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By George Newton

When Mr. Bailey asked us to present a paper describing our new BOF shop, he requested that we avoid a presentation heavily laden with detail and statistics. Not only have we attempted to do this, but also we have prepared a number of colour slides which, hopefully, will provide you with a graphic conception of the facility. The installation of the BOF facility at the Steel Co. of Canada's Hilton Works was delayed many years because of the remarkable production growth of the oxygen open hearth furnaces in No. 3 shop. However, in mid-1960 it became strongly evident that not only would increased ingot capacity be required, but also that N0.2 shop - with vintage non-oxygen open hearth furnaces - would have to clean its stacks in the near future, or be closed down. A decision to embark on the BOF facility was made in 1967 after an extended period of in-depth planning and assessment of industry trends.

Jan 1, 1972

CONTENTS PAGE. WHITE, DAVID.-Environmental Conditions of Deposition of Coal. Discussed by E. C. Jeffrey, George H. Ashley, Reinhardt Thiessen, S. W. Parr, David B. Reger, Wilbur A. Nelson, James F. Kemp, E. S. Moore, Homer G. Turner, David White, A. C. Noé, W. A. I. M. van Waterschoot van der Gracht 2 THIESSEN, REINHARDT.-The Constitution of Coal. Discussed by Edward C. Jeffrey, Reinhardt Thiessen, Ralph H. Sweetser, David White 12 TURNER, HOMER G.-Microscopical Structure of Anthracite. Discussed by E. S. Moore, Edward C. Jeffrey, Reinhardt Thiessen, H. J. Rose, James F. Kemp, David White, Clarence A. Seyler, A. C. Noé 14 JEFFREY, EDWARD C.-Coal in Relation to Coke. Discussed by H. J. Rose, David White, E. S. Sinkinson, S. W. Parr, James F. Kemp, Edward C. Jeffrey, Reinhardt Thiessen, Chas. R. Fettke 17 FRANCIS, W., and WHEELER, R. V.-The Resolution of Coal by Oxidation. Discussed by Edward C. Jeffrey, S. W. Parr, E. S. Sinkinson, Reinhardt Thiessen, David White 23 TIDESWELL, F. V., and WHEELER, R. V.-The Constitution of Coal. Discussed by David White, A. C. Fieldner 24 JOLLY, J., and WHEELER, R. V.-Organic Sulfur Compounds in Coal. Discussed by S. W. Parr 25 SINNATT, F. S.-Selective Combustion in Coal. Discussed by J. D. Davis, A. C. Fieldner, Geo. S. Rice, W. M. Grant, H. J. Rose, S. W. Parr, David White 25 COBB, JOHN W.-Nitrogenous Constituents of Coal. Discussed by S. W. Parr, H. J. Rose, Reinhardt Thiessen 28 PARR, S. W., and HOBART, F. B.-Coal and Oxygen. Discussed by J. D. Davis, W. T. Thorm, Jr., S. W. Parr, H. J. Rose, A. C. Fieldner, F. F. Jorgensen, David White, W. M. Grant 30 FIELDNER, A. C., and DAVIS, J. D.-Modern Views of Chemistry of Coals of Different Ranks as Conglomerates. Discussed by S. W. Parr, David White, Reinhardt Thiessen, A. C. Fieldner, Clarence A. Seyler 32 EBY, J. BRIAN.-Contact Metamorphism of Some Colorado Coals. Discussed by Geo. C. McFarlane, W. T. Thom, Jr 35 WHITE, DAVID.-Progressive Regional Carbonization of Coals. Discussed by A. C. Fieldner, Homer G. Turner, W. A. J. M. van Waterschoot van der Gracht, A. C. Noé 37 THOM, W. T., JR.-Moisture as a Component of the Volatile Matter of Coal. Discussed by A. C. Fieldner, S. W. Parr, Clarence A. Seyler, W. T. Thom, Jr., R. D. Hall 39

Jan 7, 1925

By W. E. Wrather

SERIOUS consideration was given by the Petroleum Division to a wide variety of subjects, during six busy sessions at the Annual Meeting. Beginning with a joint session on engineering research and production engineering, Tuesday afternoon, conducted by E. A. Stephenson and H. C. Fowler, problems of petroleum technology, domestic and foreign production, proved oil re- serves, economics, and stabilization were mooied almost without interruption until nearly everyone was "talked out,' and the meeting was adjourned at the end of the annual Petroleum Division dinner, late Thursday night.

Jan 1, 1933

By P. Ramachandraraa, T. R. Anantharaman

THE technique developed by Duwez, Willens and Kle-ment' for rapid solidification of molten alloys in small quantities by ejecting them on to a highly conducting substrate with the aid of a shock wave has come to be known as "liquid quenching" or "splat cooling" in literature and has already been applied to alloys of many binary systems.' The very high cooling rates of the order of l060 to 1080 per sec obtained in this technique and the consequent drastic undercooling of the melt have led to such striking results as formation of new amorphous and crystalline metastable phases and extension of solid-solubility limits in many alloy systems. The cooling rates in these experiments can, however, be neither accurately measured nor effectively controlled and hence the occurrence of either more than one metastable phase or appreciable differences in constitution in splat-cooled alloys of the same composition cannot be ruled out.3 In fact, workers in two laboratories have reported formation of two different cubic metastable phases in liquid-quenched Au-Si alloys containing 17 to 20 at. pct si.4,5 The present note deals with some new and interesting results obtained in a Ag-21 at. pct Ge alloy and a Au-27 at. pct Ge alloy subjected to the liquid-quenching treatment at different cooling rates. Two alloys of nearly the same composition had earlier been rapidly solidified by the standard "gun technique" in the same laboratory and shown to solidify in nonequilibrium structures, viz., an hcp phase (a = 2.987Å;c =4.718Å) in the Ag-Ge system6,7 and both hcp (a = 2.885Å; c = 4.754Å) and tetragonal (a = 11.627A; c = 22.491Å) phases in the Au-Ge system.3 Apart from different substrates (copper and stainless steel), different melt temperatures (50º to 500°C above the liquidus), and different capillary sizes (0.4 to 1.5 mm diam) in the "gun technique", slower cooling rates of the order of l050C per sec were also obtained in the present work by replacing the substrate by water at room temperature in a modification of the technique due to Olsen and Hultgren.8 No attempt was made to measure the cooling rate in any experiment. The products varied from fine powder (>40 pct by wt—200 mesh) obtained by quenching in water to thin flakes and foils (11.0 sq mm to 4.0 sq cm) produced by splat cooling. They were subjected to the Debye-Scherrer method of X-ray examination in each case. In case of the Ag-Ge alloy, in addition to the expected metastable hcp phase,6 a coexistent tetragonal phase (a = 5.093,Å; c = 7.009Å) was detected in some experiments. Eight weak X-ray reflections from this phase could be identified, two of them being the same as reported earlier.7 With increase in the cooling rate, the dominant hcp phase seems to be first accompanied by traces of silver or germanium and then either homogeneous or mixed with traces of this new tetragonal phase. The splat-cooled Au-Ge alloy showed generally the expected hcp and tetragonal phases,3 but sometimes traces of germanium were also present. Further, two new tetragonal phases with the following lattice param ters could be clearly identified in samples quenched

Jan 1, 1970

By Granville S. Borden

MANY complaints have been filed by mine prospectors, explorers and producers about inequities in mining taxation. They have insisted upon improvement, and in the past 35 years there has been some progress. Many of the best taxation provisions made to date are those contained in the Revenue Act of 1951. Mining economics presents special problems, a fact even recognized by many textbooks. Certain provisions have been made to take care of mining taxation rights, but these have been made by Congressional act and do not represent basic, constitutional, guarantees. Despite special provision, in the form of depletion allowances, there remain injustices. The industry faces the problem of gaining adequate income tax allowances for exploration and development expenditures, operating losses, and bonus and subsidy payments. Problems in mine taxation arose soon after the adoption of the 16th Amendment. This amendment gave Congress the power to impose income taxes. Supreme Court decisions against a number of mining companies held that Congress, under its power to tax income, could tax net operating revenue before depletion allowance was deducted. The court also ruled that the right to deduct depletion is a matter of Congressional permission. There is no statute provision permitting mining stockholders to recover their investment out of dividends while the mine is being operated. The Supreme Court did not recognize that part of mining proceeds are actually amortization of the cost of mineral rights. Both these omissions stem from failure to recognize that by its very nature mining consumes its mineral rights and therefore that a part of gross proceeds are not income but recovery of capital. Suppose a Congress unfriendly to mining interests repeals the provisions that allow deductions for depletion. Under such a situation assume that a corporation buys a mineral deposit for $300,000. They mine the deposit and earn an operating profit of $500,000. At the current rates they would pay a Federal Income tax of in excess of $250,000. This venture results in a loss of $50,000 as shown in the table below. For the example given the absence of depletion provisions in income tax law would turn ore into waste rock, because the word "ore" connotes commercially mineable rock. [ ] In retrospect the conclusion is clear: If the Supreme Court had recognized that a part of mining proceeds represent in reality sales proceeds of mineral rights, then profits derived from such sales would have been taxed at the favorable long-term capital rates, instead of being taxed at the high normal, surtax and excess profits rates. It is a question whether percentage depletion allowances offset this tax situation. History The history of depletion allowances has been one of general improvement. The original act did not include depletion, but an allowance at the rate of 5 pct of gross proceeds was provided in 1913. The Acts of 1916 and 1917 allowed depletion upon cost of property, and in 1918 the law was further changed to permit depletion upon cost, or market value as of date of discovery. In 1932 metal, coal and sulphur properties were permitted to elect depletion in percentages of gross income, limited to 50 pct of net income, in lieu of cost depletion. Shortly thereafter the rule was changed and percentage depletion is now allowable in any case where it is higher than cost depletion. Since 1942 percentage depletion allowances have been extended to cover many nonmetals, and in 1951 the rate for coal mines was increased from 5 to 10 pct of gross income. It is interesting to note that these allowances have been retained, and even

Jan 1, 1952

By Ralph H. Sweetser

BENEFICIATION of iron ores from the blast-furnace point of view means more than the usual enrichment of the iron contents by the removal of a large part of the clay, carbonic acid gas, silica, or moisture of the natural ore; it includes all these, but it also embraces several other mechanical .processes made , necessary by the exacting requirements of present-day blast-furnace practice. The increasing use of iron- bearing by-products, to as much as a third or more of the total ore burden, has introduced still another series of processes for improving the blast-furnace ore burden. As we look back over the past three decades of blast- furnace practice 'in. this country, we see that many of the blast-furnace troubles were directly due to lack of proper preparation of the iron ore burden,, and we realize that beneficiation in one form or another would have remedied the trouble. This was particularly true in the smelting of magnetic iron ores, where run-of- mine ore included such big lumps of 'magnetite along with rich fines that the furnace operations were greatly retarded and control of the furnace such as is usual today, was completely unknown.

Jan 1, 1930

By Ronald C. Whiting

SINCE the advent of what has been aptly called "chemical flotation," about 1920, the number and complexity of the various chemicals used in practice have increased enormously. Over 300 patents have been issued dealing exclusively with flotation reagents, and many of these embrace from two or three up to a score or more of specific compounds. The exact number of compounds actually finding a practical use in flotation would be difficult to determine, though the U. S. Bureau of Mines gives an annual list by groups.

Jan 1, 1938

By C. E. McWhorter

IN underground mining recent trends toward mining large tonnages of low-grade ore have created, among other things, a need for cheaper and more flexible ore transport. A relatively new development has been the adaptation of shaker conveyors to meet this need. Although widely used in coal mining, only in the last few years have shaker conveyors been used in underground metal mining. The equipment consists of a driving engine, either electric or air powered, upon which is mounted a drive trough supported in ball-bearing frames. The trough line, or conveying medium, is made up of a number of sections, each section connected to another, usually with bolts. The length of each trough section is controlled by the length that can best be handled underground, but is usually from 9 to 13 ft over-all. The length of a complete conveyor line is determined by the character and weight of material to be handled as well as by the size of the ore body. Trough lines vary in lengths from 100 to 300 ft and the trough has a cross-section area of 127 sq in., and is 22 in. wide by 6 ½ in. deep.

Jan 1, 1948

By F. C. Hull

The grain size of a metal or alloy is one of the most important factors determining its properties. In steels, for example, grain size affects hardenability, toughness and machinability; in brasses, grain size is related to hardness and deep-drawing quality. In the field of heat-resistant alloys, grain size has a marked effect on ductility, creep and endurance strength. In order to determine these effects, as well as to control the properties of materials, many accurate and rapid measurements of grain size must be made. This paper presents a new and improved method for the estimation of grain size. Usual Methods OF EvaluatiNg Grain Size A frequetly used method of estimating grain size is that of comparing the image of a polished and etched specimen on the ground-glass screen of a metallographic microscope with standard grain-size charts. Several types of standards are available for use with different classes of microstructures. Geometric Grids.—The Metals Handbook' has a series of hexagonal grids ranging in size from ASTM No. I to 8. Idealized Grain Networks.—Idealized grain.boundary networks for ASTM grain sizes I to 8 are included in the American Society for Testing Materials Tentative Standard E 19 - 39 T, standard Micrographs & Metals Handbook and ASTM Tentative Standard E19-3gT contain micrographs of hypo-eutectoid and hypereutectoid steels ranging in grain size from No. I to 8. The grain size of annealed brass (diameter of the average grain in millimeters) is obtained by comparison with 10 micrographs of varying. grain size in ASTM Tentative Standard E 2-39 T. A handicap to accurate evaluation of grain size by this method is the fact that it is difficult to compare photographs in a dimly lighted room with the image on the ground-glass screen, or, if the general illumination is increased so that the printed standards may be clearly seen, the contrast of the image of the unknown is decreased. It is easier to estimate grain size by comparing a micrograph of the unknown with the grain-size standards. However, photographing every specimen on which the grain size is desired is too costly in time and materials to be practicable. For hardened steels, the Shepherd or Jernkontoret fracture grain-size standards are very accurate and useful, but this method obviously cannot be applied to ductile alloys such as brass, stainless steels and austenitic heat-resistant alloys. Jeffries' method for grain-size measurements consists of counting the number

Jan 1, 1948

By F. C. Hull

The grain size of a metal or alloy is one of the most important factors determining its properties. In steels, for example, grain size affects hardenability, toughness and machinability; in brasses, grain size is related to hardness and deep-drawing quality. In the field of heat-resistant alloys, grain size has a marked effect on ductility, creep and endurance strength. In order to determine these effects, as well as to control the properties of materials, many accurate and rapid measurements of grain size must be made. This paper presents a new and improved method for the estimation of grain size. Usual Methods OF EvaluatiNg Grain Size A frequetly used method of estimating grain size is that of comparing the image of a polished and etched specimen on the ground-glass screen of a metallographic microscope with standard grain-size charts. Several types of standards are available for use with different classes of microstructures. Geometric Grids.—The Metals Handbook' has a series of hexagonal grids ranging in size from ASTM No. I to 8. Idealized Grain Networks.—Idealized grain.boundary networks for ASTM grain sizes I to 8 are included in the American Society for Testing Materials Tentative Standard E 19 - 39 T, standard Micrographs & Metals Handbook and ASTM Tentative Standard E19-3gT contain micrographs of hypo-eutectoid and hypereutectoid steels ranging in grain size from No. I to 8. The grain size of annealed brass (diameter of the average grain in millimeters) is obtained by comparison with 10 micrographs of varying. grain size in ASTM Tentative Standard E 2-39 T. A handicap to accurate evaluation of grain size by this method is the fact that it is difficult to compare photographs in a dimly lighted room with the image on the ground-glass screen, or, if the general illumination is increased so that the printed standards may be clearly seen, the contrast of the image of the unknown is decreased. It is easier to estimate grain size by comparing a micrograph of the unknown with the grain-size standards. However, photographing every specimen on which the grain size is desired is too costly in time and materials to be practicable. For hardened steels, the Shepherd or Jernkontoret fracture grain-size standards are very accurate and useful, but this method obviously cannot be applied to ductile alloys such as brass, stainless steels and austenitic heat-resistant alloys. Jeffries' method for grain-size measurements consists of counting the number

Jan 1, 1948

By Jasper L. Stuckey

GEOGRAPHICALLY, North Carolina consists of three divisions, the coastal plain on the east, the piedmont plateau in the center, and the Appalachian mountain region on the west. Geologically, the State may be divided into two main divisions, an eastern or coastal plain region, and a western or piedmont plateau and mountain region. The eastern region is underlain with unconsolidated sands, clays, marls, and shell limestones varying in age from Cretaceous to Recent. The western region is, in general, underlain with gneisses, schists, slates, sheared volcanics, and igneous intrusives of Pre-Cambrian age. In the mountain and upper piedmont portion of the western region are several areas of irregularly metamorphosed sediments of early Paleozoic age. Throughout the piedmont plateau and a part of the mountain portion of the western region, important areas are underlain with igneous intrusives of late Carboniferous age. Along the eastern edge of the piedmont plateau are two narrow belts, trending northeast-southwest, underlain with sediments of upper Triassic age. Although North Carolina contains a

Jan 1, 1947

NORTH AMERICA ALASKA Anchorage.-Culver, H. W. Geehan, R. W. Strandberg, H. Chicagof.-Russell, J. C. Tracy, Q. S. College.-Dorsh, J. B. Fox, E. F. Joesting, H. R. Smith, M. C. Wilcox, H. G. Douglas.-Cahill. W. E. Fairbanks.-Adams, J. M. Barber, R. J. Beistline, E. H. Crawford, J. D. Doheny, L. C. Earling. R. B. Greves, J. H. Harris. Q. P., Jr. Henton. H. M. Herbert, C. F. Nester, W. B. Hopkins, J. E. CANADA ALBERTA Calgary.-Allen, R. E. deHart, J. B. Dunn, W. Gray, J. G. Johnson. R. V. Link, T. A. Slipper. S. E. Soul, N. Thorne, B. L. Thorne, H. L. Edmonton.-Ball, M. W. Lilge, E. O. Pitcher, N. C. Nordegg.-Shanks, J. Turner Valley.¬MacKenzie, W. D. C.

Jan 1, 1941

Executive Committee Board of Directors L F Reinartz, Chairman, H DeWitt Smith, Vice-Chairman, T B Counselman, M L Haider, Philip Kraft Finance Committee Board of Directors Andrew Fletcher, Chairman, A B Kinzel, D Wilson Endowment Fund "X" G F Moulton, Chairman, Erle V Daveler, '55, Philip Kraft, '56, I Brigden, '57 Honorary Memberships W M Peirce, Chairman, '56, M L Haider, ex officio, Andrew Fletcher, ex officio, John M Lovejoy, '55, D H McLaughlin, '57, Henry Krumb, '58, L F Reinartz, ex officio Investments Erle V Daveler, '57, Chairman, W M Peirce, '55, Henry Krumb, '56, G F Moulton, ex officio as Treasurer, Andrew Fletcher, ex officio as Chairman Finance Committee Local Section Appropriations A B Kinzel, Chairman, M L Haider, W S. Cumings, Fred J Meek

Jan 1, 1954

By R. M. Waterstrat, E. C. van Reuth

BINARY- alloy phases having the A15-type crystal structure have been described as occurring at a simple and more or less invariant stoichiometric composition (A3B) which corresponds to the relative number of atoms occupying each of the two crystallographi lattice sites in this structure.1,2 It is frequently assumed, therefore, that each crystallographic site is occupied exclusively by one kind of atom. In most cases, however, there have been insufficient experimental data to establish whether atomic ordering is, in fact, complete. Recent studies have shown that binary A15-type phases are sometimes stable over an appreciable composition range3''* and, occasionally, the composition range of stability does not even include the "ideal" A3B stoichiometric composition.5-7 We have observed the existence of nonstoichiometric A15-type phases in the binary systems Cr-Pt and Cr-Os. This has not been reported in previous work on these alloy systems.1,8-11 A series of alloys, each weighing approximately 30 g, was prepared by are-melting in an Ar-He atmosphere using 99.999 pct Cr, 99.999 pct Os, and 99.99 pct Pt as starting materials. Each alloy was melted four times with a total weight loss of less than 1 pct. The stoichiometric (A3B) alloys were sealed in evacuated quartz tubes and annealed at 1200°C for periods of time ranging from 3 days to 2 months. Examination of the alloy microstructures revealed that little change had occurred over this time interval and it was therefore assumed that the microstructures were fairly representative of equilibrium conditions. No evidence of contamination was observed although there was apparently some loss of chromium which was confined to a thin layer at the surface of the specimens. The quartz tubes were quenched from the annealing temperature into cold water. X-ray diffraction and metallographic examination of the stoichiometric alloys revealed an estimated 10 to 30 pct of second phases which were tentatively identified as phases previously reported in these binary-alloy systems.8-11 A second series of alloys was prepared by mixing -325 mesh metal powders having a nominal purity of 99.9 pct and compressing these mixed powders in a cylindrical die at a pressure of 43,000 psi. These alloys, each weighing 15 g, and some of the arc-melted alloys were annealed in a high-temperature vacuum furnace heated by tantalum strips at a pressure of 10-8 Torr and were rapidly cooled by turning off the furnace power. X-ray and metallographic examination of both series of alloys served to establish the composition ranges of the A15-type phases. Although some chromium losses occurred during the vacuum annealing, they were largely confined to a thin layer on the outer surfaces of the samples. It was established that the A15 phases occur in the Cr-Pt system at 21 ± 1 at. pct Pt after 1 week at 1200°C and in the Cr-Os system at 28 ± 1 at. pctOs after 1 day at 1400°C (see Table I). We also observed that an arc-melted stoichiometric (A3B) alloy in the Cr-Ir system was single-phase (A15-type) in the "as-cast" condition in agreement with previous work.8,13 In addition we obtained a sample of the Cr-Os A15-type phase from Argonne National Laboratory. This alloy contained less than 1 pct second phase12 and was submitted to a density measurement. The density measurement yielded a value of 11.14 g per cu cm in comparison to a theoretical value of 11.25 g per cu cm calculated using the observed lattice constant (4.6806Å) of this alloy. The uncertainty in measurement was 0.1 pct but the sample may have contained some cracks or minor imperfections which could account for the low experimental value. We have also studied the atomic ordering in these phases by means of integrated line intensity measurements using thick, flat, rotating powder samples and CuK a radiation in an X-ray diffractometer. We have obtained order parameters of 0.90 for the Cr-Pt phase, 0.89 for the Cr-Ir phase, and 0.64 for the Cr-Os phase using the formula: where s is the usual Bragg and Williams order parameter, ra is the fraction of chromium atoms in A sites, and FA is the fraction of chromium atoms in the alloy. The values obtained are estimated to be accurate within ±4 pct. If the unusually small value for the order parameter of the Cr-Os A15 phase were due to the existence of lattice vacancies on the "B-atom" sites, then a density of 10.04 g per cu cm would be expected in contrast to the observed value of 11.14 g per cu cm. We, therefore. conclude that the fraction of lattice vacan-

Jan 1, 1967

By Frank T. Sisco

The discovery of phosphorous is usually credited to the German alchemist Brand, in 1669, and the element was rediscovered the next year by Boyle in England. IT was more than 100 years later, however, before its presence was detected in high-carbon iron produced in early blast furnaces. In 1781 the German chemist Meyer published the results of his investigation on the ?white earth? that he had found in cast iron made from bog ores. This white earth was metallic in appearance, it was extremely brittle, it was readily fusible, and it was not attracted by magnet. Meyer noted that cast iron containing this white earth was more fusible than other cast iron, and he was sure that he had discovered a new metal ? for which he proposed the name Wassereisen, or the Latin term Hydrosiderum. Two years later the distinguished Swedish Chemist Bergmann made the same discovery, finding a ?white calx? in cast iron, which he also mistakenly considered to be a new metal, and for which he proposed the Siderum.

Jan 1, 1944

By Herbert Clark Hoover, Lou Henry Hoover

IN the last book I have explained the methods of delimiting- the meers along each kind of vein, and the duties of mine officials. In this book1 I will in like manner explain the principles of underground mining and the art of surveying. First then, I will proceed to deal with those matters which pertain to the former heading, since both the subject and methodical arrangement require it. And so I will describe first of all the digging of shafts, tunnels, and drifts on venae profundae; next I will discuss the good indications shown by canales2, by the materials which are dug out, and by the rocks ; then I will speak of the tools by which veins and rocks are broken down and excavated ; the method by which fire shatters the hard veins ; and further, of the machines with which water is drawn from the shafts and air is forced into deep shafts and long tunnels, for digging is impeded by the inrush of the former or the failure of the latter ; next I will deal with the two kinds of shafts, and with the making of them and of tunnels ; and finally, I will describe the method of mining venae dilatatae, venae cumulatae, and stringers.

Jan 1, 1950

By Strathmore R. B. Cooke

That calcium will activate quartz for flotation with anionic collectors such as soaps has been known for a number of years,1 2 3 and the method has been applied to the concentration of various iron ore 4 5 6 as well as to other materials. Clemmer gives the permissible pH range for the activation of quartz by calcium as between 9.5 and 12.5 with an optimum value of 11.0, and Hertzog7 has determined the calcium abstraction of iron ores and of Ottawa sand, but otherwise little quantitative data are available. The purpose of the present investigation was to determine those conditions under which dilute solutions of calcium chloride will activate quartz for anionic flotation and to determine the amount of calcium ion adsorbed by quartz. Those variables, the influence of which was primary, such as calcium, sodium, and hydrogen ion concentrations, were studied. Other factors which influenced the results are discussed in the description of the experiments. Three different experimental methods were used to determine the activation of the quartz. The first method was to treat a sample of ground, deslimed quartz with solutions of calcium chloride and sodium hydroxide, and to determine the calcium adsorbed by chemical analysis of the solution. Ad- vantages are that a direct value for the

Jan 1, 1949

By T. D. Thomas

CONTENTS PAGE T. D. Thomas-Misfires in Anthracite Coal Mines 3 W. H. Forbes-Misfires in Bituminous Coal Mines 12 A. W. Worthington-Misfires in Non-metallic Mining (Limestone) 18 Misfires in Anthracite Coal Mines BY T. D. THOMAS,* LANSFORD, PA. (New York Meeting, February, 1929) IN THIS paper, major attention is given to misfires in mines where electric multiple shot-firing is the system used. Misfires are sometimes caused by one action or condition and at other times by a combination of two or more. They may be divided into two classes: (1) those caused by workers in the mines, (2) mechanical or manufacturer's causes. The second cause will be discussed first.

Jan 1, 1929

By Norman Ketzlach

Manganese Products, Inc. has developed a chemical process for the recovery of high-grade manganese oxides from low-grade manganese ores. Ammonium sulphate is also produced. Manganese ore is leached with sulphurous-sulphuric acids. The impurities are removed with ammonia, heat, and air. Manganese oxides are produced by addition of more ammonia and air under pressure. Ammonium sulphate is recovered from the remaining solution.

Jan 3, 1950

By Henry Sturgis Drinker, Rossiter W. Raymond

Jan 1, 1914