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By Robert E. Manning

The Federal Coal Mine Health and Safety Act of 1969 has placed stringent limitations on the noise levels in which employees may work. This act can result in both increased labor costs because of noise-exposure time limitations and in high capital costs for modification of present equipment, and the design of new equipment, to comply with the law. The development of new noise-control systems is thus of immediate interest to industry. A current Research program at U. S. Steel is aimed at developing methods of controlling both the exhaust-air noise and the mechanical noise of a Stoper drill, a pneumatic percussive tool used for roof-bolting purposes in coal mines which has an approximate air consumption of 100 cubic feet per minute. This program is being performed under a contract between USS Engineers and Consultants, Inc. and the Pittsburgh Mining and Safety Research Center of the U. S. Bureau of Mines. In previous work at U. S. Steel, kidney-shaped mufflers were designed that wrap around the air leg of the drill for control of the exhaust noise. These mufflers were designed with the aid of a digital computer program that predicts the acoustic performance of mufflers.

Jan 1, 1975

By Panshi Xie, Yingyi Zhang, JIANJIE DUAN, Shenghu Luo

A multi-layer gangue roof of a steeply dipping coal seam with a large mining height face area was analyzed using physical simulation, numerical simulation, theoretical analysis, and field measurement methods to evaluate the roof deformation and the mechanisms associated with the instability of the hard gangue and soft coal interlayer. The results indicated that the first weighting step of the multi-gangue roof was larger than that of a non-gangue roof, but periodic weighting steps were similar. The overburden collapse height was lower in the multi-gangue roof than in the non-gangue roof due to the buffering and supporting function of the collapsed gangue. Moreover, the failure of the coal interlayer was the key factor in the collapse of the multi-layer gangue. A mechanical model was established for the hard gangue and soft coal interlayer based on a revised Prandtl squeezing theory. The limited load of the interlayer and maximum resistance of the shield support was thusmodeled. The maximum resistance of the support increased with the dip angle of the seam and burial depth. It also increased with the interlayer thickness at thicknesses below 2.75 m. It reached a peak when the interlayer thickness was between 2.75 and 3 m and exhibited a decreasing trend when the thickness was greater than 3 m. The results were confirmed using physical simulation and a field test. Certain measures were proposed to control the stability of the gangue roof, including zoning control of the mining height and resistance and advancing the support while maintaining roof contact, thus ensuring the integrity of the support and surrounding rock system.

Jun 30, 2020

By N Ganjian, A Delavar, F Rashidi Nejad

Iran is one of the most seismically active countries in the world, being crossed by several major fault lines that cover at least 90 per cent of the country. As a result, earthquakes in Iran occur often and are destructive. So, it is important to consider the seismic stability and reliability of all structures including tailings dams.In this study, the tailings dam stability of the Sangan Iron Ore Mine in Khorasan Razavi, Iran is considered for the case study. The tailings storage facilities of the mine have three cells with the capacity of 45 million cubic metres. The first cell, which has three stages of dam raising, has been recently brought into operation. This cell has a downstream-raised retaining embankment. As the risk of seismicity in this area is high, seismic response of this dam was evaluated by numerical methods. To do this, appropriate models were developed for materials used in foundation and body of the embankment. Then for seismic stability analysis, Tabas (Iran – 1978) and Chi-Chi (Taiwan – 1999) earthquake acceleration simulations were applied.The results of this study indicated that the upstream portion of Stage 3 of the dam and dam crest did not experience significant horizontal displacements during earthquake period, but the downstream portion of Stage 3 of the dam showed a maximum horizontal displacement of 60 cm at the third stage of dam raising. This is three times more than what was estimated by the designer. Also, the maximum vertical displacement resulting from simulation of the Tabas earthquake was 35 cm. The results of dam response to Tabas and Chi-Chi earthquakes indicate that displacement, shear stress and pore pressure by the Tabas earthquake were higher than the case of Chi-Chi earthquake. The higher energy of Tabas earthquake and the higher frequency near to the natural frequency of Tabas earthquake could be the reasons of this difference. The results of this case study confirm that if the studied tailings dam impacted by an earthquake of a similar magnitude to Tabas, the dam will be seismically stable and the developed strains will not be significant.CITATION:Delavar, A, Rashidi Nejad, F and Ganjian, N, 2015. Seismic stability analysis of Sangan Iron Mine Project tailings dam, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 173–182 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By TUIJA MONONEN, LUDGER BENIGHAUS, CHRISTINA BENIGHAUS, Virginia del Rio, SARI KAUPPI, JUHA M. KOTILAINEN, JAVIER GÓMEZ, JARI LYYTIMÄKI

The understanding of public debates over mineral exploration and mining largely originates from exceptional situations such as mining accidents of conflicts. Less is known about how mining is portrayed and understood under more conventional settings. What storylines dominate the local day-to-day public debate? This article presents results from a comparative case study focusing on newspaper coverage of mineral exploration and mining in three European countries representing different geological and socio-economic contexts. Newspaper articles from the Geyer-Erzgebirge region in Germany, the Andalusia region in Spain, and Northern Finland are studied. The sample looks into the period between September 2018 and February 2020 and shows that regional newspapers report about mining issues relatively intensively even in the absence of major accidents or other media events causing peaks of attention. The tone of the articles is generally neutral to positive towards mining activities, reflecting the specific local settings, historical experiences, and future expectations. Despite the different contexts of the three countries, there were considerable similarities to the topics highlighted, including common themes of mining revival, mining events and social interaction, history of mining, and damages related to mining. Past, present, and future employment opportunities related directly or indirectly to the mining sector are key storylines. Another recurrent underlying theme is the need to balance environment and safety risks and socio-economic prosperity, typically covered through ordinary disputes among the mining sector, public authorities, regional non-governmental organizations, and local initiatives.

Jul 6, 2021

I have headed this paper with a question and for the impatient among you ûthe answer is no we have not run out of developments but, and it is a big æbutÆ, we need to be innovative and ahead of the game or ænoÆ will be æyesÆ before we know it.Why do I believe that our future lies in innovation? Thirty years ago, knowledge doubled every 14 years. It is now doubling every seven years. In 1965, Gordon Moore, one of the founders of the chip maker Intel, made an observation that growth in memory chip performance is doubled every 18 months which became known as MooreÆs Law. Now there is fibre law, where the transmission line capacity doubles every nine months and storage capacity, under disc law, doubles every 12 months. What does this mean? Well, firstly there is a massive rise in information flow and availability with no limits in growth for at least the next ten years. Secondly, unlike our grandfathers, we are most unlikely to be employed by the same firm for our working career - we may not even have the choice to stay with the same company. In a phenomenon Richard Foster and Sarah Kaplan (2001), borrowing from Schumpeter, termed æcreative destructionÆ, companies are unable to sustain market-beating levels of performance for more than ten to 15 years. In the 1920s the turnover rate of companies in the United States was 1.5 per cent, so a company could employ almost three generations from the one family. A company had a half life of 60 years. In other words, you could well be in the same working environment as your grandparents. Today the churn rate is estimated to be eight to ten per cent. A company has a half life of five to six years. So for large companies, as an employer or employee or as a contractor, your working environment has a 50 per cent chance of changing in five years. Innovation is the driver of this rapid rate of change. Innovation is not for the faint hearted (Cutler, 2001) but it is the core for success in the global economy. The rate of change in our world is not going to decrease. We must learn, not only to manage change, but to enjoy the process of changing û to ride the tsunami of the knowledge economy.

Jan 1, 2002

The coal reserve base is defined for coalbeds having sufficient thickness for underground mining within a depth range compatible with economic recovery. The reserve data are compiled by the Federal Bureau of Mines by updating and reevaluating previous estimates of the U.S. Geological Survey, State geological surveys, and others. Through the application of computer techniques, the tonnages are compiled by State, county, coalbed, and rank. Coal reserve base is allotted to sulfur categories by a statistical apportionment of data from available Bureau of Mines reports and records. The coal reserve base in those States east of the Mississippi River, minable by underground methods, is estimated to be 169 billion tons in coalbeds greater than 28 inches in thickness to a maximum depth of 1,000 feet. Excluding those coals in reliability categories other than measured and indicated, the underground reserve base includes 162 billion tons of bituminous coal and 7 billion tons of anthracite. Of the total, 27 billion tons contains 1.0 percent or less sulfur. Most of this low-sulfur coal is in the southern Appalachian area. Approximately 16 percent of the underground reserve base is without available analyses. Included in this report is a glossary of terms applicable to a classification system for coal resources and reserves. The purpose of this system is to provide a common yardstick for determining coal resources and reserves.

Jan 1, 1974

By Meimei Zhang

In the overall open pit mine planning process, mining phase design is a strategic driver in guiding and constructing the block extraction sequence and determining the annual net cash flow distribution. Mining phase design should obey some practical constraints, such as ?minimum mining width? and ?flat mining phase bottom?, to allow space for haul road development and truck and shovel access on each bench. However, these practical mining phase design requirements are not taken into account in all first-cut mining phase design methods and post-processing is always required to convert an impractical design to a practical one, resulting in a potentially significant loss of Net Present Value (NPV) relative to the first-cut impractical designs. In this paper, we present a method using a meta-heuristic algorithm ? Simulated Annealing ? to enforce those practical constraints in determining a mineable phase design whilst ensuring minimum NPV loss.

Oct 1, 2009

By J. E. Ryan

General Description Due to the extreme cold weather experienced in Flin Flon during the winter months, thought and precaution were necessary in the design of the plant buildings. The machine shop, carpenter shop, drill shop, and coal plant buildings are similar in the building materials used in their construction. They are sided with two-inch shiplap, insulated with celotex and asbestos paper, and covered with corrugated iron on all side-walls. Roofing consists of 2 by 4 lumber on edge, laminated, and further covered by celotex and three-ply roofing. These buildings are heated by means of unit heaters. The heaters are primarily steam-heated radiators, through which the air of the buildings is circulated by electrically-driven fans. Our machine shop is located to the east of, but central to, the main operating buildings of the mine and plant, and is so connected by a net work of tracks as to be able to serve all portions of the entire plant conveniently. The building is divided into two bays, the main bay 53 ft. by 340 ft., and the east bay 24 ft. by 340 ft. The shop office and drafting room, a two-story annex 24 ft. by 30 ft., is located on the west side of the shop. The arrangement within the shop is such as to house conveniently the several departments, namely, heavy machine tool section, repair floor section, boiler shop heavy tool and floor section, blacksmith heavy tool and forge section, tool room, electric welding rooms, stock room, tin and copper shop, and electrical parts and armature winding and repair shop (see Figure 1). All the heavy tools, the repair floor section, and railway tracks are so located in the large open bay as to be fully serviced by an electrically operated 15-ton bridge crane, with a span of 50 feet and a travel the full length of the shop. A standard-gauge railway track, branched off the main line, penetrates the full depth of the building. This track lies along the extreme east side of the main bay, allowing easy entrance and movement of rolling stock and heavy machinery, loaded on standard flat-cars, to the repair floors in the main bay. Eight jib cranes, affixed to building columns, further facilitate the heavy repair work throughout the various shop divisions. Our light and heavy machine tools are standard equipment, not unlike tools used in mine, mill, and railway shops.

Jan 1, 1935

By E. J. Karges

[For reasons well known to Mining Engineers, fine grinding in the wet form is quite universal inn plants engaged in the traction of metallic values from crude ore In the processing, of non-metallic and industrial minerals, however, fine grinding in dry form is the more common method. The crude materials generally contain less moisture than required for wet grinding, and the products are usually marketed or used in the dry form, most of them as powders. To grind wet would therefore entail the addition of water and the expense for drying the product, which is not justified. This paper will concentrate on the particle size reduction or fine grinding of materials to produce a dry powder]

Jan 1, 1963

By L. L. Oden

The U.S. Bureau of Mines and the Department of Energy (DOE), through its contractor EG&G Idaho Inc., are collaborating on a multiyear research project to evaluate the applicability of three-phase, electric arc furnace melting technology to vitrify materials simulating low-level radioactive and mixed wastes buried or stored at the Idaho National Engineering Laboratory and other DOE sites. The melter is a sealed, 1-t (1.1-st), three-phase, 800-kV?A electric arc melting furnace with 10.2-cm-(4-in?) diameter graphite electrodes, water-cooled roof and sidewalls, and four water-cooled feed tubes. A water-cooled copper fixture provides for continuous tapping of slag. An instrumented air pollution control system (APCS) with access ports for analysis and a feeder based on screw conveyors and a bucket elevator are dedicated to the facility. Test data are provided by an arc furnace analyzer and by sensors indicating feed rate; slag temperature; and temperature, pressure, and velocity in the APCS. These data are received by a data logger, digitized, and transmitted to a personal computer for storage and display. This unique waste treatment facility is available for public and private use on a cost-sharing basis.

Jan 1, 2010

By G K. N Subasinghe

Metallurgists operating Knelson Concentrators (KC) often rely on manufacturerÆs recommendations for selecting operating parameters, such as fluidising water flow rate and cycle time. Recent studies have shown that these parameters are not only dependent on the machine parameters but also on the feed characteristics, such as size distribution of the gold and gangue particles and the composition of its constituent minerals. It is known that a particle entering a KC initially traverses a circular path within the bowl. For a particle to maintain a given orbit, the required centripetal force must be supplied by external means. It has been argued that this centripetal force, which is dependent on the mass of the particle, its radial position and the rotational speed of the bowl, is provided by the fluid drag force created by inwardly moving fluidising water and the BagnoldÆs force created by the particle/particle collisions. Depending on the fluidising water flow rate, one of two situations can occur where the porosity of the bed increases or decreases, which influences the amount of material retained within the bowl. The amount of material of a given size and density retained in the bowl is thus dependent on the extent of the centripetal force provided. Based on the above concept, a criterion that can be used to predict the amount of material recovered in the bowl has been derived and validated by experimental data. It may also be construed that this criterion demarcates the transition of the bed from a packed-bed state to a fluidised state. By identifying the transition values for the different constituent mineral particles in the feed, it is possible to estimate the optimal fluidising water flow rate that would maximise gold recovery while minimising gangue recovery. In addition, the kinetics of gangue displacement by incoming heavy mineral particles were also studied using synthetic mineral mixtures. The experimental data suggests that this process follows first order kinetics and that the build-up of heavy mineral reaches a maximum. A model has been proposed to predict the optimal batch cycle time for a KC in terms of the feed characteristics and machine operating parameters.

Jan 1, 2006

By Scott Honan, Tassos Grammatikopoulos, Mike Johnson, Kelton Smith, Niels Verbaan, Ernesto Bourricaudy, Eric Larochelle, Rick Sixberry

"NioCorp is developing the niobium/scandium/titanium Elk Creek carbonatite resource deposit. The carbonatite phase contains significant niobium (0.71% Nb2O5), titanium (2.68% TiO2) and scandium (72 g/t) and is composed predominantly of calcite, dolomite and ankerite. Niobium is mostly (80%) contained in the pyrochlore and the balance in various Fe-Nb-Ti oxides, which also host most of the titanium. Scandium is distributed homogeneously throughout the ore mineral assemblage. The process flowsheet recovers separate niobium, titanium and scandium products. Scandium is extracted from whole ore hydrochloric acid leach solutions through solvent extraction, and is further refined through a re-leach and precipitation process. Scandium leach residues are treated with sulphuric acid to recover separate niobium and titanium precipitates. Both hydrochloric acid and sulphuric acid reagents are recycled within the flowsheet. This paper will discuss key bench and pilot test results (focusing on the scandium flowsheet) and will present a conceptual flowsheet developed by the project team for NioCorp at SGS Minerals.INTRODUCTION NioCorp is developing North America's only niobium/scandium/titanium project. The Elk Creek project is located near Elk Creek, Nebraska, and is the highest grade niobium project in North America and the largest prospective producer of scandium in the world. These elements are unique and valuable superalloy materials that are strategic and critical to many industries and national defense technologies. The project includes the Elk Creek Carbonatite (the Carbonatite) that intruded older Precambrian granitic and low to medium grade metamorphic basement rocks. Both the carbonatite and Precambrian rocks are interpreted to be unconformably overlain by approximately 200 meters (m) of Paleozoic marine sedimentary rocks of Pennsylvanian age. As a result of this thick cover, there is no surface outcrop within the Project area of the carbonatite, which was identified and targeted through magnetic surveys and confirmed through subsequent drilling. The available magnetic data indicate dominant northeast, west-northwest striking lineaments, and secondary northwest and north oriented features that mimic the position of regional faults parallel and/or perpendicular to the Nemaha Uplift."

Jan 1, 2017

By A. K. Snelgrove

At a time when water resource planning is proceeding on a continental scale, such as the proposed $100 billion North American Water and Power Alliance, which would redistribute water among three nations, including seven provinces of Canada, 35 of the United States, and three States of Mexico, the selection of a single river basin for study may seem to require an apologia. None is offered because of ( 1) the magnitude of the Indus , itself a part of the great Indo-Gangetic Plain drainage system, with Himalayan sources, upon which the thickly populated northern sub-continent of Indo-Pakistan depends for agriculture and hydroelectic power; (2) the extraordinary problems created by dismemberment of the world?s largest irrigation system through legal beheading of the Eastern Waters under the Indus Waters Treaty of 1960; and (3) the herculean effort to contain the twin encroachments of waterlogging and salinization in a basin which faces a shortage of fresh water. The British irrigation system of barrages and canals on the Indus was a venture admirable in conception. Unfortunately, it is now a legacy burdened with unwanted consequences, due to interference with the hydrological regimen, particularly the rise of water table occasioned by leakage.

Jan 1, 1967

By F. F. Aplan

Separation of the slightly soluble minerals (Ksp? 10-10), one from the other is one of the more difficult tasks confronting flotation engineers. This study has focused on means of separating such prominent members of this class as scheelite, fluorite and calcite from one another. Some experimental work has also been done on the minerals magnesite, dolomite and apatite. Carboxylic acid-type collectors are commonly used industrially to float all of these minerals. Thus, the problem at hand is to ascertain means of achieving selectivity between minerals known to respond rather similarly in flotation. Four techniques have been proposed for the separation of minerals of this class from each other: 1. Control of potential determining ions 2. Use of stereo-specific collectors 3. Use of flotation rate differences 4. Use of selective activating and depressing compounds. This study was directed toward a cursory evaluation of each of these techniques, and each was found to be a possible method of achieving selectivity. Stereo-specific collectors -- those whose parking area may closely match the available adsorption site on one mineral but not on another -- are a possible means of achieving selectivity between scheelite, fluorite and calcite. Stereo-hindered carboxylic acid salts and sulfonates all show selectivity between the three minerals tested. Separations also appear to be possible by the controlled use of the lattice ions (e.g., Ca and [W0=4] for scheelite, CaW04), H+, [OH-, C0-3 and HCO=3]; all of them ostensibly potential determining in the systems studied. Flotation rate differences of the minerals as a function of pH under conditions of starvation collector usage also showed promise. Scheelite and fluorite float most rapidly with sodium oleate in slightly acidic (pH 4-7) solutions whereas calcite floats most rapidly near pH 10. Use of Mn++, Pb++, or other heavy metal hydroxy complexes as activators was seen to effect each of the slightly soluble minerals differently. This is in sharp contrast to the oxygen containing, relatively insoluble minerals, where all minerals respond in a similar manner to such activation procedures. Results indicate that all four methods outlined above may potentially be used to achieve flotation separation of the slightly soluble minerals. More extensive research should be undertaken to detail the spcific applicability of each of the procedures and to make a more complete evaluation of the effect of collector type and concentration, mineral type, pH and size effects.

Jan 1, 1983

By R. R. Rollins

Field data combined with theoretical derivations were used to design a surface mining operation using explosive casting. Calculated casting results varied from 44 to 65% depending on bench height. This model was then applied to field tests at an eastern, contour, coal stripping operation. Results from five experimental casting shots are summarized and compared to conventional mining methods. The overburden material removed by casting ranged from 35 to 65% with an average of 50%. Fragmentation was improved and it was demonstrated that this procedure is economically attractive with a resultant cost savings of $.59/m3 or $5.93/t of clean coal.

Jan 1, 1987

By W. D. Mcmillan

"Magnetic surveys made by the Missouri Bureau of Geology and Mines in 931 and 1932 disclosed a large positive anomaly about a mile south of Bourbon, Mo. 3/ Electrical resistivity measurements made by the Division of Geophysical Exploration of the Bureau of Mines in the winter of 1942-43 indicated that the source of this anomaly was in the pre-Cambrian rhyolite at a depth of more than 1,400 feet. 4/In order to determine the character of the material that caused the magnetic anomaly, which might be either a body of magnetite or a large intrusive of basic rock, the Bureau of Mines drilled four holes to depths of 1,800 to 2,300 feet. Magnetite in rhyolite porphyry was encountered at 1,600 to 2,000 feet, and this is doubtless the main source of the magnetic anomaly, although it is possible that additional iron ore exists at greater depth.Hole 1 was apparently located southeast of the source of the anomaly and encountered only small stringers of magnetite. Hole 2 penetrated four mineralized zones having a total thickness of 125.7 feet and an average weighted content of 43.52 percent iron and 31.62 percent silica. These zones were tested again by a deflection hole, 2A, which gave nearly identical indications. Hole 3, 500 feet north of hole 2, penetrated 58 foot of mineralized rhyolito containing an average 43.4 percent iron.Metallurgical tests showed that the silica in the ore is tightly locked with the magnetite. After grinding to minus 100 mesh, a 66 percent iron con¬centrate with 7 percent silica was obtained by flotation."

Oct 1, 1946

By A. G. Loomis

Although secondary-recovery methods have not been applied widely in California, it is apparent that increasing attention and effort must be given to this phase of recovery if the State is to maintain its high rank as a petroleum producer. Steadily increasing demands for petroleum products and decreasing rates of discovery of new oil fields, with rapid depletion of existing reserves, emphasize the prospect of an adverse situation of supply and demand in the not-far-distant future. If the trend of discoveries becomes more favorable or if more complete economic recovery of the oil in place can be obtained by secondary recovery, this situation can be averted. Not only are these reserves of economic importance to the petroleum industry for meeting increasing market demands; but economic reclamation of such reserves is an important conservation measure, which will prolong the productive life of many fields. Accordingly, progressive operators in California are alert to the possibilities of secondary recovery and have done much to implement such operations wherever feasible. Most current operations are of the pressure-maintenance type, in which the reservoir pressure is maintained or partly maintained by injecting natural gas to in-crease oil recovery. The possibilities of recovering additional oil from stripper fields by gas drive and water flooding (including water disposal) also are being tested in experimental field projects. Table 1 summarizes current gas-and water-injection projects in California.

Jan 1, 1952

By M D. Taylor, G Duclaux, K Atkinson, L A. Fisher, A R. Latham, M F. Gazley, S J. de Beer, C M. Tutt

Geological logging by mine and exploration geologists involves the application of a logging code that requires a geologist to make a subjective decision to classify a particular rock unit. This will most likely result in inconsistencies in logging that will be difficult to monitor or assess over time. A potential solution to this problem is to have an objective method to determine the true nature of a given rock unit. This can be achieved using portable X-ray fluorescence technology (pXRF), as large geochemical data sets can be collected rapidly and at low cost. Plutonic Gold Mine (Plutonic), Western Australia, has a growing data set of more than 150 000 pXRF multi-element analyses from core and underground face samples, reconciled to Au fire-assay concentration, and logging codes. This study investigates and statistically validates the consistency with which the logging codes have been applied at Plutonic for the last four years, with respect to both Au distribution and other elements. In doing so, we have developed a schema that allows objective logging to occur once core has been sent for assay and analysed by pXRF. While far from replacing the geologist in the field, this is a complementary method that adds significant value to a data set.CITATION:Gazley, M F, Tutt, C M, Latham, A R, Duclaux, G, Fisher, L A, Taylor, M D, de Beer, S J and Atkinson, K, 2013. Objective geological logging using geochemical multi-element data - Plutonic Gold Mine, Western Australia, in Proceedings World Gold 2013 , pp 455-462 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Caio Moreira, Saulo De Rezende, Nelly Ruíz

The present project sought alternatives for this material through the Mining Lab Beginnings program, which was developed by Nexa in partnership with Escalab to find solutions for the company's highly complex challenges. Through the program, several solutions were evaluated, with additives for the construction market being the most prominent. Tests were conducted to confirm the efficiency of jarosite in the mixture that composes this material. With successful laboratory tests, the technology was tested on an industrial scale, where it also demonstrated its technical and economic viability. The project is now moving into the operational phase, demonstrating that circular economy is the best solution for disposed tailings.

Sep 29, 2023

By H. A. Doerner

"During the year which has passed since the last progress report on reduction of zinc by natural gas,3 the laboratory experiments on this investigation have been completed. In this concluding report, the whole subject will be reviewed and additional data presented.Chemical ReactionsIn a thermodynamic study of zinc smelting, Maier 4 discussed the use of methane for reducing zinc oxide, and predicted equilibria at various temperatures for the sore important reactions. The study has been extended to include the following list.Maier predicted that 870°C. would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1) at equilibria would be substantially complete at or above 927°C. A subsequent papers described experimental verification of these predictions and gave data on reaction rates under various conditions.It methane is passed through a heated bed of zinc oxide at a low enough rate reactions (1), (3), and (4) reach an equilibrium which can be expressed by reaction (10). The equilibrium concentrations for the products of this reaction in the temperature range 900° to 1100°C. were calculated by applying the thermodynamic constants to the stoichiometric relations. 6 The results of these calculations are listed in table 1 and shown graphically in figures 1, A and B. These data have major importance, and experimental work has shown that they are subtantially correct."

Dec 1, 1934