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Compared to alternative ways of dealing with coal fines, oil agglomeration has always been a commercial bridesmaid and never yet a bride. Yet interest is high in the process, as shown by a number of pilot plants in operation that are funded by industry as well as government. In the past in the US, alternative ways to handle coal finer than 100 to 200 mesh included flotation, or no treatment except dewatering, or discarding the fines as waste. There are now a number of factors that tilt the economics more toward fine coal recovery. Today, the cost of mining a ton of underground coal runs from $22-30, and discarding even 10% as unrecovered fine coal is a real economic loss. A number of attempts (notably by EPRI) have been made to quantify the effect of coal cleaning on utility boiler operations. Transportation and ash handling costs, frequency of unscheduled outages, fouling and slagging problems, and boiler tube erosion are all lowered by cleaning coal. The advantage of coal cleaning on these parameters has been shown, but the dollar amount varies with many assumptions and is difficult to pin down. The message to a utility, however, has not been lost and the trend toward cleaner steam coal is accelerating. This may lead to fewer installations that only wash the coarse coal, and add back the unwashed fine coal until a maximum contractual ash limit is reached. And, as the proportion of coal fines continues to increase by continuous and longwall mining, it may become impossible to clean the coal sufficiently without cleaning the fines. Flotation and oil agglomeration are the only processes that presently deal directly with cleaning the very finest coal fractions. Flotation has proven its effectiveness in cleaning blackwater and in separating fine coal from mineral matter. It has the achievable potential for far greater pyrite rejection than is now obtained in commercial preparation plants. While flotation will continue to be the predominant method for fine coal cleaning, there are conditions and opportunities where oil agglomeration can be a

Jan 8, 1980

By J. D. Miller

Certain bituminous coals of recent geological age are known to contain a significant quantity of natural (fossil or subfossil) resin. Such resinous coals are found in the western U.S., particularly the Wasatch Plateau coal field in Utah. Some of the seams in this field contain approximately 5% resin which has been recovered by gravity and/or flotation processes since 1929. Resin concentrates thus produced are of low quality and are usually refined by solvent extraction and precipitation. The purified resins are of commercial importance, being used in the adhesive, varnish, enamel and ink industries, etc: Recently, an improved flotation technique has been developed which involves ozone conditioning to selectively float resin from such coals. In this flotation process, a concentrate product which contains 95% resin at a recovery of 80% can be obtained in a single stage from coal containing approximately 10% resin, whereas conventional flotation at a similar level of recovery produces a concentrate having a resin content of 30-40%. Economic analysis shows that the ozone flotation process has good potential for use by industry.

Jan 1, 1988

By Williams R. Reynolds

Studies of the northeastern Mississippi bauxites were initiated primarily for the purpose of ascertaining the quality and quantity of the ore. Subsequently, this ore was found to have a rather dubious economic value as was previously suspected but never established in earlier economic reports (1, 2, 3). However, the quality of ore was found to be higher than previously thought. Even though the ore bodies were determined during the early stages of this study to be too thin, small and widespread for commercial production a continuation of the study was not abandoned. On the contrary, the present investigation was intensified concentrating less on the economic application and more on stratigraphy and genesis. Considering the ever increasing demand for aluminum products the northeastern Mississippi bauxite district which includes portions of Tippah, Benton, Pontotoc, and Union Counties may soon become, in spite of inferior quantities of ore, an attractive area for bauxite production. Presently, however, the meager quantity of ore discourages exploitation. On the other hand, these northeastern district bauxites are facies of more extensive units of lignite bearing high aluminum clays, and considering the advances in aluminum extraction from clay these clays may in the future beckon mining interest. The bauxite of the northeastern Mississippi district, mapped as a part of the Betheden Formation (4). has an outcrop trend along the county lines of Tippah and Benton Counties and the extreme western portion of Union and Pontotoc Counties. Studies of exposures and cores stratigraphically positions the outcrop between the middle Midway Porters Creek Clay and the lower Eocene Wilcox sands and

Jan 1, 1977

By R. H. Busch, S. M. Loscutoff, F. T. Cross, R. E. Filipy, P. J. Mihalko, R. F. Palmer

INTRODUCTION During the last decade, several studies in France (e.g., Perraud et al. , 1970; Chameaud et al., 1974, 1979 and 1980) and the United States (e.g., Stuart et al., 1978; Cross et al., 1978, 1980 and 1981) have demonstrated the systematic production of emphysema, fibrosis and tumors in the lungs of animals exposed to radon daughters alone or to mixtures of uranium-mine air contaminants. The studies in beagle dogs have been particularly interesting because of the uncertain etiology of the disease and the (apparently) diverse results of the studies at the University of Rochester and the Pacific Northwest Laboratory (PNL). In the Rochester studies, reported by Morken (1973), beagle dogs were exposed to "normal" room air dust loads and radon daughters from 200 to 10,000 WLM*, delivered in 1 to 50 days (rate of delivery, about 200 WLM per day of exposure). Histological examination of tissues was conducted at 1, 2 and 3 years after exposure for all exposure levels. No cancers were noted in these dogs that received estimated alveolar doses of 34 to 1700 rad (0.34 to 17 Gy). Pathologic changes were found only in the alveolar and bronchiolar regions of the lung. These changes were small, subtle, variable, and widely separated, involving only a very small fraction of lung tissue. Lesions appeared as focal thickening of alveolar septa, with some metaplasia of alveolar cells and some hyperplasia of bronchial epithelium. In the PNL experiments reported by Cross et al. (1978), beagle dogs were exposed in lifespan studies to mixtures of radon daughters (rate of delivery, about 14 WLM per day of exposure), uranium ore dust and cigarette smoke. One group of dogs was exposed to cigarette smoke alone. Except in control and smoke-only groups, the dogs died within 4' years of the first radon daughter exposure, or were killed when death appeared imminent because of pulmonary insufficiency (characterized by rapid, shallow breathing). Control and smoke-only animals were killed at periods corresponding to highmortality periods in the groups exposed to radon daughters and mixtures of uranium ore dust and cigarette smoke. Emphysema and fibrosis were much more prevalent and severe in the lungs of dogs exposed to the mixtures. These dogs also had adenomatous lesions, which progressed to squamous metaplasia of alveolar epithelium, epidermoid carcinoma and bronchioloalveolar carcinoma. Pathologic changes in the upper airways of these dogs were most prominent in the nasal mucosa, and included a few squamous carcinomas in the nasal cavity. Respiratory tract neoplasia was noted after ~4 years exposure and at cumulative exposures exceeding approximately 12,000 WLM. Apart from differences in associated carrier aerosol (room air dust vs. uranium ore dust) and radon-daughter exposure rate (200 WLM/day, shortduration exposure vs. 14 WLM/day, long-duration exposure), the most obvious difference in the Rochester and PNL studies was the observation time following exposure (3 years maximum vs. >4 years). Although neoplasia may not have been observed in the Rochester animals because of the earlier termination of the experiments, it is surprising that other lesions, such as prominent fibrosis and emphysema, were not reported. A follow-up study (reported here) is currently in progress at PNL to determine the pathogenic role of uranium ore dust alone and, in particular, to clarify the role of the ore dust in the production of the massive pulmonary fibrosis observed in the earlier study. Pulmonary function testing (a recently acquired capability) was included in the follow-up study as an indicator of progressive change in lung tissue. MATERIALS AND METHODS Chronic (4 hr/day, 5 days/week) exposures began when the dogs were about 2 1/2 years old. Two identical exposure chambers provided space for simultaneous, head-only exposure of 24 dogs to ~l5 mg/m3 carnotite uranium ore dust. An aerosol diffusion system was incorporated in each chamber in order to channel fresh aerosol past each dog's head; uranium ore dust was added to the inlet room air with Wright Dust Feed Mechanisms* (WDFM). Uranium ore dust and condensation nuclei concentrations were measured daily; chamber aerosols were monitored occasionally for particle-size distributions as described for previous hamster experiments (Cross et al., 1981). The carnotite ore used in these experiments, from the Mitten mine in Utah, was furnished in 1970 through the Grand Junction, CO Office of the (then) U.S. Atomic Energy Commission (now the Department

Jan 1, 1981

By E. Robert Kiehl

In the early days of the United States, gypsum was most commonly used for the manufacture of plasters with energy being used for quarrying, grinding, and calcining of gypsum rock. With the dramatic switch to gypsum-drywall construction after World War II, the energy usage per ton of rock processed increased more than threefold, and with the rapid growth of the construction industry, the total energy consumption in gypsum-board production alone increased eightfold during the period from 1940 to 1973. The gypsum industry was one of the first to recognize the need for energy conservation and has voluntarily reported its progress to the Federal Energy Administration for the past several years. Efficiencies in the use of energy have resulted in decreasing the unit consumption an estimated 10 percent during the past six years. Improved combustion efficiencies, optimum operating conditions, more liberal use of insulation, and heat recovery will all contribute to the gypsum industry's goal of using less energy. Gypsum products today are vital to over 85 percent of new housing construction in the United States.

Jan 1, 1978

By S. J. Parkin, P. Shead

Extraction of coal at Harworth Colliery is undertaken in the Deep Soft seam at roughly 1000m depth where the strata temperature is 42 "C. Production employs the longwall retreating method using high powered mechanised methods to extract coal at a rate of approximately 40,000 tonnes per week from a single face. This paper describes the climatic conditions encountered on a typical district , 6's district, where the initial ventilation set-up was as a typical U-type district which was antitropally ventilated. Under this initial set-up climatic conditions in the intake typically exceeded 30 "C effective whilst in the face area and in the return airway effective temperatures in excess of 32 "C and 33 "C were common . The paper then proceeds to describe the methods employed to attempt to improve the climatic conditions on the district, especially with regard to the coal face and return airways and describes in detail the effects of reversing the district airflow direction, employing homotropal ventilation, on the climatic conditions. The results of this reversal have been dramatic and have resulted in a substantial improvement in the climatic conditions experienced , however problems have been encountered with the control of methane gas since the changeover. The final part of the paper describes the results of computer simulations to analyse the effect of various ventilation designs on the predicted climate for future production districts in order to de- fine a district layout which will produce acceptable climatic conditions in the working zone without the need to use refrigeration techniques and which will improve methane gas control .

Jan 1, 1997

By Chuck Hornaday, Brad Miller

Geosynthetic clay liners (GCLs) are manufactured barrier layers containing a high-quality sodium bentonite clay attached or adhered to geotextiles or a geomembrane. The GCL's low permeability and high strength make it an ideal replacement for low permeability soil or clay liners for mineral extraction and processing containment applications. This paper will discuss the advantages of utilizing a GCL versus compacted clay in containment applications. Some of the advantages include: the GCL's lower permeability (5 x 10-9 centimeters per second (cm/sec)) and corresponding better composite liner leakage protection, the GCL' s greater resistance to desiccation, differential subsidence and freeze­thaw, and lastly, the ease and speed of installing the GCL. This paper will also detail a number of important case studies related to the mineral extraction and processing industry. These case studies include using GCL in two large reclamation capping projects, as a secondary liner in two gold heap leach pads, as a composite liner in a dam for stormwater runoff control, and lastly, as a primary liner for a tailings runoff diversion channel.

Jan 1, 1997

By J. P. Wilson

The Tessenderlo-Kerley Leach process has been shown to be effective in the removal of residual copper from molybdenite concentrates. Concentrates of varying mineralogy, including those containing relatively large amounts of chalcopyrite, have been successfully leached on laboratory and pilot plant scales. The lixiviant system is ammonia and ammonium bisulfite with air / oxygen addition. An abrasive is added which greatly enhances the kinetics, and it is subsequently screened out and reused. The dissolved copper is easily recovered using existing technology. Extraction profiles, reagent consumptions, and mineralogical data are presented.

Jan 1, 1999

By J. P. McDonnell, L. A. Beckett, K. Y. Hammy

Dangerously high stress areas can be controlled by proper mine planning and/or destressing. This paper reviews practical methods to detect and destress high-stress zones along coal faces. The US Bureau of Mines investigated stress-related burst problems and destressing efforts at a cooperating mine. Laboratory tests of the drilling yield method for high stress detection were conducted to determine the correlation between the volume of cuttings obtained and the magnitude of the applied stress. A three- dimemiom1 computer modeling program was used to evaluate the effectiveness of stress relief methods.

Jan 1, 1987

By George H. K. Schenck

Decisions to develop deposits of calcareous materials for cement production are based largely on anticipated markets for heavy construction which utilizes concrete. The geologist should understand the fundamental factors that underlie such management decisions, so that his field work and reports will more effectively relate to the information requirements of managers in the cement industry. The paper examines the relationships that exist between exploration and development of calcareous raw materials for cement manufacture and changing factors in the marketing of cement. Continued overcapacity, improved technology, changing distribution patterns, ease of entry, economics of scale, and the nature of product demand are some of the characteristics of the cement industry that are basic to decisions regarding exploration programs and property development.

Jan 1, 1966

By S. Becker, M. Gruner

"Microstructure stabilized crushed rock salt is a newly developed backfill material for infrastructural openings in HAW repositories. The motivation for this research is based on the fact that the microstructure stabilized crushed rock salt is considered to be superior to the currently used crushed rock salt. The avoiding of settlements with a simultaneous 100% backfilling of openings, early stabilization of the geological barrier and low permeability (< 10-14 m²) are the main improvements. With the newly developed backfill material, the gap between the crushed rock salt and the saliniferous composite backfill materials is closed. Due to the minimized amount of a binding agent, the material will still be easy to handle like a bulk material, yet guarantees close to 100 % backfill success without any settlements. This is accomplished with a long-term stable re-mineralization that is formed by the components of the binding agent. INTRODUCTION The permanent storage of high active waste in underground geological formations (HAW-repository) is the labored method in Germany as well as internationally. Experiences have been made over the last decades, e.g. in the Waste Isolation Pilot Plant (USA) and the mines Morsleben and Asse (Germany). For this purpose salt formations are preferred as host rock due to the adequate heat conductivity, creep capability, and low permeability. In order to maintain the low permeability of the host rock and to avoid any contact of the stored waste with the biosphere, the formation of flow paths has to be prevented. The cavities which have been mined for the purpose of waste storage have to be backfilled with material that is alike to the host rock. Therefore crushed rock salt is considered as an appropriate backfill material. Crushed rock salt is a bulk material that is produced by mining saliniferous formations. This material is mainly used in underground repositories as a dry backfill that is brought into the cavities by the use of mechanical (loading machine, slinger machine or scraper) or pneumatic energy (pneumatic stowing). In Germany it is intended to use dry crushed rock salt with a maximal grain diameter < 64 mm for backfill in a future repository in saliniferous formations. With this method applied, the porosity of the backfill is up to 35 % [1]."

Jan 1, 2015

By R. A. Jankowski

Laboratory tests were conducted to evaluate the silica collection efficiency of flooded-bed scrubbers using six different filter panel designs at two operating velocities. Test results indicated that reductions in filter density negatively impacted respirable dust collection. Silica collection efficiency for the least-dense filter was as much as 33 % lower than the collection efficiency of the most-dense filter. At the low operating velocity, the least-dense filter allowed more than 40% of the respirable silica dust in the scrubber intake air to pass through the unit and back into the mine environment. Operation of the scrubber at the higher test air velocity increased silica collection efficiency regardless of the filter panel tested The density of the filter panels also impacted the quantity of air moved through the scrubber, with higher-density filters reducing scrubber airflow. For each filter, the relationship between dust-collection efficiency and air-moving capacity must be considered to determine the overall effectiveness for each mine application.

Jan 1, 2000

By D. G. Fredlund, J. A. Wilson

Conventional disposal of waste rock results in the construction of benches with fine and coarse layers dipping at the angle of repose. This interbedded structure influences flow pathways within the waste rock. A numerical modeling program was conducted to study a four-layer system consisting of alternating fine and coarse waste rock. The system was inclined from the vertical to forty-five degrees with heights varying from one to twenty meters. The results show the effects of gravity as preferential flow developed under unsaturated flow conditions.

Jan 1, 2000

[The development of economically effective and safe methods of mining thick coal seams enables to involve considerable coal reserves into the energy resources in different countries all over the world.]

Jan 1, 1975

By Gretchen K. Hoffman, George S. Austin

Soil amendments or soil conditioners generally carry the con- notation of being useful for problem soils or soils needing special treatments to produce maximum yields. Many different materials have been utilized, both inorganic and organic. Only the most commonly used and those that appear to have potential to become commonly used will be discussed. Soil productivity depends on many factors. Soil amendments mainly modify physical characteristics and microbial action, and/or change the pH of a soil, rather than directly supplying plant nutrients. They give soil the needed physical properties to allow plant growth, fight erosion, or save water. Some soil amendments provide nutrients in addition to altering the physical, biological, or chemical characteristics of soil. The term "soil amendment," as it is used by Soil Science Society of America, allows soil amendments to be materials other than those used primarily as fertilizers (Anon.,1987). Soil amendments as fertilizers of any type will not be considered here because this aspect is more relevant to the previous chapter entitled "Agricultural Materials: Fertilizers" in this volume. Several inorganic soil amendments have been used since the early 20th century to alter the character of soil: limestone, lime, and similar calcium-rich carbonates and oxides for acid soils, and calcium sulfate (gypsum) and native or uncombined sulfur for alkaline soils. The use of these amendments (limestone, lime, gypsum, and sulfur) or their equivalents has been studied and documented in many basic soils tests (McCaslin and Boyle, 1980). Perlite and vermiculite are considered in separate chapters and only a brief statement of their use as soil conditioners will be made in this chapter. Peat is the principal natural organic soil amendment, but manure, both as a fertilizer and soil conditioner, is used in every part of the world. In less-developed countries, manure is the primary soil fertilizerlconditioner. An organic-rich material designated as "humate" has been marketed as a soil amendment for many years and will be addressed in this paper. Other materials are discussed by the Soil Science Society of America in its Special Publication 7, "Soil Conditioners" (Stewart, 1975). They include bitumen emulsion, polyacrylamide, polyvinyl acetate, polyvinyl alcohol, bentonite, nonionic surfactants, and natural mulches. Zeolites can be added to the list of miscellaneous soil amendments (McCaslin and Boyle, 1980), as can calcium chloride (Pressler and Pelham, 1985), sulfuric acid, ferric and ferrous sulfate, aluminum sulfate, ammonium polysulfide, calcium polysulfide, and ammonium bisulfite (Stromberg and Tisdale, 1979). Sludge will not be considered as a soil amendment because it has properties more consistent with fertilizers. All these "other materials" account for a very small amount of the volume and value of soil amendments used and will be only briefly discussed.

Jan 1, 1994

By Julius Rubinstein, Victor Badenicov

The development of column flotation is the most significant achievement in the area of mineral processing in the last few decades. The high efficiency of column flotation allows a reduction in process time, a decrease in the number of cleaner stages and in the volume of the circulating load in the flotation circuit, and, as a result of this, an increase in consistency and reliability of operations. Unique multisectional column flotation apparatuses were developed. Such designs have a number of essential advantages as compared to monocells. A change from monocells to multisectional column allows to provide favourable conditions for separation of particles of various floatability. To attain that aim particular hydrodynamics and aeration regime is established in each section of the column, operational variables being adjusted according to the floatability of the material. Therefore in multisectional column machines the material-apparatus feedback can be established, process variables optimized depending on the characteristics of the floated materials. This concept forms the basis of column designs we have developed. For the first time column cell with alternating slurry Rows (combination of co- and counter-current flows) were developed and commercialized . Successful operation was reported of the new generation of columns with cell volumes of 10 to 80 m3 and the height of 4-6 m in copper, molybdenum, antimony, tungsten and nickel ores and coal slurry processing at different plants. Operation experience of these cells showed their considerable design and operational advantages and verified the proposed options and relationships. The new apparatus is provided with a pneumohydraulic aerator allowing to control bubble size distribution, the service life of the aerator is not less than two years. A multilevel flotation model was developed and used to work out a technique of column design and process parameters calculation. A method of the apparatus design parameters calculation based on laboratory test results (scaling up) was worked out. The method is based on flotation macro and micro-hydrodynamics simulation.

Jan 1, 1995

By R. H. Grau

This Bureau of Mines report describes methane liberation trends from all U.S. coal mines liberating over 100 Mcfd (100,000 cfd) (2.8 Mm3/d). Detailed are results from the latest Bureau survey performed in 1985 and shown are mine and company name, location, coalbed and methane liberation quantity. The report shows that in 1985, there were 180 mines producing more than 100 Mcfd (2.8 Mm3/d) and the total quantity of methane liberated by these mines was 303,900 Mcfd (8,605 Mm3/d). This data is compared with previous studies performed in 1971 , 1973, 1975, and 1980. From 1971 to 1985, there was a 10% decrease in the number of mines liberating at least 100 Mcfd (2.8 Mm3/d) but there was a dramatic 34% increase of liberations from these mines. The increase seems to be caused by new mines being developed in deeper, gassier coalbeds, particularly in Alabama. Likewise, in comparing the ten highest liberating mines in 1975, 1980, and 1985, an increase in methane liberations each year was experienced. The report classifies mines by three levels of liberations: greater than 100 Mcfd but less than 500 Mcfd (2.8 to 14 Mm3/d); 500 Mcfd to 1 ,000 Mcfd (1 4 to 28 Mm3/d); and greater than 1,000 Mcfd (>28 Mm3/d). It was found that 87% of liberations were from mines producing over 1,000 Mcfd but these accounted for only 38% of all the mines in the study.

Jan 1, 1987

By Ian M. Loomis, Malcolm J. McPherson

A fuel-rich fire exists when the quantity of fuel exceeds the oxygen available to support complete combustion. The transition of a mine fire from Oxygen- rich to Fuel-rich combustion, at this time, represents a point-of-no-return in the fire fighting efforts. Once the transition has been made to fuel-rich the fire can spread at a rate 6 to 10 times as fast as in the oxygen-rich state. Utilizing available technology the fire fighters are left to seal the fuel-rich fie as the only technique to extinguish it. In order to minimize the devastating effects of a fuel- rich fire it is important to understand the means by which the fire becomes fuel-rich and by what means the fire may be returned to an oxygen-rich state. This paper covers: the development mechanism of a fuel- rich fire in a coal mine entry and the physical and chemical effects of applying water to a fire. Experiments concerning these matters have been conducted in a 30 cm square wind tunnel constructed at the Virginia Polytechnic Institute and State University as a model coal mine entry. This paper also addresses the results obtained in testing application of a water mist to fuel-rich fires in this model. These tests have centered on the development profile of a fuel-rich fire in a duct and demonstrate a means of regaining control of a fuel-rich fire by returning it to an oxygen-rich state.

Jan 1, 1995

By W. J. Bronkala

Dense-medium circuits have been installed in many mineral treatment plants since its, original development about thirty years ago. In the intervening, period the process has been thoroughly evaluated and many innovations have been introduced. The Heavy Density. Cyclone is one of the newer systems which has extended the operating range of this process to 65 mesh size. Several different finely divided materials have been used to produce the separating bath but nearly all new plants use a ferro-magnetic medium. The, advantages of magnetic medium include: 1. Smaller recovery plant 2. Lower cost recovery plant both in initial and operating cost 3. Excellent medium stability 4. Dependable medium supply at reasonable and stable cost. Magnetic separators are used to recover this magnetic medium and the smaller plants and lower operating costs are directly related to their use.

Jan 1, 1964

By Scott Brien, O&apos

Cyclones have become standard unit operations in mineral processing for both dewatering mineral slurries and for making separations at given particle sizes. Conventional cyclones are normally able to make moderately sharp cuts. However, the limited ability to control water flow out of the apex means that cyclones have difficulty handling fluctuations in feed. Underflow-regulated cyclones are cyclones with a rubber boot attached to the underflow. This boot acts as a non-return valve and restricts flow out of the apex of a cyclone. Normally, this type of restriction on a cyclone causes severe difficulties in cyclone operation. However, by adding a siphon arm to the overflow, water flow can be controlled. The siphon arm creates a vacuum that reduces or eliminates the air core, permitting better control of the ratio of water flow out of the overflow and underflow. A Linatex-developed underflow-regulated cyclone was compared to a conventional cyclone for its ability to dewater a sand slurry. The underflow-regulated cyclone produced slurries with solids contents as high as 80% in the underflow. Conventional cyclones produced lower solids content in the underflow under similar conditions.

Jan 1, 1997