Search Documents

By J. E. Papin

Morenci ores contain as an average about 0.015 pct molybdenite, MoS2. Incidental to the concentrating operations applied for the recovery of copper minerals, approximately two-thirds of the molybdenite is floated and appears in the final copper concentrate. The economic importance of molybdenum and the success achieved in its recovery in milling operations elsewhere encouraged research directed toward its recovery in marketable form. Several procedures are utilized to effect separation of molybdenite from copper and iron sulphides, but only two have wide application. In the better known of these two methods the molybdenite in the copper concentrate is depressed in a flotation operation using soluble starch as the depressant. The tailing from this treatment thus becomes a low-grade molybdenite concentrate which after thickening, filtering, and low temperature roasting is repulped with water and subjected to additional flotation steps for recovery of the molybdenite. A thio-phosphate collecting agent is employed in flotation of the copper minerals. Presumably the stability and lasting effects of that collector type necessitated the practice of depressing molybdenite followed by subsequent roasting to insure elimination of copper and iron sulphides from final molybdenite concentrate.

Jan 2, 1955

By Peres EC

The flotability of monazite, zircon and rutile in the presence of sodium oleate, potassium octyl hydroxamate and a commercial hydroxamate was investigated through microflotation tests in a modified Hallimond tube. Zeta potential determinations in the absence/presence of collectors were performed in a microelectrophoretical cell. The microflotation testwork showed that, in general, the flotability characteristics of all three minerals are very similar. Commercial hydroxamate is, by far, a stronger collector than the pure potassium octyl hydroxamate. Electrokinetic studies indicated that the adsorption of collectors shifts the isoelectric point (IEP) of the minerals towards lower pH values. These collectors also are capable of changing the zeta potential values to more negative figures in the pH region above the isoelectric point. An increase of the conditioning temperature, generally, enhances the floatability of the three minerals. A depressant is required in order that selective flotation is feasible in the system monazite-zircon-ruffle. Sodium metasilicate is an efficient depressant for zircon and rutile and affects only slightly the flotability of Monazite.

Jan 1, 1993

By J. L. Huiatt

Kerosine, fuel oil No. 2, vapor oil, and fuel oil No. 6 were separated into general hydrocarbon fractions by ion exchange chromatography and adsorption chromatography. The collecting properties of these fractions were evaluated by flotation of molybdenum and copper minerals from a natural chalcopyrite ore. Paraffin fractions and aromatic fractions of low polarity produced the best molybdenum recoveries. Selective flotation of molybdenite from copper sulfide minerals was not possible with any of the chromatographic fractions.

Jan 1, 1972

By J. Kallioinen

Flotation of low grade Ni ores with serpentinite host rock tend to yield low recoveries of Ni With high MgO contents in the concentrate. The recovery can be enhanced by optimizing the sub-processes in the pulp and in the froth. The new OF-100 flotation cell has been designed to be adaptable to different feed fineness (Coarse, Fine). The losses can according the research conducted at Outokumpu's Hitura plant be substantially decreased by OF-100's new rotor and stator design and froth zone geometry. The froth residence time is used to adapt for feed particle size changes measured by the Outokumpu PSI- 200. Models for the behaviour of different particle Sizes in the sub-processes have been developed. The modified froth zone geometry and the capability of maintaining a froth of desired thickness allows efficient washing of the obtained concentrate producing low levels of MgO.

Jan 1, 1994

By Mwaba CC

Ok Tedi Mining Ltd has been using flotation for the production of copper/gold concentrates from a complex copper sulphide ore for several years. During this period, much effort has been devoted to metall- urgical treatment of the ore. This paper examines some of the mineralogical aspects of the sulphide minerals in the ore using the electron microprobe analyser. Results have revealed the complexity of the copper sulphide minerals and in particular, chalcocite. Analysis of both plant and laboratory flotation products has provided further insight into the effects of mineralogy on the flotation of copper and iron sulphides. A significant observation is that some of the pyrite minerals apparently exhibit natural floatability. The implications of the mineralogical characteristics of the sulphide minerals on the flotation of the ore are also discussed.

Jan 1, 1991

By R. A. Pallanch

IN his recent paper, "The Controversial Art of Flotation," (Mining Technology, March, 1944) E. H. Rose states that "flotation is a science in so many variables that only art can blend them." This statement is apt. It contains meat. In other words, a valid scientific reason is behind every flotative effect. Some of these reasons we understand, but much the greater number of them still escape us. This does not prevent us from "going places," as familiarity and experience with the problems result in an increasingly intelligent and artful handling of these effects. Hypotheses are built up by the individuals concerned to explain certain happenings. Many of these hypotheses have to be abandoned when placed under the glaring scrutiny of actual trial. A few survive the severest of tests, come through unscathed, and are elevated to the rank of theories, something susceptible of certain chemical and physical explanation, under the conditions of the particular plant concerned. If these theories continue to hold water under all the variations existing in most milling plants, they gradually become accepted as facts in the minds of the plant operators. But-and here is a big BUT-these so-called facts may fall down completely in another plant working under an entirely different set of conditions. In other words, each plant tends gradually to build up its own facts, which may or may not be facts at another operation.

Jan 1, 1945

By J. C. D. Gush

Paper written on project work carried out in partial fulfilment of Laboratory-scale testwork was undertaken to recover oxidic copper-cobalt minerals by froth flotation, which requires maintaining a certain sulphide level in the pulp. To improve control of the sulphide concentration, an electronic closed-loop system was designed that responds to the potential output of an ion-selective electrode. The PID control was improved by adding a pre-emptive control and a self-calibration feature; a data logging facility is also included. An inexpensive valve design was incorporated using locally available parts. The operating results of this control design are presented.

Jan 1, 2005

By A. W. Hahn

ALTHOUGH enormous tonnages of sulfide lead and lead-silver ores are treated by flotation, the products of flotation mills treating oxidized ores of lead and silver are almost negligible. However, each year there is a slight tonnage increase, and it is possible, should a sizeable oxidized lead ore tonnage be developed, the field will become an important one. In 1918, the Shattuck-Arizona Copper Co. erected a plant at Warren, Ariz., for the treatment of oxidized gold-silver-lead ores. Glenn L. Allen worked out the metallurgy for this plant, employing tabling, followed by flotation concentration. The Shattuck-Denn Mining Co., successors to the Shattuck-Arizona Co., now employs straight flotation in the same mill, treating about 200 tons daily. In 1922, the San Diego mill of the American Smelting & Refining Co., in the Parral district, Chihuahua, Mexico, started operating a 600-ton mill on a mixed sulfide-oxide gold-silver-lead ore. Tables and flotation are used here, and about 200 tons of oxidized slime treated by flotation. In 1923, the Eureka Holly Mining Co. started operating a 90-ton mill at Eureka, Nev., using tables and flotation, on an oxidized lead-silver ore. In 1924, the American Smelting & Refining Co. started a 250-ton mill in northern Peru, to treat a high-grade oxidized gold-silver ore with very low lead values. In 1924, the Grand Central Mining Co. started a 200-ton flotation mill on old oxidized gold-silver-lead tailings at Fairbank, Ariz. In 1926, the Compania Internacional Minera, a subsidiary of the Union Corporation of London, started a 250-ton flotation mill on oxidized lead-silver ores, and during April of this year, the Phelps-Dodge Corpn. will probably start a 250-ton mill at Warren, Ariz., on oxidized lead-silver ores, similar to those being treated in the Shattuck-Denn mill. METHODS All of these mills use sodium sulfide for filming the oxide minerals, with the possible exception of the North Peru mill, and all use oily reagents. The total tonnage of strictly oxidized lead-silver ores concentrated by flotation is probably less than 2500 tons daily. The following figures give the various types of ores being treated:

Jan 1, 1928

By A. W. Hahn

ALTHOUGH enormous tonnages of sulfide lead and lead-silver ores are treated by flotation, the products of flotation mills treating oxidized ores of lead and silver are almost negligible. However, each year there is a slight tonnage increase, and it is possible, should a sizeable oxidized lead ore tonnage be developed, the field will become an important one. In 1918, the Shattuck-Arizona Copper Co. erected a plant at Warren, Ariz., for the treatment of oxidized gold-silver-lead ores. Glenn L. Allen worked out the metallurgy for this plant, employing tabling, followed by flotation concentration. The Shattuck-Denn Mining Co., successors to the Shattuck-Arizona Co., now employs straight flotation in the same mill, treating about 200 tons daily. In 1922, the San Diego mill of the American Smelting & Refining Co., in the Parral district, Chihuahua, Mexico, started operating a 600-ton mill on a mixed sulfide-oxide gold-silver-lead ore. Tables and flotation are used here, and about 200 tons of oxidized slime treated by flotation. In 1923, the Eureka Holly Mining Co. started operating a 90-ton mill at Eureka, Nev., using tables and flotation, on an oxidized lead-silver ore. In 1924, the American Smelting & Refining Co. started a 250-ton mill in northern Peru, to treat a high grade oxidized gold-silver ore with very low lead values. In 1924, the Grand Central Mining Co. started a 200-ton flotation mill on old oxidized gold-silver-lead tailings at Fairbank, Ariz. In 1926, the Compania International Minera, a subsidiary of the Union Corporation of London, started a 250-ton flotation mill on oxidized lead-silver ores, and during April of this year, the Phelps-Dodge Corp. will probably start a 250-ton mill at Warren, Ariz., on oxidized lead-silver ores, similar to those being treated in the Shattuck-Denn mill.

Jan 1, 1927

By Albert Hahn

ABOUT three years ago John Hays Hammond took over the control of the Eureka Metallurgical Co., at Salt Lake City, Utah. Funds were advanced for investigating the process invented by R. V. Smith, for concentrating oxidized lead ores. A great deal of laboratory work was done and a reagent was developed by C. M. Nokes of Salt Lake, which was found to be particularly suitable for oxidized copper ores, refractory manganese silver ores, and oxidized gold ores. After sufficient laboratory work had been performed to demonstrate the fundamental principles of these inventions, a test mill, having a capacity, of 20 tons of ore daily, was erected at Murray, Utah. In this test mill approximately 1200 tons of various types of ores have been concentrated by means of the above-mentioned process and reagents, and this large-scale work as well as laboratory work is being continued at present. Details of these mill tests are given in Table 1, and a representative group of laboratory tests are shown in Table 2. The process requires no special machinery or appara-tus. Its success depends entirely, on the method of preparing the pulp and its subsequent flotation in clean water, as outlined in the Smith patent. The reasons for the success of the Nokes special reagent are not definitely known. The outstanding feature, which seems to be of extreme importance, is that when the concentrates are examined under the microscope, each particle of mineral appears to have a particle of paraffin, attached to it. This paraffin-mineral combination seems to be particularly suitable for flotation and it follows that any coating oils readily attach themselves to the paraffin-mineral combination.

Jan 9, 1923

By L. Martins

To increase zinc recovery in the concentrate, this investigation performed mineralogical characterization, dispersion studies, bench and pilot-scale flotation experiments and an industrial flotation trial. The objective was to verify the flotation behavior of the silicate zinc ore (calamine type) in the presence of slimes, with the aid of dispersing agents. Characterization studies identified the major minerals in the flotation feed as hemimorphite (calamine), quartz and dolomite. Dispersion tests showed that enhanced dispersion of the particles in the pulp in the absence of reagents occured at a pH range between 8.5 and 12.0. Bench-scale flotation experiments were planned using the statistical tool of complete factorial design at two levels, replicated once. These experiments showed, and were confirmed at the pilot-plant scale, that higher doses of sodium sulfide and polymeric dispersant combined with sodium silicate favored a higher metallurgical recovery. At 6,800 g/t (218 oz/st) sodium sulfide and 6,992 g/t (224 oz/st) polymeric dispersing agent combined with sodium silicate, a zinc grade of 38.4% in the final concentrate was achieved, at an average metallurgical recovery of 72.4%. The industrial trial confirmed the pilot scale results, leading to zinc recovery of 76.1% and a 37.3% zinc grade in the concentrate. Key words: Froth flotation; Flotation reagents; Flotation depressants; Zinc/ zinc ores

Jan 1, 2010

By P. Raffinot, M. Rey, V. Formanek, G. Sitia

CONCENTRATION of oxidized copper and lead ores by flotation has been practiced for 30 years, but flotation of oxidized zinc ores has remained unsolved until a few years ago. This problem is, however, of great importance in mining districts where large tonnages of oxidized zinc ores exist in underground mines or in dumps. Some sulphide ores also possess a degree of oxidation high enough to justify recovery of oxide zinc minerals. Various attempts have been made to float the zinc carbonate, smithsonite.

Jan 4, 1954

Flotation of Phosphate Gangue from Magnetite Fines - Non-Ionic Surfactant as Atrac Collector Modifier

Sep 13, 2010

By H. Sis, S. Chander

The beneficial effect of a series nonylphenol polyethylene glycol ether surfactants were tested in the flotation of phosphate ores in which the mixture of sodium oleate and dodecane was used as collector. The performance of nonionic surfactants was first tested in the microflotation of pure apatite mineral. Microflotation experiments showed that the recovery of apatite depends on the number of ethoxylation of the nonylphenol surfactants and decreased with higher ethoxylation. The nonionic surfactant with the smallest ethoxylation group used in this research (NP-4) was then tested in batch flotation of phosphate ores. The flotation of three different size phosphate ores was carried out in the absence and presence of NP-4 surfactant. The beneficial effect of nonionic surfactant was obtained for fine size (-35+150 mesh) and very fine size (-150+400 mesh) phosphate ores at different collector dosages studied. But, in the flotation of coarse size (-16+ 35 mesh) phosphate ore the beneficial effect of nonionic surfactant was obtained only at high collector dosages.

Jan 1, 2002

By Janusz S. Laskowski

The most important type of potash ores, sylvinite, contains sylvite, halite and a small percentage of insoluble gangue [sulfates (anhydrite), carbonates (dolomite), and clay minerals]. Primary normal long-chain amines are exlusively utilized to float sylvite from halite, but since mines are also adsorbed by insoluble slimes, the process requires prior desliming. This is carried out either by mechanical means, or by flotation of slimes and blocking off the adsorption centers on clays with the use of polyelectrolytes. Fractional crystallization is employed to produce fertilizer grade KC1 from disseminated ores with a high content of slimes. An extender oil is needed in addition to mine to float coarse sylvite fractions. The process is carried out in a saturated brine at mine concentrations exceeding the solubility limit and is strongly affected by temperature fluctuations. All these important features, which make this process differ from a conventional flotation, result from a high electrolyte concentration.

Jan 1, 1994

By N. Sahin, M. Can, Z. Ekmekçi, Y. Öztürk, Ö. Biçak, I. B. Çelik, B. Kocabiyik

"In this paper, a case study from Çayeli Bakir Isletmeleri A.S. (Rize, Turkey) about the selective flotation of copper minerals from sphalerite is discussed. Çayeli Cu-Zn Sulfide Ore contains different ore types, such as yellow ore, clastic ore, bornite-clastic ore, bornite-yellow ore, and black ore. For some of these ore types, selective flotation of copper and zinc is very difficult presumably due to presence of secondary copper minerals such as bornite, chalcocite and covellite, and also surface oxidation. These factors affect Cu-Zn selectivity due to activation of sphalerite particles in the ore during the process. The main objective of this work was to improve Cu-Zn selectivity by optimization of the pulp chemistry for different ore types of Çayeli ore. After preliminary flotation tests investigating effects of different chemical conditions, a plant survey was performed to determine the plant performance and sources of the problems when problematic bornite-clastic ore is treated in the plant. Various chemical conditions are tested in the laboratory scale test for better depression of sphalerite in copper flotation circuit. Combination of Na2S+ZnSO4+MBS was found to be the most effective depressant scheme. INTRODUCTION Ore variability is one of the most important factors affecting performance of a process plant both in short and long term planning. The geometallurgical modelling becomes a common tool to determine ore variability problems and develop the most efficient solution during life of mine (1, 2). Flowsheet design and equipment selection and sizing are usually done based on the results of ore variability test works. However, in some cases ore variability may not be foreseen during the design stage and therefore the solutions should be developed based on the existing flowsheet and equipment in the plant. In this situation, ore characterisation, problem statement and diagnostic testing should be applied step by step. The problem could be due to changing feed grade, mineralogical characteristics, grindability and surface characteristics when flotation is involved. The variability in feed grade with fixed mineralogy can be handled with relatively simple modifications (i.e. adjusting throughput or equipment capacity) in the plant. Variability in ore mineralogy is the most complex and difficult problem to tackle. Because, mineralogical variations could bring variations in mineral composition, texture and liberation. These variations can potentially lead to the variations in grindability of the ore and flotation behaviour. Variations in grindability are usually managed by optimization of operational parameters in grinding circuit, as it would be costly to replace the existing equipment in the circuit (3). The variations in flotation behaviour are mainly due to variations in mineral types and distribution, texture and surface oxidation. One or all of these factors could be observed in a flotation operation. Therefore, a comprehensive investigation both in plant and lab scale should be conducted for definition of source of the problem. The testwork to solve the problem and retrieve the performance is planned and conducted depending on the source of the problem (4, 5)."

Jan 1, 2017

By Walter Morley

This paper is a record of the first of a series of tests on sulfide minerals to be made by the metallurgical department f the University of California. The purpose of the tests here recorded is to determine the action of standard oils, oil mixtures, and addition agents on the flotation of pyrites. The question of the commercial value of pyrite was not considered. Of the many factors affecting flotation, only two-the oil and the other agent used-were made variable. The flotation agents used are given in the accompanying table. PENSACOLA TAR AND TURPENTINE CO. (PENTARCO) NON-POL., SP. Dis. REF. PER No. KIND GR. POINTS INDEX ?VISC. CENT. 200 Refined wood creosote oil 0.965 105-275 1.5096 1.7 7-8 350 Crude pine wood oil 1.019 70-345 1.525 2.9 4 75 Crude wood turpentine 0.887 65-217 1.456 0.9 10-12 80 Crude pine oil 0.911 70-232 1.4894 1.1 8 750 Heavy pine tar oil 1.063 165-350 1.557 41.0 400 Wood creosote oil 1.025 190-360 1.4977 2.9

Jan 7, 1921

By R. J. Gochin, M. A. Diaz

A modified Hallimond tube is described which allows the determination of the ultimate recovery R and the flotation rate constant k in a single, continuous experiment. The range of fine particles which can be satisfactorily floated with the modified apparatus can be extended by increasing the length of the bottom part of the tube. Findings suggest that pyrite and arsenopyrite can be separated in alkaline suspension using the so-called F series of collectors. Lime was found to act as a depressant. The collectors operate under pH and dosage control and do not require other depressants. Collectors used in the study were thio-amine (a cationic surfactant) and alkyl propionamide (a non-ionic surfactant)

Apr 1, 1995

By K. J. Miller

A two-stage froth flotation technique was developed in the laboratory to separate fine-size pyrite from coal. The process consists of the initial flotation of a 15-percent solids coal slurry with a minimum of frother; the coarse, free pyrite and other refuse are removed in the tailings. The froth product from this first stage is then repulped and treated with a coal depressant, a pyrite promoter, and a frother to float the remaining fine-size pyrite or pyrite attached to coal particles. With the two-stage process, the pyritic sulfur content of a Lower Freeport bed coal sample was reduced from 1.78 percent to 0.75 percent in the first stage, and from 0.75 percent to 0.27 percent in the second stage with good clean coal recovery.

Jan 1, 1972

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015