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By C. M. Mason

Bureau of Mines studies were made on the sensitivity of several ammonium nitrate-fuel oil (AN-FO) mixtures to bullet impact. The experimental work was done with one military rifle and two high-velocity sporting rifles with a variety of ammunition. For the three rifles used, the order of efficiency in initiating detonation in AN-FO mixtures was 220 Swift >300 Weatherby Magnum >30-&apos;06. The velocity of the bullet was found to be a decisive factor in the initiation. The sensitivity of various materials studied increased as follows: Clay-coated prills with 4 percent oil <fresh surfactant-coated prills with 4 or 6 percent oil <surfactant-coated prills with 4 or 6 percent oil and aged 270 days <crushed prills with 6 percent oil <very low-density, surfactant-coated prills (micronized), with 4 percent oil.

Jan 1, 1963

By Frank G. Schwartz

The Bureau of Mines developed a rapid test method for predicting the stability of motor gasoline during long-term storage. The amounts of gum and inorganic residue formed in 13 gasolines during a l6-hour oven test at 200° F were compared with the amounts formed in the same gasolines stored at 110° F, and analyzed following 8-, 16-, 32-, 44-, and 52-week storage periods. Satisfactory methods were developed for predicting gum and inorganic residue formation during fuel storage periods as long as 32 weeks at 110° F, the approximate equivalent of 5.7 years at 80° F. The only data required to apply the methods are the amount of gum and inorganic residue formed, and the amount of oxygen that reacted, during a l6-hour oven test. A direct relationship existed between inorganic residue formed during the oven test and during 110° F storage. Statistical treatment of the data showed predicted values were as reliable as determined values. By use of a modified Arrhenius equation, the 110° F storage time can be extrapolated to equivalent time at any temperature below 110° F. Thus by combining the stability prediction method with the mathematical extrapolation, the storage performance of motor gasoline for extended periods can be estimated at any temperature up to 110° F.

Jan 1, 1968

By R. V. Rahfuse

Noncaking 0- by 2 -inch subbituminous coal from New Mexico was gasified with air and steam at 205 prig using a stirred-bed producer to determine coal losses by entrainment in the gas for this low-sulfur, high-ash coal which contained 20 percent particles smaller than 1/16-inch sieve size. The use of fine-sized coal has particular importance because most production from mechanized mines is smaller than 2-inch size. This initial attempt showed technical feasibility for gasifying New Mexico subbituminous coal containing small-sized particles in fixed-bed producers without excessive coal loss by entrainment. Dust loss averaged about 2 percent of moisture-free coal, most of which was recovered from the gas. Ash clinkering was controlled by adding 1,010 lb/hr steam to reduce tempera¬tures in the combustion zone. Yield of low-Btu fuel gas, 150 Btu per scf, dry, amounted to 69,800 scfh from 1,490 lb/hr coal (as received) and 3,450 lb/hr air (dry).

Jan 1, 1974

By L. O. Bacon

This Bureau of Mines report summarizes the results of laboratory work in the design of instrumentation for obtaining the dynamic tensile strength of rock at minimum loading. Minimum loading is defined as the lowest tensile loading by pulse reflection to cause fracturing. The instrumentation for obtaining dynamic tensile strengths of rock cores evolved into the use of a compressed-air pellet gun to impact one end of a rock core, suspended by wires, at increasing increments of air pressure. Maximum strain was measured on most or all of the impacts, and the strain at fracture of the core was obtained by extrapolating the pellet velocity-strain curve to the pellet velocity at fracture. Stress at tensile fracture was obtained from the maximum s train, and the dynamic Young&apos;s modulus was calculated from the rod velocity by using simple rod theory.

Jan 1, 1962

By L. C. Karrick

The Bureau of Nines has received many inquiries on the subject of assaying oil-shales, both from individuals who desire to wake their own assay while in the field, and also from Commercial assayers and investigators. The present paper describes the assay retort used by the Bureau of Mines. in the research work on oil-shales now in progress at the Intermountain Experiment Station of the Bureau at Salt Lake City, Utah, and at the Colorado cooperative oil-shale laboratory, Boulder, Colorado. This retort, which was developed through experimentation in the bureau&apos;s laboratories, has been found to be convenient in use and. capable of yielding reproducible results. M. J. Gavin, Oil-Shale Technologist, gave valuable assistance in preparing the subject matter for publication and made many helpful suggestions during the experiments made by the writer in the course of the development of the assay retort. L. A. Anderson, research "fellow" University of Utah, assisted in the preliminary development of the assay retort.

Jan 1, 1921

By R. P. Beyer

[The Bureau of Mines has measured the low-temperature heat capacities and high-temperature enthalpies of crystalline K2Si2O5 as part of a program for advancing mineral resources technology with energy economy. High-temperature enthalpies of glassy and liquid K2Si2O5 and crystalline K2SiO3 were also mea¬sured. An adiabatic calorimeter operating over the range 5 to 308 K was used for the heat capacity measurements for K2Si2O5 from which the standard entropy at 298.15 K, S°298 = 45.55 ±0.05 cal/deg-mole, was calculated. Tabulated values of Cp°, S°, -(G° -HO°)/T, and H°-HO° from 5 to 300 K are given for K2Si2O5. A copper-block drop calorimeter was used in the enthalpy measurements, operating from 298.15 to 1,198 K for K2SiO3 and from 298.15 to 1,453.8 K for K2Si2O5. No transitions were found for K2SiO3. The KI2Si2O5 showed two reversible first order transitions, one at 510 K with a heat of transition of 0.29 kcal/mole and one at 867 K with a heat of transition of 0.38 kcal/mole. The heat of fusion for K2Si2O5 20 5 was calculated to be 8.42 kcal/mole. Relative enthalpies are given in equation form, and high-temperature values are tabulated for Cp°, S°, - (G°-H°298 )/T, and H°-H°298 . Also tabulated are ?H°, ?G°, and log K for formation of K2SiO3 and K2Si2O5 from both the elements and the oxides.]

Jan 1, 1979

By Robert B. Fisher

[The purpose of this paper is to acquaint manufacturers of various types of asbestos product&apos;s, particularly those that specialize in materials used for sound deadening, vibration damping, and filtration, with a recently invested depth deposit of paligorskite, a type of asbestos usually called mountain leather. In the past this mineral has been only a museum curiosity but it possesses characteristics that may adapt it to industrial uses. The deposit is on Lemesurier Island, near this entrance to Glacier Bay, in the northern portion of southeastern Alaska, at approximately latitude 58° 17? N., longitude 1360 05&apos; W. The island is about 4 ½ miles in east- west length and miles in width. The property on which the deposit occurs is owned by the locator Joe Ibach, end it was brought; to the attention of the Bureau of Mines by Col. George B. Norris. A Bureau of Mines engineer, accompanied by the owner and Chris Ellingen, visited the property sand examined the open-cuts from May 7 to 10 in 1944. The purpose of the examination was to determine the approximate extent of the occurrence and to obtain samples of the material for identification end study of its utilization.]

Jan 1, 1945

By H. W. Leavenworth

Research was conducted by the Bureau of Mines to develop a technique to grow metallic fibers from a sulfide mineral. In this research, chalcopyrite (CuFeS2) was made sulfur deficient, and the remaining sulfur partitioned to the iron in the mineral to liberate metallic copper, or to the copper to liberate metallic iron. The metals formed on the surface as fibers and in the interior as spherical particles. Fiber growth is very fast. Lengths of 3 to 4 cm form in a matter of minutes, and the diameter of individual fibers is less than 1 µm. The mechanism of fiber growth is explained, and the reactions are reversible as predicted. Copper fibers can be made to grow from the surface at 400° C or to dissolve back onto the solid surface and be replaced by iron fibers at 625° C. Growth and dissolution can also be controlled to form copper/iron duplex fibers.

Jan 1, 1974

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

The Federal Coal Mine Health and Safety Act of 1969 has dictated major changes in mine ventilation with regard to both air quantity and quality. Requirements have also been placed on the ventilation of beltlines, gob and face areas, and air velocities on trolley haulage roads are limited. Escapeways, separate from trolley haulage roads and on an intake split of air, must be maintained continuous to the surface. These and other similar requirements have not only precipitated several modifications to existing ventilation systems but also have greatly increased the complexities of new mine ventilation planning. It is apparent that the use of computers in ventilation system analysis and design is a necessity. SUMMARY Although computer oriented analysis of mine ventilation systems was introduced over two decades ago, it has yet to receive widespread acceptance in the United States. Central to this problem is the fact that, while many computer programs for network analysis have been developed, no attention has been paid to the development of computer input data. Consequently, without this foundation, program applications have been infrequent. This thesis has directly attacked this problem and has presented all pertinent information basic to the development of good computer input data. The areas that were covered include quantity measurement, pressure measurement, fan testing, survey data balancing, and the development of a network schematic from the ventilation survey results. These discussions on data collection and the corresponding reduction to computer coding have been illustrated by an application of a ventilation simulation program to an existing mine in Southwestern Pennsylvania. The use of a ventilation

Jan 1, 1977

By R. V. Ramani, K. Bode

"IntroductionThe theory of particle dispersion and deposition in turbulent flow is important to many fields of science and engineering. Dispersion has been studied in some detail since the early fifties (Taylor, 1954; Fischer, 1967; Osipov and Grekov, 1968; Skobunov, 1970 and 1973; Klebanov and Martynyuk, 1974). A broad research effort has also been underway in studying the mechanics of dry particle deposition. Friedlander and Johnstone (1957) proposed a theory, according to which particle deposition from vertical pipe flow could be described by an eddy diffusion transport followed by a final flight to the surface. There have been numerous revisions and additions to this original theory (Owen, 1960; Liu and Agarwal, 1974; Liu and llori, 1974; El-Shobokshy and Ismael, 1980) The mining process essentially consists of breaking in situ materials and transporting them out of the mine. An inherent characteristic of this process is the generation of fine particles. Fine airborne particulates are associated with a number of threats to the health of the miners; fine coal dust can also result in mine-wide catastrophic incidents such as dust explosions. For these and other reasons, it is important to understand the behaviour of airborne dust particulates, particularly their generation, entrainment, transport, dispersion, and deposition in the mine environment for their control.Mine related studies on dispersion and deposition have been few. Yet, several studies of gas and dust dispersion, diesel exhaust contamination, and methane ingress into mine workings have recognized the need for developing reliable parameter values for fundamental understanding of the phenomena (Da""Yes and Slack, 1954; Hodkinson, 1957; Hodkinson and leach, 1958; Mass and Wildschut, 1966; Airey, 1969; Courtney et al., 1986; Stefanko, Ramani, and Thakur, 1974; Stefanko, Ramani and Kenzy, 1977; Bhaskar, 1987, Bhaskar and Ramani 1990; Qin and Ramani, 1989; Shankar and Ramani, 1990)."

Dec 1, 1995

By V. R. Miller

The Bureau of Mines investigated methods for testing the tensile and sheer strength of cast specimens of bulk solder and of soldered joints in order to increase the strength and extend the useful temperature range of soft solders. A spread-area test for determining the wettability of solder on copper surfaces was developed. Mannitol was used as a flux in spread tests to control spreading and to avoid plating, etching, and other side effects of regular fluxes. Data on commercial and high-purity solders obtained by these methods show more consistency than those reported by others from similar tests.

Jan 1, 1967

By Bernard Porter

The solubility of UO2 was determined at 1,250° C. in ternary melts of UF4 and BaF2 with CaF2, LiF, and SrF2. The solubility of Ce02 was measured at 800° and 850° C. in a solution of CeF3, BaF2, and LiF. The amount of La203 which dissolves at 950° C. in a binary mixture of LiF and LaF3 and a ternary of LiF, LaF3, and BaF2 was also measured. In each case, the amount of soluble oxide was mound to be less than 5 weight-percent. A procedure was developed for filtering fused, oxide-saturated fluoride melts in order to obtain a representative sample for chemical analysis. The oxide content of the samples was determined by an inert-gas fusion procedure.

Jan 1, 1961

By Thomas J. Blalock

The volumetric determination of uranium according to the method of Sill and Peterson (6),3/ which uses cerate oxidimetry after the separation of interferences such as sulfides and cupferrates, has been used for some time by the Bureau of Mines and gives satisfactory results for many of the samples tested. However, in those instances where the uranium content did not exceed a few tenths of 1 percent and iron was present in the range of 10 to 40 percent (as Fe203),4/ the method was cumbersome and unreliable. The need for a more accurate procedure for the determination of small amounts of uranium in the presence of large amounts of iron, such as in shale or black sands, prompted this investigation. The Bureau desired that materials containing as little as 60 p.p.m. of uranium be assayed within reasonable limits of accuracy. One of the primary aims of this work has been to eliminate, as far as possible, the necessity for repeated cup ferron extractions.

Jan 1, 1960

By A. F. Colombo

Laboratory-scale tests were conducted by the Bureau of Mines on an argillaceous Michigan copper ore and mill tailing to determine the feasibility of leaching with acidified ferric sulfate solutions. The ore and tailings, containing 1.24 and 0.24 percent copper, respectively, were from the White Pine Copper Co., Ontonagon County, Mich. The investigation showed that ferric sulfate leaching of the ore and tailings followed a predictable pattern. Thus, with 4 hours of leaching, up to 58 percent of the copper in the ore was extracted, but prolonged leaching (2 to 3 weeks) was required to dissolve more than 90 percent of the copper. Similarly, about 50 percent of the copper in the mill tailings sample was dissolved in a few hours, but 8 days or more were required for extractions of over 90 percent.

Jan 1, 1962

By D. W. Scott

Thermodynamics is a powerful tool for investigating rotational isomerism in substituted ethanes and related molecules. Accurate calorimetric data can be interpreted to give information, not only about the energy difference between conformations, but also about the shape of the potential barrier hindering rotation from one conformation to another. However, a deterrent to this use of thermodynamics is the labor required to calculate the contributions to the thermodynamic functions for assumed potential functions. Tables of thermo-dynamic contributions for appropriate potential functions can eliminate that labor and greatly facilitate the thermodynamic study of rotational isomerism. In this research, tables of contributions to the thermodynamic functions were compiled for two potential functions typical of some commonly encountered examples of rotational isomerism. TYPES OF POTENTIAL FUNCTIONS Potential function 1, illustrated in figure 1, A, has two equal minima higher than the third. It has the general shape of the barrier to internal rotation in n-butane, for example. The trans conformation of n-butane has the lowest energy, and the two skew or gauche conformations have equal but higher energy. Potential function2, illustrated in figure 1, B, has two equal minima lower than the third. It has the general shape of the barrier in 2-methylbutane, for example. The two C1 conformations of 2-methylbutane have equal energy much lower than the assumed Cs conformation, which has not been observed spectroscopically.

Jan 1, 1962

By P. D. Kovscek

The Bureau of Mines has tested a low-thrust water-jet-assisted rotary drill. This work was performed to evaluate the performance of a water-jet-assisted drill operated at thrust levels typical of a handheld manual-thrust operation. Prior work by the Bureau had indicated that using water-jet assist with high-thrust drilling applications would increase drilling rate. Small-diameter holes were drilled in five different types of rock. Thrust and water pressure were varied as the drill rate was monitored. The test results indicate that drilling rates increase with increasing water pressure and thrust. The water jet has more effect on reducing the specific energy when drilling in the harder rocks than in softer rocks. Variation in drill rate for a given rock sample is attributable primarily to the material heterogeneity within the sample. One rock type (Greenwich sandstone) could not be drilled efficiently with the water-jet-assisted drill.

Jan 1, 1988

By E. R. Bauer

The U.S. Bureau of Mines is investigating strata interactions associated with mining of multiple coal beds to provide the mining industry with improved methods of planning and developing multiple coalbeds, conserving resources, and increasing the safety of underground coal mining. This study involves analytical predictions and underground observations of longwall development ground control problems at a south-central Pennsylvania coal mine affected by subsidence induced by multiple-seam mining. As predicted, strata interactions were found in upper mine areas mined over lower mine gob. Observations revealed roof deterioration accompanied by excessive water inflows in the first 170 ft after crossing the gob line as mining entered and exited the subsided area (over the lower mine gob). In contrast, superimposed mine areas and areas mined a substantial distance out over the gob showed no signs of interaction with previous lower seam mining, again as predicted.

Jan 1, 2010

By Todd M. Ruff

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying methods to prevent workers from being entangled in machinery used at mining operations. An analysis of mining accidents in the United States that resulted in a fatality or permanent disability from 2000 through 2005 showed 438 severe incidents that involved contact with machinery or equipment, an average of 73 per year. Researchers determined that the most common machinery involved in these severe accidents was conveyors. Also, a significant portion of the accidents occurred during machine maintenance and repair. Researchers are focusing on improved methods to prevent unintentional machine startup during maintenance activity and methods to detect workers near moving machine components. One new technology that shows promise for this application is intelligent video. Popular in the surveillance and security industries, these systems use cameras and computerized video analysis techniques to automatically detect the presence of people in preset zones within the camera?s field of view. A preliminary study has been initiated to determine if this technology could reliably detect the presence of workers in hazardous locations near machinery. Possible advantages of the use of this technology include improved detection zone demarcation and improved ability to distinguish between hazardous and non-hazardous proximity, compared to conventional proximity sensor techniques. Initial tests to detect a person near a conveyor system in daylight conditions showed promising results. A description of the technology, test procedures and results, implementation challenges, and future research needs are discussed.

Jan 1, 2008

By A. J. Strazisar

The Bureau of Mines conducted a laboratory investigation to study the effectiveness of low-pressure steam and water spray in suppressing respirable dust at the tips of a saw-type cutting wheel. Suppression efficiencies were found to be proportional to the amount of the water or steam applied at the cutter tips. For equivalent water output rates, a maximum efficiency of approximately 80 percent was reached for both steam and water spray. Results from the steam and water spray tests showed an increase in suppression efficiency with an increase in particle size of 1 to 8 micrometers. The data indicate no advantages for using steam as a dust suppressant.

Jan 1, 1972

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Paolo Ciambelli, Lenore Rainey

"The evolution during oxidation of the internal structure of soot and carbon black particles was studied using high-resolution transmission electron microscopy (HRTEM) and an image analysis system. Increasing ordering to the carbon structure with increasing oxidation is observed. Measures of the increased order are increases in the fractional coverage of a cross section of the particles with a layered structure, a decrease in the mean interlayer spacing, and a decrease in the spread of the interlayer spacing. The changing structure of the carbon black impacts its properties, such as the rate of oxidation.There is considerable interest in the study of the structural changes of carbonaceous materials as a function of oxidation. Davis et al.1 measured the variation of carbon dioxide surface area of various coals as a function of residence time in a flow reactor. HRTEM measurements revealed that crystallite dimensions and interlayer spacings are altered by combustion. Ishiguro et al.2 showed that oxidation alters the structure of diesel soot. The aim of our current research is to develop a better understanding of the microstructural reordering of carbon blacks with implications to their properties. The carbon blacks used in this research have already been studied and their reactivities as a function of oxidation measured.3The methodology used in this work has already been described in detail elsewhere.4 This paper presents an application to quantify the structural changes of carbon black particles as a function of oxidation and graphitization. The technique used is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, chars, etc., possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure. The carbon structure has been variously described as turbostratic5 or as crumpled sheets6 to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as the composition of the source of the carbonaceous material. The value of electron micros¬copy in studying the morphology of such materials has been well established,2,7,8 although only a few attempts toward quantification have been made.The sample observed was carbon black CB330 from De¬gussa. One set of carbon black samples were oxidized in a thermo-gravimetric analyzer (TGA) in air at 575 0C, so that the conversion varied from 0 to 96%. Another set of carbon black samples were graphitized (Graphpac-GB by ALLTECH) and then oxidized in the TGA at 680 °C until 92% burnout was reached. The latter samples are called GB 0% and GB 92%, respectively.For the HRTEM observation a small portion of each sample was ultrasonically dispersed in ethanol. The suspension was deposited dropwise on a copper TEM grid coated with a lacey carbon film. The examination of the samples was carried out on areas that extend over the holes in the supporting film in order to avoid interference from the amorphous carbon background film An oriented gold crystal was used as a calibration standard and subjected to the same techniques as the carbon black samples."

Jan 1, 1998