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By Omero Alonso-Gonzalez, Sergio Haro-Rodriguez, Ricardo Solis-Rodriguez, Francisco Alvarado-Hernandez, Juan Antonio Gonzalez-Anaya, Héctor Rene Vega-Carrillo

"Precious metals are currently associated with refractory minerals such as telluride (Calaverite, Sylvanite, etc.) and selenium (Naumannite Ag2Se), which are difficult to dissolve through traditional methods, therefore it is necessary to perform a pretreatment (oxidative or roasting) preceding the process of leaching by cyanidation. In this preliminary work the aim was to study the use of solvent extraction to remove tellurium and selenium ions from a synthetic cyanidation effluent, with the purpose of recycling the cyanide back to the process. For the extraction of these anions, TeO32- and SeO42-, tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (Amine F) were studied as extractants, using nonylphenol as a modifier in the organic phase (trimethylpentane). The results show that it is possible to recover 82% of selenium and 10% of tellurium from synthetic solutions containing either 20 mg/L Se or 20 mg/L of Te, respectively The Se or Te mole ratio to cyanide was 1:4.INTRODUCTION In relation to extraction of precious metals, the cyanidation process has been in use for over a century and despite environmental and toxicological problems it remains the most widely used and economical process available. In the late 90s, there were great efforts to recover gold and silver from refractory ores, which is difficult to do by simple cyanidation. To improve gold recovery from tellurides and selenides that occurs in some new mines, the ores are pretreated by roasting. This is one of the most effective ways of rendering refractory gold ores leachable as well as being a fast pretreatment process compared with bio-oxidation or pressure leaching (Aylmore, 2001). The most important tellurides minerals are Calaverite (AuTe2) and, Silvanite (Au, Ag)2Te4). In the case of selenides, minerals include Naumannite (Ag2Se) and Aguilarite (Ag4SeS) (Ostroumov et al., 1989). Examples of deposits containing telluride include La Bambolla Mine (Sonora, Mexico), Cripple Greek (Colorado, USA), and Kalgoorlie (Western Australia) (Aguayo et al., 1996). The main purpose of this work was to explore the feasibility of using quaternary ammonium salts such as: tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (amine F) to extract tellurium and selenium anions from aqueous synthetic cyanidation effluents, so that the cyanide solution could be recycled back to leaching process. The tests were performed on synthetic solutions similar to those found in a mine: 20 mg/L Te as TeO32-, 20 mg/L Se as SeO42- and mole ratio to cyanide was 1:4. using an alkaline medium with pH ranging from 8 to 12. Two aspects are evaluated in this paper:"

Jan 1, 2017

By Amos Bryant, Jesse Davis

This paper compares the predictions of the latest Institute of Makers of Explosives Safety Analysis for Risk (IMESAFR) model versus physical test data recovered from ISO-1 and ISO-2 tests in Woomera, SA. ISO-1 testing included placing 1054 kg (2324 lbs) of ANFO (ammonium nitrate-fuel oil) inside an ISO container on a flat bed truck. ISO-2 testing was identical except the NEW was 4000 kg (8818 lbs). The IMESAFR predictions are based on model runs using the best match available to the actual donor type involved in the test. This type of debris analysis is not the standard output of IMESAFR, as the program is designed to assess the probability of human fatality. However, all of the IMESAFR predictions presented were obtained from the use of the actual model equations and algorithms without adjustment. Test results from ISO-1 and ISO-2 will be presented as well as findings from the comparison between model results and actual explosive results from the ISO testing efforts.

Jan 1, 2010

By AIME AIME

FEW mining schools possess an art gallery and certainly none can equal the collection of paintings depicting the mineral industries now hanging in the comparatively new building of the School of Mineral Industries at The Pennsylvania State College. Dean Steidle, who conceived the idea, early this spring boasted of 55 paintings in the collection, by 24 different artists, the gallery being appraised at $18,000. Since then, eleven additional paintings have been added. Opportunity will he presented for an inspection at the meeting of the Industrial Minerals Division, to be held at the College, Sept. 24-26.

Jan 1, 1936

By S. N. Monteiro, C. M. F. Vieira, A. P. N. M. de Sa, J. P. D. Vitorino

"This work has as its objective to characterize an ash waste and to evaluate its incorporation into a clay to produce bricks and roofing tiles. The waste is a type of fly-ash resulting from the incineration of a selected part of urban garbage, which is basically constituted of organic matter and plastics. The waste was submitted to mineralogical and chemical characterization. Compositions were prepared with incorporation of the waste in amounts of up to 20wt.% into athe clay. Rectangular specimens were prepared by extrusion and fired in a laboratory furnace at 900°C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The results showed that the waste is predominantly composed of quartz and calcium compounds. The incorporation of the ash was deleterious to the evaluated properties of the clay. It is suggested that the incorporation should be made in amounts below 5wt. % to avoid deleterious effect in the mechanical strength and water absorption of the clayey ceramic.IntroductionThe world attention has turned to a subject of great concern today, the production and disposal of large amounts of industrial wastes as well as wastes of various sources. When deposed in an unsuitable place, these wastes can cause considerable harm to human health and to the environment. Our planet suffers with air pollution, groundwater and soil contamination as well as silting of rivers and lakes with the growing amounts of our society wastes.The recycling of waste materials is of great interest to the industries, mainly due to the environmental agencies legislation. One of the practices for correct disposal of these wastes being investigated is to incorporate into red ceramics, such as bricks and roofing tiles. The natural variability of the characteristics of the clays associated with the relatively simple processing techniques and also the low performance required for the products allow the presence of relatively high levels of impurities in clayey ceramics."

Jan 1, 2011

By Mariana Boger Netto

O fósforo é um elemento crítico para a qualidade dos aços, tornando a redução dos teores desse elemento uma exigência para a indústria siderúrgica. Uma forma de se medir a eficiência da desfosforação é através do coeficiente de partição do fósforo (Lp=%P(escória)/%P(aço)). O objetivo principal deste trabalho é avaliar escórias de um forno elétrico a arco através da comparação entre o Lp real com o Lp calculado por simulação termodinâmica, avaliando, também, o comportamento da partição de fósforo com relação à composição química. A partir de dados de composição química de amostras de escória e aço de uma usina siderúrgica, foram feitas simulações termodinâmicas utilizando o software FactSage. Com base nesses resultados, concluiu-se que o cálculo computacional através do software descreve bem o comportamento termodinâmico, mas tende a superestimar o Lp, provavelmente por questões cinéticas e/ou de transferência de massa e calor.

Aug 17, 2017

By Eric Sitorus, Septian Prahastudhi, Roy William, Wieda Azani

In July 2020, massive slope failure occurred in the southeast corner Grasberg open pit. This was the final episode in the breakthrough of Production Block 2 South (PB2S) of the Grasberg Block Cave to connect to the surface. This breakthrough had been rapidly evolving during the first half of 2020 and occurred as expected with no adverse impacts to safety or operations. To manage and safeguard the exposure to the workforce and operations, numerous hazards were identified and anticipated. The failure of the sill pillar between the open pit and PB2S cave was identified as the main area of interest and was closely watched during the failure process. This paper reviews the systematic approach developed to convert monitoring data into information around the collapse of the GBC PB2S cave sill pillar. The data that was interpreted consisted of micro-seismic, piezometric, ground-based radar and observational inspections. Geological structures on the boundary of the PB2S cave were clearly involved in the breakthrough process. As the cave propagation reached these structures and triggered instability, the resulting acceleration and breakdown were clearly shown by IBIS radar units associated with high movement in the slope. The focus of this paper is on the evolution of changes seen in the micro-seismic data and how it was used to understand the rapidly changing conditions of the sill pillar. The seismic parameters evaluated were event distribution, Es/Ep value, and the seismic moment tensor inversion. The changes of breakthrough indication seen in these parameters were substantiated by Shear Wave Splitting (SWS) analysis that showed a close correlation with the fractured zone above the PB2S cave as indicated by the increasing anisotropy.

Jan 1, 2022

By M. J. Raffaldi, L. A. Sandbak, K. K. Dehn, S. N. Warren, J. B. Seymour

"Confidence in the design and stability of an undercut cemented rockfill (CRF) span requires a thorough understanding of its emplaced material properties. The unconfined compressive strength (UCS) of cast 6×12-inch QA/QC cylinders is typically used as an index test to track the performance of a backfill plant. However, these strengths need to be adjusted for oversize aggregate removal and sample size effects if used to estimate the emplaced UCS. UCS testing of 6×12, 12×24, and 18×36-inch cast CRF cylinders was used to quantify the relationship between readily available 6×12-inch QA/QC strength data and the emplaced UCS. Test results indicate that the UCS of 18×36-inch cylinders is roughly 40% of the 6×12-inch UCS for similarly compacted samples. Mine QA/QC data indicate that the UCS of CRF is highly dependent on the degree of compaction as measured by bulk density. Based on these results, knowledge of the emplaced CRF density compared to 6×12-inch QA/QC density is also necessary to estimate the emplaced UCS. The scale effect reported in this study is more pronounced, compared to current understanding of backfill properties discussed in the literature, and underscores the need for further site-specific testing. INTRODUCTION The National Institute for Occupational Safety and Health (NIOSH) Spokane Mining Research Division (SRMD), in cooperation with Barrick Gold Corporation, is conducting research with the goal of determining a relationship between 6-inch QA/QC cylinder strengths and the in-place strength of cemented rockfill (CRF). CRF cylinders with dimensions (diameter × length) of 6×12, 12×24, and 18×36 inches were cast onsite at the Turquoise Ridge Joint Venture (TRJV) and Cortez Hills Underground (CHUG) mines using CRF mixed at the mines’ respective batch plants. UCS tests were performed after 28 days of curing to estimate the size correction factor for each mine’s CRF. This paper presents an overview of the mix designs, sample collections, testing methods, test results, and an estimate of the UCS size correction factor for CRF at these mines. BACKGROUND Underhand cut and fill mining methods utilizing cemented backfill are common in underground metal mines in the United States. These methods are advantageous for controlling weak or highly stressed rock mass conditions by creating an engineered material that can be placed in openings, forming a beam that provides a safe, stable back for the next undercut. Increased use of underhand methods in the last 30 years has greatly improved safety in many cut-and-fill mines. However, with the continual push for more efficient and cost effective mining, there is a need to thoroughly understand the geotechnical properties of cemented backfill to assist in designing safe, stable openings while optimizing costs and production schedules."

Jan 1, 2018

By Tulu B. Ihsan, Mark A. Van Dyke, Ted M. Klemetti

"How well do current modeling procedures calculate the rear abutment extent and loading? Does an improved understanding of the rear abutment extent warrant a change in standing support in bleeder entries? What is the optimal standing support for bleeder entries separated from the longwall startup room by a barrier pillar? To help answer these questions and to determine the current utilization of standing support in bleeder entries, four bleeder entries at varying distances from the startup room were instrumented, observed, and numerically modeled. This evaluation was intended to determine the rear abutment extent and magnitude at various locations to optimize standing support in these entries and those under similar conditions. This paper details observations made by NIOSH researchers in the bleeder entries of a deep cover longwall panel; specifically data collected from instrumented pumpable cribs, observations of the conditions of the entries, and numerical modeling of the bleeder entries during longwall extraction. The primary focus was on the extent and magnitude of the abutment loading experienced by the standing support. As expected, the instrumentation of the standing supports showed very little loading relative to the capacity of the standing supports—less than 25 tons load and 1 inch convergence. The observations of the conditions showed little to no change from before the longwall panel extraction began to when the panel was more than 50% extracted. In addition to the observation and instrumentation, numerical modeling was performed to evaluate the bleeder design. The Flac3D program was used to evaluate these four bleeder entries using previously defined modeling and input parameter estimation procedures. The results indicated only a minor increase in load during the extraction of the longwall panel. The model showed a much greater increase in stress due to the development of the gateroad and bleeder entries, with about 80% of the increase associated with development and 20% with longwall extraction. The Flac3D model showed very good correlation between expected gateroad loading during panel extraction and those expected based on previous studies. The front and side abutment extent modeled was very similar to observations from this and previous panels with similar conditions. The results of this study showed that the rear abutment stress experienced by this bleeder entry design was minimal. The convergence measured in these bleeder entries was small enough not to mandate any additional support beyond development even by U.S. or Australian standards. The pumpable crib load and convergence experienced depends on the geological setting, mining geometries, and timing. The farther away from the startup room, the lower the applied load and smaller the convergence in the entry if all else is held constant. Finally, the numerical modeling method used in this study was capable of replicating the expected and measured results near seam."

Jan 1, 2017

By Duane L. Abata

Toxic gases produced by the detonation of six explosives were measured in an underground hardrock metal mine during actual mining operations. The six explosives included two semigelatin dynamites, three slurry explosives and an ammonium nitrate, fuel-oil/ammonia dynamite combination. Explosives were detonated at the face of a drift and the toxic gases produced by the detonation were trapped to the end of the drift by a bulkhead located a short distance away from the face. Toxic gas concentrations were then measured with direct readout instruments and together with the containment volume, the toxic gas volumes per mass of explosive were calculated. Toxic gas measurements were found in the following ranges (ft3/lbm): NO, 0.010-0.035; NO2, 0.003-0.019; CO, 0.08-0.30; S02, 0.00-0.05; and CO2, 0.7-1.8. Results showed that toxic gas production (ft3/lbm) correlated with the densities (kg/m3) and energy densities (kJ/kg) of the explosives tested.

Jan 1, 1979

By V. Astucuri

El presente trabajo describe el proceso de extracción de plata de dos muestras de relaves antiguos empleando la cianuración. De acuerdo a este estudio, entre todos los procesos metalúrgicos utilizados para la recuperación de la plata como la tostación sulfatante, amalgamación, flotación, se encontró que la cianuración es un proceso completo ya que puede reemplazar a las anteriores, con excepción de la amalgamación de plata nativa y otras deficiencias. En consecuencia, la cianuración es el método hidrometalúrgico que aprovecha mejor el poder lixiviante de los cianuros alcalinos en soluciones diluídas y extrae la palta de los relaves. Por ello, se supedita a su contenido económico y a los minerales no económicos entre los que se encuentre asociado.

Oct 14, 1980

By Y. A. Chang, J. Woodford, C. R. Kao

Reactive diffusion studies between NbC and Si were carried out at 1300 °C under a vacuum of 10-5 torr and a uniaxial pressure of 1 MPa. The annealing time ranged from 8 to 100 hours. The Si used was single crystal silicon; the NbC was hot-pressed powder compact. A NbSi2+SiC two-phase reaction layer formed with NbSi2 as the matrix and SiC as discontinuous particles. The microstructure of the reaction product is homogeneous, dense, and fine. The NbSi2 grain size and SiC particle size are in the micron range. The growth of the reaction products follows parabolic kinetics. Extrapolation of the data to zero thickness suggests an apparent incubation time of 3.5 hours. However, for short annealing time «60 hours), the thickness data can be approximated by linear kinetics with an initial growth rate of about 2 11m/hr. Based on these experimental observations, a growth mechanism for the reactive diffusion between Si single crystal and NbC powder compact is proposed. We propose that the nucleation sites for the SiC particles are at the voids of the NbC powder compact. This proposed nucleation mechanism offers a potential way of controlling the SiC particle size by changing the void size and void density of the NbC powder compact. This hypothesis, if proven to be true, will allow us to control mechanical properties of the composites by tailoring the SiC particles formed. It is also pointed out that the microstructure requires Si to be the dominant diffusing species and to diffuse through the reaction layer, while Nb and Conly have to undergo local rearrangement.

Jan 1, 1996

By Zabetakis M. G.

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1973

By E. C. Burke, W. R. Hibbard

Plastic deformation in magnesium single crystals was studied by tensile tests at room temperature utilizing an improved preparation and testing technique. Consistent critical resolved shear stress values for basal slip were obtained. The advent of pyramidal slip at room temperature was rationalized upon the basis of grip constraints. A bend-twinning hypothesis was advanced as an explanation of mechanical twinning which occurs as a complex stress-relief mechanism. INVESTIGATIONS of the plastic deformation of magnesium have been limited to the determination of the fundamental kinetics which may be summarized as follows: 1—Twinning on the {102).l 2— Slip on the (001) plane in the [loo] direction at room temperature.' 3—Slip on the {101) or {102) plane in the [loo] direction above 225°C." 4—Critical resolved shear stresses for basal slip in tension at room temperature of 83 g per sq mm with a variation from 57 to 127 g per sq mm." Bakarian' studied the compression of thin wafers of magnesium single crystals and classified the components of the deformation mechanisms as follows: 1—The Basal field: (001) at an angle of less than 20" to the compression surface. Fracture along {101} or slip on (001) followed by {101} fracture. 2—The prism field: (001) at an angle greater than 60" to the compression surface. Twinning on the {102) generally occurring during the early stages of loading, basal slip in the areas of original orientation and (001) slip within twins. 3—The central field: (001) at angles greater than 20" but less than 60" to the compression surface. Slip on the (001). 4—The critical resolved shearing stress for {101} slip above 225°C was 400 g per sq mm. Observations of mechanical twins in hexagonal close-packed metals have been summarized by numerous investigatorsb-' emphasizing a lateral or rotational atomic adjustment, in addition to the pure twinning shear, and the importance of reorienting the basal plane to a position more favorable for continued slip, rather than the resulting small dimensional changes. Criterion for the operative twinning planes has not been clearly established. Schmid and Boas hurmised that an energy condition related to the atom movements is the determining factor. MillerQ bserved that twinning stresses in zinc crystals decreased as the amount of prior deformation increased. Preparation of Specimens Magnesium single crystals % in. in diam x 8 in. long were grown from the melt under an argon atmosphere in a gradient furnace similar to that described by Jillson." Magnesium containing 0.018

Jan 1, 1953

By A. R. Sorta, D. C. Sego

ABSTRACT The settling, shear strength, and index properties of oil sands fines-sand mixture tailings (FSMT) for a wide range of solids and fines content are investigated. Results indicate that the liquid limit of FSMT obeys a linear mixture law. The fines-water ratio (FWR) governs the permeability of composite tailings (CT) and CT with comparable geotechnical behaviour can be produced from the same initial FWR mixtures. A phosphogypsum (PG) dosage > 900 mg/kg does not improve the dewatering behaviour of CT. The undrained shear strength of FSMT at the liquid limit is approximately 2.4 kPa, but is dependent on fines content at the plastic limit.

Jan 1, 2013

By Joel L. Morrison

Wet bituminous coal fines from active and abandoned slurry impoundments are currently being examined as a recoverable feedstock for the production of coal water slurry fuel (CWSF). Preliminary analysis indicates that these coal fines can be converted into low solids, low viscosity CWSF with acceptable stability without the use of viscosity modifiers (dispersants) or stabilizers. Efforts are now underway to determine if the impounded coal fines can be economically cleaned by froth flotation to an ash level of < 12 wt. % and a total sulfur content of 1.2 wt. %.

Jan 1, 1995

By Reynold N. Hoover

The bombing of the Murrah Federal Building in Oklahoma City, Oklahoma, on April 19, 1995, has once again renewed public debate surrounding the availability and use of explosives in the United States. In the past, Congressional review of explosives regulation has generally followed tragic events such as the bombing of Pan American World Airways Flight 103 over Lockerbie, Scotland on December 21, 1988; the February 26, 1993, bombing of the World Trade Center in New York City; and the delivery of six package bombs to members of one family in several western New York communities, killing five people, on December 23, 1993.

Jan 1, 1996

Engineering Experiment Station, Kansas State College, Manhattan, Kansas. For publications or a list of publications, address the above Of the 29 Bulletins issued by the Engineering Experiment Station, a few on cement and road-building materials may well be listed here: Bulletin 12, Road materials of Kansas; 15, Tests of Kansas road materials, 17, Some strength characteristics of portland cement; 25, Volume change of concrete, 26, A study of fourteen brands of standard portland cement and four early-strength concretes, 28, The durability of concrete, 29, The effect of aggregate and other variables on the elastic properties of concrete

Jan 1, 1933

Organization Place - Date 1918 American Iron and Steel Institute New York, N. Y. May American Water Works Association :.. St. Paul, Minn. May 20-25 American Institute of Chemical Engineers Berlin, N. H.. June 19-22 American Concrete Institute Atlantic City, N. J. June 24-26 American Society for Testing Materials Atlantic City, N. J. June 25-28 New York Electrical Society New York, N. Y. June National Association of Stationary Engineers Cincinnati, 0. Sept. 9-13 National Exposition of Chemical Industries New York, N.Y.. Sept.23-28 American Chemical Society Cleveland, 0. Sept. National Petroleum Association Atlantic&apos; City, N. J. Sept.

Jan 5, 1918

By Flávio Beneduce

O conhecimento das características termodinâmicas do sistema NiO-CaO é de fundamental importância no modelamento do equilíbrio metal-escória-refratário para a elaboração de ligas à base de níquel em fornos elétricos a arco assim como para o desenvolvimento de base de dados consistente para a extração de níquel de minérios lateríticos. O modelamento existente para a escória líquida, baseado no modelo quase-químico modificado por Pelton e Blander, não pode ser utilizado diretamente na base de dados SLAG usada pelo programa Thermo-Calc pois utiliza um outro modelo termodinâmico para a fase escória. O presente trabalho apresenta o modelamento do sistema NiO-CaO usando o modelo quase-químico de células de Kapoor-Frohberg-Gaye para a fase escória líquida. Os dados utilizados neste modelamento foram atividades das espécies químicas nas fases sólidas, composições solvus em várias temperaturas e parâmetros magnéticos da fase NiO. A otimização foi feita com o módulo PARROT® do programa Thermo-Calc®. Os resultados obtidos da otimização ajustaram-se bem aos dados experimentais apresentados na literatura.

Aug 17, 2017

By A. Festa

Secondary crushing often gets good press for its increases in energy efficiency and SAG milling rates but for a project considering this option the proposed benefits soon get overshadowed by implementation concerns. Reverse engineering from the published case studies is risky unless the reader understands the drivers impacting stability and operability of the circuit. This paper discusses the features of secondary crushing for Greenfield and Brownfield SAG mill grinding circuits. It is the author?s view that secondary crushing rarely adds value to a Greenfield project and restricts future expansion. Its application is best retro fitted to Brownfield operations where the benefit gained for capital expended is excellent. Two case studies are presented to reaffirm these statements. The first case study shows that the implementation of partial and total secondary crushing increases SAG mill power efficiency and it offers substantial incremental increases in milling throughput with staged capital investments for the crushing and grinding circuits respectively. The paper provides a critical analysis of process conditions for secondary-crushed grinding circuits, with particular emphasis on Brownfield circuit retrofits. Furthermore, the second case study quantifies the economic impact of secondary crushing on circuit design for plant start up and it illustrates the limit imposed on plant expansion.

Feb 23, 2014