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By Kotaro Ogura

"The electrolysis process in which CO2 is selectively reduced to C2H4 at a three-phase(gas/solution/metal) interface on a copper-mesh electrode has been developed in a concentrated solution of potassium halide. At open-circuit potential, CO2 is captured on the electrode by being inserted into the double-layer consisting of halide anions specifically adsorbed and potassium cations which are located in the Helmholtz inner and outer layers, respectively. CO2 thus activated is subjected to the electrochemical reduction. In the early stage of reduction, CO2 is converted to formate radicals that are adsorbed on the electrode by taking the place of halide anions. The reductive coupling of these radicals results in the formation of intermediates such as -CH2C(O)- and CH2=CH-, and C2H4 is finally produced. The catalytic activity of the electrode process involving the insertion of CO2 into the double layer is not deteriorated at all during the electrolysis, and the continuous reduction of CO2 to C2H4 is possible with the addition of inorganic acid under the assistance of natural energy.Carbon dioxide is a serious pollutant released from fossil fuel power station, internal combustion and many industrial operations. The easy release of CO2 to the air has caused the global warming, and the technique which intends to curtail CO2 by pushing it back into the ground has been suggested. However, this problem should be greatly mitigated if CO2 can be converted to innocuous substances. Especially, the reuse of CO2 as fuels and chemicals is extremely effective not only for the mitigation of the global warming but also against the depletion of the fossil fuel reserves. Several processes for converting CO2 to valuable compounds have been proposed including hydrogenation over heterogeneous catalyst at high temperature and electrochemical and photochemical reduction. In the conversion and cutback processes of CO2, however, it is of importance that the process is feasible under mild conditions, because the secondary generation of CO2 is feared if high energy is required and supplied with a fossil fuel. In this meaning, the electrochemical reduction of CO2 taking place at room temperature, which is similar to photosynthesis, is promising. From the practical point of view, it is further necessary that the conversion rate is high enough and the product is satisfactorily valuable."

Jan 1, 2008

By T. Gupta, T. Ghosh

"In recent years, the demand for Rare Earth Elements (REE) have grown rapidly due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources of REEs, possibly Coal and Coal byproducts. Coals from certain parts of the world can be rich in REEs, and can approach a total concentration of 1000 ppm. Two Alaskan coal samples were investigated for the effect of size and density on the concentration of REEs on three selected size fractions. Flotation tests were conducted for finer fractions. Additionally Bottom ash and Fly Ash samples from a power plant have been examined for REE concentration. The results show that the upgrade potential for REEs on ash basis from whole coal basis ranges from 2:1 to 4:1 for Wishbone Hill and Healy coal samples respectively. Flotation of the finer fraction for both coal samples, conducted under similar conditions, reveal higher concentration of REE’s in the tailings. Both coal samples have a comparatively higher LREE content than HREE. Trends of REE content of the power plant products on ash basis revealed that Fly Ash has a slightly higher concentration of both LREE and HREE than Bottom Ash. Keywords: Rare Earth Elements, Coal, Coal Ash INTRODUCTION Rare Earth Elements (REEs) and their compounds are vital components in industrial, automotive, petrochemical, defense and medical applications. Dysprosium in combination with other elements is used in laser materials and nuclear control applications. Neodymium is present in magnets that are used in green power generation such as the manufacture of wind turbines and also in hybrid cars. Europium, Terbium and Yttrium are used for devices that have visual displays such as computer screens and laptops [1, 2]. REEs pose fewer environmental problems of disposal and recycling than conventional heavy metal counterparts [1]. Rare-earth metals are key ingredients for radar systems, avionics, modern national defense and satellites [2-8]. In the last 25 years China has been mining, processing and refining Rare Earth elements at affordable prices thus gaining a virtual monopoly in the market. The many fold rise of the prices of REE elements over the last few years and frequent disruptions in supply has forced various nations to invest in indigenous extraction of REEs by increasing production from previously productive sites and to expand the production from new alternate sources including coal and coal byproducts [9]. Coal and Coal beds have been found to be significantly enriched with certain critical metals and can be a potential source for both Light Rare Earth Elements (LREE) and Heavy Rare Earth Elements (HREE) [10]. Moreover, coals with high REE concentrations have been discovered in Pavlovka and Rakovka coal deposits in Russia, Appalachian deposits in USA, Sichuan Basin deposits in China and others across the globe [10-13]. A recent study from China looked at how different trace elements (including numerous REEs) partition in various size fractions of Antaibao coal from China. The finding indicates that the REEs, phosphorous, and thorium all have their high concentrations in the particle sizes 0.5 to 3 mm, and 6 to 25 mm. REEs are also often present in the form of phosphates such as monazite in coal [13, 14]. The objective of the study is to identify the concentration of REEs in Alaskan coals and to investigate the effect of density and size in the distribution of REEs in coal and coal byproducts."

Jan 1, 2016

By John W. Cole

Ore deposits in the? vicinity of Philipsburg, Mont., have been mined continuously since discovery of the Hope mine in 1865. Although originally famed chiefly for its silver production, since about 1917 the district has been the only important producer of battery-grade manganese ore in the United States. Also, it has produced substantial quantities of zinc ore and during World War I and World War II contributed notable amounts of manganese for metallurgical consumption. Nearly the entire production of base metal ores has been mined from the outcrop area of? a dolomitic limestone bed that plunges beneath overlying beds of limestone and shale northward from the outcrop area. The Hope silver mine, with a production record of over $4,000,000, was in one of the overlying limestone beds about 3,000 feet north of the base-metal producing area and about 1,000 feet vertically above the projected downward position of the dolomitic bed that has produced the base-metal ores. Furthermore, the Hope ore bodies were controlled, in part at least by east-west fractures similar to those that controlled the deposition of the base-metal ores.

Jan 1, 1949

By W. E. Wallace, S. -G. Xing, M. J. Keane, J. C. Harrison

"SummaryDiesel-exhaust particles from two sources were dispersed in aqueous mixtures of dipalmitoyl phosphatidyl choline, a major component of pulmonary surfactant, and were tested for genotoxicity. Diesel samples from the same sources were extracted with dichloromethane and transferred into dimethyl sulfoxide and subjected to the same assays. Both types of extractions yielded similar results in both the Salmonella mutagenicity assay and the sister-chromatid exchange assay using V79 cells. After separation of the samples into supernatant and sediment fractions, the activity of both diesel samples was shown to reside exclusively in the supernatant fraction for the solvent-extracted samples, and exclusively in the sedimented fraction for surfactant dispersed samples. These findings indicate that genotoxic activity associated with diesel particles inhaled into the lung may be made bioavailable by virtue of the solubilization / dispersion properties of pulmonary surfactant components.While diesel engine emissions are associated primarily with transportation, they are also very common in the workplace. Estimates for the U.S. are that as many as 1.35 million workers in as many as 80 000 workplaces are exposed to the combustion products of diesel engines (NIOSH, 1988). These occupations include, but are not limited to mining, agriculture, motor vehicle maintenance, fork lift truck driving, truck driving, and tunnel and bridge operation."

Mar 1, 1992

By B. H. Kim, P. Zhang, M. A. Van Dyke, D. Su, H. Dougherty

The National Institute for Occupational Safety and Health (NIOSH) has been evaluating longwall mining-induced strata fractures and their impacts on casing stability of Marcellus shale gas wells located in longwall pillars. To understand the extent of overburden fractures after longwall mining, NIOSH researchers drilled a postmining corehole into the fractured strata above the Pittsburgh coal seam longwall gob. Knowing the extent of the fracture zone height will help gas operators minimize the hazards of drilling into longwall gobs. The core was retrieved from the surface down to the top of the gob void. Various fractures were encountered varying from 35 to 64 degrees, depending on lithologic type and relative closeness to the gob. The longwall panel dimension was 457 m wide and 3657 m long, in which the total fracture zone height was found to be at 141 m and the hydraulic connected fracture zone at 87.7 m above the top of the Pittsburgh seam. In addition to core drilling through the gob, FLAC3D modeling was also used to simulate the formation of fracture zone and the orientations of longwall-induced fractures. This study provides much-needed evidence on the fracture zone of Pittsburgh seam longwall gobs to help gas operators avoid potential hazards associated with drilling through highly fractured zones

Mar 2, 2022

By T. Plikas, L. Gunnewiek

Computational fluid dynamics (CFD) modeling was used to evaluate the performance and optimize the design of a potroom ventilation system in an aluminium smelter facility. The ventilation system must ensure the inflow of fresh air to the workplace by natural draft and the removal of heat and hazardous emissions generated from the pot cell process. A full-scale, three dimensional CFD model of the potroom was developed to predict the air temperature distribution and contaminant concentrations throughout the potroom for the purpose of verifying that the industrial workplace hygiene standards will be met by the proposed ventilation system design. The modeling work was used to optimize the size of the floor gratings around the pot cell and roof ventilator, as well as determine damper settings in the roof ventilator. The effects of outside air temperature and external wind on the performance of the ventilation system was evaluated to ensure the design performs adequately in response to seasonal variations in climatological conditions.

Jan 1, 2006

By Tianzu Yang, Weifeng Liu, Lin Chen, BOYI XIE, DUCHAO ZHANG, HUI XIAO

The oxygen-rich bath smelting process of copper dross was simulated using Factsage software. It was found that the two-step simulation results agreed better with the industrial data, especially in the speiss. Bi, Pb, Sb, As, and Cu contents in the speiss by two-step simulation differed from the industrial data by 0.6 wt.%, 0.8 wt.%, 2.6 wt.%, 7.2 wt.%, and 8.6 wt.%, respectively. Twostep simulation results indicated that the speiss partitioning of Sb, As, and Cu increased from 60.1%, 32.3%, and 27.5%to 81.6%, 67.8%, and 47.2%, respectively, with the smelting temperature increasing from 1050 °C to 1250 °C. While the metal partitioning of Sb and Cu increased from 0% and 2.7% to 15.2% and 13.3%, respectively, with the separation temperature increasing from 400 °C to 700 °C.

Oct 19, 2020

By E. B. Kroeger

Spoil instability has been a problem at a coal mine in interior Alaska. Parameters such as original site topography, groundwater conditions, material properties, spoil-pile geometry, geology, permafrost, natural slope instability, changing weather conditions, and dense, near-surface vegetation have interacted to produce unstable slopes. Several failure modes have been identified including deep seated earth block slides, bimodal earth flows, and solifluction. Thawing of permafrost also created conditions where sliding of spoil along the interface separating the spoil and the natural ground surface occurred when the cohesion and the friction angle of that zone was reduced to zero and below 15?respectively.

Jan 1, 1992

By Lee H. G, Li H, Hayes P

Slag from the smelting of lead can contain up to 20 per cent zinc as an oxide. An understanding of the lead smelting process and of the subsequent fuming process for the recovery of zinc is enhanced by a knowledge of the activity coefficient behaviour of zinc oxide in smelting slags. The literature presents a wide range of contradictory values. This paper critically reviews the published data and outlines new measurements being made by the authors. A consistent set of zinc oxide activity coefficient data is presented for liquid slags within the ZnO-'FeO'-CaO-A1203-SiO2 system, through a combination of present and previous measurements.

Jan 1, 1993

By Dix, E. H.

THE percentage of manganese used in commercial aluminum alloys is small, and yet this element is an important addition to some very valuable alloys. When used alone with commercial aluminum containing iron and silicon as impurities, the usual percentage in wrought materials is from 1 to 1.5 per cent., whereas castings may contain as much as 2 per cent. An aluminum-manganese alloy containing nominally 1.25 per cent. manganese is much used in sheet form for the manufacture of cooking utensils and other articles requiring a little greater strength and hardness than could be obtained with commercially pure aluminum. It is also used for various purposes in the form of rods, tubes and pipes. The aluminum-manganese alloys, both wrought 'and cast, offer excellent resistance to many kinds of corrosion attack. The U. S. Naval Gun Factory uses an aluminum alloy containing from 1 to 2 per cent. each of copper and manganese, for both castings and forgings. Manganese is also used, up to about 1 per cent., as a minor alloying .element in several of the strong aluminum alloys of the duralumin type. It is felt that the role of this element when thus used has not been fully understood, but it is believed that the results obtained in this investigation will throw additional light on the subject. The earlier work on the system aluminum-manganese was general in nature, and no detailed investigations of the relations existent in the useful aluminum-rich alloys have been reported. Guilletl1in 1902 surveyed the system, and Hendrichs2 in 1908 published an equilibrium diagram which, although based on .few data, is often used in the literature. Fragmentary work has also been done by other investigators."

Jan 1, 1927

By Kenneth Gavin, Weichao Li, Paul Doherty

"The lateral load capacity is one of the most important issues to be considered in designing piles to resist berthing loads, ship impact forces and for monopiles used in the offshore wind sector. A number of semi-empirical design approaches are available to calculate the ultimate soil resistance and assumed soil reaction profile along the piles’ embedded depth. In order to investigate the response of monopiles to lateral loading, a series of field experiments were conducted on instrumented steel pipe piles. Two lateral loading tests were performed on model piles with a diameter, D, of 340 mm and embedded depth, Lem, of 2.2 m, giving a Lem/D ratio similar to those adopted in the offshore wind sector. The piles were driven into dense sand at the University College Dublin geotechnical test bed site in Ireland. 10 pairs of strain gauges were installed on each model pile along the embedded depth at 10 levels to capture the load transfer and bending moment within the piles. The deflection and rotation at the model pile head were measured by Linear Variable Differential Transformer (LVDT) and inclinometers. The tests results were used to perform a detailed evaluation of current design methods. In the final section, discussion on the determination of the ultimate lateral load capacity for monopile design was conducted. IntroductionA pile’s lateral load capacity is determined, for design purposes, by two conditions: 1) the ultimate lateral load, Fu, divided by an appropriate safety factor; and 2) the load according to the maximum lateral deflection that the support structures can sustain. In view of the first condition, design methods to calculate the ultimate load were developed for piles used in the offshore oil and gas sectors, which tend to be much more slender than monopiles used in the wind industry. The purpose of this study was to investigate whether these design methods provide reasonable estimates of ultimate capacity, for short rigid monopiles.The methods to determine the ultimate lateral load generally follow three steps: 1) determine the ultimate soil resistance, Pu, along the pile embedded depth; 2) adopt the most appropriate soil reaction profile, Pz, along the piles embedded depth when the pile subjected to the ultimate lateral load condition (four of the most popular ones are depicted in Figure. 1); and 3) ensure equilibrium of lateral forces (see Equation 1, symbols are listed at the end of the paper) acting on the pile and bending moments (see Equation 2) about a point in pile is employed to determine the ultimate lateral load."

Jan 1, 2015

By Nicole R. Henderson

Many mining engineering graduates enter the mining industry lacking training in mine emergency management. As a result, mining universities in the United Sates and other countries are beginning to form volunteer student mine rescue teams to train mining engineering students in handling mine emergency situations and give them hands-on experience managing potential emergency scenarios underground. In the early 1980s, the Missouri University of Science and Technology developed the first collegiate mine rescue team in the United States. For approximately 30 years, it was the only successful collegiate team until the Colorado School of Mines (CSM) started its program in 2009. Currently, there are at least five collegiate teams in the United States and one in Canada. At the Freiberg University of Mining and Technology in Germany, the goal is to adapt the Colorado School of Mines Mine Rescue Program to develop a collegiate team of its own. Currently, mining engineering students cover the theoretical basics of mine rescue in an occupational health and safety lecture and take a basic, one-day mine rescue training course at the Central Mine Rescue Station in Leipzig. The course covers the basic mine rescue topics and gives students the opportunity to experience working in elevated heat and smoke conditions while wearing breathing apparatus. This training gives students a small insight into the importance of mine rescue and mine emergency management. Collegiate mine rescue teaches students the importance of mine rescue and mine safety by giving them hands-on learning experiences before entering the mining industry.

Feb 1, 2014

By R. L. Hopkins

Fifteen alkyl cycloalkyl sulfides and three dicycloalkyl sulfides were synthesized to provide reference compounds in the search for these classes of sulfur compounds in crude oils. In synthesizing sulfides by alkaline alkylation the order in which the reactants were added was shown to determine the yield and purity of the product.

Jan 1, 1966

By D. T. Randall

Several years ago investigations were begun by the United States Government to determine the most efficient methods of utilizing the coals of the United States. These investigations, which were continued along several different lines, are now being carried on by the Bureau of Mines, in accordance with the provisions of the act creating this bureau . . It was because of the need for more complete information concerning the conditions under which coal could be economically burned in boiler furnaces without objectionable smoke that tests were made at the Government fuel-testing plants at St. Louis, Mo., and Norfolk, Va. In addition to this experimental work a number of commercial plants in the larger cities were inspected to ascertain what were the best methods then in use for abating smoke. The results of these investigations were reported in Bulletins 334 and 373 of the United States Geological Survey. Because of the continued demand for the information contained in these bulletins, the original editions of which are exhausted, they are reprinted by the Bureau of Mines. The text of this bulletin, particularly the information relating to smoke ordinances, was revised in the latter part of 1910 and the early part of 1911 by S. B. Flagg, engineer, who has charge of the steaming tests being conducted by this bureau.

Jan 1, 1912

By I Jabou, D G. Blazak, L C. S Hogarth

The R70 test is a good indicator of coal reactivity to oxygen and is commonly used to provide a rating of propensity for self-heating. Tests performed by The University of Queensland Spontaneous Combustion Testing Laboratory have resulted in the development of a large database that shows the impact of coal quality on this parameter. From these results it is possible to infer an R70 value, which can be used to gain an appreciation of the intrinsic coal reactivity before it is even tested. However, any interpretation of R70 values must consider the influences of coal rank, mineral matter and moisture content to provide a better understanding of the spontaneous combustion risk of a particular coal.

Jan 1, 2005

By R. DasGupta

The dissolution behavior of gold in ammoniacal solutions at 75°C has been investigated. The variables investigated include concentration of lixiviants, pH of the solution and various oxidants. The anodic dissolution of gold was studied in the absence of oxidants using the potentiodynamic polarization technique. The cathodic reaction of oxidants was studied on a platinum electrode. Tafel polarization tests were also performed to determine the dissolution rate. The overall dissolution of gold in ammoniacal solutions was examined using a mixed potential theory. A comparative study on the role of cupric am mine, oxygen, hydrogen peroxide, sodium hypochlorite as oxidants for the dissolution of gold in ammoniacal solutions has been carried out.

Jan 1, 1996

The first grant of land rights in Australia was pursuant to the Aboriginal Land Rights (Northern Territory) Act 1976. That Act has been at the core of the dispute between land rights and miners' rights. The mining industry believes that the Act, in giving a right of veto to Aborigines with respect to exploration and mining on Aboriginal land, has been responsible for a stagnation in exploration amd mining activity in the Northern Territory. In February 1985 the Commonwealth Government released for public comment its preferred model for national land rights legislation. The model has been opposed by the mining industry because it believes, first, that land rights is a matter which should be left to the States and, secondly, that the detailed mechanisms contained in the model constrain the industry in the manner of the Northern Territory legislation. Aboriginal leaders have opposed the model because it does not, in their view, measure up to undertakings given by the Commonwealth Government and, in addition, it provides for amendments to the Northern Territory legislation which are likely to result in the loss of the Aboriginal veto right. Are land rights and miner's rights compatible? The answer is yes provided all parties, including Governments, are prepared to talk and compromise and Governments recognise that the grant of land rights and any control by the Aboriginal people of exploration and mining on their land is not a substitute for raising the living standards of Aborigines as a significant group of disadvantaged Australians.

Jan 1, 1986

By J. P. Bennett

The Bureau of Mines investigated the dimensional changes of ceramic materials exposed to acid environments to evaluate construction materials for emerging technology in chemical and metallurgical processes. Six commercial ceramic materials (two red shale, two fireclay, one silica, and one silicon carbide (SiC» were exposed to H20, 20 and 30 wt pct HCl, 40 and 60 wt pct HN03, and 10 and 50 wt pct H2S04 at temperatures from 50° to 90° C for 300 days. Linear expansions ranged from a low of -0.02 pct for the silica to a high of 0.45 pct for the red shale. A general ranking of the volume expansion of the materials tested, (from high to low), is as follows: high-porosity red shale A and fireclay B » low-porosity red shale B and fireclay A > silicon carbide and silica. A general ranking (largest to smallest) of the effect of exposure environments is HCl > H2S04, HN03 > H20. An autoclave test method was evaluated. Data obtained from 8-to 24-h exposures were compared with data obtained from the 300-day exposures. The relative expansion trends were similar, indicating that this method could be used as an accelerated test.

Jan 1, 1988

By Satya Harpalani

The four most important parameters controlling the flow of gas in coal are the gas content, permeability, diffusion coefficient and cleat characteristics. Estimates of these and, more importantly, a knowledge about the variation in their values over time are required for simulation of long-term gas production. This paper describes experimental techniques to determine each of these, along with their time dependency, under simulated in situ conditions. It is shown that the permeability, diffusion coefficient and the cleat aperture values are not constant as usually assumed to be. There is a significant variation in their values as a result of changes in the microstructure of coal associated with release and flow of gas.

Jan 1, 1995

By Robert P. Stevens

It is important for a refractory supplier to make systematic petro-graphic examinations of products which have been in service in the furnaces and kilns of customers. The petrographic examination of refractory service samples involves the microscopic study of polished and/or thin sections, supplemented by electron probe microanalysis, as well as the bulk chemical and XRD analysis of zones in the samples. The evolution of the A. P. Green Refractories Company petrographic laboratory is described, and the application of petrographic methods is illustrated in the examination of service refractories from a Portland cement rotary kiln and an AOD stainless steel vessel. The objectives of such studies are to assist the customer in the solution of his refractory problems, and to accumulate data which are of use in the design of improved refractory products.

Jan 1, 1981