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By Dixon D. R, Sparrow G. J

Pressure leach liquors from the pressure oxidation of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore were treated to remove iron, either by pressure oxidation (the Hematite process) or with particles of magnetite (the Magnetite process), followed by cementation of various metals with zinc dust to obtain a purified solution from which zinc was electrowon. Satisfactory iron removal was achieved by both processes after neutralisation to pH 4.5 or 5.5. Pressure oxidation of the liquor at 200¦C and 690 kPa oxygen overpressure, conditions similar to those of the Hematite process used in the zinc industry, resulted in the precipitation of the iron as hematite. With the Magnetite process, an iron hydroxide was precipitated onto magnetite at atmospheric pressure and ambient temperature and removed by a magnetic separation step. The performances of both these processes for the removal of iron are compared. It is concluded that the Magnetite process offers considerable cost savings. Other impurities, in particular arsenic, were also removed with the iron in both processes. Cementation at pH 5.2 and 85-90 ¦C with 3.5 g/L zinc dust reduced the levels of copper, cadmium, and nickel to a satisfactory level and subsequent electrolysis in a laboratory cell gave an acceptable deposit of zinc.

Jan 1, 1989

By Shadia J. Ikhmayies

"Tin oxide (SnU2) thin films of thicknesses in the range 100-600 nm were prepared on glass substrates by vacuum evaporation at ambient temperature. The films were characterized by transmittance measurements, X-ray diffraction (XRD), scanning electron microscope (SEM) observations and energy dispersion X-ray analysis (EDAX). It is found that the films have high transmittance and non sharp absorption edges. XRD diffractograms showed that the films are amorphous and the SEM micrographs showed that the surfaces are smooth, uniform and well covered with the material. The EDAX analysis showed that the films are deficient in oxygen. Indirect optical bandgap energy and Urbach tailing in the bandgap was observed, and the width of the tail, which is related with disorder and localized states, was estimated.IntroductionTin oxide is an n-type wide bandgap semiconducting material with a direct bandgap energy of 4 eV and an indirect bandgap of 2.6 eV [1], where inherent oxygen vacancies act as an n-type dopant [2], Tin oxide thin films have been used for transparent electrodes in photoelectric conversion devices namely amorphous silicon solar cells, liquid crystal displays, gas discharge displays, etc. [3]. Perfectly amorphous thin SnO2 films show good electrical response to reducing gases in air and could, hence, be applied to construct semiconductor gas sensors where the metal oxide films function as a monograin-eqivalent active layer [4]. Amorphous SnU2 can also be used in extended gate field-effect transistors (EGFET) as a pH sensor, where the sensitive part is made of the SnO2/Al structure. This device can be used to detect and to quantify any kind of substance that can produce or consume protons, like an enzymatic reaction, therefore showing a large range of applications as biosensors [5].There are different methods to prepare SnO2 films, such as atomic layer deposition (ALD) [6], reactive magnetron sputtering [7], chemical vapor deposition [8, 9], dip coating [10], spray pyrolysis (SP) [3, 11-14], and evaporation [8], The thermal evaporation method was chosen to produce SnO2 thin films in this work because deposition by this technique does not present any compositional problems. In addition, it is a low temperature technique, which increases the probability of producing amorphous films. To increase this probability, the films were deposited at ambient temperature."

Jan 1, 2012

By Joseph M. Singer

Having established that sodium chloride reduces the incendivity of explosives, the Bureau of Mines studied the effect of sodium nitrate in reducing ignition hazards. Gallery experiments showed that sodium nitrate reduced the incendivity of certain explosives to 8 percent natural gas in air but increased their incendivity to coal dust predispersed in air. Laboratory experiments using hot jets from explosions of stoichiometric mixtures of methane-oxygen-nitrogen showed that both sodium chloride and sodium nitrate reduced the incendivity to methane, to mixtures of coal dust and methane) and to coal dust. The difference between the gallery and laboratory results with respect to coal dust is attributed to temperature-time effects.

Jan 1, 1967

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By Thomas C. Mowatt

Preliminary Bureau of Mines studies of mafic igneous rocks collected from the Rabbit Creek area, northwestern Alaska, indicated concentrations of platinum (412 to 1,406 ppb) and palladium (343 to 892 ppb) in five of eight samples analyzed. The samples represent boulders and cobbles of mafic/ultramafic rocks from this locality. They are not from outcrop. Petrologically, (on the hand specimen scale) the samples are crudely to well-layered and are troctolitic ± gabbroie in character, with primary igneous mafic minerals strongly altered. Small patches of interstitial sulfide minerals, including chalcopyrite, bornite, pyrrhotite, pyrite, and covellite are associated with these altered zones and elsewhere through the specimens. Copper values ranged from 0.1 to 0.3 pct in samples analyzed semiquantitatively; nickel, cobalt, and chromium contents are low. Chemical, mine alogic, and petrographic relationships suggest that the rocks of similar character outcropping in northwestern Alaska could also be considered as prospective for- concentrations or platinum, palladium, and copper.

Jan 1, 2011

By Joseph A. Mann

"Soil mixing is a proven solution for the construction of ground improvement adjacent to sensitive structures due to the use of computer controlled and monitored equipment. The precision to which geometry is controlled can often be the deciding factor for selection of soil mixing versus other means of ground improvement. Protection of existing structures and utilities requires careful planning, investigation, and may demand supplemental control measures. During planning, it is imperative that the process be fully developed by the project team to ensure proper control measures are budgeted; otherwise, the success and safety of a project can be jeopardized.This paper discusses case histories of soil mixing performed in close proximity to large, sensitive, and critical utilities, including foundation support for an existing earthen dam impounding a water reservoir in upstate NY, a buffer zone for a tunnel drop shaft at an operating wastewater treatment plant in Washington DC, and a containment system to protect a major water line along an interstate widening project in Baltimore, MD. The function of soil mixing as ground improvement varied; however, the selection and application of the technique versus other means of ground improvement was specific due to the controlled manner of construction with soil mixing. Through the three case studies, small diameter (3- ft [0.9 m]), large diameter (8-ft [2.4 m]), and mass mixing applications will be discussed. Furthermore, the case studies offer insight into how the geotechnical community in the Mid-Atlantic utilizes soil mixing technology for widely varying applications. Additional topics of discussion will be the design and construction of the ground improvement systems, procedures and execution of the work to protect existing structures, and the QA/QC methods, procedures, and results from the projects.INTRODUCTIONWet soil mixing, also known as the Deep Mixing Method, is a ground improvement technique that improves the characteristics of weak soils by mechanically mixing them with cementitious binder slurry. To construct columns, a powerful drill advances a mixing tool with radial mixing paddles located near the bottom of the drill string. The binder slurry is pumped through the drill string to the tool as it advances and additional soil mixing is achieved as the tool is withdrawn.Wet soil mixing is applicable in a wide range of soils. Soil mixing has been performed at depths more than 100 lf (30 m). Soils vary widely in their ability to be mixed, depending on the soil type, strength, water content, plasticity, stratigraphy, and texture. Almost any soil type, including organics, can be treated with certain soil mixing technologies, although they may require high binder contents and/or pretreatment to achieve the required results. In cases when the target soil is very soft, including some very weak clays and peats, 100% of the soil may require treatment. This complete coverage of soil mixing is referred to as mass mixing."

Jan 1, 2015

By H. L. Riley

This report describes the methods and equipment used by the Watauga Stone Co. to drill und blast limestone in a two-level quarry, and to crush, screen, blend, and load this stone. Power requirements per ton of stone produced are reported. The personnel requirements for individual phases of the operation are tabulated in man-hours per ton of stone produced.

Jan 1, 1963

By Mike Harrington, Tung Vu

The Regional Connector Transit Project is a 1.9-mile-long underground light rail system that will connect LA Metro’s A (Blue), E (Expo), and L (Gold) Lines in downtown Los Angeles. This $1.75-billion design-build project is scheduled for revenue service in Spring 2023. The project consists of 21-foot diameter twin-bored tunnels, a 300-footlong crossover SEM cavern, three new underground stations (at 1st Street/Central Avenue, 2nd Street/ Broadway Avenue, and 2nd/Hope Streets), and cut-and-cover tunnels along South Flower, Alameda, and 1st Streets. This paper, which is the continuation of our previous paper presented in RETC 2019—LA Metro Regional Connector Transit Project: Successful Halfway-Through Completion, will provide insight regarding the construction of major components, and the system integration and testing work undertaken for this complex transit project.

Jun 13, 2023

By J. B. Hanlon

In order to protect coal mine owners, operators, and lending institutions from potential environmental liabilities, responsible parties must maintain a thorough understanding of the environmental disposition of the property they control, and the ramifications of impending laws and regulations. The best way to accomplish this is to periodically conduct a Phase I Environmental Audit. The systematic approach of an audit will reveal areas of DOD compliance with SMCRA and EPA regulations which the coal owner and/or operator will be able to use to correct deficiencies and prevent the occurrence of conditions which could lead to permit block, fines, and ultimately reduced productivity.

Jan 1, 1995

By Richard M. Winar

In September of 1988, the United States Environmental Protection Agency (US EPA) published final regulations that effect owners and operators of underground storage tanks (USTs). These regulation include stringent technical requirements for owners and operators of USTs containing petroleum and certain hazardous substances. The technical requirements effect both new (those installed after December 1988) and existing USTs and include notification; performance and operating standards; release detection, reporting, investigation; release response and corrective action; and closure requirements for out-of-service USTs. The USEPA also published final regulations regarding financial responsibility requirements for owners or operators of petroleum USTs in October of 1988. These regulations require owners or operators of petroleum USTs to demonstrate financial responsibility for the costs of corrective action and compensating third parties for bodily injury or property damage caused by releases from petroleum USTs. Like thousands of other industries, the mining industry must become thoroughly familiar with these new regulations in order to properly manage their UST systems, ensure compliance, and understand other ramifications imposed by these regulations.

Jan 1, 1990

By AIME AIME

STRIP coal mining in the United States has-become noted for its massive equipment, especially its power shovels. Notable among the latest examples of this trend is the Bobolink mine of the Binkley Mining Co., at Seeleyville, Ind.,. eight miles from Terre Haute. This is only one of the Binkley company's operating properties; in all, the company owns or controls 26 mines, in fourteen seams. The Bobolink, however, is the largest strip mine in America and probably also in the world. It has an estimated life of fifteen years. The shovel used to strip the over¬burden is electrically operated, of Bucyrus-Erie make, and was. shipped to the property for assembling, a job

Jan 1, 1936

By Ian Hattie, Mark R. Wilson, T. Kurtis Kyser, Brian W. Janser

Petrographic, chemical and isotopic compo itions of auriferous and non-auriferous quartz vei ns from the Sta r Lake and Flin Flin-Amisk Lake areas of northern Saskatchewan indicate diver e origins fo r the fluids associated with gold mineralization. In the Sta r Lake area, the metavolcanic , Star Lake pl uton, and heared mafic dikes have retained their original igneous 81 80 values. The 81 80 value of quartz from mi neralized veins vary by I per mi! and range from+I0 to+IJ. The only quartz ample having a 81 80 value outside th is range came from a vein not associated wi th a dike or gold mineralization . Quartz from the Star Lake pluton has identical 8180 value to the qua rtz from mi neralized vei ns which suggests that the vei ns and the pluton are related to imilar proces es. The diffe rence in 81 80 values between mi neralized and barren vein may erve a a potential exploration tool in this area. Because o34S val ues of a limi ted number of amples of pyrite from gold-bearing quartz vei ns at Star Lake correlate directly with gold content. the gold may have been syngenetic with the su lphur and the 834 value may be useful for exploration . 8180 values of co-existing quartz, calcite, and amphibole in the veins from Star Lake indicate that isotopic disequilibrium among the minerals is common, but the val ues also record a high temperature of formation (ea . 500°C) involvi ng a component of magmatic fl uid. TheoD value of hydrou mineral from Star Lake retain their original igneous values but whole rock values are generally much lower, an effect attributed to interaction of the minerals with a late meteoric water. In the Fl in Flin-Amisk Lake area, auriferou and barren quartz veins formed from a mixture of hydrothermal and metamorph ic flu id at lower temperatures (ea . 350°C) than those at Sta r Lake. Becau e there i no apparent correlation between 8180 values of the quartz with gold content or relative age of the vein , nor between the 834S val ues of pyrite and gold content, table isotopes appear limited as an exploration tool in the Fl in FlonAmisk Lake areas.

Jan 1, 1986

This paper describes a detailed geostatistical study of producing copper orebodies at Mount Isa Mines Limited in Queensland, Australia. As a result of this work, kriging has been adopted for grade estimation for final stope design at Isa Mine. Extensive variogram and back analysis studies indicate that one relative variogram model can be used to give optimal kriged grade estimates from production sampling throughout the 100 million tonne copper orebody complex. The kriging method replaces a computer technique used at [sa Mine based on inverse distance weighting using parameters chosen from experience.Comparative stope designs based on 10 million tonnes of ore indicate a 16% increase in minable ore tonnage at a grade well above the cut-off, as a result of the geostatistical work.Although this paper is written as a practical description with simple explanations of geostatistical concepts, the theory and use of relative variograms has been expanded. A possible link is suggested between relative variograms and first order kinetics of natural mineral concentration processes.

Jan 1, 1982

By Margot Panta, Diego Guevara, Miriam Torres, Irayda Salinas

Los bofedales son humedales altoandinos considerados ecosistemas frágiles por la Ley General del Ambiente de Perú - Ley N° 28611. Este trabajo evalúa la fragmentación y conectividad de 20 bofedales ubicados en el distrito de Huachocolpa, departamento de Huancavelica; los mismos que abarcan un área total de 111.9 ha, con un área promedio de 5.595 ha por parche, con el fin de contribuir al mejoramiento de planes de manejo de la biodiversidad (fauna y flora) altoandina y facilitar la recuperación de dichos ecosistemas.

Sep 20, 2019

By Víctor R. Cabrera

Para un mayor avance en su producción, las minas de cielo abierto u "open it" de Marcona, utilizan unidades de mayor tamaño en el transporte, puesto que reduce el costo unitario del trabajo. En este aspecto, el objetivo del trabajo describe el uso de máquinas comprendidas para su uso, rendimiento de costo, pala, control de tiempo, tiempo de operaciones y el trabajo con traillas dentro de esta modalidad. etc. Como primer punto, las máquinas cargadoras, las palas mecánicas, etc, incrementan su tamaño constantemente y como tal, las operaciones de transporte cambiaron de uso de ferrocarril a de los camiones con 10,15, 20. 30 y 50 tonelajes por viaje. Posteriormente con el advenimiento de motores diesel, diseño, construcción, perforación y transporte de las máquinas cargadoras, se creó una minería de cielo abierto más económica, flexible y eficiente. En este punto, las operaciones estacionarias, sea con palas o las perforadoras de voladura, utilizaron preferiblemente la energía eléctrica que simplifica la operación y facilita el mantenimiento y las reparaciones. Mientras que las operaciones de perforación, voladura, carguío y acarreo se analiza las características de toneladas rotas por perforación, los cálculos de sobreperforación, los materiales explosivos usados, respectivamente. En cuanto la extracción de palas y volquetes, se evalúa la calidad del disparo, número de voloquetes, capacidad horaria. Finalmente en el trabajo con traillas, se evalúa la influencia del costo de las demoras relativas en las palas y los volquetes, pérdidas de la capacidad potencial de la pala cuando hay insuficiencia de volquetes, asi como las variaciones de la capacidad según la distancia de acarreo.

Jul 20, 1956

By G. J. S. Govett

World mineral production is dominated by six countries - the U.S., the U.S.S.R , Canada, South Africa, Australia and China - which also hold most of the reserves of the world?s minerals. For the developed and centrally planned countries, there is a strong positive correlation between the mineral production of a country and its land area: there is no correlation between mineral production and land area for the less developed countries. These facts imply that, after taking due account of geological controlling factors, a country may expect to produce minerals in approximate proportion to its land are a provided that political, economic, and historical factors are conducive to mineral exploration and mining. Contrary to popular political belief in many parts of the world, the developed countries are the major source of mineral imports for the industrialized countries. Moreover, exports of ores and minerals account for a relatively small par t of world trade, and are an important factor in the export picture of only a few of the less-developed countries. The looming resource confrontation between the developed and the less-developed countries is based largely on the false premise that the industrialized countries of the world are minerals-poor and owe their wealth to cheap minerals from the less-developed countries. The data presented refute this. Geological controls are relatively minor in the present distribution of world mineral production; political and economic factors are dominant. It is argued that an expansion of world trade in minerals - based on increased exploration and new forms of finance for mining ventures - rather than cartels, price-fixing and trade restrictions is by far the preferable solution to the problem of redressing the legitimate grievances of the poor countries of the world.

Jan 1, 1977

By H. J. Coleman

Knowledge of the types of naturally occurring sulfur compounds in petroleum is of both theoretical and practical interest to petroleum chemists and geologists. This knowledge has been extended by the identification of 77 sulfur compounds, including 36 thiols, 23 chain sulfides, and 18 cyclic sulfides in a 111° to 150° C boiling range distillate of Wasson, Texas, crude oil. The characterization procedure used in separating and identifying these compounds included isothermal distillation, vacuum fractionation, liquid-solid chromatography (alumina adsorption), chemical treatment, gas-liquid chromatography, microdesulfurization, and infrared analysis. The procedural steps described represent a systematic method of sulfur compound analysis considered applicable for determining the nature and concentration of the sulfur constituents present in any straight-run petroleum distillate of the above-boiling range.

Jan 1, 1966

By William W. Edgerton, Moussa Wone, David H. Corkum, Carlton M. Ray

"The DC Clean Rivers (DCCR) Project is a 25 year, $2.6 Billion court ordered project to reduce combined sewer overflows (CSOs) discharging into the Potomac and Anacostia Rivers and Rock Creek, and also reduce flooding in the northern areas of the District of Columbia. Like all massive infrastructure programs, DCCR faced technical challenges, management challenges, risks of cost and schedule overruns, procurement challenges, and financing challenges. While DC Water is no stranger to large capital improvement projects (CIP), this CSO Program represents a once in a lifetime event for the Owner requiring the assembly of a single purpose team to implement. Some of the DCCR Project team’s most successful accomplishments to date are attributable to its introduction of early contractor involvement (ECI) to thoroughly vet the work from the perspective of the future constructors, development of functional baselines to share risks that are difficult to price and reduce reliance on geotechnical baseline interpretation during tunnel excavation, and attainment of financing through Municipal Century Green Bonds based on using design criteria of a minimum of 100 year life for the structures to establish intergenerational equity and fairness. This paper will discuss these innovations in detail and provide some sets of recommendations for the underground industry on when and how to use different approaches to better manage projects of this magnitude. INTRODUCTION The District of Columbia Water and Sewer Authority (DC Water) is an independent multi-jurisdictional authority that was established in 1996. Its primary mission is to provide water distribution services to more than 640,000 residents in the District of Columbia (District), and sewer treatment and disposal to 1.6 million residents of the District, Montgomery and Prince George’s counties in Maryland and Fairfax and Loudoun counties in Virginia."

Jan 1, 2016

By EDER DOMINGOS OLIVEIRA, Leandro Viana Teixeira, Carlos Antonio Morais, Ruberlan Gomes Silva

Special attention must be considered in the production of high-grade rare earth products, such as mixed rare earth oxalates or carbonates. In the main minerals used industrially, the rare earth elements (REEs) are finely associated with impurities like calcium (Ca), magnesium (Mg), manganese (Mn), iron (Fe), aluminum (Al), thorium (Th), uranium (U) and phosphorus (P). Most of these impurities must be removed to avoid losses of rare earth oxides (REOs) as well as to prevent product quality degradation and low operational performance in the downstream steps of solvent extraction or ion exchange. The present study aims at investigating the conditions required to precipitate REEs, either as rare earth oxalates or carbonates, from purified rare earth sulfuric liquor with low Al3+ and UO22+ concentrations and very high Ca2+, Mg2+, Mn2+, and SO42− impurity contents.

By Pati±o A

The Argentine pyroclastic loess arevulcanogenic deposits, which have their sources in the circumnpacific rim. The object of this work is to realize a de-tailed mineralogical characterization of this sediments, to use it like a geo logic outline which regiters discordance or similarity in them, The sampling zone extend from 714N-4125 to 622W-339S. The descriptions of these sediments was considered like basic, mesobasic or acid rocks. The basic sediments, looking like andesite-basaltic composition, are fill-ing the andean valley. The mesobasic one have a similar composition with a pyro-clastic dacite rock, and have been found in marshy pleistocene sediments in the intermountain valley and in the pampeana prairies. The acid ashed conform rhyoda-cite-rhyolite sediments which form the pampeana loess covers in the prairie.

Jan 1, 1990