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By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By M. Goto, F. Kubota

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."

Jan 1, 2012

By Zhou Junwu, Han Long, Song Zhenguo, Sun Chuanyao

The deposit genesis, the ore property, and the mineral characteristics, which has a close relationship with the beneficiablity, could be regarded as the “Genetic Properties”, actually are the determining factors for beneficiation process development. However, in conventional concentrator’s process development and engineering, there have been lack of systematic research and test on those genetic properties, also lack of well-established collecting, statistics and analysis system for those huge amount of data such as the historical mineral processing technique research, process mineralogy study, practical operating and engineering data. Obviously it is far less than enough for profound integration combining modern IT together with traditional mineral processing technology, as a result there are a number of disadvantages in mineral processing R&D and engineering, such as long term, high cost, low efficiency as well as repetitive testwork not making full advantage of previous experiences. Aiming to make utmost of those Genetic Properties and overcome above disadvantages in mineral processing R&D and engineering, the concept of “Genetic Mineral Processing Engineering (GMPE)” is put forwarded, and the strategical study has been conducted on this regard, with the main focus on following aspects: a) Testing and extraction of the “Genetic Properties”; b) Establishment of data base and data warehouse of GMPE; c) Intelligent decision making system for beneficiation process; d) Verification testwork; e) Virtual concentrator. The technical route proposed is to firstly conduct research and test on those Genetic Properties mentioned above, based on that the specific data base will be set up and applied for intelligent process recommendation and simulation with a few verification testwork conducted in the meantime, finally achieve a fast, high efficiency and precise determination of technology and process for ore beneficiation. The systematic study on the three-in-one GMPE would make an innovative breakthrough in conventional mineral process testwork research and engineering methodology, and provide technical support for the concentrator’s design and upgrading.

Jan 1, 2018

By J. Baz-Dresch

A custom-designed shotcrete system, consisting of an 8-m3 (10-yd3) transit mixer and a shotcrete spray boom carrier, is used bya 2-man crew to transport and place up to 25 m3 (32 yd3) of steel-fiber reinforced, dry, silica fume shotcrete per II-hour shift. Shotcrete is custom blended by a local supplier and delivered predampened. Mix design and quality control is performed with a computer program that develops and graphs a properly balanced mix based upon the materials sieve analyses.

Jan 1, 1991

By T J. McGavin

This paper examines the fire life systems implemented in two existing tunnels and discusses whether the standards used were appropriate. It focuses on the Terrace Tunnel as this upgrade and refurbishment is complete.The New Zealand Transport Agency (NZTA) manages six tunnels on the State Highway network with two of these built in the last seven years. The Terrace Tunnel, opened in 1978, was refurbished with modern fire life safety systems in 2010–2012. An interim upgrade of the Mt Victoria Tunnel, opened in 1931, was also carried out at this time.In present times, few existing tunnels have undergone significant upgrades and refurbishments. The Terrace Tunnel required: new power supplies, control buildings, lighting, wall panels and jet fans, a deluge system, emergency exit lights and way-finding lights, a public address (PA) system, a radio rebroadcast system, lane control sign (LCS) and variable message sign (VMS), an over-height detection system (OHD) and a new tunnel management system.In the absence of suitable guidelines, various standards were used to carry out the refurbishment. The Austroad Guide to Road Tunnels and AS4825 Tunnel Fire Safety, although designed for new tunnels and not specifically intended for existing tunnels, provided a framework. A multi-criteria assessment of risk (MCAT) was carried out to determine the systems to be provided.The Terrace Tunnel has perhaps set a benchmark for refurbishing existing tunnels as few projects of this type have been completed recently. This paper examines the process and the outcomes.CITATION:McGavin, T J, 2014. The refurbishment of the Terrace and Mt Victoria Tunnels, Wellington, New Zealand, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 87–94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Iara Janaína Fernandes

A casca de arroz é um resíduo amplamente gerado no mundo, é o principal subproduto do beneficiamento do arroz, e tem sido utilizada como biomassa para geração de energia, o que reduz o impacto ambiental causado pela destinação. No entanto, gera outro resíduo, a cinza de casca de arroz (CCA). A CCA é composta basicamente por sílica e carbono. Sendo os elementos traço mais comumente encontrados o sódio, potássio, cálcio, magnésio, ferro, cobre, manganês e zinco. Pelo elevado teor de sílica, é um resíduo com potencial para ser transformado em coproduto para diversas indústrias, porém, dependendo da aplicação pode ser necessária maior pureza. Assim, diversos estudos utilizaram a lixiviação ácida para reduzir o teor de contaminantes ou melhorar propriedades da CCA. Neste sentido, este trabalho teve como objetivo avaliar o beneficiamento de uma CCA residual através do processo de lixiviação ácida. Para isso, foram utilizados diferentes ácidos/concentrações, relações CCA/ácido e tempos de contato. Após estes testes utilizou-se análise elementar por FRX para caracterização química. Os resultados mostraram que o ataque ácido foi efetivo na redução ou eliminação de Fe2O3, K2O, CaO, P2O5 e ZnO para todos os ácidos e concentrações testadas. Sendo que as diferentes concentrações não afetaram a eficiência de remoção.

Aug 16, 2017

By Yeliseyev AK, Shestakov AM

Comminution is the most power-intensive process in the technology for ferrous quartzite concentration. That is why improving comminution efficiency leads to the most appreciable economic effect on the concentration process. The trend towards reducing the lump size of crushed ore before charging the mill is considered to be of major importance in improving comminution efficiency. A considerable number of investigations have been performed in this direction. At the same time, a strong interest is also maintained in the increase of comminution efficiency due to optimisation of process taking place in the mill. Recently, investigations of the power intensity of the breaking process inside the mill have been carried out at the Krivoy Rog Mining Institute. It was ascertained that the routine conditions of comminution at a low mill ball charge ratio resulted in an unnecessarily high power consumption due to the force of impact of falling and milling bodies far exceeding the power required for comminution. For example, the power value for falling balls of 60 - 125 mm in diameter reaches 0.3 kNm, and the force and stress due to ball contact with the lining reaches 60 kN and 250 MPa respectively. These values exceed the force required for comminution by a factor of ten. Analysis of the mechanism of ore particle size reduction during comminution in the ball mill indicates that the size reduction is due to impact load, attrition load, and static load. The efficiency of size reduction is very low. During comminution in the ball mill, impact loads prevail and amount to 85 - 90 per cent of the total load. In this situation, not more than 10 - 15 per cent of destruction is due to attrition.

Jan 1, 1993

By Gregory B. Poole

Data collected with 16K sampling at a variety of blasting sites (construction, quarry, trench, mine) and monitoring locations was analyzed to effectively show the 16 different 1K readings all based on the microsecond that the unit went into monitoring.

Feb 1, 2020

By P. C. Good

The Bureau of Mines conducted a laboratory investigation of a sinter-leach method to recover aluminum and fluorine from waste carbon potlining residues from secondary cryolite recovery operations in aluminum reduction plants. After removal of carbon by burning, the residue was sintered at 900° to 1,100° C with silica and N2CO3, then crushed and leached with dilute NaOH solution, dilute Na2C03 solution, water, or water containing residual Na2O which remained in the sinter after reaction and decomposition of Na2CO3. Over 90 percent of the contained aluminum and up to 87 percent of the contained fluorine were extracted from this waste product in the form of a mixed alkaline solution. Treatment of the alkaline solution with CO2 yielded a white precipitate containing 89 percent of the original aluminum and 61 percent of the original fluorine as a mixture of synthetic cryolite and alumina, together with a variable excess of soda.

Jan 1, 1969

By Brabcova Z.

This contribution deals with bubble adhesion on particle surface which consists of three steps ? the liquid film thinning, the film rupture and expansion of the three phase contact (TPC). Our attention is devoted to the third step ? to the description of the TPC expansion. Three-phase contact line expansion can be theoretically described using hydrodynamic and molecular-kinetic models. Both of these models were originally developed for the interaction of the bubble with horizontal plane in pure water. Our experiments deal mainly with the interaction of the bubble with the inclined plane in the solution of surface active agents. It was proved experimentally that molecular-kinetic model corresponds also to these conditions and this model was used for the description of the TPC expansion. The model is based on the theoretical description of the bubble contact angle on the three-phase interface. These contact angles change dramatically from 180o to equilibium (Young) contact angle close to 90o. Modificated ADSA method is used for the calculation of the contact angle. This method utilizes the Laplace equation of the capillarity; the bubble profile and the contact angle are evaluated using the set of experimental points around the edge of the bubble. The comparison of the experimental and calculated bubble profile shows a good agreement. The aim of the project is to describe the process of the TPC expansion during the adhesion of the bubble with the diameter up to 1 mm. Inclined planes were used instead of an experimental solid particle. Our experiments were provided in the solution of surface active compounds. The process of the adhesion was recorded using high-speed digital camera and images were evaluated using the image analysis software NIS-Elements. Calculations were performed using the MATLAB software. Keywords: bubble-particle interaction, adhesion, three-phase contact, contact angle

Sep 1, 2012

By S Marshall, A Fowler

The Augusta underground mine at Costerfield in Central Victoria has been in operation since mid 2006; however, AGD Operations Pty Ltd have explored and undertaken open pit operations in the area for over 20 years. The high-grade, narrow gold-antimony orebody is being mined using both mechanised and hand-held methods, to produce up to 70 000 tonnes per annum at ten grams per tonne gold and six per cent stibnite. AGD Operations Pty Ltd processes the ore on site using gravity and flotation to produce two products; a concentrate which is sold to Chinese smelters and a gravity concentrate which is refined off-site. The circuit achieves up to 30 per cent recovery of gold from gravity methods. There are many challenges in the underground mine, including an orebody with an average width of 300 mm, very poor rock mass conditions in the host rock and variable dips in the ore along strike, between 45¦ and 90¦. The upper levels of the mine have been developed ready for stoping; however, their depths range from 20 m to 70 m below surface in both oxide and transitional material. A major fault structure consisting of mud has been encountered underground and is associated with the orebody causing very poor ground conditions, water inflow and requiring additional reinforcement. The northern limit of the mine is defined by the proximity of historical workings in the South Costerfield mine, which is being continuously dewatered.

Jan 1, 2008

By B. G. Cousins, L. Racine, R. S. MacPhail

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate that has shown improved collection properties over SIPX for copper-bearing and copper-activated minerals. Characteristics such as improvement of recoveries with lower dosages and high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31.The most improved results have been seen insphalerite flotation. Plant trial work carried out in the zinc circuit at the Louvicourt Concentratorin northern Quebec has produced data showing superior grade and recoveries from rougher concentrates that previously had not been attain-able with other reagents effectively. The improvement over SIPX adds up to an almost$1,000,000 annual improvement on the mine’s bottom line at present zinc prices.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthates, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by Tennants Research Technology Applications (TRTA), a division of Charles Tennant & Co. (Canada) Ltd., produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The new product has been named FLEX 31. Currently, FLEX 31 is manufactured at the Prospec Chemicals, another division of Charles Tennant & Co. (Canada) Ltd.A large amount of laboratory testing pro-grams have been carried out with FLEX 31 todate (MacPhail and Cousins, 1995; Cousins and MacPhail, 1996). One of the minerals that has a defnite affinity to improved fotation is sphalerite (ZnS). Once activated with copper sulphate, sphalerite has produced some of the most spectacular test work when FLEX 31 is compared directly to SIPX. Plant trials of FLEX31 at Aur Louvicourt Inc. carried out in 1995show that FLEX 31 is far superior to SIPX for activated sphalerite flotation."

Jan 1, 1997

By J. A. Hudson

"The paper begins with a brief summary of Professor Müller’s formation of the ISRM and the contents of the previous six Müller lectures with their emphases on rock fractures. The geological origin of fractures is described via a deformational spectrum diagram and a matrix characterising the consequences of a sequence of superimposed deformational events. The different fracture frequencies encountered along lines in all directions through a fractured rock mass are explained. The value of computer modelling and simulation is demonstrated through an example of the effects of fracture zones on the distribution of the in situ stress field. The need to establish the validity of computer programs, i.e., that the modelling/simulation, does actually represent the rock reality, is discussed with reference to the work of the DECOVALEX project. Finally, examples are given of the effects of rock fractures on engineering design and construction, from pre-split blasting to caverns.INTRODUCTIONIt is a great honour to have been chosen as the recipient of the ISRM 7th Müller Award and I am grateful to the representatives of the International Society for Rock Mechanics (ISRM) National Groups who voted for me. In addition, I am especially pleased because my working life in rock mechanics and rock engineering has been devoted to understanding the geometry and mechanical properties of rock fractures and rock masses—which were the key subjects that Professor Müller promoted. In the ISRM 50th Anniversary Commemorative Book, Hudson and Lamas (2012), Professor Charles Fairhurst notes that on 24 May 1962, i.e., the day before the constitutional meeting of the ISRM took place in Salzburg, a reporter asked Professor Müller, “Do we know the strength of rock?”, to which Professor Müller replied, “For rock tested in the laboratory, yes. For a rock mass, no. This is what we need to determine. This is why we need an International Society for Rock Mechanics”. Also, in his Opening Address at the 1st ISRM Congress in Lisbon, Professor Müller, as the then ISRM President stated,“Many experts agree with me that discontinuity and anisotropy are the most characteristic properties of the material rock and that the properties of jointed media depend much more upon the fabrics bond of the unit rock block system than upon the rock material. Therefore any theoretical investigation of that material has to go its own ways, in the same way as the construction material of soils years ago suggested to soil mechanics its own methods, which differ greatly from the way of thinking of technical mechanics”."

Jan 1, 2015

By Quast K

A series of laboratory flotation tests were conducted to evaluate the effectiveness of various depressants as arsenic (and zinc) depressants in the lead cleaner stage of the NBHC mill at Broken Hill. The depressants used included potassium cyanide, ferrous sulphate, sodium hypochlorite, potassium ferricyanide and two Cyanamid commerical depressants, Aerodepressants 610 and 633. A standard roughing stage was completed before the addition of the reagents in the cleaning stage. All reagents tested produced significant arsenic depression, with the best results being obtained with the addition of potassium cyanide and sodium hypochlorite. Some of the depressants activated the zinc in the process of arsenic depression. The best result was obtained with the addition of 90 g/t potassium cyanide at a pH of 10 when arsenic recovery was only 1/4 that of the value obtained for the standard test.

Jan 1, 1991

By M. Askari, A. Ahmadi

"This study was conducted to establish the possible application of bioleaching in the pilot scale to recover valuable metals from the sulfidic tailings of Golgohar Iron Mine (Kerman, Iran). Using bioleaching processes, solvent extraction and sulfide precipitation recovery of valuable metals including, copper, cobalt and nickel from the tailing was investigated. The results showed that the optimum pH and temperature conditions relative to the bioleaching step was 1.5 and 45°C. The extraction of the metals from the low grade polymetal resource with complex mineralogy is very important from economic, environmental and technical point of views. Moreover, the proposed method has some advantages from energy saving, tailing management and creating added value from waste materials aspects.INTRODUCTION The growing demand for base metals and strategic such as: copper, nickel and cobalt as well as high-grade resource depletion has caused them, the mining industry to extract metals from low-grade resources and driven by complex mineralogy (Xie et al., 2005). Economic extraction of metals with low grade sources requires low-cost and efficient processing methods. A source with enormous potential for metals in future, secondary sources, such as: tailings mineral industries which the lack of appropriate technology and the high cost of processing weren't recoverable with previous procedures in the past. But it is possible that with develop new and efficient technologies have the economic exploitation ability. Recovery of metals from tailings resources is very important not only in terms of precious metals but also in terms of reducing environmental problems (due to heavy metals). The metals of copper, nickel and cobalt are mainly like sulfide compounds in the nature, usually for their recovery, first they make ore with flotation method to obtain the sulfide concentrate that containing valuable metals. then for the metal production, it will be melt and purification. Due to the environmental aspects, technical problems in the recovery of base metals from low grade ore and mixes, the presence of small reserves, in the past three decades they pay much attention to the use of hydrometallurgical processes for the recovery of base metals from these resources. These processes are classified according to the solver agent to leaching sulfates, chlorides, nitrates and amines (Hackl, 1995). Early, chloride leaching under oxidation condition in acidic or alkaline solutions was recognized the best process to produce sulfide concentrates. But then the basic processes sulfates was considered as the superior process because of being easier, a better understanding of the chemistry of leaching and recovery of base metals, especially copper from the environment easier sulfate solution with an organic solvent extraction and electro winning. The bioleaching is shown its ability on a commercial scale of low-grade sulfide minerals and ore that because of environmental reasons, the possibility of melting is not possible to them. The existing industrial base factories are based on primarily on the bioleaching and pressure leaching and recovery of cathode copper sulfate solution by extraction with organic solvents (SX) and electrowinning (EW) (Wang, 2005). Preliminary analysis has shown that valuable elements such as copper, nickel and cobalt are in the float flotation unit. Hence the plan to extract these metals from the wet tailing stream has been done."

Jan 1, 2017

By Cotton R. E, Cox R

Digger Rocks is one of several nickel-bearing sulphide deposits localised within komaLiitic volcanics of the Forrestania Greenstone Bell within the Archaean YiIgam Block of Western Australia. Exploration and evaluation to April 1990 have delineated a resource, at a nominal cut-off grade of 0.5 per cent Ni, of 1.9 Mt at 1.1 per cent Ni within a lensoid sulphide body which strikes NW, dips 50°SW, and occurs at a depth of 30 - 110 m below surface. There has been no production from any of the Forrestania nickel deposits to-date. The deposit, comprising both disseminated and massive sulphides, has maximum dimensions of 400 m strike, 115 m vertically and 90 m true width. Generally the massive sulphides occur at the base of the disseminated sulphides, on or close to the base of the Digger Rocks dunite. The two main massive sulphide lenses have maximum dimensions of 120 m strike, 75 m vertically and 16 m true width (northern lens) and 60 m strike, 25 m vertically and 4 m true width (southern lens). The average grades of the massive and disseminated sulphides are 5.9 per cent i and 1.2 per cent i respectively. The massive sulphides generally have sharp hangingwall and fOOlwall contacts and display strong internal grade anisolropy.The massive sulphides are mainly within the supergene zone and consist of violarite, pyrite and marcasite. The disseminated sulphides are mainly within the primary zone and consist of pentlandite, pyrrholite, pyrite and minor chalcopyrite. Alteration zones, up to six in number, are complex in detail. The sulphides are capped by an average of 30 m of sub-economic, leached, siliceous, oxidised material.A genetic model for the deposit is described which places Digger Rocks in Category 2 (sulphides in large layered dunite bodies) of the latest classification of komatiitic nickel sulphide deposits in the Yilgam Block of Western Australia by Hill and Gole (1990).

Jan 1, 1992

By R. J. Sweigard

Three case studies were undertaken to investigate the role of land use potential evaluation in reclamation planning and to determine the impact of regional differences on the evaluation process. The three surface mines studied were representative of operations in the Appalachian, Interior, and Northern Great Plains provinces. The scope of the investigations included a survey of regional characteristics, a detailed investigation of the mining operations and site conditions, and an assessment of local land use planning activities in the area of the mine. Special attention was given to key factors that presently determine the use of reclaimed land. Also, for each case study, the postmining land use potential was evaluated using site planning principles. Specifically, the environmental, economic, and social impacts of several potential postmining land use plans were considered.

Jan 1, 1983

By Francis A. Thomson

DO the curricula of our mineral technology schools prepare their graduates to meet properly the full range of their responsibilities in after life? An unequivocal "no" could be returned to this question, because training and experience in professional work are quite as important as adequate college preparation. Furthermore, a had curriculum with a splendid corps of men doing the teaching and a competent body of students doing the learning will produce a better result than an ideal curriculum in the hands of unqualified teachers and poorly prepared students.

Jan 1, 1937

By Charles J. Zablocki, Robert J. Kamilli

"Buried, possibly mineralized granite cupolas at the Silsilah tin deposit in Saudi Arabia (lat. 26°06' N, long. 42°40' E) have been successfully located using a closely spaced electric-field-ratio profiling technique. In this study, electrical fields at 27 and 270 Hz across grounded electrodes spaced 50 m apart were measured along six traverses. This method is interpretable by inspection, unlike the dipole-dipole technique, which requires mathematical modeling for interpretation.In the study area, the technique allowed the authors to identify and distinguish among unroofed granite cupolas, cupolas with their aplite-pegmatite apical contact zones intact, strong (quartz-rich) and weak (relatively quartz-poor) greisens, dikes, faults, and pervasively argillized rocks.This method should be useful in the valuation of other shallow mineral prospects in similar settings in other parts of the world, especially deposits for which the location of vertical contrasts is important, such as veins or mineralized zones associated with the apexes of small igneous cupolas."

Jan 1, 1993

By Sang Han Son

The vapor pressures of FeCI2 and ZnC12 in the FeCl2-ZnCl2 system were measured by the transpiration method at 873K and 917K. The vapor pressure data were interpreted to indicate the formation of complex ions in the FeCl2-ZnCl2 melts. It is presumed that the complex molecule FeZnCl4 as well as FeCI2 and ZnCI2 exists in the vapors in equilibrium with molten FeCl2-ZnCl2 mixtures. The activities in the FeCl2-ZnCI2 system are shown a negative deviation from Raoult's law. These results suggest the formation of complex ions such as ZnCl42- in molten FeCI2-ZnCI2 mixtures.

Jan 1, 2003