. A least- squares analysis of the data yields that D 0.280 exp (-73,20U/RT) cm2 sec-'. These AH* and Do unlues are not anomalous; there is little reason to believe that n vacancy mechanism is not opevatiue. Apparent differences at lower temperatures may result from preferential diffusion along short-circuititing paths and/or sample contamination. WITH continued technological effort, chromium and chromium-base alloys should ultimately become useful high-temperature structural materials. Accurate measurements of self-diffusion coefficients in the pure metal are necessary for a quantitative understanding of sintering, grain growth, creep, and other related rate processes. However, two conflicting determinations have been reported.* Using an Since careful diffusion studies normally yield Do values ranging from 0.1 to 10 cm2 sec-l, the Paxton-Gondolf results require independent experimental corroboration before an undue amount of speculation arises to explain the apparent anomaly. As discussed by Nowick6 and clearly shown by Hoffman and Turn-bull7 for self-diffusion in silver, a low AH* and Do can arise from preferential diffusion along grain boundaries or other short-circuiting paths. The most reliable data come from high-temperature measurements where volume effects predominate. Following a precise sectioning technique developed for determining silver diffusion in the intermetallic compound AgMg8 and cation diffusion in the corundum oxide Cr2O3,9 the purpose of this study was to measure true volume diffusion in high-purity, large-grain samples at higher temperatures than considered previously. Another point of interest is the frequent proposal10-12 that chromium undergoes an allotropic transformation between 1375" and 1800°C where the diffusion data might then show a discontinuity. I EXPERIMENTAL 1) Sample Preparation. The highest purity (99.997 pet) Cr currently available is produced by reduction of chromium tri-iodide. Three pounds of the resulting crystal bar were shipped in a sealed container with a complete chemical analysis from the vendor.* In conformity with the procedure used for

Jan 1, 1962

By Elmars Ence, Harold Margolin

The partial isothermal section of the Ti-Cu-Zr system at 750°C has been studied. The crystal structure of Ti2Cu has been detevnlined as tetragonal and when expressed as face-centered tetragonal, a = 4.164, c = 3.611 A, and c/a = 0.867. TITANIUM systems in which ß-titanium decomposes eutectoidally into a and a compound rather readily are known as active eutectoid systems. Recently in active eutectoid alloys based on the Ti-Cu system, and containing additionally A1 and Zr, it has been found that zirconium may produce both moderate weakening and marked strengthening at elevated temperatures.' In order to obtain some insight into the behavior of zirconium, an attempt was made to determine whether compounds of the type Tix Zr and TixZryCu exist. Only results of the Ti-Zr-Cu studies are reported here since data on Ti-Zr alloys will be presented in a separate publication. EXPERIMENTAL PROCEDURE Alloys were nonconsumably arc melted in argon atmosphere as 15-g buttons, prepared from materials of the following purities: Bureau of Mines electrolytic Ti — Bhn 63 OFHC copper Reactor Grade Zirconium Bhn .C 150 Prior to alloy preparation the electrolytic titanium was premelted to avoid excessive spattering of the charges during melting. The weight losses during melting did not exceed 1 pct of the total weight of the charge. The alloys prepared are listed in Table I together with analyzed compositions. in cases where they were determined. Specimens for heat treatment were wrapped in molybdenum sheet, annealed in argon-filled quartz capsules, and quenched by breaking the capsules under iced brine. About 1 to 2 sec are required to remove the capsule from the furnace, drop it into the iced brine and break it. Because of the insulation effect of the quartz, this delay in quenching should not produce a large drop in temperature. In many instances, no difference or little difference has been detected between the same specimen quartz capsule quenched or directly quenched in vacuum by an impinging stream of water.' Ti-Cu-Zr alloys were homogenized for 48 hr at 825°C prior to annealing at 750°C. Annealing for 5 days at 750°C produced the same results as 11 days at temperature and it was therefore assumed that 5 days was sufficient to establish equilibrium. Titanium-copper alloys were homogenized for 40 hr at 900°C prior to heat treatment for 6 days at 750°C. Specimens for metallographic examination were electropolished and etched with the following solution:

Jan 1, 1962

By R. J. Allio, C. H. Randall

An automatic system for the quantitative analysis of microstrulcture has been developed. The method is based upon a statistical model of microstructure and employs phase intercept fractions as fundamental random variables. Structure-sensitive properties can be related explicitly to parameters derived from the distribution of phase intercept fractions in a matevial. THE properties of mechanical dispersions and of multiphase alloys art: intimately related to the amount, distribution, and intrinsic properties of the dispersed material. In many instances, the amount and distribution of the dispersed substances have greater influence on the over-all system properties than do the properties of the dispersed substance-Such properties as average particle size, particle size distribution, homogeneity of dispersion, volume per cent of dispersed phase, and mean free path between dispersed particles thus become critical in any evaluation of the properties of a dispersion. Unfortunately, techniques for evaluating quantitatively the microstructural characteristics of dis~ersions rapidly and accurately have not been available. If necessary, qualitative or semiquantitative devices can be utilized. Some such devices are based merely upon comparison of the specimens in question with arbitrary standards. Other techniques involve superposition of grids and tabulation of particles observed in different portions of the grid. Still other methods based upon lineal analysis entail counting lines or points at random upon the specimen to be examined; the number of intersections of the line with a given phase, the proportion of line or number of points which are covered by given phase are variously recorded. The mathematical basis for most of the techniques of quantitative metallography have been amply reviewed in the literature.'l2 without exctption, however, the standard techniques for quantitative metallography are either imprecise or are exceedingly tedious to apply. For example, tranverse integrating stage for rapid manual areal fraction measurement has been designed by Smith.3 Howerer, as in the case of any device based upon visual eslimation, operator bias may cause appreciable error. Various flying spot devices, on the other hand register particle size distributions in 2-dimensions, from which it is difficult to derive other properties of the dispersion. Thus, e.g., the 3-dimensional distribution cannot be inferred unless certain rather broad assumptions are made concerning the randomness of distribution and geometrical configuration of dispersed phase. Many limitations to the application of quantitative structural analysis can be overcome by the use of the microdensitometer, which is essentially an automated areal analysis device. Data obtained in the form of a distribution of phase intercept values are

Jan 1, 1962

By A. J. Erickson, W. W. Atkinson

Concepts developed in a geologic data recording system at the Victoria, Nevada breccia pipe-skarn copper mine, are not fundamentally new, but represents expansion of earlier ideas. The basic philosophy is that a high quality geologic data base is necessary and should be complete, clear, standardized, neat, quantitative, and readily useable. It may be multi-colored or simply black and white. Graphic, descriptive and quantitative recording of data is essential. A format for core logging is presented and discussed, as well as a mu1tiple overlay system for recording data gathered in surface mapping.

Jan 1, 1984

By Kraig W. Grubaugh, Lee W. Saperstein

Rapid growth rate of surface mining for coal has caused many states to increase the rigor and complexity of their surface mining codes. The promulgation of federal surface mining standards may cause those states containing federal land to amend their codes also. Presented is an up-to-date review of these codes with tabular summaries that divide the codes into operative functions. These summaries will be of use to new operators, multiple-state operators, and state officials. Suggestions are made for industrial efforts to present workable and acceptable amendments to these codes.

Jan 1, 1978

By George B. Clark

More economical methods of rock disintegration are needed for mining and for rapid excavation. Two major systems are drill and blast and mechanical excavation, including tunnel-boring machines. Current drill and blast methods are cyclic and there- fore limited in speed of operation. Boring machines are limited to moderately hard rock due to bearing and cutter wear. The recent development of ANFO, which has reduced blasting costs markedly, was largely fortuitous because of the method of manufacturing AN prills. New slurries and fluid explosives are easy to load and have high energy-pressure characteristics.

Jan 1, 1971

By I. C. Runge

This paper outlines in a step-by-step approach all of the major tasks to be undertaken for the design of a complex multi-seam open pit coal mine. Examples are drawn from three such projects in the Hunter Valley of New South Wales, Australia, where computer techniques for equipment production rate estimation, mining block layout, and mine scheduling were used extensively. The paper is divided into two sections - Conceptual Planning and Detailed Planning; and the various tasks associated with these sections are discussed in detail, with examples of typical problems to be overcome.

Jan 1, 1983

By WILLIAM E. NEWNAM

THE molding and loading of pig lead has, in the past, been accomplished mainly by the strong arm method and, as the pigs are usually loaded directly into the cars, it has been a hot and laborious task. Of late years it has been difficult to obtain men willing to perform such labor and the need has been felt for loading and molding machinery which would eliminate all manual handling of the hot pigs and which would be sufficiently compact to permit of installation in existing plants with little or no

Jan 1, 1924

By Joseph W. Leonard

Seven formulas commonly used to evaluate industrial screening efficiency are investigated to determine if they are suitable for calculating the efficiency of rectangular-hole screens. Six formulas were found to be limited in application to square-hole screens. The seventh, although acceptable for evaluating rectangular-hole as well as square-hole screening efficiency, was found to be unwieldy. A new formula is developed based on the concept of misplaced sizes. This proposed formula permits the single step determination of efficiency and is applicable to all types of screening applications.

Jan 1, 1975

By L. L. McDaniel

DURING the past few years a number of improvements in smelting and power equipment have been made at the Douglas smelter of the FIG. 1.-GENERAL PLAN OF SMELTER. Phelps Dodge Corporation at Douglas, Ariz. In the summer of 1935 work was started on the first unit of a new reverberatory waste-heat boiler plant which ultimately was to furnish steam for a modern high-pressure power plant. A second reverberatory waste-heat boiler unit

Jan 1, 1939

By B. C. Craft

The outstanding event of the year 1932 in this area was the intensive drilling activity in the Zwolle field of Sabine Parish, Louisiana. More new development work was undertaken and completed than during the previous year. This was due in part to the increased price of oil and in a Includes 19 parishes: Beauregard, Bienville, Bossier, Caddo, Caldwell, Catn-houla, Claiborne, Concordia, DeSoto, Grant, Lincoln, Morehouse, Natchitoches, Ouachita, Red River, Richland, Sabine, Union, Webster. B H. K. Shearer: Oil and Gas Development in South Arkansas, North Louisiana and Mississippi in 1931. Trans. A. I. M. E. (1932) 98, 159. a Includes 14 counties: Ashley, Columbia, Dallas, Drew, Hot Springs, Lincoln, LnFayette, Little River, Miller, Ouachita, Pike, Sevier, Scott and Union. * H. K. Shearer: Oil and Gas Development in South Arkansas, North Louisiana and Mississippi in 1931. Trans. A. I. M. E. (1932) 98, 159. part to the fact that production is below local market demands. Exploration during 1932 resulted in the discovery of a new oil field and a new gas

Jan 1, 1933

First actual production of titanium metal at the newly constructed Henderson, Nev., plant of Titanium Metals Corp. of America occurred in mid-October. Production will be expanded rapidly until the initial goal of 10-tons per day is reached. This will be equivalent to eight times the present world production of titanium metal. W. Eberstady & Co., New York City, has announced plans for construction of a $400 million plant for the manufacture of synthetic liquid fuels from coal in southern Illinois, if the Government will guarantee a minimum price for the gasoline and other products to be produced.

Jan 11, 1951

By C. D. Hunter, I. B. Browning, Ralph Thomas

Production of oil in Kentucky during 1938 was 5,566,154 bbl., showing a substantial increase over that of the year 1937; while in the gas areas development was somewhat retarded although deliveries were similar to those of 1937. In eastern Kentucky there was an oil increase during 1938 of over 150,000 bbl. above that of 1937. No new pools were developed and the increase was almost entirely due to the installation and expansion of secondary recovery methods and to the further development of the Maxon and Big Lime, Mississippian pools in Floyd and Martin Counties. With this development eastern Kentucky reached a level near that of 12 years previous, when the development of several large producing areas had just been completed. In eastern Kentucky during 1938 not over 50 gas wells were completed. Although the pipe-line deliveries were approximately the same as during 1937, development was retarded because of an excess of gas already developed and the intensive development of the Oriskany fields in West Virginia. In western Kentucky, in the part of the Illinois Basin lying in the state and known in Kentucky as the Western Coal Basin, the increase was due to the discovery of a number of new pools, the largest and the one producing the biggest wells being known as the Birk City pool. In fact, the discovery of this pool with the McClosky "sand" (St. Genevieve limestone) as the producing formation was in a large measure responsible for the increased activity, which in turn brought the discovery of the other areas. The discovery well in this pool is the C. T. Blackwell, which came in flowing 1000 bbl. daily from the McClosky sand at a depth of 1870 ft., drilled in April 22, 1938. This discovery, coming at a time when the major companies and many others were conducting an intensive leasing campaign and making extensive subsurface and geophysical surveys in the deeper part of the basin, resulted in renewed activity over the entire area and brought much new drilling. It also brought to Kentucky for

Jan 1, 1939

By C. D. Hunter, I. B. Browning, Ralph Thomas

Production of oil in Kentucky during 1938 was 5,566,154 bbl., showing a substantial increase over that of the year 1937; while in the gas areas development was somewhat retarded although deliveries were similar to those of 1937. In eastern Kentucky there was an oil increase during 1938 of over 150,000 bbl. above that of 1937. No new pools were developed and the increase was almost entirely due to the installation and expansion of secondary recovery methods and to the further development of the Maxon and Big Lime, Mississippian pools in Floyd and Martin Counties. With this development eastern Kentucky reached a level near that of 12 years previous, when the development of several large producing areas had just been completed. In eastern Kentucky during 1938 not over 50 gas wells were completed. Although the pipe-line deliveries were approximately the same as during 1937, development was retarded because of an excess of gas already developed and the intensive development of the Oriskany fields in West Virginia. In western Kentucky, in the part of the Illinois Basin lying in the state and known in Kentucky as the Western Coal Basin, the increase was due to the discovery of a number of new pools, the largest and the one producing the biggest wells being known as the Birk City pool. In fact, the discovery of this pool with the McClosky "sand" (St. Genevieve limestone) as the producing formation was in a large measure responsible for the increased activity, which in turn brought the discovery of the other areas. The discovery well in this pool is the C. T. Blackwell, which came in flowing 1000 bbl. daily from the McClosky sand at a depth of 1870 ft., drilled in April 22, 1938. This discovery, coming at a time when the major companies and many others were conducting an intensive leasing campaign and making extensive subsurface and geophysical surveys in the deeper part of the basin, resulted in renewed activity over the entire area and brought much new drilling. It also brought to Kentucky for

Jan 1, 1939

By Fred H. Klaer

Water supplies dependent upon induced infiltration can be developed by vertical wells, by infiltration galleries, or by horizontal water collectors. Each method is described and the advantages of water obtained by induced infiltration with respect to cost, chemical quality, and temperature are shown by specific water supplies. THE subject of ground water in industry is assuming increasing importance as new processes and new industries are developed. Industrial specifications of chemical quality and temperature for process water and for cooling purposes are becoming more rigid, and water must now have many properties to meet these requirements. As ground water is usually more constant in quality and temperature, many industries are turning to ground-water supplies to satisfy their growing need. As many published articles have stated during the past several years, the ever increasing demands have caused shortages of water supply in many localities throughout the United States. Although such shortages are generally of a local nature, they have given rise to many attendant problems, such as increased pumping costs, salt water encroachment, and rising ground-water temperatures. One partial solution to the problems of overdevelopment of the ground-water reservoirs in many areas can be accomplished by developing ground-water supplies that are dependent upon induced infiltration and by planning the use of underground reservoirs. These reservoirs can be filled during periods of excess precipitation and stream flow and can be emptied during periods of drought, in a manner similar to the use of surface reservoirs. In this way water that otherwise would be wasted into the oceans is salvaged during periods of excess. The development of water supplies dependent on induced infiltration is a relatively new concept and should be defined. When a well is pumped, the water level around the well is lowered in the shape of an inverted cone or cone of depression. As pumping is continued, the cone of depression will continue to expand, horizontally and vertically, until the quantity of water crossing the perimeter of the cone plus the recharge within the area of the cone is equal to the quantity of water being pumped.

Jan 1, 1954

By G. S. Hume

In Alberta, an oil well with an estimated capacity of 60 to 100 bbl. was "brought in" at Wainwright, the oil being derived from the Colorado group of rocks. In the Norman fields, Mackenzie River area, two new holes completed showed no oil in commercial quantities whereas the "Discovery" well has now an increased flow amounting to about 100 bbl. In Kent Co., Ontario, a well from low down in the Trenton formation gave an initial flow estimated at 200 bbl. This opens up new possibilities for the Ontario fields as this is the first oil from this depth in the Trenton. ACTIVE drilling operations for oil were carried on during the summer of 1923 in various parts of western Canada, particularly in Alberta. During the early part of the summer, interest centered in southern Alberta, in the Coutts area, just north of the producing Kevin-Sunburst field of Montana; but on Nov. 14 a strike of oil by British Petroleums Ltd. at its well near Wainwright, 120 mi. east of Edmonton, diverted public attention to a new field. According to present estimates, this well has a possible production of from 60 to 100 bbl. a day; the oil is 15° Bé. with an asphaltic base and is obtained from a sand at the depth of 2019-2036 ft. The oil stands at 1700 ft. in the casing and there is sufficient gas pressure to cause it to flow when the well is opened. The oil horizon is in a sandstone in rocks of Colorado age. It is known that there is a terrace structure of which the western edge extends in a northwesterly direction from the vicinity of Hardisty to Viking, where it probably swings more to the north. At Viking a small dome-like structure on this terrace gives rise to an important gas field. Wainwright lies directly northeast of Hardisty. The exact structure in the Wainwright field is unknown. At Fabyan, 6 mi. northwest of Wainwright, the Imperial Oil Co.1 last year brought in a large gas well estimated at 14,000,000 cu. ft.; the escaping gas sprayed a small amount of heavy black oil over the derrick. The gas was obtained at a depth of

Jan 2, 1924