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By Zhen Lei

In Alberta, Canada, heavy industrial projects are constructed using a prefabrication approach: spools and pipes are produced in the factory, and are assembled into modules that are transported to the industrial plants for installation by mobile cranes. Planning the onsite mobile crane operations is critical to the project budget and schedule. However, due to the large magnitude of industrial projects, manual heavy lift planning is tedious, and the results are not particularly responsive to site changes. This paper introduces an integrated mobile crane management system developed by PCL Industrial Management Inc., in collaboration with the University of Alberta, which investigates crane location selection and path checking for field module assembly. The project information is stored in a database, and the proposed system retrieves data, performs the calculations, and records the results back to the database; the calculations involve automatically selecting locations for the mobile crane, considering the crane capacity, lifting range and utilization. Lift paths for modules are checked for feasibility based on selected locations, satisfying the site and crane configuration constraints, and crane walking paths are planned if needed. The designed system is tested in an industrial project to validate the effectiveness of the system.

Aug 1, 2013

By M. J. Humenick, K. Garwacka

A laboratory experimental research project was conducted to evaluate the use of chlorine for the oxidative destruction of residual ammonia that may remain in ground water after in-situ uranium solution mining operations. The work tested the idea of injecting high strength calcium hypochlorite solution into the mining zone to convert ammonia to nitrogen gas as a final cleanup process for ammonia removal from the ground water system. This paper details ammonia removal efficiency as a function of chlorine dose, reactant, and product material balances, and how the concept may be used as a final ground water restoration process.

Jan 1, 1985

By K. Ebrahimi-Nasrabadi

The dependence between the extent of conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally in the temperature range of 400?1200 °C and for calcination times up to 8 h. A TGA?DTA analysis showed that decomposition begins at temperatures as low as 340 °C and is completed at 600 °C. Measurements of specific surface area (SSA), iodine adsorption number (IN), crystallite size, and loss on ignition were carried out to characterize the product quality. It was found that while all the parameters are dependent on the extent of calcination, densification of the product caused by grain coarsening affects their final values. As a consequence, SSA and IN went through a maximum with time. The study showed that high quality caustic calcined magnesia can be produced in a narrow range of temperature (600?650 °C) and time (1?4 h). Medium quality caustic calcined magnesia can be made within a wider range of parameters.

Aug 1, 2013

By Dan Wang, Qiuju Li, Xiao Guo

The chemical states and ions interaction were significant interest to understanding columbite mineral/acid solution interface dissolution and reaction. The present research work was focus to explore the specific cations ( Nb5+, Fe2+, Fe3+) distribution near the ferrocolumbite mineral/acid solution interface, and determine these cations leaching sequence in sulfuric acid solution. X-ray photoelectron spectroscopy had the potential to provide detailed dissolution information by resolving chemical state and ion distribution of ferrocolumbite during sulfuric acid leaching process. The binding energy decreased in sequence as Nb5+- O < Fe2+- O < Fe3+- O, and increased in sequence as Fe3+- SO4 < Fe2+- SO4 < Nb5+- SO4 which revealed Nb in ferrocolumbite mineral more easily leached comparing to Fe. The ratio of Fe2+- O/Fe3+-O on leaching residue decreased, and Fe2+- SO4/Fe3+-SO4 ratio increased as sulfuric acid contraction increasing suggested that the Fe2+ oxidized to Fe3+ and released Nb from mineral and dissolved into leaching solution. The ratio of Nb/Fe was lower 0.07 with sulfuric acid contraction increasing which meant Nb dissolution promoted by oxidation of iron. The dissolution mechanism of Fe element in ferrocolumbite mineral was Fe2+- O broken and generated Fe2+. Fe2+ was oxidized to Fe3+ in concentrated sulfuric acid leaching solution. The dissolution mechanism of Nb in ferrocolumbite was that Nb5+- O was directly digested by H+, and the released Nb5+ complex with SO4 2− ion formed cation − anion pairs. The coordination of formation Nb5+- SO4 pairs and oxidation Fe2+ in mineral could promote ferrocolumbite dissolution.

Aug 5, 2023

By J. `. Spitzinger

In situ recovery (ISR) of uranium alters the baseline groundwater geochemistry in order to mobilize and complex uranium to extract and concentrate it. ISR wellfield restoration is often challenging, and primarily relies on groundwater sweep, reinjection of treated permeate, and/or injection of reductants. Greater focus should be placed on injection-based approaches (using existing infrastructure) based on established engineering concepts used for in situ remediation of groundwater plumes. Such injection-based approaches could shorten restoration timeframes consequently reducing long-term operational costs. This paper addresses various types of injection-based approaches to wellfield restoration based on in-situ remediation success with other constituents that require similar treatment. This paper describes necessary design practices for injecting reactive chemicals (e.g., reductants or biostimulants), operations and maintenance (O&M) strategies to prevent fouling of the chemical delivery system and well network, and natural constraints to restoration. Best practices for successful biostimulation strategies that minimize residual uranium, radium, oxoanions, and other trace elements are as described. Advantages of such injection-based approaches could include significant reductions in restoration times, and consequently, lower restoration costs.

Feb 23, 2014

By Luis Briceño Arata

El presente texto describe los proyectos mineros desarrollados hasta el año 2000, el cual contempla los siguientes minerales: plata, hierro, fosfato, oro, carbón antracítico y bituminoso, así como las necesidades energéticas, hídricas y posibles fuentes del suministro.

Jan 1, 1975

By Luis Briceño Arata

El presente texto señala las posibilidades de evolución cuantitativa de la producción minera del país hasta el año 2000. Para ello, se evaluaron los factores que influyen en la producción, la metolodología de proyección adoptada y así elaborar la producción de elementos estudiados.

Nov 1, 1974

By Meeok Kim, Paul Beljan, Gordon Chen

"Clinton combined sewer overflow storage (CSO) facility project developed by the Department of Water Environment Protection of Onondaga County, New York, is to improve sewer facilities and infrastructure in Syracuse, New York. The below grade facility will provide a storage of untreated stormwater during highflow periods to be treated later, thus reducing CSO discharges to Onondaga Creek.The CSO system consists of three parallel storage tunnels and two end chambers (west and east chambers) as main underground structure. The storage tunnels are about 850 ft. long, 55 ft. wide, 24 ft tall and located 20 ft deep below grade. The chambers, include above access and operation structure, are about 40 to 55 ft. deep and approximately 60 to 100 ft. wide.Kiewit Infrastructure and Weidlinger Associates Inc. developed an alternative approach for the tunnels to meet the facility completion schedule, strict design guide lines and quality control as an environmental and water tight concrete structure for the project. The original design anticipated use of a TBM machine to bore three parallel tunnels between two previously constructed chambers.The alternative design used a three barrel culvert cast-in-place structure in a cut and cover excavation supported by a soil bentonite wall. The SOE along the jet grouted bottom seal provided a ground water cut off as well.The SOE system is specially designed to enhance the quality of culvert CIP structure construction by providing enough space for a full height construction. Also it further reduces the construction time by having the less squarefootage of jet grout installation. The design of tunnel systems is accomplished effectively through the utilization of soil structure interaction using a finite element methodIntroductionTo avoid construction of an additional treatment plant to handle increases in combined sewage flows, the Department of Water Environment Protection of Onondaga opted to construct the Clinton combined sewer overflow storage (CSO) facility.The Clinton CSO facility provides an environmental friendly mitigation method for combined sewer overflows on Onondaga lake which is located in northwest of Syracuse."

Jan 1, 2015

By E. H. Dudgeon

In order to make increased use of automation in copper smelting, it is evident that a useful first step .world be the accurate determination of the copper end point in the converter operation. After laboratory tests, the copper end points in a copper converter at Gaspe Copper Mmes Ltd. were determined without reference to melt samples or other observations. The results indicated that the rapid measurement of the S02 level in the gas released from the converter has potential as a new and independent method of determining the copper end point in converter operation.

Jan 1, 1966

By Pedro Hugo Tumialán

El presente texto describe la metalogenia comparada entre Perú y Bolivia -en tanto se relacionan a la Geotectónica de los Andes. Para ello, se revisa el aspecto geológico de Perú, donde en el período precámbrico se emplazó la Cordillera de la Costa y la Cordillera de los Andes se hallaba en un fondo marino. Mientras que en Bolivia, la geotectónica se refiere a la prolongación del Escudo Brazilero, a la llanura del Beni, la Cordillera Oriental y el Altiplano boliviano. Así también se indica la edad absoluta de rocas plutónicas de la Cordillera de los Andes y su relación con el magmatismo con el tectonismo y la geología del Perú y Bolivia.

Jan 1, 1980

By B Davis, M Wallace, J Stewart, C F Burrett, J B. Cannell

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Sepon district in Lao PDR contains 1.8 Mt of JORC (2012) compliant contained Cu resources in addition to &gt;4.5 Moz of Carlin-like Au in a Palaeozoic sedimentary package. The Cu deposits are proximal to an EW lineament of Permian rhyodacite porphyry (RDP) intrusive centres that are characterised by intense barren quartz stockworks. The Khanong deposit (42 Mt at 3.0 per cent Cu mineral inventory) is a carbonate replacement intermediate sulfidation deposit verging on a high sulfidation environment, where abundant pyrite, copper sulfides (chalcopyrite, bornite, trace enargite), copper sulfosalts (including tennantite – tetrahedrite, colusite), and base metal sulfides (sphalerite and galena) have replaced low dipping dolomite and limestone layers, forming a manto-style orebody fed by steep dipping intensely silica-pyrite altered structures. The Thengkham deposits (54 Mt at 1.5 per cent Cu) are composed of prograde skarns (garnet, clinopyroxene) and mineralised retrograde skarns (chlorite, magnetite, hematite, epidote, sericite, talc, serpentine, carbonates, sulfides) which are irregularly and semi-continuously distributed around an elongate 4 km long intrusive centre. Thengkham and Khanong have been strongly supergene enriched, forming secondary chalcocite breccias and exotic malachite zones.The Carlin-like Au deposits display a range of stratigraphic and structural controls and lie outboard of the Cu deposits. Similar structural controls, alteration assemblages and trace mineralogies suggest that gold and copper mineralisation are temporally and genetically related. It is hypothesised that the differences in style of Cu and Au deposits across the Sepon district are related primarily to palaeodepth and proximity to the intrusive centres.CITATION:Cannell, J B, Stewart, J, Williams, P, Wallace, M, Burrett, C F and Davis, B, 2015. The Sepon copper deposits (Laos) and their relation to Carlin-like gold mineralisation, in Proceedings PACRIM 2015 Congress, pp 399–408 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Diego de Araujo Santana

O tamanho médio dos grãos é um parâmetro estrutural frequentemente estimado quando se está avaliando, principalmente, as propriedades mecânicas dos materiais metálicos. A American Society for Testing and Materials (ASTM) estabelece, nas normas ASTM E112 e ASTM E1382, metodologias para estimar o tamanho médio dos cristais de maneira manual e semiautomática/automática, respectivamente. O presente trabalho propõe, além de uma nova metodologia semiautomática, duas metodologias automáticas para estimar o tamanhão médio de grão em materiais metálicos policristalinos monofásicos, assim como um parâmetro para avaliar a morfologia dos grãos. O tamanho de grão G ASTM encontrado utilizando os novos procedimentos testados se apresentou muito próximo aos valores obtidos pelos métodos padronizados, que também foram aplicados e usados como referência para avaliação da representatividade das medidas. Desse modo, os métodos propostos se apresentam como uma alternativa viável para estimar o referido parâmetro estrutural dos materiais metálicos.

Aug 17, 2017

By J. J. Forbes

&apos;"THE Federal Coal Mine Safety Act (public Law T. 552. 82nd Congress) was approved oil July 16, 1952. It incorporates, as Title I, the Coal Mine Inspectio1.1 and Investigation Act of May 7. 1941 (Public Law 49, 77th Congress), which gave Federal inspectors only the right to enter. coal mines for inspection and investigation purposes but no power to require compliance with their recommendations. Title 11 contains the enforcement provisions of the act; its purpose is to prevent major disasters in coal mines from explosions, fires. inundations. and man-trip 01. man-hoist accidents. At this point a brief account of events that preceded the enactment of the Federal Coal Mine Safety Act seems appropriate. The hazardous nature of coal mining was recognized by the Federal Govermment as long ago as 1865, when a bill to create a Federal Mining Bureau was introduced in Congress. Little was done, however, until a series of appalling coalmine disasters during the first decade of this century provoked a demand for Federal action. As a result an act of Congress established a Bureau of Mines in the Department of the Interior on July 1, 1910. The act made it clear that one of the foremost activities of the Bureau should be to improve health and safety in the mineral industries. One of the first projects selected by the small folce of engineers and technicians then employed was to determine the causes of coal-mine explosions and the means to prevent them. By investigations aftel mine disasters the fundamental causes and means of prevention were soon discovered, and the coal mining industry was informed accordingly. However, despite this knowledge and the enactment of State laws and the Federal Coal Mine Inspection and Investigation Act of 1941, mine disasters continued to occur with disheartening frequency and staggering loss of life. The devastating explosion at the Orient No. 2 mine on December 21, 1951, resulted in the death of 119 men. The Orient disaster rekindled the memory of the Centralia. Ill., disaster of March 25. 1947, which caused the death of 111 coal miners. These two tragedies ultimately brought about enactment of the Federal Coal Mine Safety Act. The act is a compromise measure. Senator Matthew M. Neely of West Virginia and Congressman Melvin Priec of Illinois introduced almost identical versions in the 82nd Congress, but they were considered too drastic. The final version was introduced by Congressman Samuel K. McConnel, Jr., of Pennsylvania, after considerable discussion and amendment in committee hearings. It was passed by the Congress and became effective when signed by the President on July 16, 1952. The act is somewhat limited in scope because it applies only to approximately 2000 coal mines in the United States and Alaska that employ regularly 15 or more individuals underground. It exempts approximately 5300 mines employing regularly fewer than 15 individuals underground and all strip mines, of which there are about 800. Moreover, it covers only conditions and practices that may lead to major disasters from explosion, fire, inundation, or man-trip or man-hoist accidents. According to Bureau records, such accidents have resulted in less than 10 pct of all the fatalities in coal mines. It is important to mention that the law is not designed to prevent the day-to-day type of accidents that have caused the remaining 90 pct or more of the fatalities, because it was the specific intention of the Congress to reserve the hazards which caused them to the jurisdiction of the coal-producing states. Many who opposed any Federal legislation that would give the Federal inspectors authority to require compliance with mine safety regulations claimed that such legislation would usurp or infringe upon States&apos; rights. To assure that the principle of States&apos; rights would be preserved, the act provides for joint Federal-State inspections when a state desires to cooperate in such activities. The Director of the Bureau of Mines is required by the act to cooperate with the official mine-inspection or safety agencies of the coal-producing states. The act provides further that any state desiring to cooperate in making joint inspections may submit a State plan for carrying out the purposes of this part of the act. Certain requirements are listed: these must be met by a state before the plan can be accepted. The Director of the Bureau of Mines, however, is required to approve any State plan which complies with the specified provisions. The Director may withdraw his approval and declare such a plan inoperative if he finds that the State agency is not complying with the spirit and intent of any provision of the State plan. When this paper was prepared, agreements for joint Federal-State inspections had been entered into with Wyoming and Washington. A few other states have indicated their desire to submit a State plan and negotiations toward that end are now under way. Reluctance to enter into such agreements may be due to the mine operators&apos; knowledge that in the states that adopt a cooperative plan they are prohibited from applying to the Director of the Bureau of Mines for annulment or revision of an order issued by a Federal inspector and must appeal directly to the Federal Coal Mine Safety Board of Review for such action. Experience has proved that review by the Director as provided in the act is a less expensive and time-consuming procedure to all concerned than applying to the Board. Reluctance also may stem from the fact that joint Federal-State inspections somewhat restrict the movements of the State mine inspectors and tend to reduce the number of inspections of mines. Where a State plan is not adopted, the Federal coal mine inspector is responsible under the law to take one of two courses of action if he finds certain hazardous conditions during his inspections. The first action involves imminent danger. If a Federal inspector finds danger that a mine explosion, mine fire, mine inundation, or man-trip or man-hoist accident will occur in a mine immediately or before the imminence of such danger can be elim-

Jan 1, 1955

By Christopher E. Dianora, Matthew Sorrell, Eileen Test

"Constructed between 1939 and 1945, the Rondout-West Branch Tunnel (RWBT) portion of the Delaware Aqueduct is 45 miles (72 km) long. The New York City Department of Environmental Protection (NYCDEP) first identified suspected areas of leakage from the RWBT in the 1990s. A $1 billion project is underway to mitigate the leakage through the construction of a bypass tunnel around the area of most severe deterioration, a 2.5-mile (4 km) section located beneath the Hudson River. Two shafts, 800 and 900 feet (244 and 274 m) below the ground surface, are being sunk to support the tunnel construction. The deep shafts will be subjected to high groundwater pressures and have been designed to accommodate multiple tunnel portals. This paper discusses the engineering decisions and analyses leading up to the final design. INTRODUCTION Project Background The New York City Department of Environmental Protection (NYCDEP) provides over 1 billion gallons (3.7 billion liters) of water to over 9 million residents of the City of New York and surrounding communities each day. This water is stored in upstate reservoirs and conveyed to the City via a system of aqueducts and tunnels. Water is delivered to the City almost completely by gravity and consists of three systems: the Croton, the Catskill, and the Delaware. The Delaware System is the largest of the three and supplies between 50% and 70% of the City’s daily water supply. In the 1990s, the NYCDEP discovered leaks in the central 45-mile-long (72 km) portion of the Delaware Aqueduct known as the Rondout-West Branch Tunnel (RWBT). The leaks release between 15 and 35 million gallons per day (MGD) (132.5 million liters per day) and are concentrated in two areas near Wawarsing and Roseton, New York. As part of the Rondout-West Branch Bypass Tunnel and Wawarsing Repairs Project (Bypass Tunnel Project), the leaks in the Wawarsing area will be repaired by grouting from inside the existing RWBT, and the leaks in the Roseton area will be mitigated by constructing a bypass tunnel parallel to and 1,750 feet (533 m) north of the leaking portion of the existing RWBT. Two deep shafts will be excavated on either side of the Hudson River: Shaft 5B in Newburgh and Shaft 6B in the Town of Wappinger."

Jan 1, 2016

By R. V. Lundquist

The Bureau of Mines made a laboratory study of the amenability of anorthosite rock ( from the San Gabriel Mountains , Los Angeles County , Calif . ) to treatment by the lime soda sinter process for the extraction of alumina . The study was done under a cooperative agreement with the California Division of Mines and Geology . This report presents the results of the investigation , and it includes a review of the geology of the deposit ( 7 ) by Dr. Gordon B. Oakeshott . Interest in the recovery of alumina from submarginal aluminum silicate ores is stimulated by the fact that the domestic aluminum industry depends on imports of bauxite for its alumina requirements . Of the 8.0 million long dry tons of high - grade bauxite consumed in 1961 for producing metallurgicalgrade alumina , only 0.9 million long tons , or 11 percent , was mined in this country . During past years many organizations have carried out research programs to determine if alumina could be extracted economically from such domestic ores as clays ( 3 , 4 ) , anorthosite ( 8 ) , and other silicate sources . Successful alumina extraction is the ultimate objective of the Bureau of Mines program.

Jan 1, 1963

By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan, J. H. Kang

"We have reported previously that crushing or grinding crystalline silica results in the generation of silica-based radicals on the particulate surface and that these radicals can generate hydroxyl radicals in aqueous solution. Data in the present study indicate that freshly ground silica is more cytotoxic and is a more potent activator of alveolar macrophages than comparably sized aged silica. That is, compared to aged silica, fresh silica is 4.2-fold more potent in decreasing the membrane integrity of macro· phages; is 50% more potent in activating hydrogen peroxide secretion by macro· phages; and is 4.frfold more potent in stimulating cellular chemiluminescence. Prosil 28, an organosilane material, is an effective coating agent for fresh silica. It decreases the cytotoxicity of fresh silica by as much as 78% and decreases the ability of fresh silica to induce chemiluminescence from alveolar macrophages by 58%. The data suggest that surface radicals associated with freshly cleaved dust may be an important factor in the induction of pulmonary disease. Furthermore, treating dust with coating agents may substantially decrease toxicity. INTRODUCTIONThe U.S. Department of Labor estimates that over 1.25 million American workers may be exposed to crystalline silica and that nearly 60,000 may be at risk of developing some degree of occupational lung disease (Parkes, 1982; Peters, 1986). Occupations of concern include miners, stone quarry workers, sand and gravel workers, sandblasters, foundry workers, and glass workers. Acute silicosis is characterized by inflammation, alveolar lipoproteinosis, and the rapid development of respiratory disability (Banks, 1986). In contrast, chronic silicosis develops 20-40 yr after initial exposure and is characterized by the appearance of concentric hyalinized nodular lesions and the progressive development of dyspnea (Parkes, 1982; Ziskind et al., 1976)."

Mar 1, 1992

By H. R. Manouchehri

Large variations in flotation characteristics of minerals have been observed in winter and summer in plant practices as a result of changes in pulp temperature. Variations in temperature may affect the quality for pulp and related process water through changes in dissociation of different chemical species within the pulp, as well as changing in gas and metal hydroxide solubility, reagent adsorption and its stability on mineral surfaces, water/pulp viscosity, etc. All of these affect the flotation characteristics of specific mineral to some degree or another. It has been observed in Cu-Pb-Zn and/or Pb-Zn sulfides flotation that sphalerite (ZnS) flotation is strongly affected by changes in pulp temperature. Plant practices have shown that at the both low, e.g., T <10-12°C, and high, e.g., T > 60°C, the recovery for copper activated sphalerite is dramatically dropped. Within this paper the effect of pulp temperature on flotation characteristics of sphalerite is brought into considerations and laboratory flotation tests were conducted in conjunction with surface and solution chemistry analysis to understand the effect of temperature on sphalerite recovery. The effect of temperature seems to be complex since the temperature affects both the physical (hydrodynamics) and chemical phenomena in the flotation cell. In fact all sub-processes in flotation, i.e., collision, attachment and detachment, are affected by changing in temperature. Experimental results indicating that at alkaline pH values, e.g., 8.5 to 10.5, the recovery for copper-activated sphalerite is dramatically reduced when temperature is below 10-12°C, which is in agreement with plant practice at Boliden?s Garpenberg plant in Sweden. However, results from other studies indicated that the zinc recovery is also considerably decreased at high pulp temperatures, i.e., 62°C and above.

Sep 1, 2012

By E. Keskinkilic

In this study, sulfide-type inclusion morphologies of a Ca-treated hot-rolled wheel steel, Grade-X, were investigated. The specimens taken from the hot-rolled products of Grade-X heats were studied. The size and distribution of elongated sulfide inclusions were examined for the heats of different S levels. Elongated sulfide inclusions were either not observed or rarely encountered when ladle analysis S content was below 50 ppm. The size and relative abundance of sulfide inclusions were reported to increase markedly when the S composition was greater than or equal to 70 ppm and the Ca/S ratio was less than 0.50. The effect of Ti addition (0.010?0.020% Ti) on sulfide-type inclusion morphologies was then investigated for heats having a sulfur content higher than 50 ppm. Addition of Ti was found to have a partial effect on decreasing the size of sulfide-type inclusions under real steelmaking conditions. Keywords Sulfide inclusions, Ca-treatment, titanium.

Jan 1, 2011

By W Midgley, M Torok, I Canbulat, J Katupitiya, S Saydam, S Akdag

The green energy transition is expected to require a range of valuable minerals, which could be supplied through deep-sea polymetallic nodule mining. Deep-sea polymetallic nodules are mineral deposits with a composition well suited to produce lithium batteries, which are expected to be a necessary energy storage solution (Diouf and Pode, 2015; Paulikas et al, 2020) for the energy transition. By 2050 the annual demand for both cobalt and lithium is estimated to increase by around 450 per cent from 2018 levels (Hund et al, 2023), with the annual demand for nickel being greater than 2 million tons, and copper greater than 1 million tons. Polymetallic nodule mining is well positioned to provide these minerals in the near future. An intricate and comparatively unexplored ecosystem thrives within and surrounding the nodule fields (Smith et al, 2008). Deep-sea mining operations have the potential to disrupt and permanently damage this ecosystem through introduced pollution, artificial noise and light, and habitat destruction. Hence, there is a pressing need for new engineering and scientific endeavours to focus on developing new technologies to reduce any environmental impact from mining.

Sep 1, 2024

By T. Wallmach, S. B. Blancher, A. Delaporte, P. Goncalves

"Fe-Ti oxides concentrates produced from heavy mineral sand deposits are widely used for the production of titanium dioxide pigments that are critical components of white paint, plastics and paper. According to mining industry, the Fe-Ti concentrates mostly consists of three phases: ilmenite, leucoxene and rutile. However, a few mineralogical studies have shown that the variety of Fe-Ti oxides found in sand deposits is far more complex, mostly due to alteration processes. The aim of this contribution is to characterize in detail by means of Qemscan analyses the mineralogy of the three main concentrates (ilmenite, leucoxene and rutile) produced by the Grande Côte Operation (GCO) mineralurgical plant in Senegal. The ultimate goal is to characterize the different products and textures formed during the natural ilmenite alteration processes, to localize the phases carrying the main impurities (Cr and P), and finally to determine the physical properties of each mineral component to improve metal recoveries. Along alteration processes, Ti content increase. Ilmenite (FeTiO3) is progressively transformed into pseudorutile (Fe2Ti3O9) particles which could also be altered and transformed into hydroxylian pseudorutile [FeTi6O12(OH)3.3H2O] or complex blends of anatase microcrystals (TiO2). These transformations are accompanied by significant changes in particle textures. Microporosity and fractures appear and the impurity content also increases. Anatase rich microcrystal assemblages, so far described as Leucoxene, could be identified to consist of grains with higher porosities, water contents and higher intrapore impurities. These particles are the main carriers of chromium and phosphorus. The observed mineral transition textures have a significant impact on the ore dressing processes. During these transformations, the physical properties of these phases change, the magnetic susceptibility as well as densities decreases, due to the increase in porosity. The separation of particles, especially those with high porosity will help improving the GCO mineralurgical plant performance and to reduce the impurity contents in finals products."

Jan 1, 2018