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By Alim Gül, Güven Önal

"Recently, there have been some attemps on the treatment of low grade ores and old plant tailings due to the decrease in high grade ores and the increase in the metal consumption with increasing world population. Cost of mining and beneficiation of low grade ores become prohibitive since the costs of grinding before flotation make the process unfeasable. Therefore, preconcentration of these ores prior to flotation becomes more important. The concentration of ores preconcentrated in coarse sizes provides a decrease in investment costs as well as grinding and flotation costs. Additionally, the requirements of less space for tailing disposal and less reagent consumption are also important from the viewpoint of environmental considerations.In this study, ore sample containing 0.6 % Cu and taken from Küre-Asiköy ore body was used. Ores contained chalcopyrite and pyrite as main minerals and diabaz, quartz, chlorite and sericite as gang minerals.Samples were all crushed under 9 mm by considering the preliminary studies and float and sink experiments were carried out with the sample in the size range of –9+1 mm using different densities of heavy liquids. As a result of these tests, it was shown that 60 % of the material should be discarded as tailings with 0.1 % Cu content. By considering float and sink test results, the following experiments were performed by using heavy medium cyclone and jigs.As a result of heavy medium cyclone tests, which are conducted on the sample in size range of –9+1 mm, 57 % of the feed material was discarded as tailing with 0.08 % Cu content and 7 % Cu loss, while a concentrate containing 1.43 % Cu was produced with 93 % efficiency (Table 1). Jig tests were done with the samples in the size range. As a result of jig tests with –9+1 mm size group sample, approximately 46 % of feed material was discarded as tailings with 0.13 % Cu content and 10.6 % Cu loss, while a concentrate with 0.94 % Cu content was obtained (Table 2)."

Jan 1, 2003

By Nani Pajunen, Kari Heiskanen

"Products filling our societal needs, like communication and transportation needs, are becoming more sophisticated and efficient. The cost has been an increased complexity of material combinations. The same trend is also seen in investment goods. As an example, different crusher types have almost doubled the power to weight ratio in a relatively short time while producing even higher crushing rations. This has been possible by high performance materials and advanced designs. Another example is new hybrid materials in prefabricated high-strength steel structures in construction with the aim to lighten the products and obtain energy savings in the use phase e.g. in transportation. This development in general has made the end of life phase obscure. Recycling is often understood as the first phase of the material cycle. This has been supported by the material centric point of view. When, say indium, has been collected and mechanically treated to a concentrated fraction, it is assumed as recycled. This is not the case. The same applies to special steel alloys where one tends to lose some of the alloying elements to slag or even into the gas phase in the melting and refining stage, not in the earlier steps of recycling. At present there is no clear understanding of recycling of hybrid materials and no clear willingness to create new functional recycling systems. As the EU directives and most of legislation worldwide are based on the material centric thinking and implemented even on total mass recovery basis there is neither legislative incentive nor very strong economic incentives to work out the problem. In our research, we focus on industrial design towards sustainability from a product centric point of view from product collection to final metallurgical steps. It is vital, in the design phase of product, to understand the effects of decisions on recyclability to a saleable raw material. Main goal of our work is to create the fortunate circumstances in supply chain - to pass the barriers and find the effective and fruitful drivers - for reasonable use of raw materials and recycling co-operation with industry. The boundary conditions in the work are extractive metallurgical performance and the economic viability of all the steps. It can be shown from our work that small design alterations may have a large impact on the recyclability. The earlier the decisions are made in the product life chain the more positive impact they will have. It can also be shown, that a strong processing and metallurgical industry is vital to any meaningful recycling of the modern EoL products. Finally, it is also question of the individuals and values: supply and demand. Are you ready to take up the gauntlet: demand recyclable products."

Jan 1, 2014

By Jaime Sepúlveda

"A broad diversity of critical operating conditions may influence, in very convoluted ways, the actual performance of any given mineral processing system, to the extent that it becomes nearly impossible to empirically determine the independent, decoupled impact of each condition. An effective approach to better understand the behaviour of such complex systems is via the extensive use of sufficiently detailed and reliable mathematical models, allowing the process analyst to explore and learn about the independent effect of all relevant operational conditions. Certainly, these tasks are greatly facilitated if the appropriate software tools - such as the Moly-Cop Tools software package - are readily available. Moly-Cop Tools 3.0 is a set of 63 easy-to-use EXCEL spreadsheets designed to help process engineers characterize and evaluate the operating efficiency of any given grinding circuit, following standardized methodologies and widely accepted evaluation criteria. Moly-Cop Tools 3.0 covers conventional and semiautogenous mills, crushers, HPGR’s, rod mills and vertimills, with the corresponding mass balance and parameter estimation routines; plus complementary spreadsheets regarding Bond’s Law calculations, grinding media selection and performance evaluations and other useful utility functions. As a relevant example of application, specifically focusing on semiautogenous grinding operations, the current publication describes how the models can help us learn and rationalise critical empirical observations such as the relationship between feed particle size and optimal ball filling, the role of the rocks as autogenous grinding media as well as the impact of feed size and discharge grate opening on the mill grinding capacity. Over the last 20 years, Moly-Cop Tools has gained wide acceptance around the mineral processing community in recognition to the quality of the mathematical models contained, their simplicity of application and ease of sharing of the calculations amongst all interested parties, since it is available free-of-charge with no restrictions to make as many copies as needed."

Jan 1, 2014

By Li Maolin, Cui Rui, Wang Guanghui

"As the stirrer speed directly affects the motion of grinding media, and hence the interactions with material particles to be ground, the rotation speed of a stirred mill is well recognized as one of the most important factors affecting the grinding performance. In this work, the effect of stirrer speed on grinding performance in terms of grinding rate and grinding energy efficiency was quantitatively investigated. Batch wet grinding tests of quartz powder at different stirrer speeds were performed, using a self-made horizontal stirred mill with alumina balls as grinding media. Grinding time, operating power and the sizes of ground product were recorded to analyse the grinding performance. The test results showed that grinding processes followed the first order grinding kinetics. The grinding rate constant increased with the increasing stirrer speed. Based on the grinding kinetics, the grinding energy equation was established. The energy utilization coefficient in the energy equation can be used as an indicator of energy efficiency. The energy efficiency decreased with the increasing stirrer speed. Quantitatively, with the stirrer tip speed increasing from 4.25m/s to 9.35m/s, the grinding rate constant was improved by 441.47%, whereas the energy utilization coefficient was decreased by 39.35%. The grinding rate constant and energy utilization coefficient can be used to evaluate the grinding performance when the grinding conditions need to be adjusted. The adjustment of grinding conditons would be optimal when grinding rate get significant improved with little decrease of energy efficiency."

Jan 1, 2014

By Martin Rudolph

"Flotation is without a doubt one of the major processes for the separation of fine minerals and it has been applied for more than a century. A key task of a successful flotation separation is to find the proper chemical treatment to selectively hydrophobize and thus float a certain mineral phase using molecules or ions referred to as collectors, depressants, regulators and frothers. Commonly floatability is determined by microflotation tests using the Hallimond tube with pure mineral phases. This method however requires the pure mineral phase which is very often not even taken from the same deposit which is going to be processed. In this paper we present a new approach to in-situ determine and even map the floatability of finely disseminated mineral phases within cross-sections of an ore. It is based on measuring hydrophobic effects using colloidal probe atomic force microscopy with a hydrophobic polystyrene probe based on force spectroscopy with a lateral resolution of only a few nanometers. Coupled confocal Raman spectroscopy on the same locality enables the identification of the mineral phase. We present the working principles of the method and show which signals in the force spectra characteristic for hydrophobic interactions can be used to define floatability and which can then be mapped as single quantities, e.g. jump-into-contact events due to nanobubble occurrence or parameters of the long range interaction curves most probably due to capillary effects. A finely grained silicate ore containing the valuable rare earth mineral eudialyte from southern Sweden as well as pure samples of magnetite are presented as substrates to demonstrate the capability of this new approach. This method will not only help to find the proper flotation chemistry but it can furthermore help in researching and unravelling problems of floatability within similar mineral phases."

Jan 1, 2014

By Francisco Vicuña, Miguel Becerra, Nelson Iglesias

"The following article presents the development of a dynamic tool for the estimation of Jb/Jc rate (ball filling level / total load filling level) of a SAG mil operating in a single stage mode. Using the methodology detailed in this article, it is now possible to have a dynamic estimation tool in the operation, which enables strategic decision making and achieving a continuous development in process optimization. The estimating of the load filling level (Jc) was conducted using a power model, which in this case corresponds to the C-Model developed by (Morrell, 1993) that was calibrated by measuring the load filling levels (Jc) and balls (Jb) using the FARO laser scanning technology by means of Grind-Out and Crash-Stop procedures during the year 2013 and 2014. Finally, to estimate the dynamic filling level of full charge, Jc, three independent models were developed that allowed to feed the adjusted power model: •,SAG mill discharge grate slot wear model •,SAG mill internal volume wear model •,Ball filling level estimation model."

Jan 1, 2014

By Yu. Gurevich, M. Teremova, I. Prokopev, A. Razvjaznaya, N. Algebraistova

"The objective of this work is the scientific justification and development of efficient and environmentally-friendly method of bulk concentrate preparation for selection with application of microbiological practices. This research suggests to apply Pseudomonas Japonica bacterial culture to the bulk concentrate before the selection circuit in order to clear the surface of sulphides from the xanthate skin. It is also suggested to apply bacterial consortium Ochrobactrum ?nthropi and Pseudomonas aeruginosa JCM 5962 for desorption of diesel residual concentrations. High-efficient and environmentally friendly method of copper-molybdene and lead-zinc bulk concentrate selection was developed based on theoretical and experimental research work with application of microbiological practices. In comparison with conventional methods (steaming, sodium sulphide washing) the above suggested bio-technological method of bulk concentrate preparation before selection cycle will allow to reduce material and power expenditures, and it is also environmentally friendly. INTRODUCTION High-efficient selection of sulphide bulk concentrate is gained exclusively after collecting agent is removed from mineral surface. Therefore, the problem of bulk concentrate preparing before the selection cycle is acute, since the further technological parameters of the subsequent separation depends on the effectiveness of pulp preparation. Existing traditional ways of bulk concentrate preparation. such as washing or steaming, are characterized by high energy and material costs in industrial conditions [1,2]. The microbiological treatment before separation of the bulk concentrate into different kind of concentrates appear one of perspective processes for treatment of bulk concentrates [3,4]. At the present time, the world practice of processing mineral raw materials demonstrates the wide application of technologies using microorganisms: bacterial leaching and oxidation, purification of industrial wastewater. This is due to the fact that biotechnological methods are environmentally safe, low-cost, and suitable for refining complex ores and raw materials of industrial origin."

Jan 1, 2018

By Zhongxue Li, Cuiping Li, Xiaoyun Hu, Yiqing Zhao, Huaying Wang

"Under the auspices of World Federation of Engineering Organizations’ Committee on Engineering and the Environment (WFEO-CEE) and Society for Mining, Metallurgy and Exploration (SME) Task Force on Sustainability and Mining (TFSM), and aimed at helping raise global understanding on and promote capacity building of risk management, this paper presents a framework and prototype of toolbox or knowledge warehouse for facilitating the application of risk analysis, mitigation and management techniques (RAMT) in the mining and minerals sector. The conception, design and implementation of the intended system of knowledge warehouse of risk analysis, mitigation and management techniques (KWoRAMT) are outlined. The system architecture of KWoRAMT is based on a browser/server (B/S) structured platform with web oriented interfaces and composed of data base, knowledge warehouse, searching mechanisms, and risk assessment methodologies. The knowledge sources for KWoRAMT will come from the TFSM expertise and Internet, including laws and regulations, codes of practice, standards, guidelines and best practices. The functions and outcomes of KWoRAMT consist of guided navigations with web links, categorized risk tools, annotated best practices with cases, and integrated risk approaches and solutions based on typical risk methods. Risk categories include those impacting on mine safety, mine occupational health, and mine community environment throughout the whole of mine life cycle from exploration, construction, and exploitation and processing to post-mining closure. Mining associated hazards will be identified and linked by vulnerability onto risk receptors through pathways. Risk management techniques for assessing impacts and consequences of mining induced hazards will be categorized with their pros and cons or strengths and weaknesses. Best practices and significant cases including experiences and lessons with problems, solutions, and recommendations on how solutions would be derived will be illustrated. Integrated risk approaches based upon typical methods will be developed for alternatives and actions."

Jan 1, 2014

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014

By Marco Le Roux, Martha Van Rensburg, Quentin Campbell

Fluidised bed drying is currently receiving much attention as a dewatering option during the beneficiation of fine (defined here as between 1 mm and 2 mm particles) coal. Apart from concerns about safety and combustion, the operating costs can be high if very high gas or air temperatures are used. The aim of this study was to investigate the removal of moisture from fine coal by using air at a lower temperature (25 - 55°C) within a controlled environment by lowering of the relative humidity of the air. It was firstly proven that fluidization has a major advantage over non-fluidized beds, with regards to drying rate and final moisture content. Hereafter several parameters that influence the dewatering rate and final moisture content were tested, from which it was concluded that the relative humidity of air acts as the largest driving force for dewatering. Parameters tested included relative humidity, temperature and coal composition. Energy balances showed a positive nett energy increase in the dried coal during combustion when related to the energy input during drying. In comparison with thermal drying technologies, fluidized bed drying was proven to be less energy intensive. It was therefore shown that this is a viable technology for the dewatering of fine coal.

Jan 1, 2014

By Jan Cilliers

The demand for minerals has never been higher. Moreover, the rate at which this demand is growing is unprecedented, and expansions and new mines will be required to fulfill these growing needs. This, in turn requires a skilled engineering workforce that can develop and operate minerals extraction processes to utilise effectively more complex ores. The International Mineral Processing Council (IMPC) has established a Commission on Mineral Processing Education to consider the global challenge of ensuring an adequate supply of well-trained mineral processing engineers. The Commission has, for the past four years, been collecting international information of the recent mineral process engineering supply position and with a view into the near future. The data collected by the international Commission members are as follows: ? Undergraduate student numbers in minerals engineering ? A breakdown of their male/female ratio ? The fraction of the students from each course that enter the minerals industry ? Teaching staff numbers and age profile This data has been collated and analysed, and the findings are presented. It is clear from the analysis that the supply situation is very different in different regions of the world, and that great opportunities exist for targeted recruitment into the industry to meet the future talent demand. Further, an attempt at correlate the supply of minerals engineers based on the local mineral production rate is shown, which shows that there are clear outliers.

Sep 1, 2012

By Markus A. Reuter, Albert Scholte, Ewoud V. Verhoef, Gerard P. J. Dijkema

A dynamic, interactive map has been developed of the life cycle of a number of metals, from mining through to minerals processing, metal production, product manufacturing, recovery and waste management. Whilst the existing metal process network and waste management infrastructure provide substantial scope for (product) design, these also limit change due to the complex interdependence of metals, both in production and recovery, and the strong path dependency of industry and infrastructure development. Therefore, models for dynamic simulation were constructed that allow the specification and evaluation of the metal process network and waste management infrastructure ‘products’ over a longer time span. The model has been constructed using a bottom-up approach, to enable assessment of the environmental aspects of metallurgy and to simulate changes in the system structure and technology, i.e. from reactor or individual process step up to integrated material cycles. The model comprises hierarchical mass balances and linear models of individual processes and sub-processes. Thus, at lower system aggregate levels an increasing level of technical detail is represented. Data reconciliation has been used literature data on process feed, products and residue composition to calculate representative and reliable split factors around each (sub-)process. World production figures on process capacity and recovery rates are be used to calculate the relative contribution of processes. The dynamic map is illustrated with a case on the introduction of lead-free solder.

Jan 1, 2003

By E. Hulthén

Crushing plants are widely used around the world as a pre-processing step in the mineral and mining industries and as standalone processing plants in the aggregates industry. Despite automation and different advanced model predictive control, a lot of the process is still managed by operators. The operators affect a lot of the performance. The numbers of the improvement they can achieve are at least as big as the advanced control algorithms?, today. Therefore, it is also important to train the operators so they know how to behave in different situations. Models for crushers and other production units have been developed during the years and the latest add is the different units? dynamic behavior being brought in, which gives the crushing plants dynamic time dependant performance. This can be used as a simulator for operators training. By connecting a Human Machine Interface (HMI) to a dynamic simulator with the models incorporated, a training environment for operators can be achieved. In this paper, a dynamic crushing plant simulator implemented in MATLAB/SIMULINK has been connected to an HMI via a PLC. The HMI is placed in a control room at the university and complemented with monitors showing sequences from the process connected to the simulations, thus creating a realistic control room for training. In the created training environment, the operators can be trained under realistic conditions. Simple training scenarios and how they could be simulated are discussed. Apart from the increased level of knowledge and experience among the operators, the time is an important factor. While a real crushing plant is still being built, the operators to be can already be trained, saving a lot of the commissioning time. Keywords: crushing, cone crusher, simulator, control room, operator, training

Sep 1, 2012

By P. Somasundaran, Tarun Bhambhani, S. Murthy Khandrika, Partha Patra, D. Nagaraj

Fine and ultrafine mineral particles, particularly if, altered mineralogically, can have detrimental effects on selective separation of minerals. Behaviour of altered mineral fines has been investigated in this work by studying the effects of weathered silicate slimes on the selective separation of copper minerals, particularly with focues on effect of the pulp rheological behaviour, which plays a governing role in the process. Physicochemical properties of these altered silicates fines such as morphology and surface charge are proposed to be responsible for the adverse rheological effects and resultant selective separation. Here, the effect of a number of problematic aspects such as water chemistry, froth stability, physicochemical aspects of gangue mineral aggregates on flotation sub-processes has been studied. Processing problems owing to the physical aspects of the gangue minerals, shape and morphology, are primarily due to uncharacteristic increase in the pulp viscosity. While problematic aspects other than impact of pulp rheological behaviour can interfere with each other in their contributions to how they affect the sub-processes, effects owing to pulp rheological behaviour have a direct impact on the flotation performance. Subtle increase in pulp viscosity can interfere with sub-processes in flotation leading to decrease in recovery and grade, and it is difficult to assess the effects due to such subtle changes. Reagent based strategies to overcome the problematic aspects has been explored here.

Jan 1, 2014

By Renato Oliveira, Walter Valery, Alex Jankovic, Birol Sönmez

"The ball mill is the most common ore grinding technology today, and probably more than 50% of the total world energy consumption for ore grinding is consumed in ball mills. On the other hand, high pressure grinding roll (HPGR) technology is relatively new to the mining industry, with significant application only since the beginning of the 21st century. Both ball mills and HPGRs are typically used in closed circuit with classifiers. There is a general consensus within the industry that classification efficiency and circulating load both have a major effect on the efficiency of closed circuit ball mills. Metso Process Technology & Innovation (PTI) conducted a laboratory test program to understand the relationship between classification efficiency and circulating load, and the impact on the performance and capacity of ball mill circuits. However, the effects on HPGR performance are significantly different. Metso PTI has initiated a pilot scale test program to evaluate the size reduction performance of the HPGR under different circuit configurations. A series of pilot scale HPGR locked cycle tests were performed to simulate the following circuit configurations: including closed circuit with a screen, partial product recycle and edge recycle. This paper discusses the results from the pilot scale HPGR and laboratory scale ball mill test programs. The effect of circulating load and classification efficiency on the performance of ball mill circuits is compared to the effect on HPGR circuits. The fundamentals of grinding behavior are also discussed in order to explain the difference."

Jan 1, 2014

By Kobus (J. J. ) Rossouw, P. Chris Pistorius, Johannes Sono

"Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. The tests served to evaluate both the reduction rate (during direct reduction) and the dissolution rate of carbon from the coal into an iron bath.Reduction rates of mixtures of magnetite and devolatilised coal were assessed isothermally, using samples of 55 grams. The off-gas analysis was used to follow the extent of reduction. Results are shown in Figure 1 a). Coal B was expected to be more reactive, based on its higher content of reactive macerals (77%, compared with 61% for Coal A). In line with this, Figure 1 a) does show a higher reduction rate with this coal. However, increasing the reduction temperature increases the reduction rate substantially,especially for the less-reactive Coal A.For the dissolution experiments, samples (mass: 250 g) were melted in an alumina crucible (under a nitrogen atmosphere), to give a starting composition around 1%C. When the desired temperature was reached, 25 g of char was added on top of the melt, through a feeding port. Results are shown in Figure 1 b). The more-reactive Coal B was less crystalline (the graphite crystallite size estimated from X-ray diffraction was 4.6Å, compared with 11.4Å for Coal A). This is associated with a lower dissolution rate in iron."

Jan 1, 2003

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By Yizhong Yuan, Dao Li, Nannan Xue, Tao Liu, Yimin Zhang

A new multi-stage counter-current circulation leaching process for extracting vanadium from stone coal was proposed, and the main factors on multi-stage counter-current circulation acid leaching process were investigated. The results show that the vanadium recovery could reach 86% under the conditions of sulfuric acid concentration of 4 M, liquid to solid ratio of 2 mL/g, temperature of 95 °C, reaction time of 60 min, mean particle size of 125 µm and circulation acid leaching stage of three. The losses of vanadium in acid leaching solution appeared during the four-stage acid leaching process. The strong adsorption performance of new formed KAl(SO4)2(H2O)12 crystal was main reason.

Jan 1, 2014

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By William Skinner, Ishmael Quaicoe, Jonas Addai-Mensah, Ataollah Nosrati

To date, intractable ore specific operational challenges such as poor heap geotechnical stability, permeability and high acid consumption rates associated with low grade (~1 wt%) nickel (Ni) laterites still makes the adoption of heap leaching processing unattractive. This paper presents some highlights of drum agglomeration, column leaching and characterization studies undertaken to foster the understanding and knowledge of some of the desirable product attributes of -2 mm and -15 mm, low grade saprolitic (SAP) and goethitic (G) Ni laterite feed ores and their blends (SAP/G). For column leaching, 5-40 mm agglomerate beds were continuously irrigated with 200 g/dm3 H2SO4 solution at 8.5 dm3/m2/h rate over 100 days. Ni, Co, Fe, Al and Mn extraction rates, free acid concentration, agglomerate bed slump and structural changes were determined as a function of time. The results show that at equivalent feed masses, except -15 mm G which displayed slower, pseudo-layering based behaviour, all the feeds (single and blends) displayed coalescence controlled agglomeration behaviour at varying binder dosages. Whilst the agglomerate compressive strength of the G ore was markedly higher than that of SAP ore, those of the blends were substantially similar. At fixed column leaching conditions, the Ni/Co extractions and acid consumption were higher for SAP ore whilst the agglomerate bed slump was lower than those for G ore. The bed of agglomerates produced from -2 mm G/-15 mm SAP blend was more stable than that for the -2 mm G/-2 mm SAP blend agglomerate, the latter experiencing blockage within 24 h of acid irrigation due to agglomerates breakdown. The Ni/Co extractions and acid consumption rates obtained for agglomerates of -15 mm G/-2 mm SAP blend were lower than expected based on the ratios of the SAP and G ores within the blend composition. The findings suggest that judicious saprolitic and limonitic ores’ blending could reduce acid consumption rate, improve the agglomerate bed robustness and enhance bed percolation behaviour under prolonged acid irrigation periods during heap leaching of lateritic ores of variable mineralogy.

Jan 1, 2014