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The present study investigates the nature of gold mineralogical distribution and association in a Cu-Au flotation circuit (1.6 g/t Au, feed head grade). The approach used in this study involves a combination of bulk gold assay and quantitative X-ray diffraction (QXRD), on a size-by-size basis, followed by QEMSCAN analysis on the -75+53 µm, -53+38 µm and -38+20 µm size fractions. The QXRD and QEMSCAN analysis showed that gold mineralogy is complex and fine-grained in the flotation feed, particularly in the -38+20 µm size fraction. Gold and pyrite concentration follow each other closely, suggesting gold-pyrite association. Quartz as the major gangue mineral shows a bi-modal distribution with respect to particle size. The identified gold particles were completely locked (~94 %) in pyrite as fine inclusions and 6 % locked as complex aggregates (-75+53 µm size fraction) whereas in the -38+20 µm size fraction, the identified gold grains occur as fine inclusions (~1-3 µm) within pyrite and silicates. However, in the intermediate size fraction (-53+38 µm), 75 % of the identified gold grains (10-22 µm) were over 90 % liberated and 25 % associated and locked in pyrite and complex aggregates (~2-4 µm). The identified gold grains in the -53+38 µm size fraction occurred as native and electrum with varying silver concentration between 8 and 20 % by weight. In the -38+20 µm size fraction, a gold telluride was also identified. Based on the mineralogical analysis of the feed, possible flotation strategies are discussed. Optimizing the flotation of pyrite is suggested as the primary Au recovery strategy. Keywords: flotation, pyrite, gold, liberation, QXRD, QEMSCAN

Sep 1, 2012

By J. Dubinski

Underground mining of copper ore in the Legnicko-Glogowski Copper District basin generates a number of seismic events, whose energy often exceeds 108 J (Butra, 2010). The number of tremors and their location shows that the area of rock mass involved in the deformation and failure processes significantly exceeds the area of mining operations. Locations of seismic foci of high energy tremors, as well as the aftershocks that accompany them, extend hundreds of metres, confirming that processes to restore the energy balance of rock mass occur in a short amount of time and over a wide area. Thus, an area of similar size should be considered in predictive analyses of the tremor?s position. It should be emphasized that a large portion of the rock mass still has a level of freedom resulting from the way the rock mass is held together and its geometric continuity. This level of freedom is dependent on the scale and duration of mining, the number and size of natural structures, and rock mass pressure, including gravitational pressure constricting individual fragments of rock mass in the area (Burtan, 2012). It can therefore be assumed that in real conditions, areas where mechanical strength of the layers has been exceeded may be located a considerable distance from each other and do not necessarily need to coincide with the working area location. In this sense, a rock mass influenced by mining exploitation is essentially a rock mass in which numerous fragments with concentrated energy exist simultaneously. Energy will be released within these rock mass areas each time rock mass strengths are exceeded by the induced stress changes related to mining operations. This paper presents a discussion on how to predict the location of seismic activity areas based on a change of position of seismic energy equivalents. This parameter is calculated for a given set of seismic tremors with defined foci coordinates. For a given set of seismic tremors, the location of seismic energy equivalents may be used for predicting the location of high-energy seismic events.

Aug 1, 2013

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

C THRM 1 C CALCULATION OF MINE HEAD LOSSES FROM ALTIMETER SURVEY DATA TURN 2 C PENNSYLVANIA STATE UNIVERSITY - MINERAL ENGINEERING DEPARTMENT THRM 3 C THRM 4 C THRM 5 C THIS PROGRAM CALCULATES PRESSURE LOSSES USING THERMODYNAMIC RELATION- THRM 6 C SHIPS BASED ON POLYTROPIC FLOW BETWEEN STATIONS. FOR REFERENCE SEE THRM 7 C "A NEW TREATMENT OF MINE BAROMETER SURVEYS" BY M. J. MCPHERSON IN THRM 8 C 'THE MINING ENGINEER' NO. 109, VOL. 129, P 23. THRM 9 C THRM 10 C THRM 11 C THRM 12 C IDENTIFICATION OF ARRAYS THRM 13 C NOTE THE PROGRAM HAS BEEN DIMENTIONED FOR FOURTY (40) DATA POINTS THRM 14 C BASEC(6;2) BASE INSTRUMENT TEMPERATURE CORRECTIONS THRM 15 C TRAVC(6,2) TRAVERSE INSTRUMENT TEMPERATURE CORRECTIONS THRM 16 C BASER(I) BASE INSTRUMENT READING THRM 17 C TRAVR(I) TRAVERSE INSTRUMENT READING THRM 18 C TDRY(I) DRY BULB TEMPERATURE AT TRAVERSE STATION THRM 19 C TWET(I) WET BULB TEMPERATURE AT TRAVERSE STATION THRM 20 C ELEV(I) ELEVATION AT TRAVERSE STATION THRM 21 C VEL(I) AIR VELOCITY AT TRAVERSE STATION THRM 22 C TBDRY(I) DRY BULD TEMPERATURE AT BASE STATION THRM 23 C BASC(I) BASE READING CORRECTED FOR INSTRUMENT TEMPERATURE THRM 24 C TRAV(I) TRAVERSE READING CORRECTED FOR INSTRUMENT TEMPERATURE THRM 25 C BBASE(I) TEMPERATURE CORRECTED BASE READING IN BAROMETRIC THRM 26 C PRESSURE THRM 27 C BTRAV(I) TEMPERATURE CORRECTED TRAVERSE READING IN BAROMETRIC THRM 28 C PRESSURE THRM 29 C BTRAVS(I) BAROMETRIC TRAVERSE READING CORRECTED FOR ATMOSPHERIC THRM 30 C CHANGES THRM 31 C RELHUM(I) RELATIVE HUMIDITY THRM 32 C ASW(I) AIR SPECIFIC WEIGHT TURN 33 C R(I) GAS CONSTANT FOR MOIST AIR THRM 34 C STPRES(I) STATIC PRESSURE CHANCE BETWEEN STATIONS (I) AND (1-1) THRM 35 C TOPRES(I) TOTAL PRESSURE CHANCE BETWEEN STATIONS (I) AND (I-1) TURN 36

Jan 1, 1977

By B. Bichel

For the last 70 years, molten blister copper has been transferred by rail in hot metal cars from the Copper Cliff Smelter to the Copper Cliff Copper Refinery (ex Ontario Refining Company) where it was processed in two (2) reverberatory anode furnaces by poling with logs, cast on four (4) wheels, and then electrorefined. This practice was modernized in 2001 with the installation of two (2) rotary anode furnaces at the. Copper Cliff Smelter which employ steam and. natural gas for reducing and which provide a significant reduction in emissions. A new casting shop with a single anode casting wheel is used to cast regular and stripper constant weight anodes which are transported by truck to the Copper Cliff Copper Refinery for anode preparation and electrorefining. This paper provides an overview of the copper circuit at the Copper Cliff Smelter and a description of the CDN$31 million capital project.

Jan 1, 2002

By A. W. BELDEN

Among the investigations that the Bureau of Mines is conducting witha view to increasing efficiency in the utilization of fuels belonging to or for the use of the Government is an investigation of the processesthat take place in a foundry cupola during a melt. Some observations on the results of cupola tests of cokes at the Government fuel-testing plant in St. Louis, Mo., the coke being fromcoal from many coal fields of the United States, have been stated in a previous bulletin.s Especial attention was given to the meltinglosses that resulted from the use of different grades of coke, light and porous or heavy and dense. These losses amounted in one instance to 52.5 per cent of the iron charged and showed, in convincing manner, the need of exact information in regard to conditions in the fuelbed of the cupola.b Melting losses of iron have been fully appreciated but little under-- stood. The fact that these losses were possible with either light or heavy coke led to the belief that by using small charges 80 placed that. melting would take place in that zone of the cupola where the highest heat and the smallest percentage of oxygen prevailed and by confiningall melting to this zone these losses would be eliminated and the economical use of practically any coke produced for metallurgical purposes would become possible. This widening of the field from whichcoke might be drawn for foundry purposes would serve to place the foundryman in an independent position as regards his source of supply, and would tend to conserve the better grades of coking coals, which are being rapidly exhausted, by making the poorer grades available for mixing with them. In order to investigate conditions within a cupola, the Bureau of Mines as a first step decided to install a commercial cupola, to sample the gases during their travel from the tuy~res upward, and to determine the temperature of the fuel bed.

Jan 1, 1913

By Ivan Bonchev, Elisaveta Djurova, Evgeni Visariev, Viktor Stoilov

"Two types of slag cooling is used world wide - cooling in ladles and cooling in pits. The flotation comparison of the type cooling regimes was done at Aurubis Bulgaria. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag flotation plant processes blend of three parts FSF and one part converter slag. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper content in flotation concentrate is over 20 % and in flotation tail is under 0.5 %. In order to improve the copper recovery, different cooling rate of the liquid slags should be achieved. Three cooling experiments with flash smelting furnace (FSF) slag have been done: two of them in pits with different volume and one cooling experiment in metallic ladle. The ambient air temperature during the cooling tests was from -4 to +4 OC. Laboratory flotation tests in open cycle were done with an aim to compare the slags behaviors cooled at different conditions. In this paper the effect of different cooling on the flotation process will be presented. The copper recovery and distribution by sizes in the tails, copper content in the rougher concentrate, and the concentrate yield are discussed."

Jan 1, 2014

By Rolland L. Blake

Petrographic and mineralogical studies were made on unoxidized samples from the Cuyuna and Mesabi districts to study occurrence and properties of the iron phyllosilicate minerals . Examination of 96 thin sections from the thinbedded facies of the main iron - formation of the Cuyuna district indicates that the most abundant minerals are Mn - Mg - siderite , stilpnome lane , and minnesotaite . Reconstitution and recrystallization of minerals has occurred along certain beds , and textures indicate that some minnesotaite apparently formed at expense of stilpnomelane . Three samples of stilpnome lane and one of minnesotaite were concentrated from fracture - fillings within iron- formation . Results of chemical , optical , spectrographic , X- ray diffraction , and differential thermal analyses on these samples are reported . The detection of ammonia in stilpnome lane samples is the first such occurrence reported , and its significance is discussed . New mineral data are presented on greenalite and probable septechamosite from the Mesabi district .

Jan 1, 1964

By S. Khoshjavan

Separation of refractory rock phosphate (P2O5 = 11.5%) from the Dalir area, Iran, containing quartz, calcite and other impurities, by calcination and flotation processes has been successfully used to upgrade the phosphate values. Petrographic studies of this ore showed that collophanite was the major phosphate mineral and the main gangue minerals were calcite, dolomite and quartz. The results of characterization studies showed that the liberation degree of apatite occurred below the average grain size of 140 µm. Preliminary flotation tests were used to process the phosphate samples. Results of preliminary flotation tests showed that they don?t contain any desirable efficiency (grade or recovery) of P2O5. Calcination was the best process for preconcentration of this ore. In the desliming stage, about 14.4% of total P2O5 was removed. Encouraging concentrate grades were obtained after flotation with anionic and cationic flotation, successively. The reagent schemes that have been used in this study consisted of COCO-amine acetate and fatty acid as silicate and apatite collectors, respectively, as well as fuel oil and anionic poly acryl amid as promoter collectors. The optimum pH values for direct and reverse flotations of phosphate were 11 and 6, respectively. Experiments conducted using d80=140 µm deslimed fractions has yielded an acceptable grade of more than 30% P2O5 with a recovery of more than 62%. Finally, a laboratory flowsheet for the processing of Dalir refractory phosphate ore has been proposed.

Jan 1, 2011

By Scoble M, Peck J

This paper reviews the instrumentation and monitoring of blasthole drills and electric mining shovels at a surface coal mine in western Canada. The drill monitoring component involved the development and implementation of microprocessor-based hardware on Bucyrus-Erie 45R and 60R drills. Over a two year period 3800 metres of blasthole drilling were monitored The drill data was subsequently correlated with core and geophysical logs towards identifying unique and reproducible ranges of performance parameter data for the different rock types penetrated. Using this technique, the geology of the study area benches was characterized in detail. Once these same benches had been blasted, the performance of a P&H 2800XP shovel was monitored as it worked through the blasted ground. In this regard, the influence of different digging conditions on shovel performance were identified in a range of blast and geological environments within the study area. The precise nature of these environments was confirmed by a correlation with the interpreted drill monitored data and muckpile size distributions obtained from a digital photo-analysis study. The excavation of 500 000 bcm of waste was thus monitored and a digging index derived which reflected variations in muckpile diggability. The paper concludes by proposing an integrated monitoring approach which, as a first step, uses interpreted drill data for explosive loading. This capability would permit greater accuracy in explosives loading ie. charge placement within higher strength lithologies, while avoiding weaker units. The performance of an instrumented shovel would then be monitored as it works through the resulting muckpile. Interpretation of the shovel performance data would determine the overall quality of the blast in terms of a digging index (DI), providing an indication of the relative digging effort and the effectiveness of the blast design.

Jan 1, 1990

By E. C. Lane

This paper is the first part of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,5 and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey.7 A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "competitive-price gasolines" and 105 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Miner at Bartlesville, Okla.

Jan 1, 1931

By L. H. ADAMS, C. N. HASKINS, J. K. CLEMENT

In the course of its investigations of the fuel resources in the United States and of the methods by which these resources could be utilized with greatest efficiency, the United States Geological Survey tested a great variety of coals and lignites as gas-producer fuel. Early in these testa it was found that many factors controlling the formation of gas in the generating chamber of the producer and, consequently, having a direct bearing on the management of producer-gas plants, were not as well understood as they should be. The Geological Survey therefore took up a detailed investigation of the chemical and physical processes that take place in the producer, keeping in view not only the possibility of increasing the efficiency of the producer as a source of energy, and the ensuing benefits to the public of cheaper power and greater utilization of low-grade fuels, but also the application of the results to the problems of boiler-furnace operations. - The Bureau of Mines, to which the testing and analyzing of fuels as carried on by the United States Geological Survey has been transferred, is continuing producer-gas investigations at the testing station at Pittsburg, Pa. Results of the gas-producer tests a made at the coal-testing plant erected at St. Louis, Mo., and of a study of some of the problems° that came up in the tests have been published by the Geological Survey. Results of the tests made at Norfolk, Va., and Pittsburg, Pa., and of further studies of particular problems, will be published by the Bureau of Mines. In the gas producer solid fuel is transformed into more readily combustible gaseous fuel. The transformation is relatively slow and consists of several processes: 1. The distillation of the volatile hydrocarbons from the freshly fired fuel at relatively low temperatures. 2. The combustion of the fuel by its combining with the oxygen of the air forming carbon dioxide (COO. 3. The formation of carbon monoxide (CO) and hydrogen (11 3), the essential constituents of producer gas, in accordance with the equations:

Jan 1, 1911

By Sathit Tandanand

Horizontal displacements and ground strains induced by mine subsidence are significant information needed for calculating damage and developing precautions against subsidence effects on surface structures. To devise a simple method for determining the surface horizonal displacements and strains simultaneously with the subsidence prediction, the U.S. Bureau of Mines examined the significance of the tilt number, which is the proportionality constant in the relationship between the horizontal displacement and the slope of the subsidence profile. The ratio of the tilt number to the critical radius of the subsidence trough is identical to the ratio of the maximum possible horizontal displacement to the full subsidence, which is found to be constant in most European coalfields. If this ratio is known for a particular minesite in the United States, then horizontal displacement and ground strains can be readily obtained from the primary subsidence data.

Jan 1, 2010

By Gordon Jackson

"There are two accomplishments of air and gas drilling: a new series of economic and mechanical challenges; and, acceptance as a standard drilling and completion tool.The new challenges are related to the concept of using a gaseous circulating medium in drilling for oil or gas. For purposes of discussion, a two part division has been made: the challenge of fluid invasion control and that of equipment and tools. Great strides have been made in the development of materials and techniques to combat formation fluid invasion. Chemicals and the ""mist drilling"" technique, now in use, have the versatility to cope with a wide range of downhole fluid entry conditions.Equipment and tools have been developed to meet the challenges of better, more economic drilling and completion possible with a gaseous circulating fluid. Economic and operational challenges remain.Acceptance of air and gas drilling as a normal operating tool was reached with difficulty. It is now established as a means of reducing costs in exploratory and develop-mental well drilling, exemplified in a recent study of 226 wells covering 419,407 feet of hole in the United States. Air reached the projected depth in 85 per cent of the operations, although formation water was encountered in 48.7 per cent of the holes. Slim hole bit performance and cost all compared for overall bit averages as part of analysis."

Jan 1, 1961

By L. Xinguang

Shandong MinMetals Corporation, a state-owned import and export organization located in the city of Qingdao, Shandong Province, China, was opened in 1954, with the mission of marketing metal products and industrial raw material in oversea areas for hard currency to support the modernization project of the country as well as the province. The management officers are appointed by the provincial government, and report to the Foreign Trade Department of Shandong Province. Meanwhile, the company also receives guidance from MinMetals head office in Beijing, the capital city of China. The head office does not own and control any provincial MinMetals organizations, but merely coordinate business among provinces.

Jan 1, 1990

By K. K. Kelley

Synthetic fluorphlogopite mica (KMg3AlSi3010F2) is a relatively new product developed at the Norris (Tenn.) Station of the Bureau of Mines, Thermodynamic data have applications both in the production and use of this product, and the work described in this paper was undertaken to fill the need for such data. Measurements were made of the heat of formation at 298° K., the heat capacity between 50° and 298° K., the entropy at 298° K., and the heat-content and entropy increments between 298° K. and a maximum of 1,804° K. These basic data are combined to obtain heats and free energies of formation of the mica from the elements and from molecular constituents at temperatures ranging from 298° to 1,800° K. Minimum heat requirements to form melted mica from commonly used ingredients were calculated.

Jan 1, 1959

By Dudley L. Davis, E. C. Peterson

Introduction The Darwin District is 30 miles east of Olancha which is 220 miles north from Los z4ngeles via U. S. Highway No. 6. The ore deposits occur in the Darwin hills that have been elevated above the Darwin plateau by typical basin and range-type faults. Some of these faults have been active quite recently as shown by the displacemerit of Quaternary (?) basalt flows and the rejuvenation of erosion in Darwin wash. The ore bodies occur as fissure fillings and replacement of favorable beddings in a thick series of Paleozoic limestones, dolomites, shales and quartzites. Rich oxidized lead-silver ores were dis'Overed in the early seventies. BY 1875, Darwin had a population Of about 5000, and by 1880 several small mills and smelters had been built. Early exhaustion of surface ores, the isolated location of the district, and fluctuation Of metal prices caused intermittent operations until World War 11. The district production is estimated at about $3,000,000 prior to 1900 and perhaps $4,000,000 between 1900 and 1945 when Anaconda purchased the major producing mines. 'or the Past two Years, daily production has averaged 75 tons of direct shipping and 150 tons of milling-grade ore. At present, 300 tons of mixed oxide and sulphide ore are treated by flotation, the oxidized lead minerals being activated by addition of sodium sulphide after galena and sphalerite have been recovered from the circuit. Extraction averages 85 pct of the lead, 80 pct of the silver, and about 33 Pct Of the zinc in a bulk concentrate. The mill is designed so that minor changes permit selective flotation of pyritic lead-zinc ores encountered at depth. General Geology The oldest rocks in the Darwin hills are a series of Paleozoic limestones, dolomites, shales and quartzites probably pennsyl-vanian in age. These rocks have been intruded on the Rest by the Coso granite batholith and on the east by a granodiorite stock. Numerous sills and dikes grading from orthoclase granite to gabbro are exposed in the underground workings. The sedimentary rocks have been considerably folded and faulted, the most prominent structure being a northwest pitching anticlinal fold, the crest of which lies just west of the ridge line of the Darwin hills, The east limb of this fold has been intruded by the granodiorite stock and east of the stock the sediments show several closely spaced anticlines and synclines. The minor flexures on the west flank of the major fold are structurally important in localizing the ore in the Defiance and Essex mines of the Darwin group. There are three principal systems of faulting and fissuring, most of which are post-intrusive and premineral in age, with minor amounts of postmineral movement. The Darwin tear fault is the largest, most persistent fault in the district. It strikes N 60 to 75°W, dips steeply south and is traceable for about 10 miles. It is a normal

Jan 1, 1949

NORTH AMERICA ALASKA Anchorage.-Culver, H. W. Geehan, R. W. Strandberg, H. Chicagof.-Russell, J. C. Tracy, Q. S. College.-Dorsh, J. B. Fox, E. F. Joesting, H. R. Smith, M. C. Wilcox, H. G. Douglas.-Cahill. W. E. Fairbanks.-Adams, J. M. Barber, R. J. Beistline, E. H. Crawford, J. D. Doheny, L. C. Earling. R. B. Greves, J. H. Harris. Q. P., Jr. Henton. H. M. Herbert, C. F. Nester, W. B. Hopkins, J. E. CANADA ALBERTA Calgary.-Allen, R. E. deHart, J. B. Dunn, W. Gray, J. G. Johnson. R. V. Link, T. A. Slipper. S. E. Soul, N. Thorne, B. L. Thorne, H. L. Edmonton.-Ball, M. W. Lilge, E. O. Pitcher, N. C. Nordegg.-Shanks, J. Turner Valley.¬MacKenzie, W. D. C.

Jan 1, 1941

By N. S. Spence

INTRODUCTION WHILE TITANIUM, the element, has been known for over 150 years, titanium, the metal, is a relative newcomer to the metallurgical and industrial scene. The reasons for this chiefly lie in the refract1Hy nature of titanium compounds; the high melting point of the metal; the great activity of elemental titanium, particularly at temperatures close to .and above the melting point; and the pronounced deleterious influence of certain impurities on its mechanical proper-ties. Early efforts at production of the metal were, consequently, either unsuccessful or resulted in products having sub-metallic properties. With the considerable improvement in equipment, materials, and skills that have developed within the past twenty-five years, later investigators have had a better opportunity to overcome some of the inherent practical obstacles and to come to grips with the essential technical problems. NATURAL ABUNDANCE OF TITANIUM Titanium is one of the most abundant metallic elements. It has been estimated (1) that titanium comp-rises about 0.65 per cent of the earth's crust, and therefore ranks fourth among the structurally useful metals in the order: aluminum, iron, magnesium, titanium. It must be appreciated that the relative abundance of the element is only a crude indication of its potential availability, since a very substantial proportion is present as a minor constituent in practically all igneous rocks. By comparison, present-day ores of titanium are relatively few and are but a minor fraction of the estimated total titanium contained in the earth' s crust.

Jan 1, 1951

By J. J. Demeter

As part of its work on converting coal to fluid fuels, the Federal Bureau of Mines has been studying the synthesis of liquid fuels from carbon monoxide and hydrogen by Fischer-Tropsch synthesis. A fluidized bed of nitrided, fused-iron catalyst has been operated successfully to produce high yields of oxygenated compounds. Trouble-free operation continued for over 800 hours, and the test was terminated voluntarily. About 85 percent of the fresh feed was converted when the unit was operated at a space velocity of 500 hr.-1, a 12:1 recycle-to-fresh-feed-gas ratio, a 300-p. s. i. g. pressure, and a temperature of 252° C. When operating at a fresh-feed-gas space velocity of 1,000 hr.-l and a 9:1 ratio of recycle to fresh gas, conversion of fresh feed was 68 percent, and the product yield was 235.9 grams per cubic meter of synthesis gas converted. The oxygenate and C5 and heavier hydrocarbon yield was 110.6 grams per cubic meter of gas converted, 83 percent of this was oxygenates. The atom ratio of N:Fe of the catalyst, initially 0.455, decreased to 0.288 by the end of the 800-hour experiment. Nevertheless, the yield of oxygenated compounds per cubic meter of H2 + CO converted at the end of the run was approximately the same as that obtained 500 hours earlier with identical operating conditions. X-ray analysis of the discharged catalyst indicated that only ?-iron carbonitride was present. Sieve analysis of the discharged catalyst indicated that only 2 percent of fines was produced during the reduction, nitriding, and synthesis.

Jan 1, 1959

By Jorge A. S. Tenorio, Chuanwei Zhuo, Joner O. Alves, Yiannis A. Levendis

"Reduction of combustion-emitted greenhouse gases, which are associated with global warming, may be achieved by use of CO2-neutral alternative fuels, such as bio-ethanol. Distillers Dried Grains with Solubles (DDGS) are the main co-products of the com-grain-based ethanol industries. In 2009, the North American production of ethanol from com was about 38 billion liters, which generated approximately 31.5 million tons of DDGS. Samples of DDGS were pyrolysed at temperatures of 600-1000 °C in a two-stage laminar-flow horizontal furnace, and a catalyst system was used to synthesize nanomaterials. This work presents a microstructural characterization of these nanomaterials by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results showed that the nanomaterials produced from pyrolysis of DDGS were in the form of long, entangled, rope-like structures with rugged walls, lengths in the tens of microns, and axially non-uniform diameters in the range of 100-300 nm.IntroductionThe interest in ethanol has increased considerably worldwide due to the necessity of finding renewable and cleaner energy resources [1, 2]. According to the Renewable Fuels Association (RF A), the world ethanol production in 2008 was approximately 65.7 billion liters (17.3 billion gallons), which figure represented a 24% increase in the production over that in the previous year [3]. The major producers of ethanol are the USA and Brazil, which together account for 90% of world production. The main feedstock for ethanol in USA is com grain, whereas sugarcane predominates in Brazil [2-4]."

Jan 1, 2011