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By W. Bruce Montgomery

Manganese oxides occur, with some iron oxides, in small scattered lenses on property controlled by the Columbia Manganese Co. (1943) near Evington, Campbell County, Va. The company mined some manganese ore during 1917 and 1918. A preliminary examination in May 1942 indicated the possibility of finding additional ore. On August 21, 1942, the Bureau of Mines began prospecting to verify the continuity of the ore exposures. Work on this project continued until February 5, 1943. Prospecting and development work included shaft sinking, crosscutting, drifting, trenching, and test-pitting in six separate areas indicating two types of deposits. The most predominant type is a wide brecciated area in which occur lenses or pockets of nodular manganese oxides. The other type is characterized by more of a vein structure, including thin layers of manganese oxides.

Jan 1, 1949

By R. H. Sprute

Hydraulic backfill consisting of siliceous mill tailings was successfully dewatered and consolidated by electrokinetics in a field test conducted by the Bureau of Mines at the Star mine, Burke, Idaho. A stope at the 2,000-foot level was filled in such a way that slimes and coarse sand were retained in the scope. Following settlement of solids and decant of surface water, direct current applied between buried electrodes created a firm, dense material in approximately 3 hours. This rapid densification of fine-grained material demonstrated the utility of this method and suggests other applications, particularly in the control of slime deposits that cause serious problems in many deep mines.

Jan 1, 1975

By R. J. SHAW

Oil shale has been defined as, "a compact, laminated rock of sedimentary origin yielding over 35 percent of ash and containing organic matter that yields oil when distilled but not appreciably when extracted with the ordinary solvents for petroleum." The oil-yielding organic matter in oil shale, commonly called kerogen, decomposes upon application of heat to form bituminous materials that are soluble in organic solvents and may be extracted from the inorganic residue. However, separation usually is accomplished by continuing the heating and thereby cracking the primary bitumens to gas and oil, which distill, leaving a carbonaceous material on the mineral residue. It has been suggested that this conversion takes place only at relatively high temperatures - 750°F or higher. On the other hand, other workers have found that transformation may take place to some extent at temperatures as low as 400°F. In either a solvent extraction or a destructive distillation process for separating organic material from the inorganic portion of oil shale, the quantity of heat required to raise the temperature of the oil shale sufficiently to induce a satisfactory rate of conversion of kerogen to oil is important in determining the design of an economical process. Likewise, the quantity of heat recoverable from a spent shale is important in determining the overall heat balance of the process. Published data on the specific heat of American oil shales are meager. Gavin and Sharp present data for two samples of Colorado oil shale, one from near DeBeque and one from Parachute Creek, and for a sample of spent shale over a temperature range of 68°F to 1940°F. McKee and Lydor present data on the specific heat of two samples of oil shale from near DeBeque, Colorado. Additional thermal data on various grades of oil shale over a wider range of temperature are needed in order to apply sound engineering practices to the design of equipment for processing oil shale.

Nov 1, 1947

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By Oliver Bowles

This report covers the character, properties, origin, occurrence, and uses of the traprocks and describes briefly the methods and equipment employed in quarrying and preparing them for market. Production of traprock occupies an important place in industry. In 1960 the output in the form of crushed stone reached nearly 58 million tons valued at $87 million. Traprocks are also shaped into blocks of dimension stone for monuments, building construction and decoration, and specialized products such as surface plates.

Jan 1, 1963

By John H. Soule

Appreciable quantities of sine and lead orus have been produced from the West. Pinos Altos district of Grant County, N. sex. This area was visited many times by engineers of the Bureau of ines. D. H. Johnson and 4. R. Storms visited the district in haren 1943 in connection with an acrenu road to toe wines. M. H. Storma again visited the area in July 1943 in connection with a hetals Feserve Corporation loan on the Routen-Thomas

Apr 1, 1948

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines-developed induction slag melting process is of concern to the titanium industry. The objective of the research was to determine the effect of removing the nonconductive molten calcium fluoride (CaF2) slag used as an insulator between the titanium and the segmented copper crucible. The data were obtained from single-induction-melted ingots prepared with no CaF2 insulating slag and an ingot prepared with the normal addition of 4 pct CaP2 slag. The results showed that the mechanical properties of single-induction-slag-melted and annealed Ti-6AI-4V alloy exceed the minimum values specified in "Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H." High-cycle, tension-tension fatigue testing yielded similar results. The data from 44 of the 45 specimens were contained within the typical scatter band for fatigue data on wrought Ti-6AI-4V alloy. Although the removal of the insulating slag is a desirable change, the data from the specimens with the previously standard 4 pct slag addition showed no detrimental effect from the slag inclusions.

Jan 1, 1988

By A. W. Fahrenwald

[In studying coarse sand flotation3/ the question of the relation between fineness of grinding and mill capacity logically arose. Everyone familiar with present fine-grinding practice knows that the capacity of a ball mill or similar mill is determined, among other things, by the fineness of the finished product. Undoubtedly a great many mining companies must have a good deal of data directly bearing on this point, yet no quantitative relationship between ball-will capacity and fineness of finished product has been established. The experimental study presented here is an effort to establish this relationship in a semiquantitative way. The subject is a tremendously large one and grows in complexity as the study becomes more searching. In this work the power consumed by the mill in the various experiments was not determined end neither vas the steel consumption measured; mill capacity only was considered.]

Jan 1, 1930

By K. K. Kelley, L. B. Pankratz

The heat contents of four silicate minerals -- akermanite , cordierite , gehlenite , and merwinite --were measured from 298 ° to around 1,700 ° K by the dropping method . The results were compiled into tabular and equation forms suitable for thermodynamic calculations . The heat contents of these compounds are nearly additive with respect to their constituent oxides .

Jan 1, 1964

By Sabri Ergun, Robert W. Smith, Victor H. Tiensuu

Factual geometries are considered for X- ray scattering studies of weakly absorbing materials by both reflection and transmission methods . These studies are usually made on slab specimens to obtain adequate scattered intensities ; however , the intensities are appreciably influenced by absorption of the X-rays in passing through the specimens . Conventional equations derived to account for this absorption are based on idealized geometries , but for polycrystalline carbons the use of idealized geometries leads to several percent error in the corrections to be made . Use of factual geometries substantially reduces this error .

Jan 1, 1964

By W. D. Mcmillan

Soapstone is the term applied to an impure, massive, soft rock with a greasy feel. It is of variable composition, consisting chiefly, however, of talc, tremolite, and chlorite. Although limited quantities of soapstone are used as building material, in fireplaces, and in the manufacture of laundry tubs, sinks, laboratory-table tops, and-oven and furnace blocks, the principal part of the production is ground for use in roofing paper, insecticides, and as a filler in asphaltic paints.

Jan 1, 1949

By D. R. Mathews

The solubility of carbon in electrorefined vanadium was determined to be approximately 0.27 wt pct at the eutectic temperature 1,650° C and 0.03 wt pct at 700° C. The tensile strength and hardness of vanadium increased with car-bon content to the solubility limit, but this effect was small, probably because of the narrow solubility range. Between the solubility limit and 0.3 weight-percent carbon, the second phase had essentially no strengthening effect in vanadium. The second phase, observed metallographically at the grain boundaries and within the grains, was shown by autoradiography to contain high-carbon concentrations. This second phase was identified as VgC by X-ray analysis. The VgC in the grain boundaries contributed largely to the poor cold-and-hot workability of vanadium-carbon alloys. Increased concentrations of V2C occurred at the grain boundaries of the high-carbon alloy ingots as a result of homogenization at 1,600° C for 1 hour. Alloy ingots containing more than 0.36 wt pet carbon (a calculated 2.9 wt pct VaC) following homogenization, cracked severely and failed by intergranular fracture upon swaging at 900° C.

Jan 1, 1965

By Edward M. Kawenski

Tests were made in the Bureau of Mines Experimental Coal Mine on stop-pings similar to those used in operating coal mines to obtain information on air leakage through the face and the rupture strength of a stopping subjected to a pressure differential. Block stoppings were made from cinder, slag, and gravel aggregates with and without mortared joints and coatings. Sheet stop-pings were uncoated brattice cloth and nylon or brattice cloth and expanded metal-lath coated with asphalt, latex, mortar, or rigid urethane foam. Limited data were obtained on air through stoppings subjected to simulated roof convergence and to shock forces created by the firing of an adjacent charge of explosive. The pressure differential required to rupture stoppings was determined. shows that coating the face of a stopping effectively reduces ail: leakage. Block stoppings, particularly those with mortared joints, are most resistant to pressure and shock forces than are sheet stop-pings. Where ground movement is a factor, sheet stoppings leak less air than block stoppings.

Jan 1, 1965

By K. E. Tame

As part of a Bureau of Mines survey of radioactive waste disposal , a laboratory investigation was made to study such problems in carbonate leaching mills . Because uranium concentrators employing carbonate leaching with caustic precipitation normally recycle barren solutions to the washing circuit , the disposal of liquid radioactive wastes is automatically controlled . However , it was deemed important to determine the actual radium 226 concentrations occurring in this type of milling so that the survey of the entire industry would be complete . The laboratory procedure consisted of leaching the ground ore at 85 ° to 90 ° C and 50 pct solids for 6 hours in a sodium carbonate - sodium bicarbonate solution . The pulp was filtered to obtain a pregnant solution that was reacted with sodium hydroxide to precipitate the uranium as sodium diuranate . Regeneration of the barren solution was accomplished by gassing with carbon dioxide . The solution then was reused by advancing the solution through the washing to the leaching operations . The radioactivity in the pregnant solution was unusually high , averaging 6,500 disintegrations per minute ( dpm ) of radium 226 per liter . However , over 95 pct of the radium was precipitated with the uranium . Consequently , no buildup of radium occurred upon reuse of the barren solutions for washing .

Jan 1, 1964

By Eric B. Sansone

The Federal Coal Mine Health and Safety Act of 1969 requires coal mine operators to sample accurately the amount of respirable dust in the mine atmosphere. A technique approved for such sampling employs a 10 mm nylon cyclone followed by a membrane filter (nominal pore size ????= 5 µm) and a pump. The pump is required to provide a flow rate of 2.0 ± 0.1 liters per minute. Calibrations have yielded a range of flow rates (1.4 to 2.8 1pm) at which the cyclone should be operated to remove the non-respirable portion of the dust. The purpose of this project was to evaluate the performance of the 10 mm nylon cyclone at flow rates of 1.8 and 2.0 1pm using a polydisperse coal dust aerosol. The penetration characteristics of the cyclone were to be compared to the United States Atomic Energy Commission's respirable dust standard. The effect of relative humidity on cyclone penetration characteristics was also to be observed.

Jan 1, 1973

By H. E. Powell

The magnetic susceptibilities of 57 minerals containing titanium, zirconium, vanadium, columbium, tantalum, chromium, molybdenum, and tungsten were determined. The source and petrographic analysis of each sample are given. Included are values for isomorphous series of minerals showing wide ranges of composition and for a few high-purity synthetic minerals.

Jan 1, 1968

By Harold P. Rue

The problem of removing hydrogen sulphide from natural gas has become within the last few years one of major importance to the natural gas and petroleum industry. Several gas fields in the United States produce natural gas containing hydrogen sulphide, and a number of oil fields produce gas which contains hydrogen sulphide. 3 The percentage of hydrogen sulphide in natural gas produced in these fields varies from a fraction of 1 per cent to as high as 20.5 per cent by volume. Hydrogen sulphide is probably the most toxic gas associated with natural gas, and from the standpoint of health and safety it is important that the hydrogen sulphide be removed if the gas is to be used for domestic purposes. Hydrogen sulphide, besides being toxic and therefore a hazard to animal life, is under certain conditions an active corrosive agent and very destructive to equipment. The annual loss caused by the corrosive action of hydrogen sulphide on equipment amounts to hundreds of thousands, perhaps millions, of dollars. The largest percentage of natural gas produced in the United States comes from wells which also produce oil. This associated gas invariably carries with it light fractions of petroleum, which when separated from the gas, condense to the liquid form at ordinary temperatures and pressure. Commercial application is made of this natural condition, and "wet gas" is processed to obtain so-called natural gasoline by employing the principles of absorption, adsorption, or compression and subsequent expansion accompanied by cooling. In the manufacture of natural gasoline from wet gas which contains hydrogen sulphj.de, if this contaminating gas is not first removed, some of the hydrogen sulphide may oxidize to form free sulphur and water. The free sulphur will dissolve in the gasoline produced by any of the aforementioned methods and cause the product to be positive to the corrosion test and there-fore unsuitable for commercial use in that condition. The objectionable sulphur compounds can be removed by washing the gasoline with a solution of caustic soda or other chemicals, but this treatment is expensive. It is advantageous therefore to remove the hydrogen sulphide from the gas before it is processed in a natural-gasoline plant.

Jan 1, 1932

By A. R. Taylor Jr.

The heat capacities of a-quartz form beryllium fluoride were measured at approximately 3° intervals from 8° to 300° K., using an adiabatic calorimeter. At 298.15° K the heat capacity and entropy were 12.39 cal/deg mole and 12.75 ±0.04 eu respectively. Enthalpy measurements were made with an ice calorimeter at approximately 30° intervals on the quartz and glassy forms of beryllium fluoride between 300° and 1,200° K. A melting point of 825° K and an 0,-8 type transition at 500° K with a heat effect of 75 ca1/mole were deter-mined from the enthalpy data for the quartz-type sample. Beryllium fluoride glass crystallized spontaneously into the quartz modification at 500° K. The heat of the reaction BeF2 (a-quartz) .... BeF2 (glass) was found to be 1,125 ±16 cal/mole at 298° K by solution calorimetry. This value, when corrected to 273° K, was used to correct for the heat absorbed by the formation of glassy BeF2 when the sample was dropped into the ice calorimeter from temperatures above the melting point. Using corrected enthalpy measurements, the heat of fusion was determined to be 1.13 kcal/mole at 825° K.

Jan 1, 1965

By B. H. Eccleston

Experimental data were obtained from two medium-duty diesel engines derated to qualify for use in underground mines. Gaseous and particulate emissions from these engines were measured and results provide information on the effect of exhaust treatment devices on the emissions. The devices in the study were a catalyst, a particulate trap, and an exhaust gas cooler of the water scrubber type. Emission levels of carbon monoxide and hydrocarbons were observed to be very low in comparison with emission levels of comparable engines in full-rated operation. Oxides of nitrogen and benzo(a)pyrene content of the exhaust also were found to be somewhat low in comparison with previous findings. For particulate reduction, the combination of a particulate trap and a scrubber was observed to be the most effective combination tried; in some cases, over 60 pct particulate reduction was effected by the trap-scrubber combination.

Jan 1, 1981

By William Seymour, L. D. Schmidt

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of the Solid Fuels Administrator for War and with the advice of the Coke Production Committee indicated that production of pig iron could be increased. appreciably if present blast furnaces were supplied with a more uniform coke.4/ Nonvarying percentages of ash , sulfur , and fixed carbon in the coke , together with uniform physical characteristics , such as size , strength , and porosity , would aid the blast -furnace operator greatly in his trial - and - error methods of obtaining maximum production . With nonuniform raw materials he must employ certain factors of safety in operation , such as an excess of coke , an excess of limestone , and operation of the furnace below the maximum rate . Even so , he often has trouble from iron not being up to specifications , hot tops , high blowing pressures , furnace hanging up , etc. The more uniform his raw materials (of which coke is probably the most important) , the nearer to ideally can he run his furnace and thereby save raw material and increase production . One cause of nonuniformity of the coke produced by ordinary American plant practice is the prevailing lack of precise control of the bulk density ' of the coal charge in the byproduct oven . This report summarizes the available information on the subject of bulk density of crushed coal and its control . It includes brief reviews of some of the literature , some results obtained at plants visited by the authors , and results of a few preliminary tests made at the Pittsburgh Station of the Bureau of Mines .

Dec 1, 1943