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By G. E. Steudel

The study of the possibility of effecting a lower cost in the manufacture of pig iron reveals the importance of the ever present question of slag chemistry and volume. Factors that determine slag chemistry and volume are the impurities in the ore available, the ash-sulphur content of the coke, and a flux material necessary to promote removal of sulphur. Of these, the ores present by far the major source of impurities and what may prove to be the lowest practical slag volume with desired chemistry in one locality may be considered low or high in some other center of iron manufacture. The Chicago district is not only blessed with ores of high quality, but with excellent coke and flux materials as well. It is the intent of this paper to discuss slag problems at the South Works only, where burdens consist of Mesabi ores, Michigan stone, and coke ranging from 7 to 9 per cent ash and containing an average of 0.57 per cent sulphur. Early in the development of modern blast-furnace practice, the consideration of slags was secondary to the many adjustments of mechanical difficulties, such as furnace lines, stock distribution, stove design for obtaining higher blast temperatures, improved chemical segregation and size of raw materials. Furnace operators, after making these improvements, turned their attention to the study of other refinements in practice, of which slag chemistry appeared to be the most important. It is only within the last two decades that operators have become familiar with the various aspects of slag compositions. The industry, while rather slow in its recognition, is indebted to such investigators as Rankin,1 Wright,1 Feild,2 Royster,2 McCaffery,3 Kinney,4 Holbrook,5 and Joseph,5 whose researches concerning the elimination of sulphur within the blast furnace and the effect of slag composition upon melting point, viscosity, and desulphurizing power have established criteria for the selection of slags of the requisite quality. Large slag volumes result in higher coke consumption and cost of disposal. Any attempt to lower slag quantity must be accomplished

Jan 1, 1940

By Arthur Taggart

INTRODUCTION THE flotation process for the concentration of ores is a method by means of which one or more of the minerals in the ore (usually the valuable ones) are picked up by means of a liquid film and floated at the surface of .a mass of fluid pulp. Here they are separated from the other minerals, which remain immersed in the body of the pulp. In general, the minerals which are floated are sulphides of metallic luster, but some other minerals of metallic luster such as graphite and some sulphides with adamantine luster, such as sphalerite and cinnabar, are amenable to treatment by the process. The importance of flotation lie's in the fact that it is primarily a "slimes process" by means of which the particles of valuable mineral, too fine for efficient gravity concentration, are saved with a high percentage of recovery. Recoveries in the mills treating low-grade copper sulphide ores have been advanced 10 to 20 per cent. by the installation of the process and similar increased savings have been accomplished by the same means in mills treating sulphide ores of zinc and lead. When finely ground ore containing sulphides mixed with a siliceous or earthy gangue is brought gently onto the surface of a body of water, in a direction forming an acute angle with the surface of the water, a considerable portion of the sulphide constituent of the ore floats on the surface of the liquid, while the gangue sinks. This is the so-called film flotation, exemplified by the Wood and Macquisten processes. When gas bubbles are introduced into a fluid pulp composed of finely ground ore and water, to which has been added (1) a small amount of certain oils, or (2) a small amount of certain acids or acid salts, or (3) a small amount of certain alkalis or alkaline salts, or (4) a small amount of a mixture of oil with acid or alkali, the sulphide particles in the ore are brought to the surface on the gas bubbles. These collect in a froth

Jan 8, 1916

By C. M. Moncrief, B C. Craft

A bentonite-clay drilling mud when treated with tetrasodium pyroarsenate underwent substantially the same reduction in viscosity and water loss as when treated with the complex phosphates. The complex arsenate showed a slightly higher reversion after heating; the other arsenates showed poor viscosity-reducing properties. Introduction During the past 10 years the chemical control of drilling mud has become of major importance in affecting the successful drilling and working over of wells. The desired properties of drilling mud have been well established, and in obtaining these characteristics there has developed a large market for viscosity-reducing chemicals. Viscosity reduction produced by humic acid, tannic acid, sodium silicate, sodium tannate, Calgon, and the complex phosphates has been described by Loomis, Ford, and Fidiam.l The effects Of treatment with complex phosphates and ammonium PolyPhosPhates on the rheological properties of muds were investigated by Fancher2 and the alkali vanadates have been described by Williams.3 Laboratory Investigations It is the purpose of this paper to point out the effects of arsenates in controlling the viscosity and gelling characteristics of a drilling mud. Viscosities and gel strengths were measured at room temperatures with a Stormer viscosimeter calibrated in centipoises and operated at 600 r.p.m. Water loss was determined at 80°F. with the Baroid low-pressure wall-building tester at a pressure of I00 lb. per sq. in. for 30 min. The hydrogen-ion concentration was measured with a glass electrode. The bentonite-clay suspensions were prepared in the laboratory and allowed to age several days before testing. Members of the Arsenic Group in the periodic Table include arsenic, antimony and bismuth, but this investigation was limited to arsenic. Phosphorus also occurs in Group V of the Periodic system and phosphorus and arsenic form many closely related compounds such as pH3 and AsH3, P2O5 and As2O5, H3PO4 and H3AS04 Samples of tetrasodium pyroarsenate were prepared by fusing c.p. disodium arsenate (Na2HA5O4.7H2O). According to Friend,' this re-forms the ortho-arsenate on dissolution in water. Sodium trihydrodiorthoarsenate was prepared as described by Mellor,5 from arsenic pen-toxide as follows: As2O5 + 3H20 -> 2H3AsO4 2H3AS04 + 3NaOH Na3H3(AsO4)2 .3H20 Sodium dihydrogen orthoarsenateWaHz-As04) was obtained by fusing together equivalent quantities of arsenious Oxide and sodium nitrate, dissolving the residue in water and allowing it to crystallize.

Jan 1, 1946

By Paul Hunt

UP TO June, 1923, the Park-Utah mine had shipped about 94,000 tons of a direct-smelting ore of a gross value of $4,200,000, or about $45. a ton. These values were in gold and silver only, although the ore carried small amounts of lead, copper and zinc. Freight, treatment and deductions had averaged $15.40 a ton. At the expiration of the Pittman Silver Act there was in sight about 30,000 tons of a similar ore with a gross value of about $15 a ton in gold and silver, and a large body of partly developed lead-zinc ore of a gross value of about $20 a ton, 40 per cent. of which was represented by the lead-zinc content and the balance by the silver and gold. Mine costs had been high during the life of the Pittman Act, but as a large part of the profits had gone into equipment of the mine and the orebodies were large and had good walls, we knew that mine costs could be greatly reduced. We were therefore faced by the necessity of getting lower freight and smelter rates or of concentrating the ore. We did obtain better freight rates on lower grade ore, and a favorable smelting rate on the small tonnage of siliceous silver-gold ore, but this smelter rate could not be applied to the lead-zinc ore with any profit to ourselves. The Judge mill of the Park City Mining & Smelting Co., with which we were affiliated, was running to capacity; if we built our own mill it meant a 5-mile freight haul to a satisfactory millsite and a year's delay. Fortunately, the International Smelting Co. had just inherited a mill at Tooele which, with some changes, was about double the capacity required for its own ores. Flotation tests were run on Park-Utah ore and a contract entered into with a low base treatment charge per ton, the tariff being largely fixed by the metallurgical deductions. This contract has been admirably calculated so that the miner can follow a lean orebody to its limit. Such a procedure has no doubt made it difficult for the smelting company at times, but it has resulted in finding ore extensions that otherwise might have been missed, so in the long run it has profited too. A flat rate per ton would have been like mining up to the claim endlines in a great many of the stopes. In order to offer such a contract it can be inferred that the smelting company must have been able to make high recoveries and high-grade products on a very lean ore.

Jan 1, 1928

By C. M. Moncrief

A bentonite-clay drilling mud when treated with tetrasodium pyroarsenate underwent substantially the same reduction in viscosity and water loss as when treated with the complex phosphates. The complex arsenate showed a slightly higher reversion after heating; the other arsenates showed poor viscosity-reducing properties. Introduction During the past 10 years the chemical control of drilling mud has become of major importance in affecting the successful drilling and working over of wells. The desired properties of drilling mud have been well established, and in obtaining these characteristics there has developed a large market for viscosity-reducing chemicals. Viscosity reduction produced by humic acid, tannic acid, sodium silicate, sodium tannate, Calgon, and the complex phosphates has been described by Loomis, Ford, and Fidiam.l The effects Of treatment with complex phosphates and ammonium PolyPhosPhates on the rheological properties of muds were investigated by Fancher2 and the alkali vanadates have been described by Williams.3 Laboratory Investigations It is the purpose of this paper to point out the effects of arsenates in controlling the viscosity and gelling characteristics of a drilling mud. Viscosities and gel strengths were measured at room temperatures with a Stormer viscosimeter calibrated in centipoises and operated at 600 r.p.m. Water loss was determined at 80°F. with the Baroid low-pressure wall-building tester at a pressure of I00 lb. per sq. in. for 30 min. The hydrogen-ion concentration was measured with a glass electrode. The bentonite-clay suspensions were prepared in the laboratory and allowed to age several days before testing. Members of the Arsenic Group in the periodic Table include arsenic, antimony and bismuth, but this investigation was limited to arsenic. Phosphorus also occurs in Group V of the Periodic system and phosphorus and arsenic form many closely related compounds such as pH3 and AsH3, P2O5 and As2O5, H3PO4 and H3AS04 Samples of tetrasodium pyroarsenate were prepared by fusing c.p. disodium arsenate (Na2HA5O4.7H2O). According to Friend,' this re-forms the ortho-arsenate on dissolution in water. Sodium trihydrodiorthoarsenate was prepared as described by Mellor,5 from arsenic pen-toxide as follows: As2O5 + 3H20 -> 2H3AsO4 2H3AS04 + 3NaOH Na3H3(AsO4)2 .3H20 Sodium dihydrogen orthoarsenateWaHz-As04) was obtained by fusing together equivalent quantities of arsenious Oxide and sodium nitrate, dissolving the residue in water and allowing it to crystallize.

Jan 1, 1946

By W. D. Robertson, D. A. Koss, A. J. Goldman

THE significance of the hcp (E) structure, which appears when Fe-Cr-Ni alloys (stainless steels) are transformed martensitically, has been the subject of considerable study and speculation.'-7 It has been proposed that the hcp structure is an intermediate phase in the transformation: fcc (austenite) — hcp (E) -bcc (0, martensite). However, recent studies by transmission electron microscopy6,7 have indicated that the hcp structure may be a consequence of the large shear strain (10 deg) associated with the fcc to bcc transformation. That is, the transformation to a bcc structure is accompanied by extensive dissociation of dislocations in the parent austenite, which has a low stacking-fault energy.'-'' X-ray diffraction analysis of the transformed alloy reveals a pattern of lines corresponding to an hcp structure, together with the parent austenite and the bcc product. The fact that the hcp structure is observed only in association with the bcc product in these alloys1'4'6'7 lends support to the conclusion that the hcp structure is a secondary product of the transformation. But, the evidence is circumstantial and more definite resolution of the two possibilities mains to be obtained. If the hcp structure is an intermediate product of the transformation, as in 1) above, then two distinct Ms temperatures should be observed, Ms and To evaluate this possibility, three different techniques that are particularly sensitive to the structural changes accompanying such transformations have been used in an attempt to detect two transformation temperatures in an Fe-15.1 Cr-11.7 Ni alloy: 1) high-sensitivity differential thermal analysis, 2) the temperature dependence of resonant frequency (elastic moduli), and 3) internal friction of cylindrical specimens vibrating in either longitudinal or torsional modes. To obtain the necessary sensitivity, a differential thermal analysis technique was developed for the purpose, Fig. 1. The differential temperature between a nickel standard and the specimen was amplified to produce a sensitivity of 0.02OC (0.7 v) in temperature difference. The specimen and the standard were surrounded by a copper block and the entire assembly was immersed in a solution of methyl and ethyl alcohol, freezing point, - 140OC, which provided the necessary thermal stability to reduce temperature fluctuations to negligible proportions. A cooling rate of about 1.5OC per min was obtained by bubbling liquid nitrogen through the liquid bath. In order to calibrate the experiment with respect to the evolution of heat in the transformation from fcc to hcp structures, differential cooling curves were obtained for an Fe-19.8 Mn alloy, which transforms martensitically to E.'"-' a Ms(e) temperature of 145°C was clearly defined by a temperature

Jan 1, 1964

By Stephen Birch

LATOUCHE, or the Beatson plant of the Kennecott Copper Corpn., is located in the Prince William Sound district of Alaska about 80 miles west of Cordova and 60 miles from Seward. Ore was discovered and claims located on Latouche Island in July, 1897. The mines were worked in a desultory manner until 1910, when the property was acquired by the Kennecott Copper interests. The first shipment of ore was made in 1904; only the higher grade ore was mined and no attempt was made to treat the ore until it was taken over by the Kennecott, company. Since that time the mine has been developed to produce 1500 tons a day and a mill has been erected for treating this tonnage, using flotation entirely. The orebody is more or less lenticular in shape with a maximum width of about 280 ft. and a length of about 800 ft. The southern end of the lens is split by a horse of waste for about 400 ft. The hanging-wall limit is a well-defined fault associated with a band of pyrrhotite, having an average dip of 60°. There is no defined foot wall, the value of the ore governing the limits of the mining; in one part of the mine, however, it is defined by a minor fault. The orebody is located in a shear zone of the country rock of graywacke and slate. The principal mineral is chalcopyrite associated with pyrite and quartz. The mine is located a few hundred feet from tidewater; the mill is located on the beach and the ore is hoisted direct from the mine through a vertical shaft into the mill bins. Until the past year practically all the mining had been conducted in open pits. During the past two years, the ore above the 200-ft. level has been developed and a system of stoping devised to recover this ore; however, this system has not been in use long enough to give any definite results as to costs or efficiency. It consists, principally, of dividing the orebody into stopes, across the full width of the orebody, 70 ft. wide with a pillar 30 ft. wide between the stopes. Raises are driven through the stopes at intervals of about 60 ft. and all the ore is broken by drilling from these raises; in other words, similar to a shrinkage stope, doing the drilling from the raises instead of setting up on the broken ore as is customary. The ground is very much broken up by clay slips and seams running in every direction. Shrinkage stoping had been

Jan 1, 1924

By R. E. Ogilvie, N. L. Peterson

Intevdiffusion and intrinsic diffusiorz coefficients were determined in the uranium-niobium system from diffusion couples analyzed with an electron microbeam probe. A Previously unveported intermediate phase, designated in this report as the delta phase, was found to exist along the mobium-rich side of the miscibility gap. Its composition width was determined from the concentration gradients in the diffusion couples. The presence of this phase was also confirmed by microhardness analysis and metallographic observations. THE excellent corrosion resistant properties, high-temperature strength and reasonable nuclear properties of niobium have prompted its use as an alloying element with uranium and as a possible cladding material for reactor fuel elements. Hence the formation and growth of intermetallic phases as well as diffusion data for the uranium-niobium system are of considerable practical importance to metallurgists and nuclear engineers. Diffusion zones may exhibit varying degrees of complexity dependi.ng upon the mutual solubility of the metals involved, and the intermediate phases which may form. In the simplest case where the metals exhibit a calmplete range of solid solubility, a single phase region is produced. Generally, however, the metals may react to produce a multiphase diffusion zone containing several layers of intermetallic phases. A number of investigatorsl-6 have analyzed the concentration gradients present in diffusion couples in order to investigate phase equilibria and solu- bility limits. If diffusion is the rate-controlling process in establishing a concentration gradient, the compositions at the interfaces of the intermediate phases will represent the equilibrium values expected from the phase diagram at the temperature at which diffusion has taken place. No published information is available at this time on diffusion in the uranium-niobium system. A number of investigators7-" have contributed information to the construction of the uranium-niobium phase diagram from other than diffusion techniques. There is good agreement on the high uranium side of the phase diagram, but the high niobium side of the miscibility gap still remains somewhat in doubt. The phase diagram as determined by B. A. Rogers, et al.7 is shown in Fig. 1. The present work was aimed at obtaining fundamental information about the solubility limits of the miscibility gap and diffusion in the uranium-niobium system. A Kirkendall effect, which might be expected on the basis of the rather large difference in melting points between uranium (1132°C) and niobium (2415" C), was also investigated. The concentration gradients were measured by an electron microbeam probe technique, similar to that used by Castaing,l2 Adda and philibert,13, l4 and Macres.4

Jan 1, 1961

By Clarence Zener

THE internal friction of nonferrous metals vibrating at low stress amplitudes has so far always been successfully interpreted in terms of inhomogeneities of one sort or another. Examples are the fluctuation of stress across a specimen vibrating transversely,1,2,3 the stress inhomogeneities due to the elastic anisotropy and partial random orientation of the individual crystallites,4,5 localized weak regions introduced by cold-working,6,7 grain boundaries and possibly twinning planes.8,9 Perfect single crystals are, by definition, homogeneous. Actual single crystals usually, perhaps always, contains some imperfections. The present investigation. was undertaken to determine whether the internal friction of single crystals may likewise be attributed to inhomogeneities. This study was made possible through the gift of a large single crystal of 70-30 alpha brass by H. L. Burghoff, of the Chase Brass and Copper Co. The specimen, ½ in. in diameter and 10 in. long, was similar to samples previously described by Mr. Burghoff.10 EXPERIMENTAL METHOD The experimental method used has previously been described in Institute papers.5,6,9 The measure of internal friction adopted here, 1/Q, is (1/p) X the logarithmic decrement, a measure used by some writers, and is also (1/2p) X the specific damping capacity, a measure used by other writers. In all measurements the stress level was kept so low that the measurements were independent of stress level. In all measurements in which the temperature was varied, observations were made as the specimen slowly cooled from its highest temperature. The specimen was vibrated transversely. Observations were made at the funda¬mental frequency and at the first overtone, of about 620 and 1710 cycles per second, respectively. No attempt was made to avoid acoustical losses. EXPERIMENTAL RESULTS The specimen was annealed for several hours at 450°C. The temperature dependence of the internal friction was then determined from room temperature to 400°C. As shown in Fig. 1, the internal friction increased by only a factor of 2 from room temperature to 300°C., then by a factor of l00 during the next 100° interval. These measurements are consistent with the view that the observed internal friction is the superposition of two distinct parts. One, dominant at room temperature, is nearly independent of temperature. This part may be accounted for by acoustical losses and by transverse thermal currents. It was not further investigated. The second part, when plotted in the manner of Fig. I, lies upon a straight line. Therefore it has a heat of activation H; i.e., it varies with temperature as Internal friction e~H/RT [I]

Jan 1, 1942

By Park Wright

The fact that granite has been encountered by the drill by those in search of oil and gas in Kansas is becoming more and more a matter of interest, not only to the oil producer but to everyone directly and indirectly connected with the oil business. It is, therefore, time that someone should offer an explanation for its presence and form a definite opinion, based on all the data available, in regard to the effect it will have on the future prospects of the area affected as probable oil-and gas-producing territory. At present there seems to be no consensus of opinion. To the writer's knowledge, only one attempt has been made to explain ; by Erasmus Haworth, State Geologist of Kansas, in a paper entitled Bulletin Number Two on Crystalline Rocks in Kansas. The purpose of the present paper is to offer a theory for the presence of the granite, and to draw conclusions which will aid in determining the prospective oil and gas value of the area in question. In taking up this question it will be well to consider first the tests in which granite has been reported, with a general history of each. The accompanying map (Fig. 1) shows the location of all wells described. The first well in which granite was reported was that drilled just south of Zeandale in section 27, township 10 south, range 9 east, by a local company which had taken up a block of leases in that vicinity. At a depth of 958 ft. (291.99 m.) granite was encountered. Drilling was continued to a depth of 1093 ft. (333 m.) in the same formation, at which depth the hole was abandoned. Another well was started 1 mile east of the first well and the same rock was found at a depth of 945 ft. (288 m.). Drilling was continued to a depth of 1200 ft. (365.76 m.) with the bit in the same formation. Samples of the drill cuttings have been examined and they are undoubtedly crushed granite. The next well in which granite was found was that drilled by DeLaat and Shepard, independent wildcat operators, in section 34, township 19 south, range 7 east, near the town of Elmdale. Granite was struck at 1707 ft. (520 m.) and the hole was abandoned in the same formation at 2525 ft. (769 m.). Mr. DeLaat watched the drilling of this well very closely and he has described to me in some detail the formation immedi-

Jan 1, 1918

By Harry W. Antes

The density changes that occurred on annealing cold-worked poly crystalline molybdenum, over the temperature range of 870" to 1630 SC, were determined. Increases in density were observed for recovery and the beginning of recrystallization. An initial decrease in density was observed during re-crystallization. A second decrease in density was observed after recrystallization was completed, as the microstructure changed from columnar grains to equiaxed gvains Both decreases in density were associated with an increase in gain boundary area to volume ratio. The second decrease in density was observed in the annealing range that immediately precedes secondary recrystallization as reported in the literature VARIOUS techniques have been used to identify the recovery, recrystallization, and grain growth processes that occur when cold-worked metals are annealed. As early as 1928 work was conducted that indicated measurable density changes occur when cold-worked single crystals of brass are annealed.' More recently, work by Murphy exhibited a corre- lation of density with microstructural changes observed on annealing cold-worked polycrystalline a brass.2 Other investigators have performed similar work on a brass and copper.324 In reviewing the literature, it was apparent that density work had been limited to fcc materials. Therefore, it was the purpose of this investigation to determine the density changes that accompany annealing the cold-worked bcc material, molybdenum. Two degrees of cold work, 30 and 90 pct reduction of cross-sectional area by rolling, were selected for this study. EXPERIMENTAL PROCEDURE High-purity vacuum arc-cast molybdenum was used in this study, the principal impurity being carbon in the amount of 80 ppm. The final rolling reductions were made at 1200°C in grooved rolls to provide 5/8-in.-diam rod. Density specimens 0.500 in. diam by 1.5 in. long were machined from the bar stock. The specimens were ground to the final dimensions to provide a smooth surface. Density measurements were made using a hydrostatic technique similar to that used by ~urphy.' This type of equipment permitted weighing in liquid immediately after the air weighing. During each weighing the temperature of the air and liquid was controlled to within 0.0l°C. This was accomplished by sealing the analytical balance in an air-tight brass chamber and surrounding it by an insulated wooden case. Preheated air was circulated in the air space between the brass chamber and wooden case by means of a blower. The temperature of the

Jan 1, 1964

By Ralph E. Grim

THE technology of clay minerals is defined, for the purpose of this review, as- the application of fundamental data regarding clay minerals, and techniques of handling them, to the various industries, arts, and professions concerned with clay materials. The aim of the paper is to narrate recent developments in clay mineral technology. This review does not claim to be complete, and perhaps gives undue emphasis to matters that have been worked on in the author's laboratory or with which he has some other connection. In the United States in recent years, particularly since the end of World War 11, interest in clay mineralogy has increased greatly. Many laboratories in many different fields have embarked on studies of clay minerals but unfortunately much of this work has not been published. CERAMICS In the field of ceramics, in recent years, a great deal of interest has developed in clay mineralogy. Papers too numerous to be reviewed here have been published portraying the clay mineral composition of substantially all the important types of ceramic clays in all countries. There has been a growing tendency to attempt to solve processing problems on the basis of clay mineral data rather than chemical analytical data. Likewise, there is an in- creasing tendency to control the characteristics of raw materials on the basis of clay mineral composition rather than chemical composition. In the United States in the last few years something like 50 differential thermal analyzers have been set up, and many are for the sole purpose of controlling raw material and processing. The ceramic industry is currently increasing its attention to the influence of exchangeable ions and soluble salts on physical properties. Ion concentration in clay suspensions has long been a matter of interest, but now it is also of interest in clays in the plastic state because of its recognized importance in the plastic, shrinkage, and bonding properties of clays. Students of clay have long recognized that an understanding of the plastic properties of clays is based on an understanding of the character of the water in clay-water systems, the nature of the binding force between individual clay mineral particles, and the factors that control the character of the water and the nature of the bonding force. In the last few years, some extremely important contributions have greatly increased the understanding of the nature of water adsorbed on the clay mineral surfaces. In this connection the work

Jan 1, 1952

By E. R. Brownscombe, Francis Collins

The pressure distribution in a reservoir producing an incompressible fluid by radial flow in a horizontal structure is a simple logarithmic function' used daily by reservoir engineers. The assumption of an incompressible liquid is equivalent to assuming that pressure is maintained constant at the well radius and at some external "radius of drainage," or, in other words, that the entire flow into the well passes across the external radius. In most cases a well is surrounded by other wells draining adjoining areas so that the "radius of drainage" is not a line of constant pressure with flow equal to the flow into the well but rather a contour of zero pressure gradient across which no flow occurs, production being due to the expansion of the liquid within the area. The radial flow steady state pressure distribution for this case does not seem to be extensively used despite the fact that the mathematical analysis has been given in detail' and the results are simple and generally applicable. 'The object of this discussion is to develop this result from a physical rather than a mathematical viewpoint, thereby aiding intuition in judging circumstances to which it may be applicable. If the production rate at a well in an unsaturated reservoir is maintained constant while no flow occurs across the outer radius a steady state will soon be reached in which the flow rate or pressure gradient is constant with time at all points in the reservoir. To preserve such a condition it is necessary that the pressure decline at the same rate at all points in the reservoir, that is, the curves of pressure versus radial distance at successive times are all parallel. Then each unit volume of oil is expanding at the same rate and contributing an equal share to the production. The rate of flow q across any circle r is thus proportional to the volume of the reservoir between r and the external radius re, or q = qw (I-r2/r2e) ......(1) where q, is the production from the well and it is assumed that rw is very small compared with re. This equation can be combined with the differential form of Darcy's law for radial flow, 2phkr dp q =—— ........(2) aµß dr ( where q is not a constant as in the incompressible flow case but is a function of r given by Equation (1). If Equation (1) is substituted in Equation (2) the variables p and r can be separated and the result integrated to obtain the pressure distribution p = pw +--------In------------- 2pkh[ rw 2re2] ......(3) This equation differs from the incompressible case only in the addition of the term proportional to the square of the radius

Jan 1, 1950

By George A. Packard

The shaft of the Raven mine, at Butte, Mont., is an incline 1,700 ft. in length and dipping at various angles. At the top the dip is 70" from the horizontal, but this is gradually flattened until at the 300-ft. level the inclination is only 47. This angle continues to the 1,100-ft. level, below which it curves with a 125-ft. radius to 78". In addition to these variations in dip, the shaft does not lie in the same vertical plane, with the result that the hoisting rope not only rubs at intervals on both the hanging and foot walls, but presses strongly against the west dividers near the collar, while 300 ft. below it runs close to the east end plates. The early operators used no idlers, aid wall plates cut 6 in. deep by the rope resulted. Later operators first attempted to overcome the excessive friction, and the wear of rope and wall plates, by introducing solid cast-iron idlers, 3 in. in diameter. To allow for the travel of the rope from side to side some of these had to be 3 ft. long and were very heavy. Judging from the appearance of the old idlers of this type found at the mine, they often failed to turn in the bearings, which is not surprising when it is considered that they would have to make 1,000 rev. a minute under ordinary hoisting conditions. The next rolls were made of wood, 6 in. in diameter, with an iron band about each end, and a pintle of 1-in. round steel driven in at the ends to serve as a shaft. These wore rapidly, and were soon replaced by rolls made from water pipe, 5 or 6 in. in diameter, cut to the desired length and fitted with a wooden cylinder into which the pintle was driven. Where the idlers were used on the hanging wall of the shaft the original bearing was simply a piece of + by 1 3/2 in. strap iron, 10 in. long, turned up at the end in a circle 11/8 in. in diameter to receive the shaft. A small hole served for oiling, and common black oil was generally used, although filtered oil from engine bearings and compressor bearings was also used. When the rolls were to be placed on the foot wall the bearings were made from two pieces of 1 by 3 in. steel, 6 in. long. A half circle was cut on the flat side of each piece and the two half circles together formed a bearing. Oil holes were provided, and in some cases holes were bored through the two pieces so that they could be screwed or spiked to the wall plates.

Jan 1, 1915

By F. C. von der Weid

THE mining district of São Fidelis, in the northern part of the State of Rio de Janeiro, is situated on the Paraiba River, where it crosses the Serra do Mar (Mountain of the Sea), in the center of a mountainous country having numerous graphitic outcrops. For a long time, these outcrops were irregularly explored by local people, who had little means and no technical advice. A few years ago, the Cia. Brasileira de Mineração de Grafite took over the control of some of the more important outcrops and entrusted to me the task of studying the ores and establishing a flowsheet for a pilot plant to be situated in Sao Fidelis-the ore to be concentrated being mostly of a very high grade. MINERALIZATION AND ORES The rocks of the district are mostly gneiss and crystalline schists, with occasional interstratification of dolomitic limestone belonging to the Archean Brazilian Fundamental Complex. The general direction of the beds is roughly between 60° and 80°E., with variable dip, generally nearly vertical. Mostly, direction and dip of the graphitic outcrops is concordant with the embanking gneisses or schists. These outcrops seem to be aligned in two or three parallel zones (Pádua, São Fidelis, Macabú), the São Fidelis zone being the best known and the most important to date. Two outcrops of the São Fidelis zone, Saudade and São Benedito, are now being exploited. Mining has been carried out, so far, on a small scale. The mineralization consists of a vein of nearly massive graphite in a very compact, partially granitized gneiss, with vertical dip. The vein is most irregular, with nests and lenses irregularly distributed along the fracture plane. The ore consists chiefly (particularly in São Benedito) of massive graphite appearing and disappearing along the main direction of the vein, forming a succession of irregular lenses in a sort of rosary design. The average width is more or less one foot, with variations from zero to 6 feet. The lode minerals are quartz, a little feldspar and garnet (the latter having its origin perhaps in the embedding gneisses), with rare ferruginous clays on the outcrops. In Saudade a little pyrite, pyrrhotite and chalcopyrite is found occasionally, as well as a carbonaceous mineral, very light, black and shiny, with conchoidal fracture, looking like a sort of jet. The composition of this mineral has not yet been established, but it seems to be very complex. The mineralization seems to be hydrothermal at a rather low temperature, perhaps mesothermal. The paragenesis, according to samples from Saudade, seems to be as follows, the earlier minerals being listed first: pyrrhotite, pyrite, chalcopyrite, with quartz concomitant to the three and

Jan 1, 1946

By George Packard

THE shaft of the Raven. mine, at Butte, Mont., is an incline 1,700 ft. in length and dipping at various angles. At the top the dip is 70° from the horizontal, but this is gradually flattened until at the 300-ft. level the inclination is only 47°. This angle continues to the 1,100-ft. level, below which it, curves with a 125-ft. radius to 78°. In addition to these variations in dip, the shaft does not lie in the same vertical plane, with the result that the hoisting rope not only rubs at intervals on both the hanging- and foot-walls, but presses strongly against the west, dividers near the collar, while 300 ft. below it runs close to the east end plates. The early operators used no idlers, and wall plates cut 6 in. deep y the rope resulted. Later operators first attempted to overcome the excessive friction, and the wear of rope and wall plates, by introducing solid cast-iron idlers, 3 in. in diameter. To allow for the travel of the rope from side to side some of these had to be 3 ft. long and were very heavy. Judging from the appearance of the old idlers of this type found at the mine, they often failed to turn in the bearings, which is not surprising when it is considered that they would have to make 1,000 rev.. a minute under ordinary hoisting conditions. The next rolls were made of wood, 6 in. in diameter, with an iron band about each end, and a pintle of 1-in. round steel driven in at the ends to serve as a shaft. These wore rapidly, and were soon replaced by rolls made from water pipe, 5 or 6 in. in diameter, cut to the desired length and fitted with a wooden cylinder into which the pintle was driven. Where the idlers were used on the hanging-wall of the shaft the original bearing was simply a piece of 2 by 1-1 in. strap iron, 10 in. long, turned up at the end in a circle of 18 in. in diameter to receive the shaft. A small hole served for oiling, and common black oil was generally used, although filtered oil from engine bearings and compressor bearings was also used. When the rolls were to be placed on the foot-wall the bearings were made from two pieces of 1 by 3 in. steel, 6 in. long. A half circle was cut on the flat side of each piece and the two half circles together formed a bearing. Oil holes were provided, and in some cases holes were bored through the two pieces so that they could be screwed or spiked to the wall plates.

Jan 8, 1914

By H. L. Washburn, G. L. Judy

DURING recent years thermal drying of fine coal has increased at a tremendous rate, but very little discussion of the several excellent units has found its way into print. This is particularly true for operating and maintenance costs, and the operator who is faced with his first fine coal drying installation must depend chiefly on hearsay when trying to determine what his drying costs will be. This article presents the maintenance and operating costs for the seven drying units now installed in preparation plants of Pittsburgh Consolidation Coal Co. and lists other cost information that should be obtained before any particular drying unit is selected. Plant Description: The fine coal drying section of Plant A consists of four Flash driers operating on two furnaces equipped with spreader stokers. Plant B has one Flash drier operating (together with a screen-type coarse coal drier) on one furnace equipped with a spreader stoker. Plant C has two Cascade-type driers operating on a single furnace with a spreader stoker. Plant Costs: Tables I, 11, and III present the cost of operating these units as reported by the individ- ual plants. As can be seen, the labor rates vary, depending on the amount of overtime paid and the time interval the cost figures cover. There is considerable variation in thermal units used and in the value given to the thermal units at the particular mine. There is some difference in power costs at a given location and, finally, the power costs of conveyors leading to the drying plants were included in some cases. Maintenance supply costs are simply a tabulation of the cost of all supplies used on the driers, furnaces, and stokers. Depreciation is not included, and the tables omit items such as supervision, plant cleanup, oiling, general maintenance, taxes, and insurance. These tables in themselves do not offer a true comparison of costs. This information must be reduced to some common basis. But what is this common basis to be? A mine operator must calculate his overall mine and preparation plant costs in terms of tons of clean coal sold. Unit costs on pieces of equipment within a given plant are correctly calculated on the same basis. However, when unit costs are compared between one plant and another, some thought must be given to unit design. This reasoning is similar to the old argument concerning i solid bowl vs basket-type centrifuges—the units themselves are not directly comparable without their supporting equipment. So it is with thermal driers. Except in rare cases of low entering moisture i content, driers are sized on the basis of water that must be evaporated, while the wear each unit gets de-

Jan 1, 1958

By Howard S. Lee

In central Colorado is a great belt of intrusive porphyry nearly 100 miles long (160 km.), extending from the Clear Creek district on the north to Aspen on the south, which includes many of the well known mining camps of the state. Near the southern end of this belt, at Leadville, the occurrence of these intrusives is most marked, resulting in intensive mineralization and the formation of a great variety of large orebodies. During the past 40 years, Leadville has been a steady producer of gold, silver, lead, zinc, manganese, iron, and bismuth, in the forms of sulfide, carbonate and oxide ores. It is the purpose of this paper to discuss pyrite alone, which, under present economic conditions, is valuable chiefly for its sulfur contents. The ore-bearing formation of the Leadville district consists of two beds of limestone separated by a layer of quartzite. The upper limeatone is carbonaceous, and is known locally as the blue limestone. It varies in thickness from 50 to 300 ft. (15 to 91 m.). The lower limestone is Silurian, known locally as white limestone, and is about the same thickness as the upper bed. Underneath the Silurian limestone is a layer of Cambrian quartzite from 100 to 250 ft. (30 to 76 m.) thick resting on Archean granite, which forms the limit of ore deposition. As a rule, there is a sheet of white porphyry above the upper, or blue limestone; a sheet of gray porphyry is associated with the blue limestone, either in or below it, but the porphyries are not so regular as the quartzites and limestones and are not always found in their expected positions. Throughout the district there is an elaborate system of faults and intrusive porphyry dikes, which have an important bearing on ore deposits. The writer has seen two or three orebodies which were not closely associated with either a fault or a porphyry dike, but if the minor fractures and water courses are considered as part of the fault system it is safe to say that all orebodies are directly traceable to one or both of these causes. The distribution of pyrite in the Leadville district is quite general; but, eliminating the smaller bodies and those containing prohibitive quantities of zinc or lead, and considering only the larger deposits commercially valuable for their sulfur, we find the chief pyritic ore-bodies extending in a zone approximately 6000 ft. (1828 m.) long and several hundred feet wide, from the Yak and Moyer, on the south; through the Louisville, Greenback, Mahala, Adams, and Wolftone, on Carbonate Hill; across Yankee Hill, and into the Quadrilateral, Denver City, and Tip Top, on Fryer Hill.

Jan 1, 1920

By John J. Porter

Unusual problems have arisen at certain iron blast-furnaces in Virginia through the fact that the ore-supplies, derived from the Oriskany formation, contain from a trace up to 1 per cent, of zinc oxide. Since the technical literature bearing on this subject is very scant, the following notes, based on personal experience, will probably be of value to those of our members who are interested in iron blast-furnace practice. The course of zinc through the blast-furnace is readily traced. Entering the throat as zinc oxide, finely dissemiuated through the ore, it descends unchanged to the fusion-zone, since a temperature of 1,000" C. or more is required for its reduction. At the fusion-zone, the zinc oxide is reduced by solid carbon to metallic zinc, which is set free as vapor and rises with the ascending gases to the cooler zones of the furnace. In cooling through the range of temperature from 1,000" to 500° C. the zinc is re-oxidized according to the reaction Zn + CO2 = ZnO + CO, and the resulting zinc oxide, being in a very fine state of division, is readily carried along by the ascending gases. Portions, however, deposit on the descending stock and are carried down, again to pass through the same cycle of changes. Still other portions deposit on the lining of the stack, and gradually form hard masses of "cadmia." Of the remainder of the zinc oxide, the greater part passes out of the furnace, and is either deposited in the down-comer, dust-trap, stoves, boilers and flues, or passes through the chimney into the atmosphere. A small portion escapes reduction and enters the slag as zinc oxide, while still another portion is absorbed into the lining of the furnace.

Jan 1, 1908

By Clarence Zener

IT has long been known that the density of a metal usually decreases with cold-work. Thus O'Neilll observed as early as 1861 that cold hammering of commercial hot-rolled copper is accompanied by a decrease of density of 0.2 per cent, and that subsequent annealing restores the original density. The origin of this density change, however, has remained obscure. In particular, experiment has not yet decided whether it is due to the presence of small cavities and an increase in inter-granular surface or to an actual expansion of the lattice itself. This uncertainty in the origin of the change in density is a reflection of our uncertainty as to the changes induced in a metal by cold-working. One school regards cold-working as a breaking up of the original grains into a large number of perfect crystallites somewhat randomly orientated with respect to one another.2 According to this viewpoint, the mere introduction of a large intercrystallite surface induces a net volume expansion. Another school regards cold-working primarily as a distortion of the grains. It is not obvious that this second viewpoint will lead to a net volume expansion. The purpose of the present paper is to show that this is indeed the case, and that this expansion is of the right order of magnitude to explain existing experimental data. The physical basis for the association of an expansion with distortion lies essentially in the variation of the elastic moduli with volume. This variation is considerable. Thus from Table I we see that a I per cent increase in volume for the case of copper will decrease the bulk modulus K by 10 per cent, the shearing modulus µ by 3.8 per cent. If we thus twist a rod through a given angle, we shall do less work upon it if it increases slightly in volume, thereby reducing the torsion modulus that involves as a factor the shearing modulus. A general principle3 in physics states that the rod will so adjust itself as to have a minimum potential energy consistent with the end restraints. It will therefore expand. In order to obtain a quantitative comparison with experiment, we follow Maier4 in comparing the lattice expansion with the latent energy of cold-work. This latent energy has been measured directly by Taylor and Quinney5 on copper rods subjected to torsion, and may amount to as much as 15 per cent of the total work done upon the specimens. We shall assume that this

Jan 1, 1942