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By Marc-André Villiard, C. St-Onge, V. Silla, J-C Milot

Rio Tinto Fer et Titane (RTFT) operates a metallurgical complex in Sorel-Tracey, Canada. In the Ore Preparation Plant (OPP), ilmenite ore is roasted through four parallel rotary kilns generating 95% of the plant wide sulphur dioxide (SO2) emissions. RTFT proactively set an annual emission cap for SO2 to be achieved by 2015. To achieve this targeted SO2 reductions, a technology evaluation and selection exercise was carried out, followed by detailed engineering and implementation. After a detailed evaluation of SO2 scrubbing technologies, the Circulating Dry Scrubber (CDS) system was selected as the most appropriate desulphurization system for this application. The system was implemented and commissioned from 2013 to 2015. General performance testing conducted in May 2015 demonstrated that the system achieved and surpassed the anticipated design values in terms of SO2 removal efficiency and hydrated lime utilisation. This paper summarizes the SO2 technology selection process, design features of the selected technology, project implementation and final performance testing of the SO2 abatement system.

Jan 1, 2015

By Roger V. Pierce

IN the last few years, much study has been devoted to increasing stoping efficiency. The reasons for this are shortage of manpower, shorter working hours, operating regulations, and shortages of essential materials. More efficiency in mining methods is needed to offset these adverse factors. In the past, attention has been centred upon haulage, hoisting equipment, mill flow-sheets, etc., but recently the spotlight has been focused on the cost of stoping and the cost of handling materials. Scrapers and scraper hoists have thus assumed greater importance. In order to make it possible for certain orebodies to be mined at a profit, it has been necessary to apply assembly-line practices to the streamlining of mining methods. All cycles of the mining operation must balance, and the sooner broken ore is removed from the working face, the sooner another round can be started. Since the introduction of scraper hoists in metal mines more than thirty years ago, much progress has been made in their design and application. Alert operators are now constantly watching for methods in which to apply scrapers. The saving of manpower in development work and the changing of mining methods that once employed manual handling of materials are increasing vital wartime tonnages. Essential ores from newly discovered orebodies are moving rapidly from stopes to reduction plants-because it is now possible to develop an orebody and place it in production with a minimum of manpower and development work. Today, speed is one of the prime essentials o mining. Everywhere, there is a concentrated effort to use experienced miners in breaking rock, in timbering, and in carrying out the various phases of mining that require many months of training. Much effort is being made to mechanize the working places because experienced men naturally prefer to work where the majority of materials are handled mechanically. In line with this policy, many new men are being taught the details of scraper work, because even green men can quickly become acquainted with scrapers and thereby release older heads to perform the more skilled phases of mining.

Jan 1, 1943

By G. A. Brady

Laboratory tests were conducted to determine the technical feasibility of separating anthracite particles from a water-anthracite slurry by atomizing the water and removing the resulting mist in an air current. Products containing 21 percent or less moisture were obtained from slurries made with minus 60-mesh anthracite. Typical recoveries ranged between 67 and 79 percent of the feed when the slurries were atomized in air currents with velocities below 70 ft/min.

Jan 1, 1967

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations regarding the use and testing of cage safety catches, including a brief history and evolution. Regulations are similar across provinces, with only slight variations. Currently, the “Ontario-type” safety dog is the most commonly used safety catch in Canada. Performance estimation of the compensation mechanism for different safety-dog shapes and tooth angles show this shape works well and has consistent braking results, but the best efficiency is obtained for initial tooth angles greater than 10°. Miner safety is questionable for lightly loaded cages, an issue that should be addressed technically and legislatively.RÉSUMÉ Le présent article compare les diverses réglementations de sécurité minière concernant les parachutes des cages dans les provinces canadiennes ainsi que les essais qu’ils doivent subir. Il semble que les réglementations soient semblables à travers les provinces avec quelques légères différences ou divergences. Un bref historique des parachutes et de leur évolution est présenté. De nos jours, le parachute de « type Ontario » est le plus fréquemment employé à travers le Canada et il présente des résultats de freinage uniformes. Une estimation de la performance du mécanisme de compensation pour les diverses formes de taquets de sécurité et les divers angles des dents montre que cette géométrie fonctionne bien; cependant, la meilleure efficacité est obtenue pour des angles de dents supérieurs à 10°. La sécurité des mineurs est mise en jeu pour des cages faiblement chargées et ce point devrait être traité du point de vue technique et du point de vue législatif."

Jan 1, 2016

By Jose Luis Vega

Ante la desaparición del bosque seco tropical de Piura por factores como el sobrepastoreo y la tala indiscriminada del algarrobo para abastecer el mercado de leña y carbón, se desarrolló el "Proyecto de Forestación y Manejo Forestal Comunitario en las Áreas de la Mina de Fosfatos Bayovar" donde se buscó reforestar y promover un manejo sostenible de 350 hectáreas de bosque seco despoblado. El proyecto tiene una duración de cuatro años y se gesta bajo el desarrollo sostenible que mejora la calidad de vida de los pobladores -en tanto contrata mano de obra local de la zona de Illescas-Sechura y aprovecha los nuevos recursos, así como genera un equilibrio ambiental, propiciando el cambio de un paisaje despoblado por el de un bosque que sirve de hábitat para diversas especies de flora y fauna y en el que se evita la erosión del suelo y propagación del polvo.

Oct 21, 2015

By Dominic Parmantier, Jason Page

"In the past, the designers of DSM have analyzed various failure modes and then specified a minimum unconfined compressive strength (UCS) for the soil-cement. The specified minimum UCS reflected the compressive stress in the soil-cement under design loads and an appropriate factor of safety. With the increased use of finite element analysis for the design of DSM applications where allowable strain as well as stress are considered, there is a growing trend for designers to specify a modulus and occasionally a tensile strength for the soil-cement in addition to the UCS. This paper compares the relationship of modulus and tensile strength to UCS for soil-cement from a recent DSM project with unique testing requirements. These results are compared to published data. The case is made that designers should utilize published relationships to characterize the required strength and stiffness by a single acceptance criterion: UCS.INTRODUCTIONAs the use of DSM has increased in popularity so has the use of service state deformation analysis in lieu of more traditional failure mode analysis. Most DSM designers are interested in the appropriate modulus values and occasionally tensile strength values of soil-cement as well as simply the unconfined compressive strength (UCS) of soil-cement.Although there are numerous published correlations between the UCS, tensile strength and modulus of soil-cement, some DSM project specifications are produced which have acceptance values for tensile strength, modulus, and UCS. If this specification of multiple strength properties is consistent with the nature of soil-cement, then there is really no harm except for the expenditure of client money on unnecessary testing. If however the multiple strength properties specified are inconsistent with the material properties of soil-cement, then the specifications can create the expectation that the DSM contractor can somehow create a custom soil-cement with tensile strengths and modulus characteristics which are unachievable.This paper presents a brief summary of a project in Burnaby, B.C. which specified minimum values for the tensile strength, modulus, and UCS of the soil-cement. A comparison of those test results to published correlations between the UCS and the tensile strength is presented. Additionally, a comparison of modulus derived from two different methods of testing is presented along with a comparison to published correlations between UCS and modulus for soil-cement."

Jan 1, 2015

By M. Friák, L. G. Wang, M. Šob, V. Vitek

"The paper gives an account of applications of quantum-mechanical (first-principles) electronic structure calculations to the problem of theoretical tensile strength in metals and intermetallics. First, we briefly describe the way of simulating the tensile test and the electronic structure calculational method. Our approach is then illustrated on calculations of theoretical tensile strength in W, NiAl and transition metal disilicides MoSi2 and WSi2 with C11b structure. In Wand NiAl, we consider uniaxial tension along [001] and [111] directions. Although tungsten is elastically nearly isotropic (C44 = C”), theoretical tensile strength exhibits a marked anisotropy (oth/001 = 29 GPa, o'th/111 = 40 GPa). Calculated results compare favorably with experimental value of 24.7±3.6 GPa obtained for tungsten whiskers grown along the [110] direction. Similarly, in NiAl, the 'hard' orientation [001] differs very significantly from the [ill] orientation (oth/001 = 46 GPa, oth/111 = 25 GPa). This anisotropy is explained in terms of higher-symmetry structures present or absent on the calculated deformation paths. In disilicides, the theoretical strength is calculated for [001] loading (oth/001 = 37 GPa and 38 GPa for MoSi2 and WSi2 , respectively). The role of relaxation of internal structure parameter is discussed and changes in bonding conditions during the tensile test are analyzed.IntroductionIn most engineering applications, the strength of materials is limited by the presence of internal defects. If there were no defects, then, for example, the tensile strength could be several orders of magnitude higher and its value would be comparable with that of shear modulus. Therefore, the strength of ideal (defect-free) crystal represents an upper limit of attainable stresses, which is called the ideal strength. While it may not be possible to achieve the ideal strength in practice, it is not possible to exceed it. However, the ideal strength is already approached in situations which are technologically relevant. These include the low-temperature deformation of inherently strong materials, such as diamond, Si, Ge and some of the transition-metal carbonitrides, deformation of whiskers, nanoindentation of materials with low defect densities, hardened thin films and coatings etc. The ideal strength sets the limits of elastic stability of a solid. Its knowledge is useful for estimation of the ideal work of fracture stresses needed for homogeneous nucleation of dislocations and for modelling of crack propagation."

Jan 1, 2001

By Prosser AP

The large body of knowledge about the relation between chemical process efficiency and mineralogical features is of only limited use. The profession ought to try to improve the methods of using information as well as adding to the knowledge. One attempt isòdescribed. Correlations between process efficiency factors and the mineralogical features of low- grade concentrates have been developed from both a theoretical analysis and experimental measurements. The ultimate recovery of a reactive phase in an inert matrix can be calcu- lated from simple measurements of the particle size, porosity and pore size of the concentrate, and the grain size of the reactive mineral., The rate of recovery, up to 98% recovery, can be calculated from simple measurements of particle size, porosity, proportion of reactive mineral and tortuosity. Some details are given. The correlations are of potential use in process selection and preliminary design. Satisfactory predictions have been made for near-ideal systems. Improvements in the measurement of pore size and tests on more realistic materials are required. The ultimate benefit of the correlations will be determined by the magnitude and frequency of the effects of mineralogical features other than those specified above.

Jan 1, 1975

By Choon K. Quan

Subsidence is a surface manifestation of the underground development and exploitation of minerals, and its impact on the environment is becoming of increased concern, particularly in the face of an accelerating demand for energy and minerals. In the United States, the state-of-the-art in subsidence prediction, control, and prevention and in subsidence-related damage abatement has not progressed to the level achieved in other countries. To bridge this gap, the Bureau of Mines, through its Mining Environmental Research program, is pursuing a comprehensive subsidence investigation, specifically designed to address major problems on the local, regional, and national level.

Jan 1, 1979

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

"Russia is among the nations holding the world's largest lithium ore reserves. Lithium is of key importance for the global economy. Therefore, it is important to review the current state of technology research aimed at finding the most effective solutions for the recovery of lithium from promising reserves in Russia. In Russia, a number of process solutions for the flotation of spodumene into salable concentrate (5% Li2O) have been implemented at the earlier existing complex low-grade ore concentration project. By applying these solutions, a sample of high-grade spodumene ore (4.7% Li2O) of the Greenbushes deposit was processed into a spodumene concentrate (7.5% Li2O) at a high recovery (~93%) of lithium. In Australia and Canada, new processes have been developed for the recovery of high-grade spodumene concentrates from high-grade ores using dense medium separation and flotation. For the recovery of mica lithium concentrates from low-grade ore, a flotation process was developed in Russia using the cationic collector ANP-2 and Oxifos-B as an additional collector. Low-grade ore containing 0.14% of lithium oxide was processed into a 2.7% Li2O concentrate. New hydrometallurgical lithium concentrate and ore processes are developed to avoid high-temperature (>1000 °C) roasting. The Sileach process (Australia) includes leaching of lithium ore with sulfuric acid in the presence of a halogen-containing component at a temperature of 95-115 °C. In the Russian process, lithium is recovered into an alkaline solution from low-grade spodumene ore in a pressure alkaline leaching environment (250 °C, NaOH concentration > 300 g/l). The developed concentration and hydrometallurgical methods will allow to design on their basis efficient processes for recovering salable products for hi-tech industries from lithium ores.INTRODUCTION Lithium has many unique and important properties. It is the least dense hard metal. Its alloys have some of the highest strength-to-weight ratios. Lithium has the lowest melting point of all known solid elements and is used as a highly-effective heat transfer medium. The high demand for lithium is due primarily to its unique electrochemical potential and low thermal expansion coefficient. It is used in the production of glass and ceramics, in petrochemicals, metals, medical and other industries. Since the late 20th century, the electronics industry has been the largest consumer of lithium. In recent years, lithium has attracted much attention also as an important component of ultra-lightweight electronic devices. It is also the preferred metal for electric batteries used in mobile electronic devices, vehicles, household power generators, making it an important resource for the development of environmentally friendly technology. Leading automotive brands have ambitious plans for the production of electric cars — Tesla Motors, VW, Toyota, GM, BYD Auto. It is expected that the production of electric vehicles alone will triple the demand for lithium by 2025. A sharp increase in the production of lithium is expected. Lithium has all the prerequisites to become a strategic resource of the 21st century. (Deutsche Bank, 2016; Bradley et al, 2017)"

Jan 1, 2018

By Helmut Antrekowitsch

Nowadays nearly the half of the world zinc production is used for galvanizing. After their life span most of the galvanized products return as scrap to the steel mill. During the steel process the zinc is collected in the flue dust It is astonishing to notice that between 40 and 50 % of the zinc produced is brought into the steel processing cycle by the coated scrap while only 3 to 5 % of the zinc production can be covered by the recycling of the zinc-bearing steel mill dusts. Responsible for this worse ratio is the fact that the established recycling technologies suffer from high energy consumption, low zinc yields, halogen problems and hardly any iron recovery. A development of new or an optimization of current recycling procedures for the dusts is unalterable because of increasing zinc amounts in these residues and the rising costs for the disposal. Different pyrometallurgical recycling technologies are tested in rotary kilns and vertical retorts at the Department of Nonferrous Metallurgy, University of Leoben, Austria. Various reducing agents from carbon monoxide to hydrogen and combinations are used. The results should make it possible to draw conclusions that allow an economical and ecological judgement of the different varieties. The goal is to support the affected industry to increase the low recycling rate and prevent a loss of high zinc values in the steel industry filter dusts.

Jan 1, 2003

By Richard L. Rains

The Bureau of Mines conducted a mineral investigation of the 29,000-acre Dixie Summit area near Elk City, Idaho, during the summer of 1989. At the Petsite mine a marginally economic, identified resource of 4.9 million tons with an average grade of 0.023 ounces gold per ton was delineated. Possible resources of gold, along with silver, copper, lead, and zinc, occur in at least eight other lode deposits. Placer gold may be recoverable by recreational-sized suction dredges in some stream drainages, Five lode mines in the study area have produced over 5,516 ounces of gold (placer gold production was not recorded), 4,757 troy ounces of sliver, 36,746 pounds of lead, and 3,800 pounds of copper. Current mining claims in or adjacent to the study area total 460 lode and 70 placer claims. There are two patented lode claims within the Dixie Summit study area.

Jan 1, 1991

By K. P. Gupta

In ternary systems containing silicon and transition elements, silicon was found to stabilize the a phase.1 At 1000°C a broad a-phase region was found in the Cr-Mn-Si system,1 which extends very close to the Mn-Si binary line (within about 3 at. pct Cr). Later investigation showed that, if chromium was replaced by small amounts (3 to 5 at. pct) of v,1 Ti, Nb, Ta, Mo, or w,1 the a phase or the R phase was again stabilized. Whether stabilization of complex crystal structures is possible by small additions of iron, cobalt, or nickel to Mn-Si is not known. Investigation of the Co-Mn-Si system4 shows the presence of several ternary phases, but at cobalt concentrations higher than 10 at. pct. In the present work the ternary systems Fe-Mn-Si and Co-Mn-Si were investigated at low iron and cobalt concentrations (< 7 at. pct Fe or Co) in search of phases of complex crystal structure. Experimental Procedure. The alloys were pre-pared by induction melting Co (99.8 pct), Si (99.9 pct), electrolytic Fe (99.88 pct), and Mn (99.9 pct) in recrystallized alumina crucibles under an inert atmosphere of argon gas. The alloy specimens were wrapped in molybdenum foil, sealed in argon-filled (at 1/2 atm) silica capsules and annealed for 72 hr at 1000" 1°C, and water-quenched. The use of argon-filled capsules was found to reduce the losses during annealing and the molybdenum foil prevented reaction of the manganese with silica. The total weight loss due to annealing and melting was found to be less than 1 pct for each alloy. The alloys were not analyzed chemically. A part of each annealed specimen was polished and examined metal-lographically using etching solutions, a) 0.1 to 0.5 pct oxalic acid solution in water, or b) 0.5 pct HNOs in methyl alcohol. Even though the etching solutions were quite dilute, the specimens were heavily etched and stained if the etching time exceeded more than 5 sec. Etching times found suitable were usually 1 to 3 sec. For X-ray diffraction work, a part of each annealed specimen was powdered by crushing after the exposed surface was ground off. X-ray diffraction patterns were taken with powder specimens using a 20-cm-diam asymmetrical focusing camera and Fe K radiation. These powder patterns were found quite satisfactory for the purpose of phase identification. However, X-ray diffraction patterns of single-phase alloy powder specimens were also taken using a Siemens diffractometer and filtered Cr-Ka radiation for greater resolution of the diffraction lines. Results and Discussion. In the Fe-Mn-Si system a new ternary phase was found at 1000°C between the p manganese and the MnsSi phase regions. The approximate phase relationships in this region of the 1000°C isothermal section are shown in Fig. 1. The new ternary phase, designated as the K phase, was found to occupy a narrow region about 1 at. pct in width and extending from Fee.oMn74.5Silg.5 to Fe.Mn.Silg.. At the high-iron content region, the K phase was found in equilibrium with the p manganese and the MnsSi phases but, at the low-iron content end of the K-phase region, the phases in equilibrium with the K phase were the p manganese phase, the MnsSi phase, and another new phase, designated in Fig. 1 as the v phase. The v

Jan 1, 1964

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

To reduce the environmental footprint of hydrometallurgical processing of black mass from spent lithium-ion batteries (LIBs), a green leaching system based on glycine and sodium metabisulfite (Gly-SMS) was proposed. The leaching study demonstrated that the highest cobalt and lithium recoveries of 100 percent and 99.8 percent were achieved under optimal conditions. The leaching mechanism revealed that the dissolution of LiCoO2 in the Gly-SMS solution followed the shrinking core model. The apparent activation energies for cobalt and lithium were determined as 48.05 and 41.51 kJ/mol, respectively, indicating a surface chemical reaction controlling mechanism. The leachate was then processed by an acidification- precipitation technique with oxalic acid as the precipitant to remove cobalt. Glycine complexes with metal ions by zwitterionic ligand and recycles in the leaching-precipitation circuit, reducing the reagent cost. Compared to other studies, this leaching system has near-neutral operating conditions and is cost-effective, making it an economically viable alternative for treating cathode materials from spent LIBs.

Dec 1, 2024

By Geo S. Rice

"The most authoritative compilations on the coal resources of the British Isles are given in ""The Coal Resources of the World"" issued by the 12th International Geological Congress, 1913. The reserve, calculated to a depth of 6,000 feet, in seams containing not less than two feet of merchantable coal are as follows: Mining at present is conducted at depths from about 800 to 3500 feet. The shallower coals have largely been exhausted. The present average hoisting depth probably is about 1500 feet.The thickness of individual beds at present mined varies from about 2-1/2 feet up to 40 feet in thickness, the latter thickness being found in North Staffordshire. The coal is rarely found level, but is approximately level in some parts of Yorkshire. Anthracite is mined in limited quantities in Wales, and Wales also produces a very high grade semi-anthracite or smokeless coal, which is fa famous the world round, and is equaled only by the Pocahontas and New River coals in the United States:As concerns the methods of mining, these vary widely according to the pitch of the bed, the thickness of coal, and natural conditions, but the prevailing method is some form of longwall or semi-longwall, by which all the coal is extracted. The other principal method is a so-called pillar and, stall method, by which the coal is mined out, leaving square or rectangular pillars which are extracted on the retreat, making it virtually, a retreating longwall system. This method is applied where the roof is strong, and particularly in the thicker beds, as the longwall method is not so well adapted for mining where the thickness exceeds five or six feet, unless it is what is called a multiple seam, one in which there are partings of rock that provide material for building walls, which the roof in subsiding gradually squeezes down."

Jul 1, 1920

By R. C. Gabler

Effective recycling or disposal of flue dusts is a continuing problem, particularly for secondary smelters treating low-grade Cu scrap. The Bureau of Mines investigated a variety of flue dust treatment approaches and demonstrated the technical feasibility of a bench-scale alkaline method that includes leaching, cementation, precipitation, and roasting. Flue dust was leached at room temperature with an alkaline solution of (NH4)2C03 and NHpH to solubilize ZnO and Zn metal. Some copper, lead, tin, and most of the zinc were dissolved in the leach step. Copper, lead, and tin were recovered in the cement product. The Zn in the flltrate was precipitated by pH adjustment to neutral using CO2 injection. The Zn salt was flltered from solution and roasted to give high-purity ZnO. The leach residue, enriched from 4.3 to lOA pct Sn, could find a ready market; the metallic cement product can be recycled back to the copper converter; and the high-purity ZnO product can be sold in several markets, leaving no material for disposal. The possibility for recycling of reagents, lower energy demand, and low environmental impact make this method economically and environmentally attractive for recycling secondary copper smelter flue dusts.

Jan 1, 1988

By Jan M. Mutmansky

Since 1973 when the first edition of the SME Mining Engineering Handbook was published, many significant changes have occurred in the US mining industry. The industry went through a fairly prosperous period immediately after 1973, but then many economic pressures came to bear on mining companies, particularly in the metal and coal branches of the industry. These pressures changed both the mining methods used and the general economics of the mining methods. As a result, the industry today is different in many ways titan it was in 1973. A general summary of some of the more important changes that have come about will be provided here as well as some assessment of the effects of these changes on the choices of mining methods. In the metal mining industry, the most significant trends were increased surface mining, the use of larger and more efficient equipment, and increased technology and automation. The primary impetus for these changes was unprecedented competition from foreign producers. In many cases, this competition came about because of the nationalization of foreign mines and the tendency for these mines to become a source of foreign exchange. Under these circumstances, the mines could be operated even though they were not profitable. As a result, domestic

Jan 1, 2008

By Oscar Rojas

"San Ignacio de Morococha S.A es una empresa que está innovando sus operaciones, por lo que cuando se dio la necesidad de mejorar el diseño de la malla de perforación para labores mineras subterráneas de un cuadrante de 4 m x 4 m; se inició un trabajo de investigación para poder aplicar el Modelo Matemático de Holmberg, para luego ser implementado en otras labores mineras del mismo cuadrante. Al realizar pruebas, se obtuvo resultados satisfactorios mostrando avances ya no de 2.75m, sino avances superiores a 3m. Paulatinamente se realizaron ajustes de la disposición de los taladros, burden y espaciamiento hasta unificar el nuevo diseño."

Sep 1, 2017

By Gusttavo Reis Leite Matos

Neste trabalho, a resistência à corrosão das ligas Ti-35Nb(0,0;0,5;1,0;1,5) Si e os metais puros, foram investigados em meio à saliva artificial fluoretada. Para tal, curvas de polarização, impedância eletroquímica, microscopia eletrônica de varredura (MEV), microscopia óptica (MO) e difração de raios-X (DRX) foram realizadas. O MEV e MO indicam que as amostras que contém Si apresentam maior ataque comparado aos metais puros. Esse fato foi confirmado através dos ensaios eletroquímicos onde foi possível observar que as ligas com a presença do Si apresentam menor resistência de polarização (Rp) e não passivam a superfície do material.

Oct 30, 2017

By J. P. Nielsen, H. Margolin, E. Ence

The Ti-Ni phase diagram has been investigated up to 68 pct Ni with iodide titanium base alloys by metallographic, X-ray, and melting point methods, and from 68 to 90 pct Ni by examination of as-cast structures of sponge titanium base alloys. NVESTIGATION of the nickel-rich portion of the I Ti-Ni phase diagram was first reported by Vogel and Wallbaum in 1938.&apos; This work was subsequently extended to lower nickel contents by Wallbaum&apos; who indicated the possibility of a eutectic reaction for nickel contents below 38 pct. Long et al.3 studied the titanium-rich portion of the phase diagram and found eutectic and eutectoid reactions below 38 pct Ni. However, the temperature of the eutectic indicated by Long et al. was considerably lower than that suggested by Wallbaum. Long and his coworkers synthesized their alloys by powder metallurgical techniques and encountered oxygen and/or nitrogen contamination. Thus the diagram which was obtained did not represent binary alloying conditions. However from these results the features of the binary diagram were predicted. At Battelle Memorial Institute4 the Ti-Ni diagram was investigated up to approximately 11.5 pct Ni with sponge titanium alloys. The range of temperatures used was not sufficient to define the eutectoid temperature or composition. The data of Wallbaum2 and Long et al.8 were of particular interest for the present study, and although the work was originally concerned with the region below 40 pct Ni, the investigation was extended to higher nickel contents in an attempt to resolve the differences between these workers. Experimental Procedure Preliminary work on the Ti-Ni system was carried out with duPont Process A sponge titanium alloys to reduce the amount of subsequent work to be done with iodide titanium base alloys. The sponge titanium used contained 99.71 to 99.77 pct Ti, 0.1 pct Fe and 0.005 to 0.009 pct Ni. The iodide titanium obtained from the New Jersey Zinc Co. contained 99.9 to 99.95 pct Ti. Nickel used with sponge titanium was 98.9 pct pure. The high-purity nickel alloyed with iodide titanium was cobalt-free with approximately 0.05 pct C and was obtained through the courtesy of the International Nickel Co. The 15 g sponge titanium charges for melting were prepared by compacting in a die or by placing the weighed portions of nickel and titanium directly into the furnace. Iodide titanium charges were made by drilling holes in the as-received rod and inserting the nickel or by wrapping the nickel in sheet. Sponge titanium alloys containing from 0.2 to 90 pct Ni and iodide titanium alloys containing 0.2 to 68 pct Ni were prepared by these methods. In addition to these alloys several 1/2 1b sponge titanium alloys were supplied by the Allegheny Ludlum Co. The charges were melted in an arc furnace under an argon atmosphere. The procedures used were similar to those reported in the literature5,&apos; and the furnace has been described.&apos; Except for iodide titanium alloys with 40 to 68 pct Ni (see section on copper contamination), each alloy was melted for 1 min, then either turned over or broken before re-melting for an additional minute. Currents of 200 to 400 amp were used depending on the melting point of the alloy. Prior to heat treatment, alloys containing less than 14.5 pct Ni were hot-forged at 750°C. With the exception of alloys in the homogeneity range of the compound TiNi, alloys of higher nickel contents could not be hot-forged. Heat treatment of iodide titanium base alloys was carried out in argon-filled quartz capsules which were broken under water at the conclusion of heat treatment to quench the specimens. Temperatures were controlled to ±5oC and annealing times up to 48 hr were used. For melting point determination, specimens were placed in carbon crucibles which were in turn en-capsuled in argon-filled quartz capsules. The start of melting was determined by rounding of corners and by metallographic examination. Complete melting was considered to have occurred at that temperature at which the specimen assumed the shape of the crucible. Specimens were prepared for metallographic examination by mechanical polishing or by an electrolytic procedure." For alloys containing up to 80 pct Ni Remington A etch7 50 pct glycerine, 25 pct HNO,, 25 8 HF) was used. For higher nickel alloys aqua regia and Carapella&apos;s etch (5 g FeCl,, 2 ml HNO,, and 99 ml methyl alcohol) were employed. Specimens to be exposed for powder patterns were prepared by filing, by breaking specimens in a

Jan 1, 1954