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By Ping K. Di

A naturally aged and synthesized manganese oxide-coated granular media was found in our laboratory to have the capability of the removal of soluble Mn(H) from mine drainage by adsorption and oxidation. Mine drainage commonly also includes other heavy metal ions. Extending this principle, this paper presents the removal of heavy metals including lead, copper, cobalt, zinc and nickel in the aqueous solution by using the synthesized manganese oxide-coated granular media. It was found that the adsorption of lead, copper, cobalt, zinc and nickel on the manganese oxide-coated media follows both Langmuir and Dubinin-Radushkevich adsorption isotherms except in the concentration range less than 0.1 mmole/L. The adsorption mechanism involves the ion exchange between the heavy metal ions and synthesized manganese oxide coated on the media. The synthetic manganese oxide surface has a strong metal binding ability to the heavy metals in the order of Pb2+ > Cu2+ > Ni2+ > Zn2+ > C02+ based on the adsorption results using batch and continuous column operations. The breakthrough curves of these heavy metals showed that the synthesized media could be used effectively in the removal of these heavy metal ions in a cell or packed column. The process can simultaneously facilitate the immobilization of the heavy metals on the synthesized manganese oxide coated media. A subsequent pH adjustment dislodges the heavy metals and regenerates the synthetic media. Thus, the process accomplishes the adsorption, immobilization and concentration of the heavy metal from waste stream in one monolithic procedure.

Jan 1, 1995

By Bernd Friedrich, Elif Emil‑Kaya, Merve Papakci

In the production of SmCo permanent magnets with excellent temperature stability, corrosion resistance, and oxidation resistance, samarium (Sm), one of the rare earth elements (REEs), and cobalt (Co) are employed. Cobalt (Co) is a crucial component in tool materials, nickel-based alloys, tablet and smartphone batteries, and electric car batteries. REEs and Co have been listed as critical raw materials by the European Union Commission for many years. Due to the ever-growing demand for Co and REEs in technological applications, the recovery of these elements from secondary sources has garnered significant interest. There are two types of SmCo magnets, one of which contains a high amount of iron, approximately 15.2%. This paper focuses on the recycling of Fe-bearing SmCo. In this study, an oxidative leaching process with nitric acid was developed to eliminate iron through in situ hydrolysis and to dissolve REEs and Co. The influence of experimental conditions on the formation of an amorphous iron compound through the hydrolysis of Fe3+ in a nitric acid environment was thoroughly examined based on a Taguchi orthogonal array. The optimal parameters for oxidative leaching were determined to be an acid concentration of 3 mol/L, a solid-to-liquid ratio of 1/10, and a process temperature of 60 °C.

Feb 15, 2024

By N. Kuyucak

Uranium ores leached with sulphuric acid typically have poor dewatering properties. Applicability of controlled neutralization where gypsum precipitates as crystalline particles, improving dewatering properties of material was examined. Neutralized material was then dewatered using paste thickener to increase underflow density. The objectives are to maximize water recovery due to water scarcity and to produce suitable cemented paste fill material for optimizing underground ore recovery. Work was performed on acidic slurry samples collected after leaching but before the resin-in-pulp uranium recovery. Controlled neutralization greatly reduced volume of neutralization precipitates giving higher densities and improving the dewatering (filtration) properties. As a result it would be possible to increase the water recycled to the mill. Another benefit is that sulphate in the recycled water was reduced to saturation limit minimizing scaling of process equipment. Additional test work is needed; however, Unconfined Compressive Strength results imply that controlled neutralization increases the strength of paste fill and possibly offers opportunities towards a viable backfill option.

Jan 1, 2010

By E. -R. Niinikoski, M. A. Islam, H. Mischo, G. Barakos, J. Joutsenvaara, G. Meissner

European Union's transition to a low-carbon and digital economy highly depends on securing the strategic autonomy of the Critical Raw Materials (CRMs) supply chain. This paper introduces a European Commission-funded research and innovation action, AGEMERA, which aims to create detailed geological and people's concerns maps to unlock the CRMs potential in Europe. Furthermore, the project will develop educational packages for schools and universities, publish online CRM-related games and news flashes, and arrange public events to ensure a basis for socially accepted and sustainable exploration and mining of CRMs in Europe. 1. IntroductionCritical Raw Materials (CRMs), crucial for shifting to a low-carbon and digital economy, should focus on maintaining Europe's overall supply-demand balance (Birol, 2022). Therefore, to proactively address the surge in demand and ensure the strategic autonomy of European industrial supply chains, the exploration and extraction of CRMs must be scaled out across the continent. Moreover, mobilizing Europe's domestic potential is vital for the EU to become more resilient and to establish open strategic autonomy as the demand for CRMs continues to increase quickly on a global scale (European Commission, 2021). Base metal extraction and mining have a long history in Europe. Nevertheless, CRMs mining projects have shown less success, although these have a lot of potential (Guzik et al., 2021). The main barriers are a lack of investment in mining and exploration, complicated and drawn-out national permitting processes, and low levels of public support (European Commission, 2020). It is necessary to have a vast amount of knowledge and intelligence about CRM's potential and market impact. Novel non-invasive geophysical survey techniques that enable sustainable exploration must be created and used to enhance mineral system models of ore deposits incorporating CRMs. The minerals policy framework significantly influences the mining industry's performance, stability, and sustainability. However, the EU Member States' mineral policy frameworks differ significantly (MINLEX, 2017). In addition, the Fraser Institute Annual Survey of Mining Companies offers concrete information on how managers and executives of mining companies view key policy areas that impact mining activities in the jurisdiction in which they operate or are familiar (Jackson & Green, 2015).

Feb 1, 2023

By J. D. Miller, C. L. Lin, J. Dong

Nano clay mineral particles such as kaolinite — with primary particles typically smaller than 2 μm in size — can cause significant problems in flotation processes and tailings disposal, including the processing of Florida phosphate rock and Canadian oil sands. In this study, the consolidated state of flocculated kaolinite sediment was examined, and high-resolution X-ray microtomography (HRXMT) was applied to describe the structure of the consolidated sediment. Using this tomographic information, the complex geometry of the channel network structure for the consolidated flocs was established for the first time. With the establishment of the experimental channel network structure, permeabilities were estimated by flow simulation using the Lattice Boltzmann method. Results for kaolinite sediment with and without polymer are compared and discussed. Results for flocculated kaolinite sediment in a gravitational field are also presented and discussed. The results show that as polymer dosage increases, the permeability of flocculated kaolinite sediment increases, and as suspension pH increases, the permeability of flocculated kaolinite sediment decreases.

By R. M. Hays

Jan 1, 1980

Stillwater Mining Company has an extensive history with tunnel boring machines (TBM) at the Stillwater and East Boulder underground PGM mines in Montana. The first use of a TBM was a 4 m (13 ft) diameter main beam unit at the Stillwater mine starting in 1988, where 6.4 km (4 mi) of tunnels were driven parallel to the J-M Reef orebody on four different levels. TBM?s were central to the development of the East Boulder Mine as two 4.6 m (15 ft) TBM?s drove two 5,639 m (18,500 ft) parallel tunnels to access the J-M Reef; one of these units is still in service driving a 2,591 m (8,500 ft) access West of the East Boulder mine for the Graham Creek project. For the Blitz Project, a 5.5 m (18 ft) diameter main beam unit will be utilized to drive a 6,858 m (22,500 ft) ventilation and rail haulage level East of the Stillwater mine. TBM?s have been preferred method for developing new mines and sections of the J-M reef as the geometry and geology of the Stillwater Complex allow for faster development compared to conventional methods.

Jan 1, 2012

By J. V. Thompson

The Powderhorn complex as a source of perovskite (calcium titanate) containing about 1.5% rare earths has been examined in several recent feasibility studies. Much promising exploration and process research has been done in recent years. This paper is presented with cautious optimism and with the acknowledgment that there may be some technical and economic areas yet to be explored. The Powderhorn carbonatite and alkalic stock in Gunnison County, Colorado, lies about 203 airlines km southwest of Denver at an elevation of 2450 to 2750 m (see Figures land 2). All of the mineable ore bodies are owned by Buttes Resources Company of Houston, Texas.

Jan 1, 1990

By Zhongran Dai, Nan Hu, Jianhong Ma, Hui Zhang, Zhihua Zhong, Han Zhou, Feng Li, Yonggen Qiu, Yang Ding, Yingchun Yang, Dexin Ding

In the traditional chlorination roasting-water leaching-solvent extraction process for the extraction of rubidium-bearing ore, Rb leaching from the ore and calcium removing from the leachate are conducted separately, and this results in the complicated process and high energy consumption. In order to integrate the Rb leaching and calcium removing processes, Rb-bearing polymetallic ore was firstly treated by chlorination roasting, it was then leached in a micro-reactor with raffinate, and the calcium ions in the leachate were removed in the reactor as carbonate precipitates by passing CO2 at certain pressure into the reactor. The effects of raffinate alkalinity, CO2 pressure, and CO2 reaction time on Rb leaching rate and calcium removing rate were investigated. The experimental results show that when Rb-bearing polymetallic ore was leached for 90 min by stirring with raffinate with 1.125-mol/L alkalinity, and the pulp was made to react with CO2 at 0.8 MPa for 15 min, the Rb leaching rate and calcium removing rate amounted to 92% and 98.2%, respectively. This integrated process including Rb leaching from Rb-bearing polymetallic ore and calcium removing from leachate could simplify the process for the extraction of Rb-bearing ore and increase its economic benefits.

Sep 27, 2023

By Gary L. Mowrey

Visible and sometimes audible indications of excessive underground rock pressure such as pillar fracturing, squeezes on chocks, and "roof talk" are familiar to mining engineers. Such signs often precede rock failure on a larger scale and therefore may be used as a warning. Nevertheless, these subjective observations do not provide an adequate means of evaluating the existing rock pressure conditions in a mine. One method which appears to be extremely promising in determining the stability of geologic structures in general is that of monitoring their associated micro seismic activity. Mining engineers generally agree that during the process of rock deformation and failure small-scale seismic ("microseismic") vibrations are produced in the rock itself. These transient vibrations propagate through the rock structure and may be detected at a considerable distance from the failed rock by employing suitable electronic monitoring equipment. Hardy (1) has presented a detailed review of microseismic research in the mining, petroleum, and geoscience areas, and it is apparent that relatively little application of micro seismic techniques have been made in coal mines. This is especially true in North America since here most coal mines are fairly shallow and consequently are not generally subjected to excessive stresses. Furthermore, strict Federal and State mining laws limit the use of electrical equipment in coal mines complicating the use of the necessary monitoring facilities. In terms of both mine safety and economics, monitoring microseismic activity appears to be invaluable in the detection and location of over-stressed pillars and unstable roof conditions caused by development and production work. In 1970 The Pennsylvania State University Rock Mechanics Laboratory became involved in a research project, sponsored by the U.S. Bureau of Mines, to investigate the feasibility of using microseismic techniques to detect and to locate potential regions of instability around a longwall coal-mine operation [Hardy and t10wrey (2); Mowrey (3)]. In this study geophones (velocity gages) located in an array of shallow boreholes drilled from the surface above the active area of the longwall were employed to detect microseismic activity, and a mobile micro-seismic monitoring facility was used to condition and record this data for later analysis. This project is unique in that measurements were made from near-surface geophones rather than geophones installed on the mine itself. Two advantages are apparent, namely that (1) there are no electrical limitations on the monitoring system and that (2) mining operations can continue normally because there is no monitoring equipment or cables in the mine.

Jan 1, 1978

Water contact angles in the air/water/francolite, fuel oil/water/francolite and fuel oil/water/quartz systems were measured to describe the wetting characteristics of these minerals. It was found that white francolite is more hydrophilic than black and tan francolite both in the absence and presence of fatty acid addition. The contact angle measurement results do not correlate very well with the flotation response and it appears that kinetic aspects of the bubble attachment process play an important role in the francolite-fatty acid flotation system.

Jan 1, 1997

By M. Karmis

The determination of the surface area which may be impacted by underground mining is an important consideration in subsidence engineering. A number of parameters have been utilized to identify this influence area, most notably the angles of draw and break. This paper discusses the implications of selecting an appropriate "damage angle" for defining a potential damage area due to mining, within which surface structures may be impacted Furthermore, the influence of both mining and geological factors, such as mining width and depth and overburden lithology, on this angle is examined, using the Surface Deformation Prediction System (S.D.P.S) software. Finally, recommendations are given for applying these concepts in subsidence control.

Jan 1, 1994

By Cody Giroux, Homer Scurlock, Michel Wasag

Silica and Crystalline Quartz exposure continues to be a serious health threat to nearly 2 million workers in the United States, including more than 100,000 working in high risk jobs such as abrasive blasting, foundry work, stonecutting, rock drilling, quarry work, mining and tunneling. The primary focus of this study is to identify the best methodology to reduce particulate-laden air and limit/eliminate exposure to respirable dust with silica/crystalline quartz during tunneling operations. This study focuses on two de-dusting systems employed on similar tunnel construction projects. The first project is the Coxwell Bypass Tunnel located in Toronto, Ontario Canada. The second project is the Westerly Storage Tunnel located in Cleveland, Ohio. The Toronto project is utilizing a wet de-dusting system. The Cleveland project is using a dry de-dusting system. The objective is to determine which system provides the best protection and suitability to capture, remove and ultimately reduce respirable concentrations of silica/ crystalline quartz to safety and healthy levels in underground tunneling activities.

Jun 13, 2021

By M. Misra

The dielectric properties and flotability of different ranks of Argonne Premium Coal samples are presented. The flotability of different ranks of coal are correlated with the dielectric properties and intrinsic moisture (or bound water) content. Measured dielectric properties of as-received coals and other constituents are incorporated into a mixture equation to calculate the dielectric properties of bound water present in the different ranks of coal. The nature of bound water present in low-rank hydrophilic coals is significantly different from that present in high-rank hydrophobic coals. The water molecules present in low-rank lignite have an oriented dipole-dipole interaction and are tightly bound to the surface. For high-rank coals, the water molecules are not bound to the surface and have a randomly distributed clathrate ice-like structure. Controlled thermal treatment can modify the structural nature of bound water present in low-rank hydrophilic coals and increase their flotability.

Jan 1, 1990

By S. K. Kawatra, H. J. Haselhuhn

"Fine-grained hematite ore can be concentrated by the process of selective flocculation and dispersion, which relies on proper reagent selection and control of water chemistry. While many previous studies have been performed analyzing the effects of different reagents on this process in a laboratory environment, this paper focuses on investigating the water chemistry within the process in a pilot-scale continuous deslime thickener.The pH, sodium concentration, calcium concentration and magnesium concentration were varied to determine their effects on the iron concentrate grade and recovery, and the phosphorus concentrate grade and rejection in the pilotscale selective deslime thickener. The ideal pH for the iron grade and recovery of the process using a starch selective flocculant was found to be 10.5. Phosphorus rejection, however, was increased at lower pH values. Minimization of sodium concentration was shown to improve iron grade, iron recovery and phosphorus rejection. Calcium acted as a nonselective flocculant showing higher iron recovery, lower iron grade and lower phosphorus rejection with increasing concentration. Conclusions could not be drawn from the experiments that varied magnesium concentration.The zeta potential of the solid-liquid interface of particles in each sample taken was also analyzed to show relationships between zeta potential and process performance. In all cases, a maximization of the magnitude of zeta potential correlated with increased iron grade and recovery. This supports the hypothesis that a higher level of dispersion enhances the selective flocculation and separation process.IntroductionThe United States produced 53.2 million metric tons out of the 3,000 million metric tons of concentrated iron ore produced worldwide in 2012 (Tuck, 2013). With this in mind, there has been a large increase in iron ore processing research (Bolen, 2014; Carlson and Kawatra, 2008, 2013; Halt and Kawatra, 2014; Halt et al., 2014; Haselhuhn et al., 2012a,b, 2013a,b; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). Of the 53.2 million metric tons produced, roughly 8 million metric tons of hematite (Fe2O3) concentrate were produced using a process known as selective flocculation and dispersion (Cliffs Natural Resources, 2011). This process is the only economically viable method for concentrating low grade (< 40% Fe) fine grain (< 25µm liberation size) hematite ores. It is scarcely used due to difficulty in controlling the surface chemistry of the ore and high reagent costs (Department of Energy, 2001; Haselhuhn et al., 2013a). The process is highly dependent upon both reagent selection and precise control of the water chemistry during separation. This study shows the dependence of the process performance of a pilot-scale deslime thickener on the water chemistry in the feed slurry."

Jan 1, 2015

By S. M. Woodring

Research objectives included 1) determine relationships if any between spectral response of soil and soil textural groups, Unified Soil Classification subgroups and selected landforms and 2) develop computer assisted techniques for engineering soils mapping of remotely sensed data. The sire in northeastern Kansas, 1.6 Km by 43 Km (1.0 mi by 27 mi), contained glacial and alluvial soils. Multispectral scanner data (0.40 to 1.80 pm) collected at 915 meters altitude (3,000 feet) were analyzed using two distinct computer techniques: the nonsupervised approach involving delineation of soil training areas directly by computer and the supervised approach entailing training area selection manually by the researcher. Computer classification of surface materials follows both methods. Non supervised analysis results failed to show a consistant relation- ship between landform type and soil spectral class. Landforms correlating well displayed either unusually bright or unusually dark spectral signatures. Supervised analysis results showed a strong relationship between soil texture and soil spectral class. A moderately strong tie was shown between engineering soils groups (ML, CL, CH and OH) and their respective spectral classes, and a weak association between landform type and soil spectral class. An analysis procedure for engineering soils mapping by computer of remotely sensed data was developed. 1. Locate cultural features by visual examination of imagery. 2. Produce generalized bare soil-vegetation- water map using nonsupervised technique. 3. Outline significant soil fields for computer training using supervised approach. 4. Computer-classify entire area based on these soil fields.

Jan 1, 1974

By Don Painter, Nico Sutmoller, Lori M. K. Kahikina, Brian Dorwart

This paper will address the feasibility of using low-density cellular concrete (LDCC) for an annular fill application where project conditions required pumping the LDCC material for distances of up to 16,000 feet. These conditions occurred during construction of the Kaneohe-Kailua Sewer Tunnel in Oahu, Hawaii, between 2014 and 2018. Located on the island of Oahu, Hawaii, this 13-foot-diameter rock tunnel extends for approximately three miles from the Kaneohe Pre-Treatment Facility to the Kailua Regional Wastewater Treatment Plant. The tunnel was built to convey wastewater and provide temporary storage for peak wet weather flows entering the collection system, thereby reducing the potential for uncontrolled discharges. LDCC was chosen for this project partly due to its environmental benefits, which were essential for an application contiguous to the inland marine and coastal waters of the Pacific Ocean. In order to ensure optimal performance characteristics—compressive strength (with a requirement of 300 psi at 56 days), flowability, and light weight—were achieved, extensive testing of various LDCC products and mix designs was completed. The testing measured the initial set time of the LDCC as well as the compressive strength needed to reduce the quantity of grout lifts required for the project.

Jun 13, 2021

By A. M. Whiting

Competition for coal producers and their primary customers has constantly increased during recent years. The effects of the Clean Air Act Amendments of 1990 on the electric utility industry, coupled with the normal complexities of coal production, quality control, transportation and contracting techniques have spurred both buyers and sellers to increase their level of sophistication. This paper will review the basic aspects of the U.S. coal business and explore the commercial approaches which have proven to be most successful.

Jan 1, 1994

By D. Malhotra

The effect of some of the reagents, namely hydrocarbon oil, Syntex (sulfated coconut oil surfactant), pine oil, sodium silicate, and lime, used at the Climax mill on the recovery and grade of molybdenite and gangue minerals has been investigated experimentally using factorially designed test approach in the laboratory. The results of the investigation are presented in two dimensional plots. The lower additions of lime (equivalent to a pH of 8 to 8.5) were desirable for maximizing recovery subject to constraints on grade. Higher additions of pine oil improved recovery, but only at the expense of grade. A mathematical model of the objectives of an operating plant was formulated and optimum reagent conditions obtained.

Jan 1, 1977

By Paloma Lazaro, Moe Momayez

Interactions between human beings and their work environment require the body to regulate its temperature by balancing heat production and loss. Comfortable environmental conditions are crucial for keeping workers safe and healthy and to maintain a suitable level of productivity. However, achieving a proper core body temperature may become challenging under different conditions, especially in high heat-generating workplaces such as hot underground mines. Because hot underground mines have the potential to expose workers to heat stress, compliance with standardized and regulated indices and criteria is distinctly required. The objective of this paper is to provide an overview of the current research on heat stress and strain in hot underground mines, collected from published and specialized literature. General definitions, statistics of heat-related accidents in mining, overview of the indices, standards, and recommendations for heat stress are provided herein.

Oct 6, 2020