Search Documents

By Takao Yasugi

The majority of copper in the raw material migrates to the de-copperized dross that forms when the crude lead produced in the blast furnace is treated in the de-copperizing process. The de-copperized dross is treated in the electric furnace producing matte, speiss, and crude lead. The de-copperized dross also contains the silver. Therefore, it is important to improve the rate of silver migration to the crude lead. For this reason, the behavior of silver between the matte, speiss and crude lead phases was examined. At the same time, several tests to improve the percentage of silver migrating to crude lead were conducted.

Jan 1, 2003

By Xin Li, Hai-Xing Fang, Bing Xie, Hong-Yi Li

Chromium-containing vanadium slag (V-Cr slag) was obtained by an industrial smelting process of Hongge Ore, which is valuable vanadium-titanium magnetite to extract V and Cr in China. Sodium roasting thermodynamics of V-Cr slag in presence of oxygen were calculated to evaluate the reactivity of chemical compounds. Results showed that the oxidation of FeV2O4 was intensified in presence of Na2CO3 while the oxidation tendency of FeCr2O4 was far lower than that of FeV2O4. It was probably that reactions of impurities including Al2O3, SiO2 and Fe2O3 with Na2CO3 happened and the products can promote the oxidation of vanadium or chromium compounds in lower valence. Based on thermodynamic analysis, a two-step selective extraction process of vanadium and chromium was proposed. Extraction rate of vanadium was 88.6% while 7.0% for chromium in the first extraction step; extraction rate of 90.7% and 95.4% for vanadium and chromium, respectively, were obtained in the second step.

Jan 1, 2014

By Zhenglong Li

A process has been developed to recover titanium from a blast-furnace slag which contains about 20-25% Ti02 and 12% Fe. In this process. "hot" slag from the blast furnace is directed to a separate furnace where it is reheated with additives to form two simple slag phases: one is titanium enriched anosovite (Ti3O5) and the other is a titanium lean non-crystal glass phase. The modified slag is then processed by conventional beneficiation techniques to produce a marketable titanium concentrate and a usable slag material. This paper focus on separating anosovite from glass by electrostatic separation and froth flotation.

Jan 1, 1996

By Zhao wen Wang, Ramana G. Reddy, Min Li

"The electroreduction of Co(II) in l-butyl-3-methylimidazolium tetrafluoroborate (BMlMBF4) ionic liquid was investigated by cyclic volatrnmetry at 353 K. The results show that the reaction of Co(II) to Co is irreversible in one step with two electrons transferred. The diffusion coefficient of Co(II) was estimated to be 7.6 x 10-8 cm2 s·1 at 353 K. Then the electrodeposition of cobalt was studied at different cathodic potentials (-0.80 to -0.95 V) and different temperatures (333 to 363 K) in BMIMBF 4 containing 0.20 mol L-1 Co(BF4)z. The deposits were characterized using scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD). SEM images show that a uniform, dense, and compact deposit was obtained at -0.80 V and 333 K. The deposits were identified as high-purity metallic Co for all experiments by EDS and XRD.IntroductionCobalt is known as a hard magnetic material and cobalt alloys have been shown to have excellent magnetic properties with adequate mechanical durability and corrosion resistance, which are needed for high performance magnetic recording applications [1-4]. The electrodeposition of Co alloy in the aqueous solution is generally difficult because of the narrow electrochemical potential window of water, which leads to the low current efficiency and worse quality of deposits due to the hydrogen embrittlement. Thus, aprotic ionic liquids (ILs) are expected to be the ideal alternative media for electrodeposition of cobalt or its alloy since ILs usually provide a wide working potential windows, negligible vapor pressure, and acceptable conductivity for electrolysis without the occurring of hydrogen evolution [5, 6]."

Jan 1, 2014

By A. A. Bustos

A model was developed to simulate the blow-by-blow operation of the converting process. From the weights, compositions and temperatures of all converter feeds the model calculates the composition and tonnage of both converter matte and slag as well as bath temperature at the end of each blow. The development of the model and its application to the converter aisle operation are described. There is good agreement between model predictions and observed results. At the present time the model is being used to investigate different converting schemes and their effect on pay metal recoveries, slag chemistry and temperature of the bath. Future work involves the use of the simulation model as a process control tool for the converting operation.

Jan 1, 1988

By S. Viswanathan, Q. Han, A. S. Sabau

"In spite of recent advances in the mathematical modeling of fluid dynamics for materials processing applications, no significant advances have been made in the numerical discretization of these equations. In this work, the application of two-step projection methods for the numerical simulation of interdendritic flows is discussed. Unlike previous methods, the methods presented here are constructed for the exact equations which are characterized by variable density and volumetric fraction of the liquid. The drag terms, which describe the momentum loss due to the flow around and through the dendrite structures, are treated implicitly. Numerical examples for shrinkage-induced flow during solidification of an Al-4.5% Cu alloy bar is used to illustrate the effectiveness of the proposed algorithm.IntroductionLiquid contraction during solidification plays an important role in the formation of casting defects such as shrinkage voids, microporosity, and macrosegregation. Owing to their importance, the study of transport processes during solidification have received considerable attention during the past years [1, 2]. By the use of volume-averaging techniques, the mass and momentum equations for flow through a stationary dendritic structure were derived [3]. By using the volume-averaging techniques for multi-phase systems, two-phase transport equations for solidification problems were derived [4]."

Jan 1, 1999

By O. Morfín

The most probable source of Pb contamination in the perennial reach of Aravaipa Creek, Arizona, has been determined using Pb isotope ratios and total metals analyses of samples collected from the ephemeral and perennial reaches and mine wastes located in the Aravaipa Mining District . Previously, elevated levels of Pb, Cd and As in fish in the perennial reach of Aravaipa Creek, a protected wilderness area,, were assumed to be due to off-site transport from abandoned flotation tailings piles located at Klondyke, Arizona upstream of the wilderness area.Our work replaces this inference with isotopic data that allows us to confirm this hypothesis. The Pb/Zn deposits of the district were mined between the late 1890s and the late1960s, with the most significant ore production coming from one deposit in a rhyolite dike swarm on the Western front of the Santa Teresa Mountains, a granitic pluton of Cretaceous-Tertiary age (~65 ma). Mineralogy has been well constrained across the length of the lode system: Pb and Zn sulfides predominate in the NW sector, and a mixed suite of hypogene/supergene Pb sulfide and Pb oxide minerals comprises the majority of its SE corner. Total metals analyses and comparison of metals ratios serve to constrain the source and transport of certain metals within different parts of the system. Pb isotope ratios in samples, obtained by ICP-MS analysis, define two distinct contributors. The first end-member (208Pb/204Pb = 38.513 to 38.721 and 207Pb/204Pb= 15.550 to 15.598) is characteristic of the mixed, oxide/sulfide ores at the SE end of the deposit. A second end-member (208Pb/204Pb = 38.855 to 38.946 and 207Pb/204Pb = 15.610 to 15.625) characterizes samples taken from the NW, purely Pb sulfide end of the lode. Pb isotope ratios from perennial reach sediments are closely correlated with ratios given by samples from the Klondyke tailings site and by Pb sulfide samples from the NW sector, the primary source of ores processed at Klondyke.

Jan 1, 2003

By Guy Deschênes

Thiourea solutions can be used as leach liquors to treat gold ores or slimes. It is also efficient to elute resins or strip solvents that were loaded in cyanides solutions. The hydrogen pressure reduction is a practical step to recover gold and silver from leach solutions, and strips and eluates without any destruction of thiourea. It is a critical point because these processes have to consider the recycling of the liquors to be irore economical. The effect of temperature, pressure, acidity, compotation of the solution and the nature of catalysts on pressure reduction by hydrogen were investigated. An electranetallurgical study was? carried out to investigate the mechanism. The composition of the products was studied by different analytical methods. The process shows a good selectivity to precipitate gold and silver in a thiourea solution containing iron and copper. Gold and silver concentrations can be decreased to 0.2 ppm and 0.1 ppm at respectively 70 KPa H2 and 28°C. No decomposition of thiourea was evident during the tests. Metals such as nickel powder or platinum activate the reaction and improve the reduction.

Jan 1, 1989

By Jayagopal Uchil, M. Krishna, Shanta Sastcy

"Damping behaviour of aluminite particulate reinforced ZA-27 alloy metal matrix composites processed by compocasting method is studied. The weight percentage of particulate reinforcement is 0,1,2,3, and 4%. A dynamic mechanical· analyzer is used ·to measure the damping capacity and dynamic modulus at the natural frequency of the specimen over a temperature range of 30°C to 300 °C both in the heating and cooling cycle. The damping capacity of the material is found to increase with increase in temperature and weight percentage of aluminite reinforcement although this is accompanied by a decrease in dyliamic modulus.The damping capacity and dynamic young's modulus exhibit a sharp decrease in their values around 300 °C a8 ZA-27 alloy undergoes a first order phase transition in this region which is confirmed by Differential scanning calorimetric studies. Several damping mechanisms have been evaluated theoretically for the material under study. The damping capacity at low temperatures is attributed primarily to coefficient of thermal expansion mismatch induced dislocations and high intrinsic damping of the matrix. At higher temperatures the damping capacity is attributed to ZA-27/aluminite interface, phase transformations and thermoelastic damping.IntroductionMetal matrix composites. (MMCs) offer designers many added benefits, as they are particularly suited for applications requiring good strength at high temperature, good structural rigidity, dimensional stability, and lightweight [1-5]. At present, the usage of ceramic particles as reinforcement in MMCs has attracted considerable interest from scientists and engineers. The MMCs show substantially improved elastic modulus, strength, stiffiless, and tribological properties with low coefficient of thermal expansion compared with the unreinforced matrix material."

Jan 1, 2000

By V. P. Keran

The lead and copper smelting processes employed by Mount Isa Mines Limited, Mount Isa, Australia, are used to illustrate an operating viewpoint of some problems and solutions encountered in existing commercial sulphide smelters. The smelting processes discussed; include updraught sintering, blast furnace and reverberatory smelting, and converting. Selected examples are given of methods implemented, and options available, to improve the productivity and efficiency of conventional smelting processes.

Jan 1, 1983

By D. M. Hausen

Applications of process mineralogy to the exploitation of molybdenum ores begins with early exploration and continues through the evaluation of mineralized prospects, to amenability testwork and pilot plant studies, to the development of a mineable orebody and to the development of a viable process for recovery. After plant construction, a broad range of products from a wide selection of sampling locations, i.e. grinding circuit, flotation cells, smelters and roasting kilns. etc., are evaluated analytically and microscopically, followed by periodic troubleshooting of problem points. The various crystalline phases of molybdenum that occur naturally and throughout various hydrometallurgical and pyrometal1urgica1 processes are identified and characterized by a variety of instrumental methods, including XRD-XRF, optical and electron microscopy, infrared spectrographic and differential thermal analysis.

Jan 1, 1989

By Milton Blander

A review of concepts and theories for predicting thermodynamic solution properties of multi- component high temperature liquid solutions is reviewed. During the last 50 years the ability to predict :such properties for molten salts, silicates and metals based on the generally known properties of the lower order (often binary) systems has been developed and shown to provide predictions which are quite useful in science and technology. There are many gaps in our understanding of these high temperature solutions, especially for metals, and considerably more work is needed.

Jan 1, 1996

By Derek J. Fray

"A need exists for fast and accurate analysis of species in various phases at elevated temperatures. Although modern analytical techniques are very efficient, the equipment is usually situated some distance from the industrial operation and time is spent taking the sample and sending it to the analytical facility. Several minutes can easily lapse and, during this time, heat must be supplied in order to keep the system molten and, if the composition is changing rapidly due to a refining process or reaction with the environment, the information may only be of retrospective use. Perhaps more important reasons for the use of on-line sensors are that instantaneous analysis gives better control, process optimisation and the minimisation of energy losses and pollution. To date oxygen has been the only element which is measured widely using solid electrolytes. However, the analysis of many more elements is required and possible electrolytes for other species are discussed. For some elements, ~here is no suitable conducting electrolyte and, therefore, a different approach is adopted where the electrolyte, in which one species is mobile, comes to equilibrium with another species. IntroductionThere is an ever increasing demand for the development of sensors for on-line measurements in most areas of technology and, in particular, metal processing. This is especially relevant in situations where greater control can be achieved by monitoring the chemical composition of the melt during processing and where a minor constituent in the melt can have a major effect on the properties of the finished alloy. Although modern analytical techniques are fast and reliable, the equipment due to its complexity, is frequently situated away from the process area and valuable time may be spent in sampling and transportation. During this period, heat may have to be supplied to prevent solidification and the refining reactions may be continuing, and, therefore, the analytical information may not be of direct use."

Jan 1, 1988

By W. G. Davenport

This chapter demonstrates how our matrices can be used for controlling a flash furnace. Specifically, it shows how we can determine the adjustments in industrial oxygen, air, oil and flux input rates that will; (a) correctly alter product temperatures and compositions to newly targeted values (b), maintain set-point product temperatures and compositions with varying feed compositions and feed rates. It also discusses corrective actions that might be taken when furnace temperature and matte grade unexpectedly change.

Jan 1, 2001

By De-qing Geng, Guang-liang Wu

The waste slag generated by the LF refining process of Q345B low alloy hot-rolled steel, still has some refining capabilities. If recycled, it can reduce environmental pollution, and save the economic costs. A research on melting Characteristics of Q345B steel LF refining waste slag was investigated by using orthogonal experimental method, and the effect laws of composition on that were analyzed. Through variance analysis and significance criterion, it is concluded that the optimum ingredient of the regenerated LF refining slag is 25%A12O3, 12%CaF2, 7%MgO and R= (CaO)/ (SiO2) =2.5. And the regression analysis is carried out by using SPSS software, to get the mathematical relationship between ingredient with high reliability and melting temperature of refining slag T=1451.3-6.25CaF2+2.36 R.

Jan 1, 2016

By Fei Ruan, Chang Jie, Jieyu Zhang, Jifang Xu, Kuochih Chou

"Viscosity is an important physical parameter of slag in metallurgical processes. Most studies of aluminosilicate and aluminate systems assume that aluminum occurs in tetrahedral coordination. In this case, the O/Al value was utilized to describe the slag structure in terms of the network character of aluminosilicate and aluminate systems. Composition and viscosity data from the literature and the trends were analyzed according to the O/Al value and temperature. It is shown that the O/Al value explains the trends in more than ten systems, containing more than 200 data points. In aluminosilicate system, the trend that viscosity value changed with the O/Al value which implies that alumina works as network modifier such as basic oxides or works as network former. In aluminate system, irrespective of the system and temperature, viscosity decreased steadily when O/Al value increased.IntroductionMetallurgical slags, which are made of oxides and many also contain fluorides, play an important role in metallurgical processes such as iron making, steel making and secondary refining processes. Aluminosilicate slags are applied in a wide range in metallurgical processes. A polymerizing effect of the addition of aluminum and an association of aluminum with low-field strength cations is further supported by the physical variations in aluminosilicate and aluminate systems. The behavior of alumina in silicate melts has been studied by various authors [1-6]. It is generally accepted that Al2O3 is amphoteric [7] because Al3+ ions can behave in profoundly different ways in a silicate melt. When added to a pure silica melt, Al2O3 acted as a network modifier, breaking the bridging oxygen of the pure silica network, thereby decreasing the viscosity in a similar manner to other network modifiers, such as CaO, MgO etc. to form [1/2Ca (AlO4)]4- complexes. However, when added with alkali or alkali-earth metal oxides, some of the Al3+ ions assumed tetrahedral coordination and replaced Si in the liquid network, the missing charge was compensated by Me+ or Me2+ ions. Therefore Al2O3 acted as network former [8, 9]."

Jan 1, 2011

By P. A. Botha

Most sinter producers prefer to use a range of iron ores with the aim to optimize their sinter blends. ISCOR is however limited to the use of ore from two deposits, namely Sishen and Thabazimbi. Only sinter produced from Sishen ore is described in this report. The Sishen iron ore deposit provides high-grade hematite ore with a mean iron content of 65 per cent. Three major ore types are developed: massive, laminated and conglomeratic. The main ore mineral is hematite with minor to trace amounts of quartz, mica, phosphates and, in places, carbonates. A sinter product is characterized by its mineralogical composition and metallurgical properties. The production rate also plays an important role in the economic evaluation of sinter quality. Sinter-pot tests were conducted with varying basicities, given as the ratio of CaO to SiO:< and coke content. The results of these tests were characterized by mineralogical and metallurgical methods. Basicity of a sinter mix directly influences the mineralogical composition and metallurgical properties. The content of calcium ferrite and calcium silicate increases with increasing basicity, thereby increasing the reducibility and cold strength of the sinter product. Experiments performed during this study provided a model for the optimization of the sinter mix with respect to its mineralogical and metallurgical parameters.

Jan 1, 1991

By Qingzhu Li

The adsorption process of Pb2+ from aqueous solutions by spent grains modified with Imol/L NaCI solution was investigated. The effects of solution pH, contact time, adsorbent concentration, initial Pb2+ concentration, particle size on Pb2+removal were also studied. The initial adsorption process was rapid and 90.35% of Pb2+ adsorption occurred within 30 min. The absorption equilibrium was obtained at 4h. When pH was 5.5, Pb2+ concentration in aqueous solutions decreased from the initial content of 20 mg/L to 0.0 I mg/L after 5 hours by application of IOg/L adsorbent at 25?C, Pb2+ removal efficiency reached up to 99.95% and the Pb2+ remaining in aqueous solutions was under China Sanitary Standard for Drinking Water (GB5749-85). Adsorption data fitted well with Lanf+muir and Freundlich models. However,Langmuir isotherm model was better to descnbe Pb- adsorplion than Freundhch model, mdlcatmg that the applicability of monolayer coverage of Pb2+ on the surface of adsorbent.

Jan 1, 2008

By M. C. Esposito

Seven pyrite samples purified from coal sources and one ore source pyrite (for comparative purposes) have been characterized by chemical and mineralogical analyses, inherent floatability, apparent specific gravity, surface area, semiconductor type, optical anisotropy, dissolution and oxidation rate. The data clearly demonstrate that pyrites from various coal sources differ not only from ore pyrite but from each other as well.

Jan 1, 1987

By Ramana. G. Reddy, Haoxing Yang

The electrodeposition of zinc from zinc oxide using urea and choline chloride mixture in a molar ratio 2:1 is investigated in different experimental variables, namely, the concentration of added [BMIM]HSO4, temperature, and applied cell voltage. The additive, [BMIM]HSO4, was determined to have beneficial effect on the current efficiency, energy consumed in the process and surface morphology of the deposits. The highest current efficiency (92.6%) and lowest energy consumption (2.92kWh/kg) was obtained for solution with 20mg/mL [BMIM]HSO4. The morphology showed the formation of absorbed additive layer on the cathode at higher concentration of additives. Experiments were conducted at different temperatures between 343K and 388K and at various applied cell voltages between 2.7V to 3.6V to determine the best experimental conditions. By varying temperature, highest current efficiency (91.3%) and lowest energy consumption (2.69 kWh/kg) was obtained at 373K. The electrodeposition process is enhanced between the applied voltage 3.0-3.3V by achieving lower energy consumption (2.75~3.06kWh/kg) and higher current efficiency (88.4~89.7%). SEM images showed grain size is significantly increased in higher applied voltages. While at higher temperatures, it seemed to generate particle growth as clusters at the outer deposit layer.

Jan 1, 2014