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By L. Chen, G. A. Brooks, S. A. Nightingale

The dissolution of alumina and magnesia has been investigated using laser scanning confocal microscopy (alumina) and a rotating finger apparatus (magnesia) to assess the effects of temperature, composition and forced convection on the rate of dissolution in CaO-SiO2-Al2O3based slags. The two techniques have differing strengths and limitations, and provide complementary methods for studying dissolution. Alumina dissolution was studied for temperatures from 1477 to 1577°C. Based upon the data, the rate controlling mechanism was thought to be mass transfer control in the slag. The diffusion coefficients for the alumina particles are estimated to be in the range 10-11to 10-10m2.s. MgO degradation for sample rotation speeds of 50 to 800 rpm at 1500 and 1530°C was studied for both congruent and incongruent dissolution. The results show that the rate of dissolution for this is primarily controlled by a diffusion mass transfer mechanism for congruent dissolution except at the highest rotation speed. For incongruent dissolution, the mechanism is much more complex, with the morphology and distribution of the spinel reaction product having a significant effect. At high speeds and prolonged times, mechanical forces played a major role in the degradation process. Keywords; kinetics, corrosion, refractories, dissolution rate, inclusions, mass transfer, slags, steelmaking

Jan 1, 2004

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulfide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular SO2 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, pyrrhotite, pentlandite, pyrite, chalcopyrite, and violarite have agglomerated and reacted to form two intergrown phases: 1) pyrrhotite solid solution (Fe0.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu0.03S). Magnetite formed euhedral crystals, skeletal crystals, and dendrites at the margins of the matte. Prismatic ferrohypersthene and octahedral Mg-Al-Fe spinel crystals and dendrites are present in the glassy slag.

Jan 1, 2001

By M. Roy

Safety and stability of underground coal mine workings are always in danger when opencast mines are operating in close proximity. A study was conducted to investigate the level of vibration generated from opencast blasting at similar distances on the surface as well as in the nearby operating underground coal mine openings. Eight blasts were performed and nineteen vibration data were recorded on the surface behind the opencast blasting face and also in underground openings at similar distances. It was observed that magnitude of vibration recorded on the surface were more than those recorded in underground.

Jan 1, 2007

By Robert Cluff

The Campo Morado precious-metal-bearing, volcanogenic massive sulphide district occurs in a Lower Cretaceous felsic volcanic sequence in a northerly trending belt in the Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. The deposits belong to a low-sulfidation, volcanogenic massive sulphide system formed in a subaqueous environment, and are of the siliciclastic type. Most are on the flanks of felsic domes or in adjacent basins and many are associated with heterolithic volcaniclastic rocks. The Reforma and possibly the El Rey massive sulphide deposits are interpreted to be overturned, and the Naranjo, El Largo, and Estrella de Oro deposits and the El Profundo occurrence to the south are upright. The G9 deposit and the La Lucha and San Rafael occurrences are in an over-thrust plate further to the southwest. In several of the deposits, zinc, lead, silver, and gold are concentrated near the stratigraphic top, and copper is concentrated near the stratigraphic base; copper also is concentrated in replacement bodies near the top of some domes. Major minerals are pyrite, quartz, ankerite, sphalerite, chalcopyrite, and galena. Gold and silver occur in argentian gold, and silver also occurs in tennantite/freibergite and galena. Underlying stockwork zones contain disseminated and vein quartz, pyrite, chlorite, and ankerite, with locally abundant chalcopyrite and/or sphalerite. Exploration since 2004 has enlarged greatly the El Largo and the high-grade G-9 deposits, and slightly enlarged the El Rey deposit. The cumulative in situ massive sulphides for the Reforma, Naranjo, El Rey, El Largo, and G9 deposits exceed 45 Mt.

May 1, 2006

By Kazuyuki Matsuzawa

A series of plate loading tests were carried out on a loam ground in order to investigate the influences of the plate size and the loading rate on the observed load-settlement relations. Two circular plates having diameters of 0.3 m and 1.0 m were used. Three types of loading methods were employed; 1) static cyclic maintained load test, 2) static continuous load test, and 3) rapid (dynamic) plate load test. An interpretation method called non-linear damping method was used to estimate a static load-settlement relation from the rapid plate load test signals. The derived static load-settlement relations match well with the measured results from the static load tests.

Jan 1, 2006

By W. W. Adams

[S,1.1.8'"' of explordves -permissible explosivos,21 other high explosives, and black blasting povrder -in the Uni ted States during the caJ.endar yenr 1937 reached a ~ombined total that slightly exceeded the quantity sold in 1936. A larger output was re orted. for permisAiblA and other hig! explosives but asmal-ler for black po~~er. Production of the three classes of explosives totaled 404, 744,294 pounds, more than 3 pel'CGnt over 1336. The total qrumti ty produced included 49,579,441 pounds of perminsibles, 2~8,924,253 pounds of other high ex-plosives, 36,403,950 pounds of black powder in pellet form, and 29,836,65q pounds of bla~k powder in granular form.]

Jan 1, 1938

By Gilberto Nunez, Ron Eastman, Hector Parra

The prediction of blasting outputs has proven to be a sound engineering tool to provide a guideline for design improvement. It has also been demonstrated to be extremely useful in critical situations when production can be compromised and there is no chance for error.

Jan 1, 2015

By J. R. Thoenen, Hugh D. Pallister

"INTRODUCTION The Stone Hill Copper project resulted from the recommendations made in the war minerals report on this deposit by engineers of the Bureau of Mines 4/ and a similar report of the Geological Survey. 5/ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of domestic mineral resources to the end that they make the greatest possible contribution to the national security and economy. The Mining Division, Lowell E. Moon, chief, conducts preliminary examinations, does the actual investi¬gative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests.This report was prepared under the supervision of Paul M. Tyler, former regional engineer, Eastern Region, and is based on the examination and investigation of the deposit by Hugh D. Pallister, mining engineer, made under the immediate supervision of Richard W. Smith, former District Engineer for Alabama and Mississippi.The report was rewritten and prepared for publication by J. R. Thoenen, chief, Tuscaloosa Branch, Mining Division.LOCATION AND ACCESSIBILITYThe Store Hill copper mine is about• 12 miles south of Heflin, the oounty seat of Cleburne County, Ala. Heflin, a town with a population of approximately 1,700, is the nearest shipping point for freight and express. It is on the Southern Railway, between Birmingham and Atlanta. A rural mail route passes within quarter of a mile of the mine. Paved reads from Heflin lead to Atlanta, Birmingham, and Montgomery. The country Toads leading from Heflin are well-maintained but are practically inaccessible during inclement weather. The road crossing the property within a hundred yards of the mine needs grading and repairing (see fig. 1)."

Apr 1, 1948

By H. Lowers, B. Van Gosen

The Iron Hill (Powderhorn) carbonatite complex is a 31 km2 alkalic intrusion located about 35 km south-southwest of Gunnison, Colorado. The intrusion has been well studied and described because of its classic petrology and architecture of a carbonatite-alkalic complex. The complex is also noteworthy because it contains enrichments of titanium, rare earth elements, thorium, niobium (columbium), vanadium, and deposits of vermiculite and nepheline syenite. In particular, the complex is thought to host the largest titanium and niobium resources in the United States, although neither has been developed. It may be economic to extract multiple resources from this complex with a well coordinated mine and mill plan.

Jan 1, 2007

By Thomas M. Brady

The Spokane Research Laboratory/NIOSH and the University of British Columbia (UBC) geomechanics group are focusing on the development of safe and cost-effective underground design guidelines for weak rock masses having an RMR in the range of 15 to 45. Weak ground conditions, ground support, and mining methods used in several North American underground mines were observed. The RMR values were calculated to update both manned entry span design and non-entry stability graphs, plus a database on underhand mining methods was created to reflect existing North American mining conditions. The immediate rock mass was characterized and analyzed in terms of prevailing type of ground support, potential failure mechanisms, and rock behavior to define how existing design curves must be modified for the existing weak rock mass. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making sound economic decisions that will also ensure a safe working environment.

Jan 1, 2006

By Wilfred G. Comeao

Close-in blasting occurs every time the use o f explosives for excavation or demolition requires the surpassing of the commonly accepted cosmetic damage criteriain order to arrive at reasonable and practical explosive weights per delay. One of the many effective blast design procedures consists in establishing a reasonable charge weight per delay with respect to scale, geometry, costs, requirements and constraints of the project. Once this reasonable charge weight per delay is determined, it’s environmental effects have to be estimated with respect to the surroundings.

Jan 1, 1991

By E. Kapilashrami, S. Seetharaman

Refractory/metal interactions and associated reactions are significant during casting as they can lead to inclusion formation. High-temperature interactions between aluminosilicate refractories and molten steel were studied in the present investigation using the sessile drop method. The changes in the contact angles between molten iron with well-defined oxygen levels and substrates of silica, mullite (3Al2O3?2SiO2) as well as commercial refractories were measured in the dynamic mode. In all cases, the reaction led to slag formation. The experiments were performed under isothermal conditions at 1823 and 1873 K. A known and constant oxygen partial pressure was imposed above the iron drop, through appropriate CO-CO2-Ar mixtures. For all substrates, the contact angles started decreasing due to the lowering of the surface tension of iron, as oxygen was imposed on to the system. When a critical level of oxygen was reached, slag started forming at the drop/substrate interface and at this stage, the contact angle dropped suddenly. Subsequent behaviour of silica and mullite was observed to be different, with SiO2showing a non-wetting behaviour. In the case of SiO2substrate, there were also deep erosions along the periphery of the drops and there was slag accumulation at the sides of the metal drop, probably due to Marangoni flow and/or SiO(g) formation. SEM and EDS analysis of the substrates revealed that the formed slag was fayalite. The thermodynamic criteria for slag formation and possible mechanisms of the reaction are discussed in the light of the experiments. Key words: silica, mullite, fayalite, corundum, slag formation, sessile drop.

Jan 1, 2004

By Jing Zhou

2-hydroxy-3-naphthoy hydroxamic acid code name F203 is a good collector of cassiterite, 1-hydroxy-2-naphthoy hydroxamic acid code name ZJ-3. F203 and ZJ-3 are similar series of isomers. They have similar naphthye, and similar series of functional OH and ?CONHOH, but the seat of OH and ?CONHOH group are different, on the F203 is 2.3; on the ZJ-3 is 1.2, ortho position too. According to Isomeric principle ZJ-3 is a good collector of cassiterite slime too. Using ZJ-3 as collector flotation -10µm occupies 90%, grade 1.16% Sn cassiterite slime of Da Chang Chehe concentration plant, pass one coursing flotation, two cleaning and one scarenging flotation, and obtains grand 18.26% Sn, recovery 92.68% cassiterite concentrate. The result proves the Isomeric principle of flotation reagents is correct again. This principle may supply to synthetize new flotation reagents reference. Keywords: F2O3, ZJ-3, cassiterite flotation, Isomeric principle, Isomeric principle of flotation reagents

Sep 1, 2012

Mine rehabilitation is a sustainability issue that has been revisited ad infinitum; however, the persistent lack of demonstrated on-the-ground performance and an increasingly intractable rehabilitation liability in Queensland continue to erode the credibility of the mining industry and regulatory bodies. For at least ten years the need to change the current, process-based approach to rehabilitation to an outcomes-based approach has been apparent. The ISO 14001 series temporarily diverted attention from this important point, however it would appear the limitations of an ISO 14001 approach are now more widely accepted. It is proposed that a successful outcomes-based approach cannot be achieved without meaningful community engagement. The apparently intractable nature of the rehabilitation issue will continue to generate conflict and criticism unless all stakeholders are encouraged to participate in the process of developing robust and practical outcomes for rehabilitation. Sharing the responsibility will ensure the best possible outcome. It is important to recognise the valuable resources inherent in community groups, many of whose committed volunteers have considerable expertise in relevant areas. Community groups should not be seen as adversaries but as allies in the process of solving problems that affect the wider community. Several projects that can be seen as test cases for the engagement of stakeholders exist, and in this paper the process of achieving multiple stakeholder engagement in the context of Environmentally Sustainable Development is discussed.

Jan 1, 2002

By Tjaar A. Louw, Albert P. Van Niekerk, Johannes J. Louw, Attie J. Goosen

Unlike molecular high explosives, commercial explosives based on ammonium nitrate do not detonate ideally according to the theoretical model for steady state, one-dimensional detonation. One of the reasons for this deviation from ideal detonation is the slower chemical reaction, due to less intimate contact between the oxidiser and fuel components. It is well known that the inclusion of gas pockets, such as microballoons, in the formulation of ammonium nitrate based emulsions and watergels enhances the performance of these explosives. Various different interpretations of the “hot spot” theory have been proposed to explain this phenomenon.

Jan 1, 1997

By Dale A. Sketchley

The objective of Quality Assurance and Quality Control programs on advanced exploration projects is to ensure that data from sampling, assaying, and recording of geological observations are of high integrity for the purpose of obtaining reliable mineral resource and reserve estimates. National Instrument 43-101 Standards of Disclosure for Mineral Projects states that all scientific and technical reports must be prepared and certified by a Qualified Person in accordance with professional and industry standards following Mineral Exploration Best Practices Guidelines and Definitions, and Guidelines of the CIM Standards on Mineral Resources and Reserves. Additional information is given in Companion Policy 43-101CP and Technical Report Form 43-101F1. Although the Qualified Person must discuss and describe the Sampling Method and Approach; Sample Preparation, Analyses, and Security; and Data Verification; there is little specific information in the guidelines on Quality Assurance and Quality Control programs. Examples from the Oyu Tolgoi Cu-Au Project are given for optimizing sampling protocols, following proper sample preparation procedures, safeguarding sample shipments through chain of custody, ensuring quality of assaying with Round Robin monitoring programs, verifying transcribed data, and validating data with check assays to ensure high integrity for resource and reserve estimation. Oyu Tolgoi, also known as Turquoise Hill, is in the South Gobi desert, Mongolia, about 550 km south of the capital city of Ulaanbaatar, and 875 km northwest of Beijing, China. The project covers a major copper-gold system, which consists of the South West, South, Central, and Far North deposits, comprising high sulphidation and porphyry mineralization with oxide, supergene, and hypogene ore types. Exploration is done by multiple diamond drill rigs, and samples are prepared on-site and shipped to laboratories in Mongolia, Canada, and Australia for further preparation and analysis.

May 1, 2003

By Y. D. Lee, J. H. Park, D. S. Kim, H. S. Song

The viscosities and the infrared spectra of the CaO-SiO2-MgO-CaF2(or Al2O3) slags were measured to enhance our understanding of the interrelationship among the thermophysical property, microscopic structure, and chemical thermodynamics of molten slags. The structural role of CaF2and Al2O3in the calcium silicate melts can be explained by a change of the degree of polymerization (DOP). The effect of CaF2on the viscous flow of molten slags is based on a decrease in the DOP by F-as well as by O2-ions and this was confirmed by the infrared (IR)spectra of the quenched slags. The effect of Al2O3on viscosity increase can be understood from an increase in the DOP by the incorporation of the [AlO4]-tetrahedra into the [SiO4]-tetrahedral units and this was also confirmed by the IR spectra. An amphoteric behaviour of Al2O3in the aluminosilicate melts could be correlated to the effect of ionic species of alumina, that is [AlO4]-tetrahedra and [AlO6]-octahedra, on the stability of silicate polyanions by taking the activity coefficients of slag components into account. Keywords: viscosity; infrared spectra; degree of polymerization; amphoteric behaviour; stability; activity coefficient

Jan 1, 2004

By Zach Ahinga, Mike McRae, Dave Hopkins, Steve Klein

The San Vicente Pipeline project involves the construction of an 8-1/2 foot diameter water pipeline in an 11 mile long tunnel in San Diego, California. The tunnel will be excavated in extremely variable geologic conditions consisting of strong granitic and metamorphic rocks, weak sedimentary rocks, abrasive conglomerates, and mixed face conditions. This paper discusses the challenging geologic conditions and some of the key design evaluations for the project. Currently design work for the project has been completed and construction will be underway by mid-2005.

Jan 1, 2005

By Sam Ash

The Murray Mine was one of the first mechanized cut-and-fill underground gold operations in northern Nevada. At the end of 2002, mine production began to decline. So the mine entered a phase of remnant mining and began preparations to close down. The remaining mining took place along the ore waste boundary in previously condemned areas and in challenging ground conditions. To remain economically viable, new techniques were implemented in operations, geology, engineering and rock mechanics. These improvements pushed the edge of known and accepted mining practices and have allowed the Murray Mine to remain in operation.

Jan 1, 2006

By D Craw

Previous studies of alluvial gold in Otago and Southland placer deposits have suggested a gold-mercury association for some deposits derived from Caples Terrane schist, whereas alluvial deposits on Torlesse Terrane basement typically have no mercury. A regional study of gold from Otago Schist vein deposits from both Caples and Torlesse Terranes has revealed the presence of both Au-Ag and Au-Ag-Hg alloys in both terranes. Au-Ag alloy (3 - 4 wt per cent Ag) is typical for gold found in most Torlesse vein deposits, and Au-Ag-Hg alloy (3 - 8 wt per cent Ag, 2 - 8 wt per cent Hg) is found in many Caples vein deposits. Au-Ag-Hg alloys are not exclusive to the Caples Terrane, however, as Au-Ag-Hg alloys with up to 4 wt per cent Hg are found in vein material from the Torlesse-hosted, HydeMacraes Shear Zone. In addition, not all Caples-hosted deposits have a gold-mercury association; gold grains from the Carrick and Invincible gold fields have no detectable mercury. The present study characterises gold compositions from various hard-rock vein deposits and has potential for determining placer-source relationships.

Jan 1, 2003