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By Shuo Wang, Yu Wang, Bing Xie, Rui Tang, Hong-Yi Li, Kun Wen

"During present converter vanadium extraction process, phosphorus could not be removed from hot metal due to absence of CaO in slag though it is an efficient way for vanadium extraction. In order to improve the phosphorus remove and produce CaO-containing vanadium slag, which could be directly used in subsequent roasting process, during the converter vanadium extraction process, lime dissolution in FeOx-Si02-V203-Ti02 slag was investigated by using a rotating cylinder technique and the slag-lime interface was characterized by SEM/EDS. Results showed that changes in the slag chemistry and phase compositions during the lime dissolution process were similar to that in CaO-Si02-FeOx based slag during the BOF process. The V and Ti in the slag were expected to diffuse into the lattice of2CaO·Si02 solid solution, which formed a rather thinner layer in thickness at the slag-lime interface than that in BOF process, leading to improvement of lime dissolution in the slag.IntroductionVanadium is important material that widely applied in industries. The traditional technique to extract vanadium was to leach vanadium after sodium salt roasting. However, the sodium salt roasting process has several problems including lower yielding rate[!] and environmental pollution[2]. Therefore, the more environment-friendly technique of calcium roasting[3-4] was proposed. In order to increase roasting efficiency of vanadium slag, it is essential to study the dissolution/reaction mechanism between lime and vanadium slag. Many investigations about the dissolution reaction of lime in molten slag have been carried out from the standpoints of rapid slagging to De-Pin steelmaking process[5-6]. However, their studies were focused on BOF slag and the reaction mechanism between solid lime and slag containing vanadium has not been reported yet. In present work, the dissolution process was studied with rotating cylinder technique and the reaction interfaces were observed and analyzed by SEM/EDS to elucidate the dissolution mechanism of lime in vanadium slag. This work was supported by National Natural Science Foundation of China No. 51090382."

Jan 1, 2013

By Gerald Onyedika, Tochi Onwumere, Martin Ogwuegbu

"The kinetic study for the leaching of iron from cassiterite ore in KOH solution was studied. The effects of KOH concentration, particle size and reaction temperature on the leaching rate of iron were also examined. The results of leaching studies showed that the leaching of iron from cassiterite ore in KOH solution is significantly influenced by the reaction temperature, KOH concentration, and decrease in particle size. The study showed that 90.62% of iron ore was leached in 8M KOH solution at 80°C within 120 minutes. The experimental data were well evaluated using the shrinking model for surface chemical reaction and diffusion control through the product layer. The activation energies for the iron ore dissolution using the two models were calculated to be 32.06KJmor1 and 97.97 KJmor' respectively.IntroductionIn recent times, there has been increasing attention on the kinetic study of mineral dissolution. In most of these studies, the experimental results were analyzed with a suitable shrinking core model under the assumption that the ore is a homogeneous spherical solid phase [1-4]. A study of the dissolution kinetics of a Nigerian cassiterite ore by hydrochloric acid showed that increase in the hydrochloric acid concentration is accompanied with increase in the amount of cassiterite ore dissolved at various times [4]. The optimal concentration was found to be 4.0M HCl, after which there was a decline in the amount of the ore dissolved, which showed that the concentration of the reagent has a significant effect on the leaching rate of the ore. Also in studying the effect of stirring speed on the rate of cassiterite ore dissolution while keeping other conditions constant for 120 minutes, the result showed that the rate of cassiterite ore dissolution was dependent on the stirring speed over a range of 0 to 630 rpm. Above 360 rpm, the stirring speed no longer had any effect on the solid dissolution. The dissolution rates of cassiterite were analyzed using a suitable shrinking model. The results showed that the reaction was controlled by the diffusion of tin through the porous product layer, a reaction order with respect to hydrogen ion concentration of 0.92 M and activation energy of 50.05KJmor'. In another kinetic study on the leaching of a low grade niobium-tantalum ore with concentrated KOH solution the effect ofreaction temperature, KOH concentration, agitation speed, particle size and alkali-to-ore mass ratio on the dissolution rate of niobium were examined [5]. The result of niobium leaching from low grade niobium-tantalum ore with concentrated KOH, solution at different agitation speeds showed that the dissolution rate increased with increase in agitation rate. In the case of particle size effect, the results show that small particles require much shorter time for complete dissolution than the large ones."

Jan 1, 2013

By Ximeng Li

The entries that are subjected to dynamic pressure are much more difficult to maintain due to repeated disturbance. A case study of an entry stress distribution was performed using the FLAC3D program. By analyzing the distribution of stress field around the entries, this paper provides guidelines for entry support design in the lower (#16) seam subjected to the repeated disturbance from longwall mining in the immediate overlying (#17) seam, 72ft (22 m) above. The results showed that there was stress superposition inside the barrier pillar in the lower seam, 15ft (5m) to 45ft (15m) deep, during development. The influence zone of the front abutment pressure in the upper (#16) seam was about 100ft (30m) outby the faceline. The stress-relieved zone was from 0 to 100ft (30m) inby the face. The area further inby the face (i.e., 230 ft (70 m) inby the face) was within the gob compaction zone. Along the face advancing direction, the affected zones of the entries in the lower (#17) seam that were subjected to the dynamic pressure from longwall mining of the immediate overlying seam could be divided into four stages: pillar development stress stage, front abutment pressure stage, unstable gob stage, and stable gob stage. Those entries within an area from 100ft (30m) outby to 100ft (30m) to 230ft (70m) inby the faceline should be reinforced with special supports. The numerical modelling matched the monitoring results well.

Jan 1, 2013

By Esperidiana A. B. Moura, Michelle Gomes, Cordelia M. F. Escanhoela, Francisco R. V. Diaz, Angel Ortiz, Rene R. Oliveira

"This work evaluates changes in morphological, mechanical and thermo-mechanical properties of electron-beam irradiated HDPE/nanoclay and HDPE/Piassava fiber/nanoclay. Material samples irradiated with 100 and 200 kGy using a 1.5 Me V electron beam accelerator (room temperature, presence of air) were submitted to tensile, flexural, and HDT tests. MFI, SEM and XRD analyses were carried out. Correlation between properties was discussed. Results showed that incorporation of piassava (Attalea funifera Mart) fiber and nanoclay, followed by irradiation represented significant gain in thermo-mechanical properties. Changes in surface morphology and reduction in MFI were observed. In conclusion, it may be claimed that the incorporation of piassava fiber in small size particles and nanoclay in the HDPE followed by electron-beam irradiation effectively improved the polymer properties and led to materials with superior properties suitable for several industrial applications.1. IntroductionIn recent years, the preference for using natural fibers instead of synthetic ones in polymer composites has been growing significantly. In Brazil, due to the great diversity of woody and fibrous plants of our forests, a vast potential of natural fibers is found, presenting good mechanical strength properties, chemical and biological stability, fire resistance, abrasion resistance, shear strength and lightness, among other which may contribute to the development of new materials for different applications such as automotive, aerospace, construction, food segment, cosmetics and others [ 1]."

Jan 1, 2013

By Duan Xin-hui, Wang Xin, Peng Jin-hui, C. Srinivasakannan, Zhang Li-bo

The work attempts to optimize the process of preparation of modified semi-coke from semi-coke using phosphoric acid (H3P04) as the activating agent using the response surface methodology (RSM). The influences of three major dependent variables, the impregnation ratio, activation time, and activation temperature were assessed on the independent variables yield and the iodine number. The empirical relationship between the dependent and the independent variables were established using the quadratic response surface models, which were utilized to optimize the process parameters. The significance of each of the parameters and interaction among the parameters on the independent variable was assessed based on analysis of variance (ANOVA). The process variables were varied within the range of impregnation ratio (IR) from 1.5 to 4, activation time from 30 to 90 min and activation temperature from 550 'C to 650 'C. The optimized process conditions were estimated to be an IR of 2.29, activation time of 32 min, and an activation temperature of 605°C respectively using the process optimization tool. The BET surface area of modified semi-coke of the optimized sample was estimated to be 915m2/g, with the pore volume of0.71cm3/g, with an average pore diameter of 3.09 nm, with micropore volume fraction being 52.36%. The scanning electron microscope (SEM) images were utilized to visualize the surface pore structure.

Jan 1, 2013

By Gaifeng Xue, Lei Zhang, Xia Liu, Lina Wang, Pu Liu, Benquan Fu

"Experiments were conducted to investigate the behavior of the integrated process with a three-dimensional electrode reactor combined with Fenton process for coking wastewater treatment. Effects of initial pH value, reaction time, H20 2 dosage, Fe2+ dosage on Total organic carbon (f OC) removal rate were investigated. The kinetics of degradation of TOC from coking wastewater by three-dimensional fluid bed electrode reactor combined with Fenton process was also studied. Experimental results shows that three-dimensional fluid bed electrode reactor combined with Fenton process had better synergic effect, average 17.4% TOC removal rate was improved within an hour. It was found that TOC degradation in coking wastewater followed a pseudo-first-order reaction kinetic model. The optimum degradation efficiencies of TOC were up to 60% as pH3.4, 3.5 mM ofFe2+ andl.2-1.8ml/L H20 2 in 90min reaction period. Furthermore, the integrated process showed a rapid reaction performance at a low temperature within a short reaction time and remained high efficiencies for TOC removal. Overall, the integrated process was proved feasible for coking wastewater treatment in practical applications.IntroductionCoking wastewater is generated from coal coking, coal gas purification, and by-product recovery processes of coking, which is composed of phenolic compounds, heterocyclic compounds, polycyclic aromatic hydrocarbons, ammonia, cyanide, polycyclic nitrogen-containing aromatics, acyclic compounds, etc. Most of these constituents are refractory, poor biodegradability, toxic and carcinogenic['-31. Currently, coking wastewater is usually treated by different forms of A/O biological nitrogen removal process as the primary treatment process, but the aforementioned processes are not efficient enough to meet the requirements from the National Discharge Standard in China (GB13456-1992). According to the continuous requirement on improving environmental protection for coking industry (revised 2008), increasing wastewater utilization ratio and reducing discharge of effluent in the coke industry has to be implemented for cleaner production and sustainable development. Therefore, advanced technologies need to be developed to treat coking wastewater and reutilize the product as industrial cooling water, which would be one of the best choices to achieve zero discharge of wastewater and reduce water consumption per ton of steel [4-51 . In this study, three-dimensional fluidized bed electrode reactor combined with Fenton process was adopted to advanced treatment of coking wastewater, and the effects of operating conditions, including H2O 2 dosage, Fe2+ dosage, initial pH, and reaction time on TOC removal rate, were investigated. Meantime, study of kinetics of reaction was estimated."

Jan 1, 2013

By Jun Lu

The Pittsburgh seam is the most extensively mined coal bed in the Appalachian Basin. Unlike most other prominent coal seams, the Pittsburgh seam typically includes a sequence of immediate roof coals and intervening rock binders (or ?draw slate?), most of which are within mineable horizons. Furthermore, unlike the main bench, the thickness of the overlying roof coals and their intervening rock binders can vary significantly. For instance, in southwestern Pennsylvania, the Pittsburgh seam main bench typically ranges from about 5.0 to 6.0 feet thick with minimal variation over short distances. On the other hand, the Pittsburgh seam roof coals and immediate roof binder typically range from a few inches to several feet, and in certain geologic settings can vary significantly over short distances. Additionally, in some locations, very thick draw slate can totally replace the roof coals. Since the draw slate, which typically consists of claystone or clayladen shale, is relatively weak, the presence of thick and variable draw slate in the roof and rib can significantly affect mine safety and productivity. This paper presents the adverse effect of thick draw slate on a 1500-foot-wide longwall face in a southwestern Pennsylvania coal mine. Mapping of the thick draw slate, numerical models which illustrate stress distribution and failure associated with thick draw slate, and operational adjustments instituted to mitigate the negative impact of thick draw slate will be discussed in detail.

Jan 1, 2013

By Sheng Zhang

The compressive strength of coal in Yanlong mine area of China is less than 3 MPa. Basically, it is powdery. The roof and floor rocks are mudstone. Therefore this coal seam is a typical ?three soft? coal seam. Roof bolting cannot be used due to the very soft strata. When the conventional U-steel support was used, roadways deformation exceeded 30% of its original dimensions in some sections one half month after development. The required repair work was huge, seriously affecting the daily mine production. This paper describes how to support the soft coal roadways. The deformation characteristics of soft coal roadway were investigated. The conventional U-steel support is not subjected to uniform load, so the whole supporting structure must be strengthened. In addition, drilling holes in the coal seam can transfer high stress from near the ribs to the deeper parts of the surrounding strata, which is beneficial to the stability of the roadway. This new support method is to combine the strengthened U-steel support with pressure-relieving drill holes, providing an economic and efficient way to support the very soft coal roadways.

Jan 1, 2013

By D. H. Diering

Definition of mineral resources and reserves forms the basis for effective mine planning and reliable public reporting of mineral assets. Historically, the mineral resource and reserves declaration process has been the domain of the geology and surveying disciplines, with the declaration of the reserves by the surveyor being based on the application of modifying factors to the declared resources available for mining. As part of an ongoing process to improve efficiency, reliability, and reproducibility of results, this approach has been revised and enhanced through the introduction of a revised process and reconciliation tools. The revised approach to reserve definition is based on the definition of scheduled resources, at an appropriate confidence estimate in the context of an approved business plan, over the anticipated life of the mineral asset being applied to define reserves. This planning and scheduling is developed, during the annual business planning process, by the mine planning department using tools such as CADSMine?. The scheduled area together with the application of revised modifying factors is tabulated in the BME (basic mine equation) and reflects the mine production plan over time. Simplification of the modifying factors to dilution and losses underpins the simple yet robust approach to improved definition of reserves in this process and in the basic resource to reserve equation (BR2RE). Dilution intrinsically affects grade but not metal content, whereas the losses reflect both the efficiency of mining and planning and are reflected in metal losses, area losses, or both. Reconciliation of the derived 'resource converted to reserve' area (which is based on the business plan from CADSMine?) versus the 'resource available for mining' (which is derived from Datamine?) underpins the robustness and auditability of the reserves declaration. This R&R accounting and reconciliation approach is transparent and facilitates interrogation of the logic and rationale of long-term business planning and project strategy. These numbers are processed and reported in the logic of the basic resource equation (BRE), which also addresses aspects such as white areas (future and historic), tail management, and partial extraction (non-scheduled pillars, etc.) in compliance with SAMREC definitions. Areas that do not have the necessary confidence and data support to be declared as resources find their space as pre-resource (outside the domain of public reporting), outlining existing potential for future extraction and reporting. Use of the BRE leads ultimately to a complete, refined accounting and reconciliation-oriented approach for all production entities. The revised resource and reserve process includes the discipline of mine planning as intrinsic to the definition and declaration of resources and reserves. Subsequent to the change in process, the resources and reserves have truly become the domain of the mineral resource management discipline. This paper defines the logic of the basic resource equations and outlines their application in the definition and reconciliation of mineral resources and reserves at Anglo American Platinum Limited.

Jan 1, 2013

By Jean Igor Margem., Lucas Barbosa de Souza Martins, Frederico Muylaert Margem, Sergio Neves Monteiro, Artur Camposo Pereira, Rômulo Leite Loiola

"The fibers extracted from the stem of the bamboo plant have been investigated as possible reinforcement composites due to their relatively high tensile strength. Although previous works have already been conducted about the mechanical properties, up to now a dimensional characterization of the distribution and the effect of diameter on the elastic modulus of bamboo fiber of the specimen dendrocalmus giganteus has not been performed. The aim of the present work was to statistically characterize the distribution of the diameter of a lot of bamboo fibers of that specimen. Based on this characterization, diameter intervals were set and the dependence of the Elastic Modulus (E) of theses fibers with a corresponding diameter was analyzed by the Weibull Method. The results indicated an inverse dependence, in which the highest Elastic Modulus were obtained for the thinnest fibers. Moreover, it was found that a mathematical hyperbolic relationship fit well this inverse correlation between the Elastic Modulus and the bamboo fibers diameters.IntroductionBamboo is a well known grass-type plant with a hard and stiff stem or culm that can reach, in some species, more than 10 cm in cross section diameter and stand several meters height. Owing to its low density, approximately 0.9 g/cm3, bamboo culms have been used in house construction from scaffoldings to panels. As an abundant natural resource in tropical and temperate regions, specially in Asia and South America, bamboo is also a substitute for wood and plastics in furniture and lightweight parts of automobile [1,2]. The cylindrical shape of the culm is, however, a limitation for its direct use in engineering systems. Consequently, research works have been conducted on bamboo fibers stripped off from the culm as reinforcement of polymer composites. [1-12]. According to Shin et al [3] bamboo fiber-epoxy laminates can be made into specific sizes and shapes, preserving the natural microstructural properties. These fiber composites overcome the limitation of the culm's cylindrical macrostructure. As a further advantage, Shin et al [3] indicated that cracking and bioerosion caused by insect pests is prevented."

Jan 1, 2013

By Linda D. Raedeke

The main platinum-group metal (PGM) deposit in the Stillwater Complex is associated with a stratiform zone formed by magma mixing. In general, the intrusion is a large, layered body of Archean age which formed by repeated magmatic injections in- to a single, large, hypabyssal magma chamber. The Complex is broadly divided into the lower Ultramafic series of olivine ± orthopyroxene rocks (1000-2000 m thick) and the upper Banded series of predominantly plagioclase-rich rocks (24500 m thick). The latter is further divided into Lower, Middle, and Up- per Banded zones. The Ultramafic series, plus most of the Lower and Upper Banded zones formed from repeated injections of an olivine-saturated magma, the rocks accumulating from the floor upward with a crystallization order of olivine, or- thopyroxene, plagioclase, clinopyroxene. The olivine-bearing subzones of the Middle Banded zone formed predominantly from a magma which crystallized in the sequence plagioclase, olivine, clinopyroxene. Olivine-bearing subzone I, with which the PGM mineralization is associated, occurs generally -400 m above the Ultramafic series-Banded series contact. Ore grade mineralization is usually found in plagioclase or plagioclase-olivine cumulates. The platinum-group elements are associated with disseminated base-metal sulfides dominated by the assemblage, pyrrhotite-chalcopyrite-pentlandite. Olivine-bearing subzone I marks an interruption in the crystallization sequence of the Lower Banded zone, with the reappearance of cumulus olivine and an associated change of the crystallization sequence. These changes indicate the addition and mixing of a secondary magma of the same composition as that which later dominated in the formation of the Middle Banded zone. Characteristics associated with mixing include laterally discontinuous but well-developed layers, xenoliths of ultramafic rocks, and sedimentary-type structures such as slum- ping and graded layering. The influx of new magma caused sulfide saturation by one or more of several chemical changes including addition of sulfur, decrease in oxygen fugacity, decrease in FeO, or increase in SiO2. Once an immiscible sulfide liquid was formed, platinum-group elements were scavenged from the magma by the sulfide liquid and segregated.

Jan 1, 2013

By Andre Zingano

An underground mine using room and pillar and retreat mining methods was developed during the 1950?s. In 2009 an open cast mine was opened in the same reserve with the objective of mining five coal seams including the one previously mined. Recently, a series of slope failures were detected at the open cast mine. The surface mine map was overlain on the underground mine map, and it was observed that the slope failures were located above a retreat mined area where the overburden had caved and the ground subsided. The deformation and displacement attributable to subsidence caused a loss of strength in the overburden strata. The objective of this paper is to study the causes of slope sliding (or failure) due to the ground subsidence of rock layers above oldmined out areas. A map was created to overlay the two mines -- the abandoned underground mine and the active surface mining. Two- and three-dimension numerical modeling was conducted to simulate the slope behavior and to verify whether the mine subsidence was the cause of slope instability. This study indicated that the subsided rock layers were the cause of slope instability and sliding.

Jan 1, 2013

By T. L. Heidrick

Late Cretaceous-early Tertiary Cordilleran porphyry Cu-Mo districts and their consanguineous Zn-Pb-Ag-Au-W vein and replacement deposits of the Rocky Mountain region comprise one of the largest, best studied, diverse, complex, puzzling, and richest compound metallogenic provinces on earth. A concise space-time definition of intermineral plate, regional and local structure-tectonic frameworks is crucial to deciphering their diachronous metallogeny and enhancing the explorationist's odds of future discovery.

Jan 1, 2013

By Hongli Wen, Guangkun Shen, Qiong Deng, Shoujian Huang, Min Gan, Xiaohui Fan

"Due to the low iron grade and high sulfur content, pyrite cinder is difficult to be directly used for iron-making. In this paper, technology of magnetic roasting -grinding and magnetic separation -acid leaching was put forward for reclamation of pyrite cinder. For pyrite cinder of TFe53.51%, S2.20 %, studies showed that good magnetic effect can be achieved at roasting temperature 650~7000, reducing atmosphere CO/(CO + C02) 10~20% and roasting time 10~30 minutes. In separation conditions of grinding size -0.045mm accounting for 96.09% and magnetic field intensity of 1240 GS, iron concentrate of TFe64.81 %, S0.18% and iron recovery rate 91.44% was achieved. Acid leaching was studied to strengthen desulfurization. Results showed that high-quality iron ore concentrate of TFe66.3 l %, S0.10% was obtained under the conditions of hydrochloric acid mass fraction of 5%, pulp density of30%, leaching temperature of70? and leaching time of2 hours.IntroductionPyrite cinder is produced as a by-product of sulfuric acid industry [1] Domestic production is more than 12 million tons every year and occupied area is over 10 million square meters [2,3]. The pyrite cinder outdoor not only pollutes air but also damages surrounding surface [4] It after treatment used for iron-making is an ideal reclamation approach for its rich iron which is commonly 40-60% [5]. But pyrite cinder gets low utilization for its low iron grade and high sulfur content in China [6]. Therefore, comprehensive utilization of pyrite cinder has profound significance to environmental protection and the development of domestic iron and steel industry."

Jan 1, 2013

By Takeshi Yoshikawa, Kazuki Morita, Kunitoshi Matsunaga

"In metallurgical grade silicon (MG-Si), most impurities mainly exist at the grain boundaries and distribute in silicon grains at extremely small contents. Grain boundary phases in MG-Si transform into liquid above the eutectic temperature, and migrate towards high temperature regions when heated under a temperature gradient. With the migration of all liquid phases in MG-Si to the surface, the impurity contents will be decreased less than their solubilities in principle.In the present work, the fundamental research was conducted to discuss the possibility for purification using the liquid phase migration technique. The purification limit was estimated by thermodynamic calculations, and metallic impurities were estimated to be effectively removed except for Fe and Al. The migration behavior of the liquid phase in the synthesized silicon substrate was investigated by unidirectional heating under infrared radiation at 1523-1548 K, and the proceeding of migration was confirmed. The migration velocity was 1.4--2.0xl0-7 mis, and found to be controlled by the liquid phase diffusion.IntroductionPhotovoltaic energy is one of promising energy resources in a sustainable society because of its inexhaustibility and cleanliness. Although the production and installation of solar cells have increased significantly during the last decade, the cost of solar cell installation is still high. To enable the widespread use of photovoltaics and for the photovoltaic electricity price to reach grid parity, a low-cost and abundant feedstock of solar grade silicon (SOG-Si) is essential. Recently, a modified Siemens process and a fluidized bed reactor process were developed to address the cost and energy issues associated with the conventional Siemens process. However, their cost reduction potential is limited because of the large energy consumption needed to convert silicon into gaseous compounds. Purification of silicon through metallurgical routes offers a promising way for producing SOG-Si from metallurgical grade silicon (MG-Si), because it enhances productivity and can also lower the process costs. Although several metallurgical processes such as directional solidification [l ], vacuum refining [2-4] and plasma oxidation [5-7], have been developed, processing times and refining efficiencies still have to be optimized."

Jan 1, 2013

By R. H. Batey

"The process control and cost of monitoring mining slurries is normally accomplished using a continuous mass flow system, conventionally embodying a volumetric magnetic flow meter and nuclear density meter. DuPont’s Maxville Mine at Starke, Florida, USA was chosen to examine costs associated with performance of a nuclear density meter. Since it is typical of many mid-sized establishments and has a long history in their use. The published accuracy under ideal conditions of a nuclear density meter is ± 1.0%, but in practice considerable ambiguity of cost in annual production implies ± 2% at best. Using such accuracy in a 400mm (16”) pipe carrying zircon slurry at 75,000 tons/day, the cost of ambiguity, together with initial and running costs, amount to nominally $962,000 per year.Such cost leaves much to be desired. This paper describes an unique continuous, direct mass per unit volume Density Meter used for mining slurries in pipe sizes up to 1000mm (40”), which significantly reduces the cost of ambiguity of measurement and running costs. At the same time the disadvantages of nuclear devices are obviated.In an effort to reduce costs, a 400mm non-nuclear Density Meter was installed at the DuPont Maxville mine. A typical on-site accuracy can be shown to be ± 0.285%, whereby the cost of ambiguity, initial and running costs in the example above shows an annual improvement of $78,660, a reduction of over $880,000 per year.Even higher cost savings may be demonstrated with mass flow systems having gas entrainment compensation. Unlike nuclear and other inferential density meters, the signal quality of this non-nuclear Density Meter is totally unaffected by entrained gas found in mining slurries. This non-nuclear density meter is then ideally used with a vortex velocity domain sonic flow meter, and provides for the first time compensation in wet density or dry % solids, as well as wet or dry mass flow of mining slurries with entrained gas, resulting in enormous reductions in cost ambiguity."

Jan 1, 2013

By Kevin Phelps, Jason Baird, Philip Mulligan, Dominique Nolan

Determining the transitions from run-up to optimal cut length and optimal cut length to run down, without bias, from the penetration of a linear shaped charge (LSC) is difficult. The stresses applied to the targets during explosive testing can distort the targets in such a manner that determining the true distance of cut, penetration, or fracture can be demanding. Through the course of this research, it was observed that the researchers made many of the errors involved in the collection of data. Among these errors researchers found problems in: determining and fitting the sample to a single plane from which to read measurements, determining where along the path of cut the three phases of penetration transition, and the precision of measurement based on handheld tools and the human eye. This study looks at three methods of recording the data of a series of linear shaped charge tests. The tests resulted in samples which are not ideal for measuring with common laboratory devices like measuring tapes, calipers, or rulers. The first method utilized these common laboratory devices and the difficulties the authors experienced are described in this paper. The second and third methods involve digital photography, image manipulation, and the use of AutoCAD. Methods two and three are then compared to the simple observational method and discussion is made in regards to the precision and accuracy of each method.

Jan 1, 2013

By Richard H. De Voto

The Pb-Zn-Ag deposits within the Lower and Middle Paleozoic strata of central Colorado (Leadville, Gilman, Aspen, and others) occur principally in Late Mississippian karst-solution features within dolomites and, to a lesser extent, limestones. Several un- conformities within the Devonian and Mississippian carbonate rocks and the subregional dolomitization of the Leadville (Mississippian) Formation that occurred during the Late Mississippian resulted from recurrent uplift of elements of the Ancestral Sawatch, Gore, and Front Range areas within central Colorado. Uplift of these areas also strongly influenced the details of the extensive karst topography that developed during the Late Mississippian. In particular, uplift of the Sawatch Range area caused paleovalleys from 300-600 ft deep to form on the karst landscape. The pattern of karst-solution caverns, sinkholes, cutters, channelways, and breccia-rubble zones was strongly controlled by incision of surface drainages and the strong northeast-trending Mississippian joint system. These subterranean karst-solution features and breccia-rubble soil [ ] zones are the primary controls of the location of the Pb-Zn-Ag ore deposits in these rocks. In the Leadville and Aspen districts, the deeply incised paleovalleys occur immediately adjacent to the principal areas of mineralization. Pennsylvanian deposition of a thick terrigenous and evaporite sequence occurred within central Colorado in response to actively subsiding extensional basins and adjacent high-relief uplift areas. Hot brines developed within the Pennsylvanian strata, migrated laterally to, and moved upward vertically along, basin- margin faults during continued Pennsylvanian subsidence and deposition. These metal-rich brines migrated into karst-solution features within the Lower and Middle Paleozoic dolomites and limestones, principally within the Leadville Formation, in basin- edge uplifted locales where the Pb-Zn-Ag minerals were precipitated. Field relationships, mineral assemblages and paragenesis, fluid-inclusion data, and isotope studies suggest that the metals and brines were derived within the Pennsylvanian sedimentary sequence and that the ore minerals were deposited under different temperatures and at different depths from deposit to deposit. Chemical reaction with the carbonate cave sediment and wallrock, cooling of fluid temperatures, and mixing with meteoric ground waters were the probable combined causes of mineral deposition in the karst-solution features. Late Cretaceous-Tertiary intrusive activity has subsequently modified some of the primary Pb-Zn-Ag deposits in local areas.

Jan 1, 2013

By Willie M. NeSmith, W. Morgan NeSmith, Alan Roach

"In 2013, Augered Cast-in-Place (ACIP) piles are a mature foundation technology throughout the United States. General guidelines for the design and construction of ACIP piles are available along with numerous references for design in specific North American geologies. In fact, the current generation of contractors and geotechnical practitioners might view ACIP piles as just another deep foundation option to be considered, along with driven piles, drilled shafts and others. This acceptance has developed, however, over a 60-plus year period.The term, Augered Pressure-Grouted (APG) pile is often used when referring to ACIP piles because the piles emerged out of construction processes at the Intrusion-Prepakt firm in the late 1940s. The company’s specialty was pressure grouting and preplaced aggregate concrete. The grouting was typically accomplished by driving a pipe to a target level and then injecting grout under pressure. In some soil conditions, it was necessary to use an auger to reach the desired grouting depth. In these circumstances, the grout pipe was driven beside the auger and grout was pumped as the auger was withdrawn. The grout pipe was then withdrawn as well. This was the genesis of the APG, or ACIP pile, and many piles were installed using this technique. The patent application, “Method for Forming Piles” was filed by Raymond Patterson of Intrusion-Prepakt in 1951, and the patent was granted in 1956. The process was eventually modified when a suitable hollow-stem auger was developed. Licenses were granted to the Lee Turzillo Contracting Company and Berkel & Company Contractors, Inc. in the late 1950s. Each of the three companies Patent, LicensesThe patent application, “Method for Forming Piles” was filed by Raymond Patterson of Intrusion-Prepakt in 1951, and the patent was granted in 1956. The process was eventually modified when a suitable hollow-stem auger was developed. Licenses were granted to the Lee Turzillo Contracting Company and Berkel & Company Contractors, Inc. in the late 1950s. Each of the three companies coined their own terms for the piling process: “Pakt-In-Place” for Intrusion-Prepakt, “Auger Pressure-Grouted” for Berkel and “Augercast” for Turzillo. Over time, “Augercast” was frequently used as a generic term for the system. The installation of these piles was, and still is, a highly nuanced process; “contractor dependent” is a term often seen today. Intrusion-Prepakt, Berkel and Turzillo all had personnel who were part of the original group that developed the system and who appreciated the craftsmanship involved in forming sound piles."

Jan 1, 2013

By Shu Xinqian, Zhou Weining, Shan Zhiqiang, Feng Jifu

"Modified calcination conditions on the extraction of rubidium resources from muscovite (KAlz[AlSi301o](OH)2) ore are systematically studied. The impact of various factors on the rubidium leaching rate is also analyzed, including the agent types, roasting time, the mass ratio, roasting temperature, etc. The results indicate that the best agent is a combination of sodium chloride and calcium chloride, its mass ratio ofmuscovite/NaCl/CaClz is 1:0.25:0.25. Calcined at 8500 for 30 minutes, the rubidium leaching rate is up to 90%. The reaction of muscovite ore with the chlorinating agent CaC12 has been studied by TG/DSC, the calcined intermediates are identified by XRD, and the surface morphology before and after leaching is characterized by SEM. Rubidium chloride products can be obtained with a purity of 92% by using t-BAMBP extraction, hydrochloric acid reextraction and purification.IntroductionRubidium is one ofrare alkali metals, which is found in 1981 by German R.W. Bunsen and G.R. Kirchhof. Rubidium includes the following features: atomic number is 37, each atom weight 85, the body-centred cubic lattice, each unit cell has two metal atoms, and the density is 1.532g/cm3. The properties of low melting point (312.46 K) and malleability make rubidium have a strong chemical activity and photoemission. Rubidium provides a main material for manufacturing phototube with a wide range oflight waves, which possess high sensitivity and stability. Efforts are being made to carry out research on rubidium ion gngine, magnetic flux generators and thermoelectric transudcer, etc. Rubidium exists in muscovite ore(KA12[AlSh01o](OH)2 (monoclinic system and hexagonal layered structure) as isomorphism and replace the large radius of the potassium atoms, as well as part of rubidium locate between structure layers. The complex components bring great difficulty in comprehensive recycling."

Jan 1, 2013