Search Documents

By S. Chama, K. Nyirenda, J. Machona, P. W. Chishimba, S. Parirenyatwa, G. Kaluba, Y. R. S. Hara, D. M. Musowoya

Our study focuses on upgrading of copper and cobalt from the Democratic Republic of Congo tailings, containing 2 wt% Cu and 0.5 wt% Co. Cobalt is in the complex iron silicate matrix such that its recovery by direct leaching is not possible. Two concentrating methods were employed in order to obtain copper and cobalt concentrates. Copper was concentrated via flotation and, at the optimal conditions its grade in the concentrate was 31.9 wt%. Cobalt was concentrated to 8.6 wt% b ycarbothermically reducing the flotation tailings with coal in a temperature range of 800–1050 °C and followed by magnetic separation. The reaction products were analysed by atomic absorption spectrometer (AAS) and scanning electron microscopy (SEM) techniques. The best carbothermic reduction temperature was found to be 950 °C due to maximum metallisation and less sintering between gangue and metallic/alloy phases.

Mar 1, 2017

By Harold Bailie

The purpose of this Bureau of Mines report is to furnish information on mining practices applied to flat-bedded fluorspar deposits in southern Illinois. It presents new and improved operating procedures and specialized techniques applicable to deposits of this type. All of the operating mines of the Ozark-Mahoning Co. in this area have been opened by vertical shafts which connect with levels consisting of haul-age ways, stopes, and loading stations. The stoping practice used locally called room and pillar, is open stoping with pillars left at different distances and diameters. To facilitate haulage and drainage, the mines are worked from openings turned off the main haulage drift on a grade to conform with the dip of the ore beds. The ore is predominantly fluorspar with smaller amounts of galena and sphalerite that contain traces of cadmium and germanium. The principal gangue minerals are limestone, calcite, shale, barite, and sandstone. The rock hardness ranges from relatively soft shale to hard, abrasive sandstone.

Jan 1, 1960

By M P. Sandy, R M. Stephenson

Portals to access underground mines are important infrastructure and their design requires careful consideration. Portals are generally expected to last for the life of the mine. Typically, the exposure of personnel and equipment is high, with many hundreds of movements through the portal per day. Consequently, the risk associated with geotechnical instability must be extremely low. Portals are often established from a boxcut. In areas where the weathering profile is well developed, the design and execution of the boxcut can involve significant effort, with the objective of minimizing the volume of the boxcut, whilst ensuring that conditions at the design depth are suitable for establishing a stable portal. Properly designed site investigations are a critical part of this process. Currently available portal design guidelines have not been updated for decades, however the equipment and ground support systems have changed significantly in recent years. Many mine portals have since been constructed in a relatively short time frame with success, often in challenging ground conditions using some of the more modern approaches to ground support. This is beneficial because delays in establishing a portal will generally delay other critical path activities, and lead to cost overruns.

Mar 15, 2021

By ERJIINICI FERRARIS

1. HISTORICAL REVIEW AND INTRODUCTION. THE development of the mining industry in Sardinia dates from the application of the minim law of 1859, which, following the example of the French mining law of 1810, declared prospecting to be free, and suppressed the liens which had previously attached the mine to surface ownership. The first ore-dressing plants were installed by German engineers upon the classic models of the Harz and of Freiberg; but in 1880 Sardinia commenced to open a new path in that industry, utilizing the refuse from the mining of rich, selected minerals, of poor deposits, and of mixed ores. The first experiments were attempts to adapt the existing apparatus to local conditions, but progress was rapid, as was demonstrated already in 1887 by the calamine-dressing-mill of Monteponi, which exhibited a large plant designed in accordance with the experience gained, and constructed entirely in the machine-shops of the country, after new models and designs.1 This example was followed two years later by the Société Malfidano, with a large plant of the same sort, and with the reconstruction of the old-fashioned-dressing-mill, built in 1880 by the Austro-Belgian Company. In 1900, almost all the mines of Sardinia had adopted the new designs, and the island contained 32 concentrating-works, employing 2,000 h.p. and 1,924 workmen. Since that time, there have been added a large dressing-mill for blende at Gennamari, and two for calamine, at San Giovanni and at Masua, while the establishments at other mines have been enlarged and perfected. For the treatment of intimately mixed ores, a large establishment has been built upon the new

Jan 5, 1908

By Johnson M. W

Factual data about the sedimentation in the Newcastle Coal. Measures are presented. Data concerning the total coal measure sequence (isopachs, sand /shale ratio and total coal thickness variation), data about three coal seams (Borehole, Dudley and Victoria Tunnel) and data about interseam con- glomerate units are discussed. From this data conclusions are drawn about the coal measure environment. The western edge of the coal basin, the Lochinvar Dome, although a high feature was apparently stable during coal measure time. Despite its height it apparently supplied little sediment to the basin. The northern and north-eastern edge, which was unstable, suppl- ied most of the coarse detritus including the conglomerates to the basin. The conglomerates show patterns of fluvial origin but after a period of "normal" variations in pattern they become restricted to two parallel zones evidently tectonically controlled. Deposition of conglomerates is episodic and separated by periods of coal formation when deformation was apparently slight. Formation of each of the three seams considered followed a rather similar pattern - each shows development of thick coal around the basin edge and poor thin coal in the "axial" region of the present synclinal structure. Evidence of in-situ formation of some areas of the seams is discussed and periodic deformation of the basin during coal measure time is postulated.

Jan 1, 1969

By R. L. Pearson

The 1987-88 Denver Brown Cloud Study was performed to determine the sources of the particle cloud which forms over Denver each winter. The study was organized under the leadership of Colorado Governor Roy Romer , EPA Region VIII and the Greater Denver Chamber of Commerce. The study was sponsored by over 40 organizations representing governmental agencies, the natural gas industry, the coal industry, utilities, oil companies, railroads, the motor vehicle industry, and other Denver area companies and organizations. The cost of the study was $1.5 million which was raised almost entirely from private sources. The study team was headed by Dr. John Watson of the Desert Research Institute of the University of Nevada. Dr. Watson is a recognized expert in conducting studies of this type.

Jan 1, 1990

By J Franz, S Bock, N Hentrich

Artificial ground freezing is the unrivalled method for groundwater control during mine shaft sinking. Moreover, ground freezing may also provide temporary ground support. The fast development of fibre-optic temperature monitoring devices, three-dimensional freeze pipe survey methods and numerical modelling software provide grounds for developing new and reliable tools for ground control during freeze shaft sinking. This paper presents examples of predictive numerical models that are based on back-analysis and calibration of temperature data that covers the complete construction cycle from pre-freezing through to artificial thawing. The back-analyses showed that standard numerical models are not capable of predicting the prevailing thermo-mechanical conditions satisfactorily. This paper describes the development and implementation of new tools for improved consideration of concrete hydration and latent heat, along with the introduction of other algorithms that improve and simplify the efforts of managing complex numerical models. A function is presented that allows for an automated correction of the model’s mesh based on results of three-dimensional freeze pipe surveys. This paper demonstrates that the latter consideration is important, because the often employed assumption of idealised freeze circle geometry in numerical models impacts on the accuracy of such model’s predictions. Subsequently, the verification of these extended numerical models is demonstrated. Due to its flexibility, the FLAC3DTM code was employed for the numerical modelling. This software provides the possibility of implementing additional functions written in internal FISH or Python language into the models. It is concluded that state-of-the-art techniques for freeze hole drilling and surveying, on-site monitoring and advanced numerical analysis provide a significant potential for both the design and the operation of largescale ground freezing measures. The application of the extended numerical models for predictive simulations during construction allows for temporary shaft lining optimisation, for assisting in operational decision making and for compensating temporary loss of monitoring data. Suggestions are made for required future work in order to further improve the developed ground control tools. CITATION:Bock, S, Franz, J and Hentrich, N, 2018. New tools for ground control in freeze shaft sinking, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 393–406 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By J. J. Jonas, G. Gagnon

SHG zinc was extruded in the temperature range 110" to 350°C and the strain rate range 0.05 to 5 sec-1 The strain rate/flow stress/temperature results were analyzed using a power sinh stress relationship. When temperature changes due to the heat of deformation and to heat losses are neglected, the exponent of the sinh function of the stress is 5.6, and the apparent activation energy of deformation is 28 kcal per mole. When these changes are taken into account, the exponent decreases to 4.7 and the activation energy to 23 + 2 kcal per mole. The corrected stress exponent and activation energy are in very good agreement with published values obtained from creep experiments, and suggest that the hot extrusion of zinc is controlled by a mechanism involving self-diffusion. When the extrusion and creep data are compared using a Zener-Hollomon parameter and either a sinh or an exponential stress term, an appreciable offset is observed, which may be due to the difference in impurity content. For a given set of extrusion conditions the ram speed, maximum pressure, and initial temperature can also be correlated using a Zener-Hollomon parameter and a sinh pressure term. THE deformation of metals at temperatures over about one-half the absolute melting temperature has been extensively studied at creep strain rates. By contrast, relatively little work has been carried out on the behavior of metals at hot working strain rates. Most of the latter investigations have been performed using simulative methods, such as hot torsion and hot compression, in which the friction conditions and temperature rise during deformation may differ appreciably from those existing under industrial conditions. Recently, however, Wong and Jonas1 used a scaled-down industrial process to determine the stress and temperature dependence of the strain rate during the extrusion of aluminum. In such tests, the effects of friction and adiabatic heating are closer to those produced in industrial operations. Also, with regard to the testing of materials of limited ductility such as zinc, hot compression and hot torsion do not permit the attainment of true strains as large as the deformations usually applied commercially. The present study was undertaken to investigate the extrusion behavior of Special High Grade (SHG) zinc. The detailed objectives were: 1) to establish the stress and temperature dependence of the strain rate with and without a consideration of adiabatic heating, 2) to study the pressure and temperature dependence of the ram speed, and 3) to investigate the microstruc- tural changes occurring during the deformation. The last aspect of the investigation will be covered in a separate paper. The treatment described below differs from that of Wong and Jonas in that the adiabatic temperature rise during deformation is taken into account, and the calculation of the mean equivalent strain rate is based on the redundant as well as on the homogeneous work. EXPERIMENTAL PROCEDURE Rods from two shipments of continuously cast SHG zinc* were used in the investigation. The composition *Supplied by courtesy of Cominco Ltd. range of the impurities present, as given by the supplier, was: Pb: 0.0013 to 0.0023 pct, Fe: 0.001 pct max Cd: 0.0001 to 0.0006 pct, Cu: 0.0002 to 0.0005 pct, Ti: 0.0001 pct max; thus, by balance, zinc valued from 99.9963 to 99.9966 pct. The as-received rods were machined into billets having a nominal diameter of 1.56 in. and a nominal length of 1½ in.; longer billets up to 4 in. in length, were also used to investigate special aspects. The as-machined rods were annealed at 400°C for 24 hr and slowly cooled. This treatment produced a columnar grain structure, with a grain size of about $ by 2½ cm which was appreciably larger than the as-cast one. A 150-ton, direct extrusion, vertical press was used. Ram displacement and force were recorded continuously against time. A constant flow control valve permitted the maintenance of a range of preselected ram speeds up to in. per sec. The selected speed was held constant, irrespective of the required force, as long as the load developed was below the maximum available. Strain gages were used to determine the force; the gages were calibrated before and after each testing period with a 200,000-lb capacity load cell. Further details of the experimental equipment can be found in Ref. 2. The billets were preheated for 90 min in the extrusion container, which was well insulated so as to minimize temperature gradients. This period was sufficient for the billet to reach a uniform temperature at all temperatures between 110" and 350°C. A square-shoulder die having a 0.290-in. diam central hole was used. The extrusion ratio was 30 to 1. This is equivalent to a reduction in area of 96.7 pct, an elongation of 2900 pct, and a true strain of 3.4. The ram speed was varied over two orders of magnitude from 0.0027 to 0.26 in. per sec. The ram was water-cooled during most of the tests, although some experiments were conducted with a preheated, uncooled ram. All extrusions were run without lubricant, which resulted in conditions of sticking friction. EXPERIMENTAL RESULTS Stress Dependence of the Strain Rate Neglecting Adiabatic Heating. The maximum force required to extrude is given in Table 1 for each of the five initial

Jan 1, 1970

By D Kilkenny, D Nardini, P Kline

This paper is a case study highlighting learnings and success in two areas challenging underground miners: change management and collaboration. It examines the implementation process of a new automated loading system in the bulk stoping area of Telfer Mine in Western Australia, controlling multiple load haul dump machines. Here, the new technology has brought together different functions and different companies to deliver a well performing automation system in a changing and challenging mining environment. The introduction of a new and different technology on site has driven collaboration between all stakeholders to break down the traditional barriers to achieve the sustained performance required. Historically, different teams have operated within silos and not always aligned to deliver a ‘best for project’ solution. Technical teams focus on the mine design, maintenance teams focus on reliability and operations execute the plan. Mining contractors focus on productivity and cost. Manufacturers focus on supply of goods and service. Optimising each silo individually is not guaranteed to provide an optimal mining solution. Involving elements from each team as seen at Telfer, has resulted in an optimal mining solution for the automated loading system. A change of focus from the technical teams to include automation parameters in the mine design; operability and maintainability built into the system design allowing for collective ownership and responsibility resulting in a more resilient solution. The implementation of the new technology was not only a technical change but more importantly, successful management of change. Elements of successful change management such as communication, vision, leadership and planning, are essential to harness a trusting site culture which is responsive to new technology. Learnings and challenges from this change process will also be discussed with the intent to improve the success rate and timelines of technology implementations in the future.

Mar 15, 2021

By P Wahyono, H Vega, S Riza, P Vergara, P Gonzalez-Carbonell

PT Freeport Indonesia (PTFI), operating in the Ertsberg Mining District in the Province of Papua, is developing the Grasberg Block Cave copper-gold mine. The site aims to output 160 000 t/d and will be located underneath the current Grasberg Open Pit. Initial studies of the potential to develop a block cave mine in the Grasberg orebody have revealed that the mine will require significant volumes of air. The Grasberg Block Cave (GBC) project requires four primary fans (3750 kW each) to support production at full capacity.Fan #1 commissioning was accomplished successfully on 9 February 2012. However, Fan #2 chamber, which is separated by a 20 m pillar, had not been completed. The main challenge was Fan #2 chamber still needed to be benched. The risk of damage to the critical infrastructure in Fan #1 chamber, including ground support, cracks in pedestals, and misalignment in the impeller shaft were considered. The challenges were blasting the bench without damaging the surrounding infrastructure, completing the work safely and meeting the schedule. This was achieved with the engineering control methodology. This paper summarises the benching process of Fan #2 chamber and its impact upon Fan #1.CITATION:Vega, H, Riza, S, Gonzalez-Carbonell, P, Wahyono, P and Vergara, P, 2013. Excavating an underground primary fan chamber that is adjacent to a fully operational primary fan in PT Freeport Indonesia's Grasberg Block Cave Mine, in Proceedings The Australian Mine Ventilation Conference , pp 115-122 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By Trevor Saldanha, Nawshad Haque, Will Sikora

This study reported life cycle assessment (LCA) of six copper mines in Australia, Papua New Guinea and Portugal. Inventory data was sourced from published papers, sustainability reports by mining companies, independent technical reports and previous CSIRO studies. Sima Pro software and various databases were used to evaluate life cycle based environmental impacts. The impact indicators were: global warming potential (GWP), acidification potential, water footprint, ecotoxicity potential, ozone depletion potential and human toxicity potential (carcinogenic and non-carcinogenic), abiotic resource depletion potential (minerals and fossil fuels), particulate matter and ionizing radiation. Generally, open pit mines were found to have a GWP of approximately 1.0 t CO2-eq/t Cu concentrate while underground mines had approximately 1.3 to 1.8 t CO2-eq/t Cu concentrate. Environmental impacts varied between mines considerably due to several factors, most notably: ore grade, mining method, flowsheets and ore mineralogy. Energy consumption and sources were significant contributors to most impact categories.

Mar 1, 2018

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By John R. Turney

The success of the Mclaughlin acid pressure oxidatiun process has proved that a complex hydrometallurgical process can be an economically viable means of treating refractory gold ores. Homestake's Mclaughin acid pressure oxidation process was commissioned in August 1985 and ts currently operating at design tonnage of 3,000 tons per day. Mineralogical and process studies on the operating plant are discussed to show the improved understanding: of the process and its future applications. These studies are also compared with the initial process development work, thus illustrating the success of the initial scale up considerations.

Jan 1, 1989

By Norman Paley

A blasting project was undertaken at the Teck Alaska Red Dog Mine to determine the extent that Semi-Autogenous Grinding (SAG) mill throughput could be increased by using electronic detonators. The Julius Kruttschnitt Mineral Research Centre (JKMRC) blast fragmentation, jaw crusher, and SAG mill breakage models were used to relate changes in the blast fragmentation measured with the SPLIT image analysis system to the SAG mill performance. For optimum performance a SAG mill requires a particular size distribution; a number of large rocks to facilitate breakage by impact, as few as possible middle size rocks that become critical size, and the maximum fines which will pass quickly through an open-circuit mill. Physical constraints of drill and charging equipment size limit the extent that pattern geometry can be changed, and the powder factor increased, to maximize fines. However, a growing number of studies have shown that the use of electronic detonators can lead to increased fragmentation and greater muckpile uniformity, providing an alternate means of increasing primary breakage by blasting. Unfortunately results in the literature rarely quantified the changes to the fragmentation distribution. The measured gyratory crusher fragmentation of 2,750,000t of ore was used to compare stockpiles constructed from shots using pyrotechnic detonators to those using Orica i-kon electronic detonators. In the first stage of the study, stockpiles shot using 25 ms inter-hole timing with pyrotechnic detonators were compared to stockpiles shot using the same inter-hole timing with electronic detonators. In the second stage of the study, stockpiles shot using 17 ms inter-hole timing with pyrotechnic detonators were compared to stockpiles shot using 8 ms inter-hole timing with electronic detonators. When electronic detonators were used with the inter-hole timing kept constant, fragmentation uniformity was slightly increased, but mean fragment size increased by 20%. When electronic detonators were used with faster inter-hole timing, fragmentation uniformity was slightly reduced, but mean fragment size decreased by 30%. Modeling was used to determine the SAG mill throughput which could be expected from this change in fragmentation to determine the pairs of pyrotechnic and electronic blast pattern geometries that would provide similar throughput. The economic benefit from the electronic detonator shots was calculated to assist in determining the optimum blast designs for their use.

Jan 1, 2010

By E. Herrera Alarcón, L. Mariscal Samaniego

The Teniente Converter (wet charge type) was commissioned in august 1995 and was designed to smelt 744 tpd (metric tons per day) of dry copper concentrates. Its products are white metal (73% Cu) that is sent to the Peirce Smith converters, slag that is cleaned in Reverberatory Furnaces and the process gases that are sent to the Sulfuric Acid Plant. Since its start up, the Teniente Converter smelting capacity was increased 1.6 times, from 800 tpd to 1,280 tpd using 33% oxygen-enriched air, and reaching an operative availability of 97%. By the other hand its campaigns have reached a record duration of 530 days without hot patching tuyeres and a partial refractory lining repair in the last four campaigns. This paper describes the most relevant improvements, as well as the strategies that had been used to reach these achievements.

Jan 1, 2007

By M Grigorescu, J H. Hodgkinson, H Alehossein

A new framework that collates and interprets pre-existing data to assess vulnerability and ultimately plan to avoid or minimise flood-related risk to infrastructure, people, downtime, environment and revenue has been developed. The æClimate Related Adaptation from Terrain Evaluation ResultsÆ (CRATER) method tested at a coal mine in Queensland, provides semi-quantitative information to assist decision makers when designating investment for minimising vulnerability of mining operations to climate. Here we present the processes involved in this three-step approach that uses pre-existing spatial data of the mine site and local knowledge to build a set of visual tools to assist decision-making. The first step of the process is performing multi-criteria evaluation (MCE) within a geographic information system (GIS) on ranked natural conditions at the mine, such as elevation, slope, drainage, soil and vegetation, which is performed to identify critical flood areas. Secondly, a fault-tree analysis identifies how impact can occur and what options there are for impact reduction. Finally, a resource assessment of the mineÆs capacity to adapt reduces the adaptation options to those most suited to the mine. The results are confidential, but for the purpose of introducing the methodology, we present simplified results, particularly of steps 2 and 3. CRATER can also be used for future æwhat-ifÆ flooding scenarios to identify the most suitable locations for roads, buildings or other critical infrastructure. The methodology is transferable to any mine, series of mines or locations along the mining value chain that have sufficient data, providing a practical decision-making tool to identify æno-regretsÆ actions that not only could reduce downtime after or during an event, but in some cases may enhance production between extreme events. We now plan to test this method at a broader scale, to encompass more than one mine in the analysis.CITATION:Hodgkinson, J H, Grigorescu, M and Alehossein, H, 2013. Climate Related Adaptation from Terrain Evaluation Results (CRATER) - interpretation of pre-existing data for mine site flood vulnerability and management, in Proceedings Water in Mining 2013 , pp 259-266 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By Norman A. Jull

"IntroductionThe scope of this paper is intended to deal mainly with cyclones in grinding circuits. However, the section on Cyclone Equipment, contains more general descriptions, to cover most of the cyclones used in mineral separation plants.Cyclones as heavy media separation vessels are discussed by Mark Freberg (this volume). Their use in tailings deslirning is discussed by P.C. Lighthall, eta/. (this volume).Cyclone EquipmentCyclone TerminologyApexObviously, the apex of a cone is the smallest end. However, with cyclones the term is usually used for the fitting which is attached there to control discharge of the underflow stream.Note that the cyclone need not be so mounted that the apex is the lowest point, although that is the most common method. Keeping the apex below the rest of the cyclone helps avoid plugging when the underflow contains very large particles and the tonnage of underflow solids can fluctuate.Various devices for adjusting apex diameter or otherwise controlling the underflow are discussed later under ""Cyclone Construction"".BypassingThe transport of a portion of feed slurry directly to underflow so that classification is bypassed by that portion of feed.This action is fundamental in any hydraulic classification, whether gravity or centrifugal, because the large particles going to underflow have some void volume between them, which remains filled with feed slurry.D50By definition, D50 is that particle size which has an equal probability of going to overflow or to underflow.It is calculated by drawing a curve of recovery vs particle size and noting the size at which 500Jo recovery occurs.This may be done equally with corrected or with gross recovery (see below) and the resulting value should therefore be identified as d50c (corrected d50) or as d500 (gross d50).Note also that it is common in industry practice to plot size analysis data on the retained size rather than on the average of passing and retained (the middle of the size band). To portray sizing alone it makes no difference, but to read a D50 value off a curve of corrected or gross recoveries, it is essential to plot those values on the average size of each band."

Jan 1, 1989

By C. N. J. Wagner, E. N. Aqua

The bee alloys of the terminal solid solution of rhenium in niobium were investigated by X-ray diffraclion methods. The analysis of the broadening of the powder pattern peaks from the niobium-rich alloys, cold-worked by filing, showed evidence for faulting on (211) planes. The alloys with larger rhenium concentrations were brittle, and fractured when filed. The analysis of the shapes of the diffraction profiles from powders produced by hammering with steel plates) of these brittle alloys indicated that the broadening was due predominantly to platelets bounded by clibe planes. This result was consistent with the Laue patterns from single-cleazlage facets which showed evidence for clearage fracture on {100} planes. The influence of faulting on the mechanical properties of face-centered cubic (fcc) metals and alloys, i.e., how faulting affects the various dislocation configurations in fcc metals, is well-known.' The important question is whether or not faulting occurs in body-centered cubic (bcc) metals and alloys, and, furthermore, if faulting does occur, to what extent it affects the mechanical properties. Theoretical calculations indicate that the stacking-fault energy is rather high in most bcc metals.2 The results of sev-eral studies using transmission electron microscopy have indicated that faults are present in well-annealed and lightly deformed bcc metals and alloys, such as tungsten,3 vanadium,4 and Mo-Re alloys.5,6 These faults, as have been observed, may be stabilized by the presence of interstitial (C,N,O) atom segregation to the extended dislocations. In addition, there is considerable X-ray diffraction evidence for faulting in bee metals,7-8 using the same techniques that were successful for the study of faulting in fee metals and alloys.7 This X-ray diffraction method is currently the only technique applicable for the investigation of faulting in metals with high stacking fault energies, i.e., when severe amounts of deformation are required to produce sufficient amounts of faulting to be detectable by X-rays. The thinned films of heavily deformed metals will become opaque in the electron microscope due to the high dislocation densities present. In a previous investigation of faulting8 in bee metals of group Vb and VIb, the authors observed that niobium was ductile when filed at room temperature, and showed the highest density of faults on the (112) family of planes. A niobium-base alloy system was therefore chosen to study the effect of alloying on the occurrence of faults in a bcc alloy. There is a large range of terminal solid solubility of rhenium in the alloys of the bee refractory metals. All of the Group VIb-rhenium alloys, i.e., Cr-Re, Mo-Re, and W-Re, exhibit solid solution hardening without loss of ductility.9 In fact, the ductility reaches a maximum for alloys with compositions near to the limits of solubility. This enhanced ductility has been attributed to the lowering of the stacking-fault energy in the alloy; i.e., the increased amounts of twinning provide an additional mode of deformation, resulting in the observed high ductility.' Because of this demonstrated effect of rhenium in bee alloys, it was decided to study a series of alloys of Nb-Re. Using the same X-ray diffraction methods as described in the previous investigation,' one is able to identify the possible causes of broadening of the powder pattern peaks, e.q., particle size, microstrains, stacking faults, and/or twin faults. The separation of these various contributions to the measured peak shape is accomplished by the Warren-Averbach analysis.7 I) EXPERIMENTAL PROCEDURE A series of seven bee solid solution alloys containing from 2.5 to 21.5 at. pct Re (remainder niobium) were prepared at the General Electric Research Laboratory. Buttons, weighing 25 g, were alloyed from electron-beam-melted niobium chips and random rhenium sheet by arc melting in a water-cooled copper crucible, under an argon atmosphere. The buttons were inverted and completely remelted to promote homogenization. The nominal alloy compositions are listed in Table I. Samples of the cold-worked alloys were obtained by filing to produce a powder for the X-ray study. Alloys too brittle to be filed were hammered with steel plates. The resultant filings or brittle impactings were screened through 150-mesh classifiers and compacted to the required shape for the diffractometer holder. The X-ray diffraction peaks were automatically recorded by fixed time counting at uniform 28 intervals, or by continuous registration with a ratemeter. In all cases, the (110)-(220) and (200)-(400) pairs of peaks and the (211), (310), (222), and (321) reflections were measured on a GE-XRD5 diffractometer using CuKa radiation with nickel filter or MoKct radiation and a LiF monochromator in the diffracted beam. The first part of the data reduction, completed with the aid of a series of programmed computations,10 was the analytical resolution of the Kol component of the diffraction profile. Subsequent computations were then made with reference only to the resolved Kol peak shape. These included the measurement of the

Jan 1, 1967

By Jack C. Haptonstall

This paper describes the analytical characteristics of Western subbituminous coal and the manner in which these characteristics apply to their use in a utility-sized steam generator. It compares these characteristics with those of typical Midwestern coal and Eastern bituminous coal. The paper also reviews in detail the design considerations that must receive attention when various blends of these three coals, or any combinations thereof, are planned to be used. This research paper describes variations in analytical and utilization characteristics when coals from different origins are blended in order to achieve a predetermined sulfur content for the purpose of predicting sulfur oxides emissions as they affect environmental regulations and the resulting alterations in utilization characteristics such blending would cause, and how such blends of coal would affect a utility-sized steam generator.

Jan 1, 1979

By Kwadwo Osseo‑Asare, Isehaq Al‑Nafai

The hydrometallurgical processing of bastnasite is a well-known process that is used to extract rare earth metals. However, more accurate measures are required to enhance the efficiency of extracting and recycling rare earths. In this work, Pourbaix (Eh–pH) diagrams for La-, Nd-, and Pr-(F)-(CO3)-(SO4)-(Cl)-(NO3)-(C2O4)-H2O systems were theoretically derived to investigate the stability relations during the hydrometallurgical processing of bastnasite. The diagrams for RE-H2O systems show similar trends to the original ones drown by Pourbaix. The stability domains of RE carbonates were presented by RE-CO3-H2O systems with pH range of 4.5–11. In contrast, the diagrams for RE fluorides showed a large stability region of insoluble REF3 (pH ~ − 1.7–12). The decomposition behaviors of REFCO3 were studied by constructing Eh–pH diagrams for RE-F-CO3-H2O system. The stability regions of bastnasite species extend from nearly neutral to basic media (pH ~ 6.5–12). The acid treatment (using H2SO4, HCl, and HNO3) of bastnasite was investigated by constructing Eh–pH diagrams for REF- CO3-(SO4)-(Cl)-(NO3)-H2O systems. According to these systems, REFCO3 can be decomposed at pH ~ 6.5 when treated with H2SO4 and at pH ~ 1.7 when treated with HCl and HNO3 acids. On the other hand, the alkaline treatment of REFCO3 converts it to RE(OH)3 at pH ~ 11. The recovery of rare earths ions was studied with the aid of RE-C2O4-H2O systems which shows a wide stability region for RE oxalates in pH range of − 2–11. This theoretical approach explained the aqueous relations in the hydrometallurgical processing of bastnasite ore and it can improve the practical hydrometallurgical processing of such ores.

Feb 9, 2024