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By Edward D. Thimons

As U.S. mines go to greater depths, the high temperatures and humidities characteristic of such depths make it difficult to maintain a comfortable environment in working areas. Better techniques for cooling these deep working areas are needed. At the Homestake gold mine in South Dakota the Bureau of Mines has tested a water spray cooler inserted into the fresh air vent tube entering a warm stope. The cooler supplied more than 6 tons of refrigeration to the stope air, which dropped from an inlet temperature of 83° F dry bulb and 75° F wet bulb to 73.5° F dry bulb and 71.5° F wet bulb. These preliminary results show the water spray cooler to be a feasible concept. However, there is a need for substantial refinement and further testing, and work on the concept will be continued under contract to the Bureau.

Jan 1, 1979

By John Durkin

Electromagnetic narrow-band signals were transmitted through the earth at 27 coal mines located throughout the United States. From those Bureau of Mines tests, apparent earth conductivity values were derived based upon a homogeneous half-space model of the earth. The derived conductivity values were found to be inversely proportional to the transmitted frequency and mine depth. A linear regression model relating the logarithm of the conductivity to the mine depth was formulated, and the results indicate that the mine depth can be an adequate predictor of the apparent earth conductivity above coal mines. Apparent earth conductivity was found to decrease with mine depth.

Jan 1, 1984

By John Durkin

Electromagnetic narrow-band signals were transmitted through the earth at 27 coal mines located throughout the United States. From those Bureau of Mines tests, apparent earth conductivity values were derived based upon a homogeneous half-space model of the earth. The derived conductivity values were found to be inversely proportional to the transmitted frequency and mine depth. A linear regression model relating the logarithm of the conductivity to the mine depth was formulated, and the results indicate that the mine depth can be an adequate predictor of the apparent earth conductivity above coal mines. Apparent earth conductivity was found to decrease with mine depth.

Jan 1, 1984

By Allen D. Look

Underground fires often prove difficult to control , and a small fire can quickly grow into a large one , endangering life and causing large property damage . Even a small underground fire may produce enough noxious gases to cause suffocation ; therefore , every precaution should be taken to prevent and control such fires . It is ironic that mine fires should be caused when utilizing materials that are in themselves fire - resistant ; yet , cutting and welding of iron and steel are proving to be common causes of underground fires in metal mines . This paper includes 19 examples of underground fires of this nature , and undoubtedly this is only a fraction of the number of similar fires that have occurred in the last few years . This paper will review some metal - mine fires caused by cutting or welding and point out precautions to be taken to prevent other fires from this cause .

Apr 1, 1948

By J. G. Croeni

The high thermal-neutron cross section of gadolinium and the good mechanical and corrosion properties of titanium suggest that alloys of these two metals might be useful as control rod material. To aid in establishing the feasibility of this combination, the Federal Bureau of Mines investigated the titanium-gadolinium system. The results indicate that the system is composed of a single eutectic reaction and a peritectoid reaction involving the alpha-beta transformation of titanium. The eutectic isotherm extends from 1 to 99 pct, gadolinium at 1,240° C. The established eutectic composition is about 95 pct, gadolinium. The peritectoid reaction occurs at 885° C. and extends almost over the entire composition range. Hardness increases slightly with additions of gadolinium, and little change is obtained by heat treatment. Alloys containing less than 10 pct. gadolinium are amenable to extensive cold-working, but alloys having higher percentage of gadolinium content are only moderately cold-workable. All alloys can be hot-worked in iron sheathing at 750° C. Observation indicates that all compositions possess good machinability. Corrosion resistance to water at room temperature is apparently poor, especially in the gadolinium-rich alloys. INTRODUCTION A combination of the good mechanical and corrosion properties of titanium and the variety of thermal-neutron cross sections characteristic of the rare-earth metals suggests that alloys of these metals may be used for control rod materials. For this reason the Bureau of Mines proposed a study of the titanium-gadolinium alloy system, and the Atomic Energy Commission sponsored the investigation.

Jan 1, 1961

By Robert J. Hundhausen

This paper describes the methods and costs of sinking a 2-compartment shaft at the Hope mine, Clark Fork, Idaho. The Hope mine is owned by the Hope Silver-Lead Mines, Inc. Albert E. Nash, of Clark Fork, is president and manager.

Jan 1, 1948

By Paul R. Amyotte, Omotayo Kalejaiye, Kenneth L. Cashdollar, Michael J. Pegg

The Siwek 20-L chamber is widely used throughout the world to evaluate the explosibility of dusts. This research evaluated the quality of dust dispersion in the Siwek 20-L chamber using Pittsburgh coal, Gilsonite, and purple K dusts. A Pittsburgh Research Laboratory (PRL) optical dust probe was used to measure optical transmittance through the dust cloud at various locations within the chamber. A total of 540 tests were performed, with triplicate tests at five nominal dust concentrations and six locations. The two standard dispersion nozzles (rebound and perforated annular nozzle) were compared. The transmissions corresponding to the normal ignition delay period were used to: (a) determine variations in spatial uniformity of dispersion obtained with both nozzles; (b) make comparisons between the experimental transmission data and those calculated from theory for the three dusts; and (c) make comparisons with transmission data measured in the PRI, 20-L and Fike 1 -m3 dust explosion chambers. The uniformity of dispersion for the three dusts was similar with both nozzles, despite the differences in nozzle geometry and mode of operation. Transmission data of the three dusts were all significantly lower than those calculated from theory. This was discovered to be, in part, due to significant reduction in particle size that occurred during dispersion. By measuring particle sizes before and after dispersion, values of 60%, 50%, and 20% reduction in particle size (based on the surface weighted mean diameter) were obtained for Pittsburgh coal, Gilsonite, and purple K, respectively. Transmission data from the PRL 20-L, Fike 1 -m3 and the Siwek 20-L chambers indicated comparable results in terms of uniformity of dispersion. However, transmission data from the Siwek 20-L chamber were significantly lower than those of the PRL and Fike chambers. Again, this was attributed, in part, to the significant reduction in particle size that occurred during dispersion in the Siwek chamber. The design of the outlet (dispersion) valve of the Siwek 20-L apparatus charge vessel was largely responsible for the particle break-up. The contribution to particle break-up by the dispersion nozzles and the high level of turbulence in the chamber were found to be minimal. This is a significant finding in that the dust particle size tested for explosibility in the Siwek chamber is considerably smaller than the original dust sample.

By Aner W. Erickson

Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.

Jan 1, 1948

By Robert W. Smith

Computation of the thermodynamic properties of the reaction products in the deflagration of explosive gas mixtures has been a most valuable guide regarding the possible kinetic mechanisms of homogeneous combustion processes. Knowledge of the physically possible end states is indispensable for understanding observed deviations from equilibrium in heterogeneous combustion. However such information on dust flames is entirely lacking. To complement a Federal Bureau of Mines study of stationary graphite dust flames burning in pure oxygen,6/ this report gives examples, at atmospheric pressure and room temperature, of composition profiles in an idealized oxygen-dust flame, with both mass and enthalpy being preserved. Similar profiles can be obtained from the data of the paper for elevated temperature and pressure.

Jan 1, 1960

By T. J. Ballard

Corundum is a natural alumina (A120 ) and is next to the diamond in hardness . Except for the gem varieties , it is used principally as an abrasive , chiefly in grinding , dressing , and polishing metals and optical glass . Natural corundum is preferred to artificial abrasives for certain specialized jobs . Most of the corundum ( excluding emery ) mined in the United States came from the Corundum Hill mine in North Carolina and the Laurel Creek mine in Georgia . The Corundum Hill mine provided over half of the domestic production of corundum prior to 1900. Since 1900 , the importation of foreign corundum and the manufacture of artificial abrasives caused the decline of corundum mining in the United States .

Mar 1, 1947

By W. E. Lamont

Flotation studies of phosphate-bearing waste pond materials, low-grade washer products, and raw ores, all from the Tennessee brown phosphate district, showed that these types of materials could be treated without des liming to recover high-grade phosphate concentrates. The investigation showed that fine grinding before flotation was a requisite for increased recovery of the phosphate values and that the optimum pH conditions were in the range of 10.0 to 10.5 when using anionic collectors. Multiple-cleaning of the rougher phosphate concentrate was required to produce high-grade concentrates. Phosphate recoveries ranged from 60 to 82 percent and were inversely related to the grade of concentrate produced.

Jan 1, 1972

By Charles Sabine

The 27,960-acre Newberry Mountains Wilderness Study Area (WSA) is located in the Mojave Desert, 17 miles east-southeast of Barstow. In 1983, the U.S. Bureau of Mines, in conjunction with the U.S. Geological Survey, investigated mineral resources of the area as part of the wilderness review process. The Newberry Mountains are underlain by Paleozoic metamorphic rocks, Mesozoic plutonic rocks, and Tertiary volcanic rocks. Eleven mines and prospects were examined. Of the seven sites within the WSA, only the Northrup Prospect is mineralized. Only a few tons of manganese-bearing rock, containing 49% manganese oxide (MnO), are exposed, but exploration may disclose larger deposits. The Azucar Mine, a past producer of gold, is the only site examined outside the area that appears mineralized. Sample data from quartz veins exposed at the surface do not indicate that resources are present; however, the occurrence could not be fully evaluated because underground workings were not accessible. Sand, gravel, and stone are plentiful in the WSA, but alternate sources outside the WSA are available.

Jan 1, 1985

By S. J. Broderick

"INTRODUCTION Dark soils are commonly believed to be better for agricultural purposes than light-color soils. Much of this feeling may be purely psychological, as many persons have unconsciously acquired the habit of associating richness of soil with color light soils, however, may be just as rich in humus and plant foods as the best of the dark soils. A dis-cussion of the manifold attributes that play an important role in soil technology is beyond the scope of this paper, but the color factor will be considered, as it has a particular bearing on some field experiments using coal-mine waste as a darkening medium.It has been established that dark soils absorb more of the sun's radiation, consequently are maintained at a higher temperature than light soils. This physical principle is applied in our daily lives in the choice of clothing. White clotnes in summer are cooler than dark ones. Conversely, dark clothes in winter are warmer than light-color clothing. A decided advantage of dark soils over light soils is the higher average temperature of the former, resulting in an earlier maturing crop. This advance of the maturing season may range from a few days to a month, depending on such factors as climate, crop, and degree of color of the soil. It has been reported that in parts of Russia where the growing season is short, perhaps comparable to that in Pennsylvania and. New York, cotton has been grown successfully on soils originally of light color, but darkened with coal, dusts. The growth of cotton is, accordingly, speeded up a full month. 3/"

May 1, 1940

By Duvall Wilbur I.

This is the second report to be presented on th application of stress analysis to underground Mining problems. In part I2/ of this investigation the stress distribution around single openings in unidirectional and hydrostatic stress fields was analyzed. Relationships between maximum stress concentration and size and shape of openings were determined by the photoelastic method. In most cases the results were verified by mathematical methods This report considers the stress distribution in pillars formed by two or more openings in a. unidirectional stress field. Relationships between stress concentrations and size and shape of pillars are developed. Applied to mining, results snow how estimates may be made of the stress distribution in pillars, what factors cause high local stresses, and how local stress concentrations may be reduced by proper design of mine openings. The photoelastic method was used, as in Part I, to study the stress distributions, and, whenever possible, the results were verified mathematically. A description of the photoelastic method and equipment is .given in Part I.

Jan 1, 1948

By John J. Sammarco

Mining has one of the highest annual average fatality rates among major US industries. Health and safety dangers have been inherent to mining since the early days of picks and shovels. Even though miners' health and safety has improved over the years, mining is still one of the most dangerous occupations. Mining was traditionally a low tech industry. It is now driven by competitive pressures to go high-tech by using programmable electronics (PE) for machine control, atmospheric monitoring and material processing. The industry's experience with the functional safety of PE is limited compared with other industries. Thus, PE is an emerging technology for mining that can potentially create or worsen hazards. The US National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory in Pittsburgh, PA is addressing the safety of this new technology. NIOSH has a proactive project to generate recommendations for addressing the functional safety of PE-based mining systems before the technology proliferates. The recommendations take the form of a safety framework encompassing the entire life cycle for a PE-based mining system.

By Gerald W. Elger

A new process under development by the U.S. Bureau of Mines for producing synthetic rutile from ilmenite is described. Rutile formation is based on oxidation and fluxing of titania slag produced by electric furnacing of ilmenite. Laboratory tests show that phosphorus pentoxide flux additions to oxidized slag enhance conversion to rutile by forming a phosphate-based glass matrix. This matrix contains most of the major impurities, including the oxides of iron, aluminum, magnesium, manganese, and silicon. Rutile crystals of 5 to 150 microns in size were formed in slags heated to temperatures of 800° to 1,550° C. The synthetic rutile crystals were liberated from ground slag by treating with phosphoric acid to weaken the glass matrix, followed by attrition scrubbing. Rutile fractions analyzed as high as 94 percent titania content. In several instances, more than 90 percent of the titanium in the shag was recovered to yield combined rutile fractions containing 90.2 to 92.6 percent titania.

Jan 1, 1971

By I. N. Beall

The present survey indicates 'that the average volatility of motor gasoline now being marketed throughout the country falls well within the limits of Federal Specifications. As would be expected, there is a slight decrease in volatility as compared with the gasoline marketed last wine:., but on the average the gasoline sold today is about the same as that sold last summer. During the past five years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States. To obtain a sample of each gasoline sold is obviously impracticable, but the cities in which samples have been collected have been so chosen as to be representative of the more important marketing territories. It is believed, therefore, that the samples obtained are indicative of the quality of gasoline marketed throughout the country.

Jan 1, 1925

By N. S. Dalal, X. Shi

"Electron spin resonance measurements provide evidence for the formation of long-lived Cr(V) intermediates in the reduction of Cr(Vl) by glutathione redtuctase in the presence of NADPH and for the hydroxyl radical formation during the glutathione reductase catalyzed reduction of Cr(Vl). Hydrogen peroxide suppresses Cr(V) and enhances the formation of hydroxyl radicals. Thus Cr(V) intermediates catalyze generation of hydroxyl radicals from hydrogen peroxide through a Fenton-like reaction. Thus the mechanism of Cr(VI) toxicity might involve the interaction between macromolecules and the hydroxyl radicals.C(Vl) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals (1-3). In contrast, most Cr(III) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic (1,4). Cr(VI) and Cr(III) oxidation states are different in their metabolic pathways: Cr(VI) , ions are rapidly transported across cellular membrane (1,4,5), while Cr[III) moieties do not easily penetrate cells and are not oxidized by cellular constituents (!). Since it is known that the reduction of Cr(VI) ion is required for its reaction with DNA (1), the molecular mechanisms for the intracellular Cr(Vl) reduction has been the focus of current studies but the details are still not understood.Earlier studies on the mechanism of Cr(Vl) reduction include those on the reduction of Cr(VIJ by glutathione (GSH) .0,6-8), ascorbic acid (9), glucose (10), lactose (IO), galacturonic acid (11), microsome (12), and mitochondrial electron transport chain complexes (13). These studies have shown that the Cr(VI) reduction involves the formation of Cr(V)-containing species which are often considered to be the toxic form of chromium. Thus far, however, no information is· available on the subsequent fate of those biologically formed Cr(V) species, in particular employing well defined biochemical systems. In this context, we report here our investigations of the reduction of Cr(VI) by glutathione reductase (GSSG-R). This enzyme was selected because it is ubiquitously present in cellular systems and it has been postulated to be involved in the Cr(VI) reduction (14-17) but the underlying mechanism has not been clarified. We find that the reduction proces·s involves not only Cr(V) but also ·OH radicals. We further investigate the reactivity of Cr(V) and find that it catalyzes generation of OH radical from H2O 2 through a Fenton-like reaction. The role of ·OH in Cr(VI) carcinogenicity is suggested from this study."

Jan 1, 1989

By John M. Dower, Ralph W. Plummer, Terrence J. Stobbe, Hyunwook Kim

"The relationship between exposure to coal mine dust and the development of various respiratory diseases is well recognized. The cause of these diseases however. Is still uncertain. To study this cause-effect relationship, It Is necessary to characterize the coal mine dust In terms of the quantity of dust present and mineral content of the dust. Dust samples were collected using a Portable Continuous Aerosol Monitor (PCAM) and 4-stage cassette Impactors at various locations in an upper Freeport seam coal mine In West Virginia. The samples were analyzed using an X-ray microdiffraction film technique and energy dispersive scanning electron microscopy. This paper presents the results of the first phase of this characterization work which Includes determining the size distribution of the dust and the mineral content of the size intervals.IntroductionDiseases associated with dusts in coal mine environments continue to afflict miners in today's modem mines. These diseases still persist because, as Olishifski points out an employee rarely experiences exposures to a single environmental stress but rather to an Intricate Interplay of multiple stresses.(1) In the case of coal mining the multiple stresses are varying sizes of dust particles originating from coal imbedded minerals. Immediate roof strata bottom strata. Incombustible rock and the coal itself. The site of this Intricate Interplay Is the miner's lungs and the resulting diseases are a function of the composite dust exposures.The proper study of coal mine dust toxicity requires that the dusts used replicate existing coal and mineral dust compositions in their relevant size fractions. The purpose of this project is to develop the size and mineral content data necessary to support this ongoing toxicological effort.Existing coal mining standards and regulations also address total and respirable dust exposures. These dust terms refer to both the quality and quantity of the dust segment in the mine atmosphere. Dust quality addresses its coal and mineral content. whereas dust quantity Is described by mass per unit volume (mg/m3) The comprehensive characterization of coal mine dust exposures will enable revision of these standards and regulations to address the specific minerals and size fractions found to be toxic to human lung tissue."

Mar 1, 1989

By J. E. Doo1ey

To process and use the heavy ends of petroleum effectively, the development of suitable separation and characterization procedures not currently available was required. A systematic procedure was developed by the Bureau of Mines using such techniques as isothermal and molecular distillation, chemical treatment, silica-alumina gel chromatography, gel permeation chromatography, and spectrometry. Using these techniques, the Bureau achieved a detailed separation and characterization of a 370° to 535° C distillate from Gach Saran, Iran, crude oil. Such a systematic procedure and the semiquantitative data resulting therefrom should be of value in selecting feedstocks and in optimizing petroleum processing operations.

Jan 1, 1973