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By G. Thorsen

An alternative way to the normal practice of precipitation of jarosite, goethite, or hematite for removal of iron from zinc sulphate process liquors/ is to employ the techniques of solvent extraction. The process presented avoids the addition of any external alkali for the extraction of iron by integrating the leaching and solvent extraction steps in a hydrometallurgical zinc plant. By starting the leaching of zinc from the solid zinc calcine material with an organic solution of an acid liquid cation exchanger, the organic phase is loaded with the organic zinc salt from the direct reaction with zinc oxide. The residue from the organic leaching is transferred to a hot acid leach circuit where the remaining zinc oxide and the zinc ferrites will dissolve form¬ing an aqueous sulphate solution of zinc and iron. In the subsequent solvent extraction of iron from this aqueous leach solution, iron is exchanged with zinc from the organic phase. The commercial carboxylic acid Versatic 10 (Shell) is highly efficient for this integrated process of leaching and solvent extraction. The resulting iron-loaded organic phase is heated to 150-200 C in the presence of water whereby the iron will be directly precipitated from the organic phase as iron oxide of high purity and the regenerated organic acid is recycled to the organic leaching step for reloading with zinc.

Jan 1, 1980

"Tell us how you got involved in mining and about your career path.My dad was a coal miner and my uncle was a metallurgist, so when I enrolled at Penn State’s New Kensington Campus, I chose the College of Earth and Mineral Sciences — exact majors didn’t get picked till the end of your sophomore year. Penn State New Ken had an associate degree in mining program and one of the guys in my carpool was going to take Mining 30 in the evening and the other guy (mechanical engineer) was also able to take an evening class. I didn’t want to break up the carpool, so I took Mining 30, complete with essay tests. I could write, so I did well, and the professor said I should go into mining engineering. Fast forward to the end of the next term at University Park, and I realized there wasn’t enough chemistry in mining. Switching to metallurgy would have meant another term at that point, so Dr. Lovell, my advisor, trotted me down the hall and to the next building and said I was a mineral processor. That stuck. I was a summer student at U.S. Steel Research between my junior and senior year and they paid for my master’s degree — all about clay and macerals in coal flotation. During that time, the steel industry tanked, and I thought a Ph.D. would be a good idea — I could always teach at the university level if I had those credentials. The Electric Power Research Institute had a Coal Cleaning Test Facility in Homer City, PA, and I conducted my Ph.D. research on rate and residence time in conventional coal froth flotation cells there and at a local cleaning plant. I went to work at the test facility in 1987 (later CQ Inc.) and stayed there until I started PrepTech Inc. in 1997. PrepTech offers some consulting services for coal cleaning plants and sells mineral processing equipment, mostly to coal companies. I can’t believe it’s been 21 years.And what about your SME career?Of course, I was a student SME member at Penn State. We used many of the SME books in class, so who wouldn’t want the student discount? While in Homer City, I became involved with the Appalachian Plateau Subsection of the Pittsburgh Section. We’d hold quarterly meetings with interesting speakers and had good attendance. I was the secretary. I’m still the secretary and also get the bank statements. We’ll need to close that out some time, but I guess I’ve been hoping for resurgence in the Indiana/Cambria/ Somerset area."

Jan 3, 2018

By J. J. Snodgrass

Faults, sandstone channels, and abandoned mine workings present severe safety hazards, disrupt mining, and necessitate costly precautions or discontinuance of operations. In addition to fault detection, mining companies have a need to map discontinuities such as seam thinning and previously mined areas in both longwall and room-and-pillar operations. Initial field tests demonstrated successful generation and propagation of higher order guided wave modes. Theoretical studies indicate potential for improved resolution by sensing small details in the coal seam and roof structure. Controlled- waveform source transducers and specialized detectors are particularly useful to preferentially excite and detect the Love (SB) and Rayleigh-type (P-SV) waves, including the higher frequency modes. The distinct observation of reflections using the transducers in the shear wave mode makes feasible the detection of the water-filled voids.

Jan 1, 1984

By James A. Hartlage

Work on the design of Kelex 100 was initiated several years ago at the Research Laboratories of Ashland Chemical Company. The effort was specifically directed toward the synthesis of an organic molecule which would strongly and selectively chelate copper ions in acidic solutions and form an oil soluble complex which would be stable in contact with an aqueous phase having a pH of approximately one. This publication describes efforts to establish data which could be used to estimate the economic utility of the new reagent. For helping to accomplish these ends, the author wishes to acknowledge the assistance of Mr. A. V. Henrickson of Hazen Research, Inc. for gathering a portion of the data presented here and to thank the copper companies who supplied leach solutions for studies described in this paper.

Jan 1, 1969

By C. W. Nelson, A. G. Moody

This paper describes the design, equipment selection and onshore fabrication of the largest facilities module ever installed in a single lift in the Gulf of Mexico. Measuring 35.5 x 70.1 x 21.3 m (110 x 230 x 70 ft), the three operating level structure houses Frasch process sulfur mining equipment and weighed nearly 49 million N (5500 tons) during lift. An operating weight of over 74 million N (8300 st) combines with bridge reactions acting on the in-place module and results in a total operating vertical load on the supporting platform deck of about 107 million N (12,000 tons). A Vierendeel truss structural system was selected for framing the module to allow maximum equipment access and routing flexibility for complex, insulated large diameter process piping. Research and finite element analysis of crimp plate siding behavior in shear was carried out during selection of siding type for the module. An interactive design sequence was carried out that incorporated in-place operational criteria, onshore fabrication considerations, complex process equipment requirements, plus load-out, ocean transport and offshore lift analyses. Project schedule dictated that design, procurement and fabrication be fast-tracked with parallel activities accelerated to the maximum extent possible. Design and construction of this largest and most complex module was done concurrently with 52 other components of the project including jackets, decks, process and living quarters modules as well as two 122 x 22 m (400 x 72 ft) sulfur tankers. Total tonnage of steel structures for the project exceeded 90.7 kt (100,000 st). The 5 kt (5500 st) mining module proved the viability and costeffectiveness of larger modules than commonly used in Gulf of Mexico waters. This technical advance can be matched with economic opportunity for other large-scale offshore installations.

Jan 1, 1994

By Jeff Hussey

Since 1955, Gaspe Mines has produced 150 Mt (165 million st) of ore averaging 0.9% copper. The ore was mined from two open pits and from underground workings. In 1994, four exploration drill holes discovered a buried porphyry/skarn copper-molybdenum (Cu-Mo) deposit at depths of between 1,000 and 1,700 m (3,280 and 5,580 ft) below the top of Porphyry Mountain. The mineralization and alteration associated with the Porphyry Mountain quartz monzonite does not outcrop. Prior to 1997, about 19,500 m (64,000 ft) of drilling in 12 drill holes had outlined 200 Mt (220 million st) grading 0.73% Cu and 0.08% Mo. Mineralization occurs as veins and disseminations of chalcopyrite and molybdenite.

Jan 1, 1998

By R. D. Doepker, P. L. Drake

The dissolution of metals from various metal- mine tailings has been studied through a series of submerged tailings batch tests at US Bureau of Mines laboratories. Tailings selected for this study included both reactive (as determined by column leaching studies) and benign tailings. Metal mobilization in aerated (97% saturated with oxygen) samples appeared to be consistently greater than metal dissolution from stagnant (79% or 70% saturated with oxygen) waters. In the early weeks of the study, sulfate concentrations increased with solid-liquid contact time, while calcium dissolution remained early constant. Metal concentrations varied in relation to solid-liquid contact time and aeration. Leachate pH appeared to be nearly independent of solid-liquid contact time for basic tailings. Reactive tailings having both a submerged and a surface component demonstrated increased metal mobility.

Jan 1, 1991

By Terry M. Hertel

The chemistry of waters processed by Acid Rock Drainage water treatment plants can affect the Total Suspended Solids quality of the plant effluents. The sulfate ions in the ARD water will combine with the calcium ions from the lime that is used to adjust pH to form calcium sulfate. When the sulfate content of the waters to be treated is greater than about 1400 parts per mil­lion, the resulting calcium sulfate concentration will be approx­imately 2100 parts per million. This concentration is above the saturation point for calcium sulfate, and the salt will drop out of solution until the concentration falls below the saturation point. This "salting" phenomenon affects the total suspended solids of the treatment plant effluents by virtue of the fact that the salts will report to the filtration apparatus used for the analy­sis. This scenario is exacerbated as an effluent sample ages. Zortman Mining's water treatment plant effluent was being affected by "salting" during the spring and summer of 1995, and it seemed as though the effluents were exceeding the TSS lim­its; for no obvious reason. A testing program was initiated to verify an observation that "salting' was taking place. Treatment plant samples were collected and allowed to age, with TSS analyses being performed every day that the samples aged. Synthetic solutions were also prepared to study the "salting" phenomenon.

Jan 1, 1996

By G. D. Hood, B. E. Davis

A problem that has continued to plague the Florida phosphate industry is loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µm) in a separate circuit have resulted in limited success, but recovery is still not optimum. A fundamental examination of the mechanisms involved in the conditioning of the coarse phosphate has led to results that seem to supersede common paradigms. The Bureau of Mines investigated conditioning parameters such as fatty acid/fuel oil dosage, residual clay content in the feed, conditioning time, mixing intensity, and conditioner solids content. The study revealed that the effect of all these parameters was important. However, it was discovered that contrary to common beliefs, the conditioning time affected the grade of the rougher concentrate much more than the recovery. Specifically, the longer the conditioning time, the less quartz that was floated. It was also discovered that high mixing intensity conditioners could lower the conditioning time required for good grade. Many phosphate operators use low intensity drum type conditioners. Optimizing the conditioning time, mixing intensity, and other conditioning parameters resulted in a rougher concentrate grading 30 pct P.2O5, with an attendant recovery of 95 pct.

Jan 1, 1993

By Anthony Edey

It is a generally accepted and widely discussed fact that the world in general, and the United States in particular, face a shortage of energy at the present time which will become worse in the future. There is, however, no sign of a similar concensus as to the actions which would prevent or overcome this expected shortage. An immense variety of solutions has, however, been put forward, ranging from the purely political to the outer fringes of sophisticated technology. One resource which surprisingly is often only cursorily included in this discussion is the immense known petroleum reserve lying within the United States. When this subject is discussed, indeed, it is usually in the context of the improvements in production or new discovery rate that could be expected to result from possible politico-economic actions that would raise the real price obtained for domestic crude. This interest in the potential for improved domestic production is undoubtedly justified, but very little attention is normally drawn to the fact that even under the most favorable policy framework the majority of the oil that has been, or will be, discovered will remain in the ground due to the inherent limitations of production through surface wells.

Jan 1, 1979

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By George A. Desborough

Marine black shales of Paleozoic age in the Western United States that exceed 10 weight percent organic carbon contain as much as 5,000 ppm vanadium, 1,000 ppm molybdenum, 1,300 ppm nickel, 600 ppm cobalt, 16 ppm silver, 7,000 ppm chromium, 18,000 ppm zinc, 280 ppm cadmium, and 350 ppm selenium. Depositional settings include: (1) continental-rise and marginal-ocean basins, (2) continental-shelf and foreland basins, and (3) cratonic-platform embayments. Most of these metalliferous organic-rich shales have not been examined for resources because of rapid weathering and poor exposures which preclude easy sampling of unoxidized rock necessary to determine actual concentration and residence of indigenous metals. Generally, the marine black shales of Paleozoic age in the Western United States are richer in metals than marine Paleozoic black shales in the Eastern United States.

Jan 1, 1982

By R. A. Bergman, P. G. Thornhill

Development of the Falconbridge Ferronickel Process for treatment of lateritic nickel ores began with laboratory work in 1955, the year the Company commenced exploration of its concession in the Dominican Republic. Process development centred on selective reduction originally directed to producing calcines amenable to ammonia leaching, but later found suited to electric smelting. The reduction step of the process was developed in a 25 tpd shaft furnace pilot plant located in the Dominican Republic, to which was later added an electric melting furnace. After almost 3 years of development work on this scale the plant was expanded to 100 tpd for fixing design data for a commercial plant. This took the form of the 30,000 ton per year Nickel Ferro-nickel Complex of Falconbridge Dominicans, which started up in 1971.

Jan 1, 1979

By Marlin D. Schutte, Graham M. Fraser, Paul M. Kubera, Ronald J. Weetman

Mixers play an important function in the operation of multi-phase reactors in the minerals processing industry. They must suspend solids, transfer oxygen, maintain pH and temperature uniformity, assist in heat transfer, and, in biological processes, avoid the development of excessive shear rates. The LIGHTNIN A315 impeller (Figure 1) effectively supersedes the older Rushton turbine (Figure 2) which has been classically employed in gas­Iiquid-solids applications such as bacterial oxidation, cyanide destruction, etc. Since a stirred tank reactor can be such a key part of the overall process, it is essential that the mixers be designed for long term reliable operation, both process and mechanical, to insure a high percentage of on-line availability. Mixers in gas-liquid-solids processes may experience extraordinary loading conditions which must be taken into account to guarantee a robust mechanical design. Given the recent trend towards the design of world-class process units with maximum capacity equipment, there is increased importance and emphasis on the integrated design of the complete agitation system -mixer, vessel, and structure -to insure trouble free, post­commissioning performance. This paper presents some of the considerations necessary to specify the process functions of the mixer in multiphase applications, as well as special considerations for the mechanical design of the integrated reactor system.

Jan 1, 1993

By Krystyna Raszka, Jerzy Iskra

The paper presents results of spectrophotometric investigations concerning the adsorption of sodium oleate on silicon carbide in the presence of the cations of multivalent metals, applying the ATR IR technique with computer-aidedprocessing of the spectrum. The analysis of these spectra indicates the occurance of distinct OH and COOH bands in the pH range in which the hydroxy complexes of metals of the type MeOH+ and MeOH++ reach in the respective cases the highest concentration in the solution. The correlation of these results with those of flotation, measurements of the zeta potential confirms the proposed mechanism of activation of the flotation of silicon carbide, applying sodium oleate as a collector, the collection taking place over the adsorption of hydroxy complexes of the type MeOH+ and MeOH++

Jan 1, 1995

By Joseph B. Alberts, David D. DiPonio, Francis B. Manning

From 1996 to 2001, Wayne County and 13 suburban Detroit communities constructed the Downriver Regional Storage and Transport System (DRSTS) to improve area water quality, protect public health and alleviate basement flooding. The project consisted of a 10-mile long storage and transport tunnel, a pump station at the existing wastewater treatment plant, 9 miles of relief sewers (6 in tunnel and 3 in open cut). The work was separated into 10 contracts. Due to hydraulic design requirements and other constraints, the tunnel profile was located generally 65 feet below ground surface within a soft to medium clay strata which skimmed along the top of a very dense glacial till “hardpan” overlaying bedrock. Boulders within the tunnel bore were recognized as a significant, but indeterminate risk. This paper presents a case history of the owner’s contracting strategy for risk assumption and management of the boulder impacts on the project. Actual conditions encountered during construction and contractual adjustments made to address problems are reviewed, and recommendations for future contracts are included.

Jan 1, 2003

By James R. Miller

Recent experience over extensive areas of the Basin and Range Province has demonstrated the importance of the basin's (valley's) geology and geomorphology in locating large quantities of good-quality aggregate. First, a geologic map depicting basic geomorphic-geologic units in a valley is made in the office from aerial photography. Next, derivative maps are made from geologic maps and field-derived information such as parent rock type, source area and depositional environment, relationship to adjacent deposits, and Quaternary geologic history. Studying the derivative maps leads to selection of test sites for potential deposits of high-quality aggregates. Subsequent field studies provide more detailed information about geologic processes and samples for laboratory testing. Combining all information allows the characterization of aggregate potential of very large areas. Favorable areas can be further tested. This phased approach has proven to be cost effective. The methodology used in mapping and characterizing basinfill deposits is applicable over much of the western United States. Map units were developed by focusing on the predominate geomorphic process, grain size, cementation, and relative age. The resulting functional map units are of use to engineers and planners. This study led to many conclusions, including the fact that the best quality basinfill aggregates are found in selected alluvial fan deposits and Pleistocene lakeshore deposits. The best quality aggregates are derived from Paleozoic carbonate and quartzitic parent materials that can also provide high-quality crushed-rock aggregates.

Jan 1, 1987

By L. L. Gagné

The Churchill Falls Development will eventually be the largest source of hydroelectric power in North America. Churchill Falls was discovered in 1839, but until recent years it was not practical to begin development of this site to tap the 7 million horsepower available. This $1 billion project is located in Labrador, 700 miles northeast of Montreal and 650 miles northwest of St. Johns, Nfld. The construction will divert the Churchill River 5 miles upstream from the 245 foot Churchill Falls. Rapids above and below the Falls, together with the Falls proper, give a natural head of 1,040 feet. In contrast to the basic simplicity of the surface installations, the powerhouse labyrinth is astounding in size and complexity. The largest in the world, it consists of three major chambers - the powerhouse, 972 feet long by 81 feet wide and 154 feet high; the surge chamber, 763 feet long, 40 feet to 64 feet wide and 148 feet high; and the transformer gallery, 856 feet long by 50 feet wide and 39 feet high. Other major features include eleven inclined penstocks, each 1200 feet long and 20 feet in finished diameter; eleven draft tubes averaging 37 feet in finished diameter and 162 feet long; six vertical cable shafts each an average of 865 feet in length; a series of eleven short bus tunnels linking the powerhouse and the transformer gallery; a vertical power-

Jan 1, 1997

By Jean-Marie Deschamps

In an approach to the complicated study of bauxite from Les Baux de Provence it is necessary to consider the paleogeographical context of all the bauxites in southern France. These bauxites are of Karstic type, belonging to a metallogenic area extending from the Pyrenees Mountains to the Alpine Massif. Within this area each deposit does not always correspond to the same geological period. There are differing opinions regarding the origin of Karstic-type bauxite and a discussion of these various theories is beyond the scope of this paper. Bauxite of Les Baux, in Provence, was discovered in 1821 by the chemist, Berthier, near this picturesque village located in the region of Arles. It is Les Baux from which the name of bauxite originates. For a long time this bauxite was of no interest because of high silica 'and mediocre alumina content. Besides, the calcium carbonate content is somewhat high and is one of the main characteristics of Les Baux bauxite. The problem of exploration of the Les Baux deposit has been to prospect minable zones according to traditional norms where silica and carbonate are low.

Jan 1, 1977

By Alfred Weiss, Andrew E. Nevin, Thomas J. Neil, O&apos

As Edward E. Runyan, 1983 AIME President, in an interview excerpt in ME, June, p. 607, stated, "...the AIME Transition Committee has recom¬mended to the AIME Board that each Constituent Society be allowed the option of separate incorporation, whereby each could become its own separate legal entity." Background The American Institute of Mining Engineers (AIME) was formed in 1871 by 22 engineers in Wilkes-Barre, PA. Although originally a mining organization, it became a home for metallurgists, iron and steel industry people, and for the individuals in the expanding petroleum engineering profession. There are now four Constituent Societies: Society of Mining Engineers, located in Littleton, CO, 29,000 members; Society of Petroleum Engineers, located in Dallas, TX, 47,500 members; The Metallurgical Society, located in Warrendale, PA, 10,000 members; and Iron and Steel Society, located in Warrendale, PA, 6,500 members. Each of the four groups has grown and continues to serve the specific and/or diverse needs of its membership. As the needs and requirements of their industries and professions change, each of the Societies has perceived and initiated programs that serve their constituency rather than AIME as a whole. Therefore, each Society has recognized an increasing need for autonomy to better augment their own programs. An AIME Ad Hoc Transition Committee, with Robert Merrill, AIME Past President, as chairman, made a number of recommendations pertaining to AIME operations that were approved in October 1982 by the AIME Board of Directors. One of the recommendations was to endorse separate incorporation of the Constituent Societies on an individual-society-option basis. The AIME Board commissioned a task force of Constituent Society representatives to develop specific revisions to the AIME Certificate of Incorporation and the AIME Constitution and Bylaws. This was done to allow separate incorporation and to reflect the decentralized structure of the Institute. The SME-AIME Board of Directors subsequently approved the recommendation of SME Working Party #69 that SME pursue separate incorporation. Meanwhile, Working Party #69 continues to work with the other Constituent Societies and with the AIME Task Force on Reorganization to determine the form and substance of the separate incorporation. Why Incorporate? George Webster in The Law of Associations quoted Chief Justice Marshall's (1819) definition of corporation as: "A corporation is an artificial being, invisible, intangible, and existing only in contemplation of law. Being the mere creature of law, it possesses only those properties which the charter of its creation confers upon it, either expressly or as incidental to its very existence. These are such as are supposed best calculated to effect the object for which it was created." SME-AIME attorneys, Davis, Graham & Stubbs, have pointed out that the status of an organization operating as an unincorporated association is always unclear. At present, SME-AIME administers assets of almost $3.5 million (mainly property and inventory) but technical ownership and ability to enter into contractual relationships resides with AIME. However, the operation appears to outsiders (particularly those with whom SME-AIME does business) to be an independent operation which would be expected to be a legal entity in its own right. Advantages of Incorporation Liability. Because of legal ownership by AIME of all assets of the Constituent Societies, those assets are subject to the claims of any of the creditors of AIME or any of its constituent parts (i.e., the other societies). Liabilities can be those usually encountered in business but also encompass special risks, which could develop if there were a careless and erroneous publication of material that might be used in practice or if standards are improperly established. The recent US Supreme Court decision in American Society of Mechanical Engineers, Inc.,

Jan 10, 1983