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By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By Mariana Beatriz dos Reis Silva

A influência da temperatura de reaquecimento e do tempo entre passes na evolução microestrutural dos ASTM F138 e ISO 5832-9 durante o processamento termomecânico simulado foram investigados. Ambos os materiais foram reaquecidos a 1200°C e, por comparação, o ISO 5832-9 foi reaquecido a 1250°C. As amostras foram submetidas a simulações de deformações em testes de torção com tempo entre passes de 50 e 5 s. As amostras foram caracterizadas por MO, MET, EDX, EBSD e testes de microdurezas. As curvas de tensão-deformação, a evolução microestrutural e precipitação foram analisadas e correlacionadas com o refinamento de grãos. O aço ISO 5832-9 reaquecido a 1250°C mostrou um comportamento diferente devido a maior dissolução dos precipitados.

Aug 17, 2017

By R. C. Anderberg, F. J. Caervenyak, F. J. Frattali, H. J. Kandiner, R. A. Brown

"INTRODUCTION Considerable interest was shown .prior to and during World War II in the winning of metallurgical-grade alumina from anorthosite, kaolin, siliceous bauxites, diasporic clays, and other aluminum-bearing ores. Laboratory and pilot-plant investigations were made on many of these ores by the Bureau of Mines, and a series of reports on them is being prepared. This report covers the tests made on the application of the lime-soda-sinter process to anorthosite, which is a mixture of albite, NaAlS1308, and anorthite, CaAl2Si208. Extensive deposits of anorthosite occur in the Laramie Range in Wyoming and extend into Colorado; other deposits are found in New York, with outcroppings appearing in Vermont, Maine, and Labrador.Anorthosito can not be treated by the Bayer process for the production of metallurgical-grade alumina, because excessive losses of soda and alumina occur from the formation of sodium-aluminum silicate due to the large amount (50 percent) of silica in the ore.RESULTS OF INVESTIGATIONSSmall-scale laboratory tests supplemented by pilot-plant runs have demonstrated that the alunina and soda occurring in the Wyoming anorthosite from the Laramie Range can be extracted and recovered satisfactorily by the lime-soda process. It has been shown that liquors containing approximately 95 gram of A1203 per liter can be consistently produced at Na20:A1203 ratios from 1.75 to 2.27, and that these liquors can readily be desilicated and carbonated to yield high-grade alumina trihydrate of quality comparable to that essential for cell-grade alumina. The optimum results were obtained with Na20:A1203 mol ratio of 1.03 and Ca0:Si02 ratio of 2.14 in the sinter when calcined at an average temperature of 2,444ºF. for 25 minutes."

Nov 1, 1947

By Dennis Asmussen

The peatlands of the U.S. and Canadian parts of the Upper Great Lakes region have a long history of modest utilization in agriculture, forestry, horticulture, and as natural undisturbed areas. Only recently have they been assessed as potential sources of non-renewable or renewable energy. This new interest in peatlands, should current proposals be realized, might mean the commitment of millions of acres to energy production purposes. The magnitude alone of this potential utilization of peatland signals the possibility of substantial environmental disturbance, local resource shortages, resource use conflicts, and social and economic change. Peat- land resource managers in the region are just beginning to weigh the advantages and disadvantages of large-scale peatland utilization. The Minnesota Department of Natural Resources has made a considerable effort to study peat resource management issues and will shortly make recommendations to the state legislature regarding utilization alternatives. What follows is a general discussion of peatland utilization and management trends in the region with a focus on Minnesota and its peatland management efforts.

Jan 1, 1980

By N. Melnyk, H W. Habgood

The conventional low temperature process for extracting' helium from natural gas involves liquefying the whole gas stream in order to remove the relatively small fraction of helium. A process based on the selective diffusion of helium through a semi-permeable barrier is, in principle, more economical and flexible, particularly for the treatment of small re-serves and low concentrations. The well-known permeability of glass to helium offers the possibility of such a diffusion process and McAfee of the Bell telephone Laboratories showed in 1958 that practical separations could be achieved by passing natural gas over bundles of fine capillary glass tubing. Developmental studies have been carried out involving larger units and more extended field tests than those of McAfee. Fine capillary tubing of Pyrex glass 0.0035 in. diameter was prepared by drawing ordinary 6 mm. laboratory tubing in a furnace. Extraction units were pre-pared containing about 10,000 such tubes, 4 ft. long and cemented inside

Jan 1, 1961

In 2005, a total of 4,490 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.6% of all mining operations. ? Mines producing the primary commodity of limestone (crushed and broken) comprised the largest number of operations (n=2,039; 45.4%). ? Stone mining operations were located in all states and territories except Delaware and North Dakota. ? Of all states, Pennsylvania had the most stone mines (n=379; 8.4%).

Jan 1, 2008

By H. E. Perlee

Mathematical expressions are derived for the histories of the pressure, flame radius, mass fraction burned, and burned and unburned gas temperatures associated with a spherical flame propagating concentrically in a spherical vessel. The equations are solved numerically for a 9.5 pct CH4/air mixture using the best available information for the burning velocity, expansion ratio, and specific heat ratio. Calculated histories are in complete accord with experimental measurements. The accuracy of calculated histories is determined relative to errors in the system parameters, and it is found that 10 pct errors in either the burning velocity or the expansion ratio results in a 40-pct error in the pressure history. A 10-pct error in either burned or unburned specific heat ratio results in a 22-pct error &apos;in the pressure history. It was further established that the usual assumption of constant specific heat ratio is unacceptable, but equating the burned and unburned specific heat ratios result in no apparent error in the histories. The cubic law (P = Kt3 + Po) is derived and discussed, and it is found that the law is valid only during the early period (P<2 atm) of flame growth.

Jan 1, 1974

By Guy D. Bruno

Through the remainder of this century, world consumption of fluorine per ton of primary aluminum produced will continue to be substantially reduced. Growth of the primary industry will offset some of the unit consumption, but demand for new fluorine sources will decline sharply. Continued application of dry fume scrubbing systems will be the most significant factor in reducing demand.

Jan 1, 1978

By Roland Arnold, Richard Gradnik, Martin Zeindl

This paper presents the details of the Kramer tunnel project in the Federal State of Bavaria, Germany. This road tunnel, which has been under construction since December 2019, is the key component of the western bypass of the town of GarmischPartenkirchen. Once completed, it will relieve the town’s central district from enormous volumes of traffic. The contractor is the joint venture named ARGE Kramertunnel consisting of BeMo Tunnelling and Subterra. The whole project will be completed and handed over to the project owner, Staatliches Bauamt Weilheim, in 2023. The opening of the entire bypass section including the tunnel to traffic is planned for 2024. The tunnel, with a total length of 3,609 m (2.24 miles) and an estimated cost of EUR 178 million (incl. VAT), is designed as a single-tube, double-lane structure with one traffic lane for each direction of travel. The safety issue that exists for single-tube tunnels is solved by a parallel escape tunnel passable for vehicles. All tunnels and ducts are excavated according to the principles of the New Austrian Tunnelling Method (NATM). In order to reduce the geological risk for the owner, the escape tunnel was supposed to be completed before the design process for the main tunnel ever began. The exploratory tunnel was awarded to a competitor with an separate contract.

Jun 13, 2021

By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016

By PEILIN LAN, LEONARD HILL, SIMON TIMBILLAH, BERNARD FOSU, CESAR SOSA-BLANCO

The use of sodium hydrosulfide (NaHS) in most of the operations in byproduct molybdenum flotation comes with safety concerns and, in some instances, a high reagent cost. Engineered solutions at the various operations where NaHS is used have immensely reduced the possibility of hydrogen sulfide (H2S) gas evolution. However, the threat of exposure remains, and this, coupled with the high dosages of NaHS consumed, supports the continued search for alternative depressants. This paper focuses on efforts to study the applicability of disodium carboxymethyl trithiocarbonate (DCMT), an organic depressant, as an alternative to NaHS. Bench-scale rougher flotation results for samples from the Sierrita copper–molybdenum (Cu–Mo) plant showed the best DCMT performance at 8 kg/t of DCMT, pH 10.5, 30 min of shear conditioning and 10 min of flotation conditioning. The Aminpro plant model simulation confirmed that 4 to 8 kg/t DCMT under certain shearing and conditioning times achieved superior or equivalent Mo–Cu separation efficiencies when compared\ to NaHS.

By Hebblewhite B, Humphreys D

An experimental mining project has been carried out in the Collie Basin to demonstrate the safe operation of total extraction mining techniques in the underground mines of the basin. To achieve this, it was necessary to design and install a means of controlling or removing groundwater so that goafing of the overlying strata could be safely achieved as part of the mining operation. The site chosen for the experiment was a triangular panel adjacent to Western No 6 (WD6) underground mine, which includes the 3 to 4 m thick Wyvern Seam beneath 130 to 180 m of overburden. The test area abuts a major fault on the downdip side. The overburden and underburden sequences include several horizons of permeable sandstones which form major aquifers. Water problems have long been recognized in all underground mines in the Collie Basin, and have previously prevented the successful application of total extraction mining. Following extensive hydrological investigations, dewatering and depressurization systems were designed to dewater the immediate roof aquifers and to depressurize aquifers higher in the sequence and in the floor. This would enable stable roof conditions to develop and controlled goafing to be achieved. The roof dewatering/depressurization procedure involved a combination of in-mine vertical roof drainage holes and conventional dewatering bores constructed from the ground surface above the mining trial area. The dewatering system was installed and operated for 29 months before the commencement of mining. Mining was eventually successfully completed in two trial panels using a retreat Wongawilli extraction system using bridge conveyors and continuous miners. Water inflow into the mine workings was channelled to a constructed sump area at the lowermost corner of the panel and pumped to the surface via vertical sump bores. The dewatering and depressurization measures adopted were successful in permitting the first controlled and systematic total extraction recovery of coal from the Collie Basin. This trial mining exercise demonstrated the potential for increasing substantially the recovery of coal from the Collie Basin, where previously recovery rates of around 30 percent from underground mining were commonplace, using only bord and pillar methods.

Jan 1, 1988

By Curt Swanson, David C. Mathy, Dru R. Nielson, Kent VonAspern

In 1997, Central Contra Costa Sanitary District undertook the design of the Martinez East Side Trunk Sewer Improvements Project. Microtunneling was specified for approximately 1,035 meters (3,400 feet) of 600-mm (24-inch)diameter pipeline to be installed through estuarine soil deposits (San Francisco Bay Mud) and alluvium beneath the congested city streets of downtown Martinez, California. Directional drilling was specified for approximately 275 meters (900feet) of 200-mm (8-inch) diameter pipeline in four separate segments to be drilled through bedrock within narrow utility easements between residential properties. This paper presents a case history for the design and construction of themicrotunneling and directional drilling aspects of the project.

Jan 1, 1999

By I. Demers, A. Blier, M. Mbonimpa, M. Benzaazoua, B. Bussière

The Doyon Mine in Quebec, Canada, evaluates the possibility of desulfurizing its tailings to produce material to be used as cover for the acid-generating tailings disposal site. Laboratory tests showed that a single-layer cover made of desulfurized tailings placed over reactive tailings can prevent the generation of acid mine drainage. Modeling with the software Vadose/W was used to optimize the design parameters, namely, cover thickness, water table position and residual sulfide content of desulfurized tailings following laboratory work. It was found that the optimal configuration includes a 1-m (3.3-ft) desulfurized tailings cover containing 0.8% S, with the water table kept at the interface between the reactive tailings and the cover. To maintain the cover performance to reduce oxygen flux toward acid-generating tailings even in the event of a long dry period, a sand layer is suggested to protect the cover from excessive evaporation. It is possible to reach the environmental objective for oxygen flux chosen for the Doyon Mine (10 mol/ m2/year) with the protective sand layer, even in extremely dry conditions.

Jan 1, 2009

By T Raynlyn, R J. Holmes, J R. Manuel, A Poliakov, L Lu

The prediction of sintering performance of iron ore fines and the possibility of targeted optimisation of specific sinter properties are very important for both the iron ore industry and related research organisations. Physical pilot-scale sinter runs require large amounts of raw materials and are expensive, so it is critical to target large test work programs with many different sintering parameters effectively. To predict values for sintering performance parameters such as tumble index (TI), low temperature reduction disintegration index (RDI) and productivity, a comprehensive database of pilot-scale sintering experimental results has been established and empirical modeling conducted. Similarly to earlier work, physical, chemical and mineralogical characteristics of the iron ores have been considered. However, in contrast to the previous work where only one textural parameter was taken into account, namely the proportion of dense haematite ore texture, the current model includes the abundances of several different textures which were combined into different textural factors corresponding to different sinter properties. Coefficients for the variables within specific regression equations can provide a better understanding of the effect of the variables on the corresponding sintering performance. The modelling results have also been used for predicting the sintering performance of mixtures that were not part of the database used for establishing the models. Comparison of experimental and modeling results for the verification test data is also reported in this paper.

Jan 1, 2009

By Thiago Vieira Lopes

O mercado siderúrgico atual encontra-se cada vez mais competitivo e exige das empresas esforços na diminuição do custo de produção para que seus produtos mantenham atratividade no cenário global. A incorporação crescente de produtos siderúrgicos oriundos da Ásia no mercado ocidental obriga as indústrias encontrarem alternativas de diminuição de custo de produção, as rotas para que tal objetivo seja alcançado geralmente estão ligadas ao aumento do rendimento metálico e diminuição no tempo de processamento dos produtos. O equipamento gargalo na linha de laminação a quente da CSN, é a cadeira reversível da laminação de desbaste, R2, e pequenas reduções de tempo no processamento de placas são responsáveis por incrementos elevados na produtividade da laminação. Visando ampliar a competitividade da CSN no cenário siderúrgico foi criada uma função, chamada RM-NECK, no modelo matemático do laminador que classifica todos os materiais gargalo desbaste por grau, espessura, largura, número de fornos de reaquecimento e comprimento de placa, permitindo assim, a diminuição no tempo de processamento na zona do VE2/R2. O estudo evoluiu para um verdadeiro trabalho em equipe, envolvendo especialistas da manutenção e operação e, consolidando anos de experiência no desenvolvimento de um algorítmo inteligente o suficiente para reduzir o tempo de processo observando os princípios da teoria das restrições.

Aug 17, 2017

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By A. Holland, T. Krumins, E. Olin, J. F. M. Castilleja, J. Geldart, C. Fleming, I. Jackman

A flowsheet has been developed to treat the flotation tailings from a copper mine in Mexico to recover gold and silver by cyanidation and carbon-in-pulp (CIP). The plant will treat ~15,000 t/day of a 60:40 blend of current flotation tailings and the mine’s historic tailings. The tailings also contain a significant amount of cyanide-soluble copper, and the economic viability of the project is strengthened by recovering most of the copper and cyanide associated with this process. The solution and solid phases in the CIP tailings will be separated in a counter current decantation (CCD) circuit and the CCD solution overflow will be treated by a SART Process. Copper precipitates as a salable copper sulphide product in the SART Process and the cyanide that is associated with the copper complex is regenerated as free cyanide. After SART, a portion of the SART product solution will be recycled to leach to reuse the free cyanide, while the remaining solution will be used as wash water in the CCD circuit. Incorporation of the SART Process in the flowsheet allows the CIP circuit to be operated aggressively as a gold plant, which means most of the silver in solution passes through CIP to SART. Silver co-precipitates with copper in SART and is recovered very efficiently with the copper sulphide by-product. Incorporation of SART also allows the leach and CIP circuits to be operated with relatively high levels of free cyanide, which enhances silver leach kinetics and helps keep copper from loading onto the carbon in CIP. The flowsheet was developed in the laboratory and successfully demonstrated in a fully-integrated pilot plant in 2018.

Jan 1, 2019

By L. A. Haas

The Bureau of Mines conducted bench-scale leaching tests with recycled spent copper electrolytes and copper-nickel mattes produced from the Minnesota Duluth Complex concentrates. This report describes the first stage of an overall two-stage leach operation. The objective of this research was to determine the matte-leach technology required to convert spent copper electrolyte into an enriched nickel liquor suitable for a nickel refinery and there-fore essentially free of copper, iron, and sulfuric acid. The experimental variables investigated were matte composition, particle size, spent electrolyte content, pulp concentration, oxygenation, temperature, and time. The time required to produce an enriched purified nickel liquor decreased with increasing pulp concentration, temperature, and oxygenation, but increased with increasing particle size and electrolyte copper and acid content. Nickel-rich (about 50 g/l) liquors at a pH of about 4 and containing less than 1 g/l of copper and iron were produced at 70° C by leaching minus 325-mesh low-iron (less than 5 pct) matte for 8 hours with spent electrolyte containing 22.4 g/l Cu, 28.9 g/l Ni, less than 0.1 g/l Fe, and 50 g/l H2S04 at a pulp concentration of 1 kg of matte per liter of spent electrolyteo Varying the nickel content of the spent electrolyte from 11 to 101 g/l appeared to have no appreciable influence on the matte leaching characteristics.

Jan 1, 1981

By M. Oliazadeh

Spodumene [LiAl(Si2O6)] is the most common and desirable economic lithium-bearing mineral due to its high lithium content. In Canada, there are several spodumene deposits at the development stage that have the potential to help narrow the forecast lithium supply gap stemming from the widespread acceptance and increasing use of electric vehicles. Spodumene processing can be conducted using Dense Media Separation (DMS), flotation or combination of both. If spodumene liberation is sufficient at coarse particle sizes, DMS can be used for primary lithium concentrate production and silicate gangue minerals rejection. If liberation is not sufficient, flotation is then the main processing route for spodumene concentration. Even in cases where DMS is a viable beneficiation option, flotation may still be required to process the DMS middlings and/or the undersize fraction which is outside the particle size range for DMS. Considering flotation as a technique for spodumene beneficiation, there are several alternatives including the use of mechanical flotation cells, column flotation cells, coarse particle flotation cells, and/or Staged Flotation Reactors (SFR), either alone or in combination. Ore sorting can be incorporated at the start of the spodumene flowsheet to remove gangue minerals, particularly amphibole and pyroxene in the early stages. The main objective of flowsheet development for hard rock lithium deposits is to evaluate the ability of these options to produce a spodumene concentrate with a concentrate grade above 6% Li2O, lithium recovery of above 80%, and with the minimum operating and capital cost. This paper aims to describe the various processing options available for the beneficiation of spodumene from hard rock deposits and compare the associated operating and capital costs for each.