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By M. Holm

Coal is an important fuel for energy generation, and since there are no adequate alternatives it will also be for the next decades. The deep lying hard coal is important in particular because of its high energy content. Automation of underground mining has led to major improvements in productivity and safety. A fully mechanized longwall shearer workface has already reached a high degree of automation and provides a high productivity for example utilizing the memory cut. Current researches and developments in longwall mining are focused on extending this method by adaptive cutting drum height adjustment. The so-called horizon control is often based on memory cut methods. Horizon control in this way requires information of the environment, which can be provided by models (seam model, cut model) and coal interface detection (CID). Available CID systems only provide an optimal output under specific conditions. The authors propose the shield-data-based horizon control (SDHC) system as an alternative approach. SDHC does not require information from a CID system or an environmental model. All necessary information is provided by roof supports, shearer and process monitoring. The SDHC system was tested in simulation under different seam conditions and yielded promising results which will be presented in this paper. In cooperation with the German mining company RAG the SDHC has already reached an experimental stage. A test assembly was built up at the surface and the SDHC system was implemented on real mining equipment. To make the test scenario as realistic as possible, the SDHC system was only connected to the monitoring system, not to the simulation model. The aim of these tests was to establish the cooperation between all subsystems, find appropriate controller parameters, locate and address safety critical aspects and finally to achieve an automatic cutting drum height adjustment. An introduction of SDHC for shearer guidance is given in this paper. The experimental tests are described and the control results of the realized SDHC system on the test assembly are shown.

Aug 1, 2013

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

By J. W. McCammon

CRANGES in construction ideas and the continually rising costs of labour and conventional building materials, particularly since World War II, have prompted widespread investigations into the development and adaptation of new materials to meet the new requirements and to help reduce costs. Lightweight aggregates have been prominent in these investigations. The lightweight aggregates most commonly used today are foamed slag, cinders, pumice, diatomite, exfoliated vermiculite, expanded perlite, and bloated clay or shah. Lightweight aggregates contribute to the building industry in several ways: ( 1) in large structures the reduction in deadweight effected by the use of lightweight materials reduces the amount of reinforcing and structural steel necessary to support the structure; ( 2) the decrease in weight of lightweight blocks makes handling easier and faster; (3) pre-fabricated floor and roof slabs and tilt-up walls of lightweight concrete have become feasible and popular; ( 4) lightweight aggregate concrete has good nailability and is easily channelled; (5) concrete and plaster made with lightweight aggregate have good heat and sound insulation properties.

Jan 1, 1957

By Jun Dai

Based upon research findings from several countries, the combination of microwave and mechanical means to break hard rock holds promise for the future. To achieve this goal, it is essential to understand the laws governing strength reduction of hard rock, such as granite, induced by microwave irradiation. Two aspects to consider are: 1) laws associated with the tensile strength of hard rock after microwave irradiation and 2) the sensitivity of different types of rock strengths to microwave energy. In this study, granite with a range of tensile strengths was exposed to microwaves for various time periods to compare the response of rocks with different strength values exposed to the same microwave irradiation. In addition, a method based on hotspots is presented to explain the mechanism by which granite strength is reduced by microwave irradiation. Granite extracted from Qinling Mountain in Shaanxi Province, China is used in the research. ?50 × 50 mm cylindrical granite specimens were exposed to microwaves at a specific power level. The strength values of the heated granite specimens were compared with those of unheated specimens. Through the comparison and analyses, relationships were determined between 1) reduction in granite strength and microwave irradiation time period, and 2) granite strength and sensitivity to a given energy of microwave irradiation. Finally, a mechanism to explain the experimental results is proposed. Research findings will aid in the design of a microwave + machine rock-breaking system for use in rock breakage in underground mines at depth and for future mine applications on earth and other planets. In addition, the experimental approach could be used to test other rock types to further our understanding of rock damage induced by microwave irradiation.

Aug 1, 2013

By M. Fall

The progressive depletion of ore available at shallow depths in several underground mines around the world means that underground mining operations would increasingly be carried out at greater depths and therefore at higher temperatures. However, our understanding of the effect of hot temperatures on the response (mechanical, economical, environmental) of cemented paste backfill (CPB) is still limited. Hence, an extensive laboratory investigation was conducted to study the performance of young and aged CPB, in response to deep mine temperatures. Several CPB samples with different compositions, cured at different temperatures (20 to 50°C) and different times (7 to 160 days) were tested regarding their mechanical properties, economical performance (binder consumption) and microstructural properties. The results show that hot temperatures significantly affect the performance properties of CPB at young and advanced ages. An increase in the curing temperature leads to a considerable improvement of the rate of gain of CPB strength and also to a significant increase of the strength of CPBs studied. CBP samples cured at hot temperatures show lower binder consumption and finer pore structure. Results of this study could serve as background information for the development of optimal mine backfill design procedures.

May 1, 2007

By Arthur Laing

"IT is indeed a pleasure to have the opportunity of addressing this group today. Not only does it give me the opportunity of meeting with representatives of what is considered by many to be the most dynamic segment of industry in Canada today, but it also allows me to talk about a subject of para-mount interest to myself, the development of the North, and to explain, if even only briefly, some of our beliefs and hopes in this regard.It is inconceivable that all lands north of the 60th parallel, representing 35 per cent of Canada's total land area, which we believe contain a great natural resource potential, will remain as an undeveloped portion of Canada. The re-sources are there, although the people and private industry are as yet not there in sufficient numbers.It has been estimated that in the west and north of Canada there are 1.6 million cubic miles of sedimentary rocks. Of this figure, 342,-000 are thought to lie in Alberta, 115,000 in British Columbia and about 1 million cubic miles are thought to lie in Canada's northern regions, the bulk in the Arctic Islands. On the basis of apparent volumes of sedimentary rock, we estimate that as much as 13 billion barrels of petroleum may lie beneath the permafrost of the North-west Territories, another 3 billion barrels in the Yukon Territory and 33 billion barrels in the Arctic Islands. This is, indeed, a rich and elusive prize, and one which must be sought with a view to fulfilling demands on the production of petroleum."

Jan 1, 1966

By T. A. Lazier, C. S. Longley

"Paymaster Consolidated Mines, Limited, owns several groups of claims in various parts of the Porcupine district. The area in which mining has been carried on includes parts of lots 5, 6, and 7, con. 1, Tisdale township, and twelve adjoining claims in Deloro township to the south. Highway No. 67A between South Porcupine and Timmins crosses the property.The discovery of the Dome mine in 1909 caused a rush of prospectors to the district and in a few weeks practically all territory adjacent to the Dome was staked. At that time work was started on the West Dome, West Dome Lake, Apex, and Standard properties. These were consolidated in 1930 to form the present Company. Gold was produced from the West Dome Lake from 1915 to 1930, and from the Standard-Paymaster from 1922 to 1928. The total production of the previous and present companies from 1915 to November 30, 1946, has been 487,170 oz. gold and 149,342 oz. silver from 2,337,554 tons of ore."

Jan 1, 1954

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory's waste water, was achieved at Tarbiat Modares University's mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By P. Blonde

Recent analysis has suggested that a balanced recovery profile can improve flotation bank performance. Test work was conducted to test the balanced profile concept at the Penhorwood talc mine near Timmins, Ontario, Canada. Plant trials were devised to determine how to control the recovery profile and the resultant impact on grade and recovery in a rougher bank of four cells. Accompanying gas dispersion measurements revealed a maintenance issue with one cell that was corrected. By manipulating air and frother addition it was possible to bring the bank closer to a balanced recovery profile and the down-the-bank grade/recovery improved. Plant production showed an increased talc grade at similar yield with the balanced profile. The results provide justification for a long term plant trial.

Aug 1, 2013

By M. Amsden

"Since the computer program is far from complete this must be only a brief progress report on the computerization of flotation metallurgy at the Ecstall concentrator at Timmins.Ecstall is currently treating about 10,000 tons per day of two different ore types. One is a low sulphide copper-zinc ore, the other is a high sulphide lead-zinc-silver ore. The concentrator is divided into three individual grinding and flotation circuits. In effect there are three mills under one roof. Normally there are two circuits on copper-zinc ore and oneone lead-zinc-silver ore. At this point in time one of the copper-zinc circuits is under computerized metallurgy control.The first step in this control is the use of an ARL on-stream x-ray analyzer, coupled with a Honeywell 21 computer which types out assays and recoveries for each individual circuit. Our approach to a computer program was to keep it simple. The program was written to coincide as closely as possible to what an operator would do in the performance of his duties based on the in-formation he was getting from the x-ray analyser read-out. Initially, computer control was put on just the copper circuit of the ""A"" Division, controlling the collector addition at three points in the circuit; primary, secondary, and scavengers. The control was based on recoveries and the grade of the copper concentrate. Targets like 95% recovery and 24% copper concentrate grades that it was felt the circuit could achieve were set to start with. It quickly became apparent that this alone was not enough because if on a certain ore the best recovery that could be made was only 94.9% the computer kept calling for more reagents until the circuit was completely out of control. On another ore it might have been quite possible to get 96% recovery but when the set point of 95% was reached the computer stopped trying for any more. To overcome this problem a very simple optimum seeking program was devised by one of the Ecstall staff and it has worked very satisfactorily since being put into use in July 1970.In the copper float only the two collectors R-208 and the xanthate R-317 are under computer control. The addition of frother and depressant is left to the operator. The flotation cells have automatic level controls which can be adjusted by the operator. pH is controlled automatically through a lime loop-sensor arrangement."

Jan 1, 1971

By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By M. M. O?Brien

THE SULLIVAN MINE The Sullivan mine of the Consolidated Mining and ? Smelting Company of Canada, Limited, is situated at Kimberley, B.C., nineteen miles from Cranbrook, a divisional point on the Crowsnest Pass branch of the Canadian Pacific railway. Production started on a small scale in 1900, and in 1914 the mine became the largest lead producer in Canada. In 1925 it was the largest single producer of lead and zinc in the world. Since operations commenced, 4,800,000 tons of ore have been produced from stopes and 170,000 tons from development. At the present time, ore is being mined at the rate of 1,100,000 tons per year, with a yield of about 200,000 lb. lead, 110,000 lb. zinc, and 4,000,000 oz. silver. The town of Kimberley is easily accessible by road as well as by rail. The altitude at Mark creek, a tributary of the St. Mary's river, is 3,700 feet. To th'e north of the creek, Sullivan hill rises to a height of 6,100 feet, and it is on the southern slope of this hill that the mine is located. Sullivan hill is in the Purcell range, which rises between the Rocky Mountain trench on the east and Kootenay lake on the west. It thus lies within what is commonly referred to as the East Kootenay district.

Jan 1, 1926

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By Ian Ewart, Trevor Bergfeldt, Gourab Satapathy, Ajay Patel

"Conventional electrowinning (EW) of nickel from sulfate electrolytes is complicated by several factors including the requirement for a diaphragm cell to separate the anolyte and catholyte and the need to minimize nickel mist emissions. Developed and commercialized by emewCorporation, this novel process electrowins high purity nickel cathode (99.5%) from copper refinery bleed streams using the proprietary emew vortex EW technology. The emew nickel process incorporates high flow rate in an enclosed cylindrical EW cell operating at high current densities that overcomes the challenges of conventional nickel EW and completely eliminates the risk of nickel mist emissions. The tubular cathodes are easily harvested and mitigate the effect of plating stresses inherent in nickel EW. The present paper describes the emew nickel process and its most recent application to copper refinery bleed streams at full-scale.INTRODUCTION To meet the stringent demand of customers, nickel producers are giving prime importance to production of high purity nickel cathodes. The major challenge for refineries is to improve cathode quality and appearance despite fluctuating electrolyte impurity levels. The basis of achieving good quality cathode includes the control of electrolyte impurities and consistency of specific process conditions. The commercial operation of emew nickel technology has been successfully implemented and has demonstrated the ability to produce high quality nickel cathode from refinery bleeds. This paper emphasizes the importance of upstream impurity removal to achieve the required nickel emew feed composition by evaluating the benefits of using selective precipitation as a purification scheme with the aim of improving the overall nickel recovery while ensuring suitable nickel concentration in the advanced electrolyte is achieved. Nickel electrowinning is similar to other electrowinning processes that employ insoluble metal anodes & cathodes. It requires the passage of direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. For the recovery of nickel from solution, the most common methods are electrowinning and hydrogen reduction. Electrowinning usually occurs from sulfate, chloride or mixed sulfate/chloride electrolytes. In sulfate electrolytes, nickel electrowinning cells are normally designed to achieve specific criteria as outlined below (Robinson & Tuppa, 2002):"

Jan 1, 2017

By R. Hagiwara, S. Kobayashi, K. Yasuda, T. Nohira, K. Kondo

To establish a process for the electrochemical recovery of rare earth elements from used magnet scraps, the electrochemical formation of RE-Ni alloys in molten NaCl-KCl-RECl3 salt at 973 K was investigated. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of RE-Ni alloys. The formation potential for each RE-Ni alloy phase was determined from the results of scanning electron microscopy and X-ray diffraction of alloy samples prepared by potentiostatic electrolysis of a Ni plate electrode at various potentials. The optimum electrolysis conditions for the separation of Nd, Dy, and Pr are discussed.

Jan 1, 2014

By W. A. Jones

"The Ross mine, a subsidiary operation of Hollinger Consolidated Gold Mines, Limited, is near the north end of lot 1, con. II, Hislop tp., Ontario. The property comprises the north half of lot 1, con. II, and the south onethird of lot 1, con. III. It is readily reached by a good motor road from the village of Ramore, 7 1/2 miles to the southeast on the Ontario Northland railway. The mine is being developed to a depth of 1,500 feet, and the current daily production rate is approximately 300 tons. From the inception of operations in March 1935 until December 31, 1945, 692,000 tons of ore, with a total value of $5,762,685, was milled . The silver to gold ratio of 1.48 to 1 is unusually high for Ontario gold mines.TYPE OF 0REBODIES AND MINERALIZATIONThe orebodies consist of lens-shaped and pipe-like stringer lodes and tabular vein zones composed of parallel quartz stringers. The host rocks are steeply inclined eruptive breccias and tuffs, striking N.70°W., intruded by very small stocks of red syenite. The orebodies appear to be spatially related to an intricate system of fault planes. Hydrothermal alteration is widespread and is not zonally related to individual quartz stringers. The wall-rocks contain abundant fine-grained pyrite, but gold is confined to the quartz stringers.RELATIONSHIP TO REGIONAL STRUCTURELack of outcrops has prevented the detailed mapping of the Keewatin complex in the vicinity of the Ross mine with the degree of success that has been achieved in the Porcupine area.A northwesterly trending belt of slates and greywackes, bounded by faults, forms the central part of a broad anticlinal arch about 3 1/2 miles north of the Ross shaft. Lava flows forming the south flank of the structure face south toward the mine. If the sediments are to be tentatively correlated with the large areas of Keewatin slates and greywackes of the Porcupine area, it must be assumed that they are younger than the lava flows and that they have been down-faulted."

Jan 1, 1954

By T. T. Chen

The iron- and elemental sulphur-rich residues generated during batch and continuous pressure oxidative leaching of Inco Limited's Voisey's Bay nickel sulphide concentrate at 150°C in sulphate-chloride media have been characterized by X-ray diffraction analysis and scanning electron microscopy. The residues produced during the continuous leaching of the pentlandite- and pyrrhotite-rich concentrate consisted predominantly of hematite and elemental sulphur, with minor amounts of goethite. Although the iron species generated in the batch leaching tests were similar to those formed during continuous leaching, the morphologies of the hematite and goethite particles were significantly different. In addition to the tiny spheroids and bubble-like particles, the hematite and goethite generated during batch leaching occurred as larger "hollow" shell-like particles that contained residual pentlandite or sulphur cores. Although the leach solution from which the iron oxides had precipitated contained 5-15 g/L sodium, sodium jarosite was detected only in trace amounts in a few of the leach residues.

Jan 1, 2006

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

By M. Leahy

"Very little is known about the large scale fluid dynamics and associated distribution of copper in an operating electrowinning cell, yet they will have a major influence on mass transfer and plating quality. The CFD model in this work is used to simulate an entire EW cell with 60 cathodes and 61 anodes, or 121 anode–cathode pairs, elucidating for the first time the three-dimensional (3D) flow and copper distribution in an industrial cell. Two methods for the distribution of electrolyte are modelled:1. Downcomer method: electrolyte is fed by a downcomer at one end of the cell, overflowing at the opposite end.2. Manifold method: a horizontal manifold pipe runs the whole length of the cell and feeds electrolyte via small holes in the top of the manifold pipe.The recirculation that develops within each anode-cathode pair, driven by oxygen bubble generation on the anode, is similar to that seen previously in two-dimensional models of single anode–cathode gaps. However a more complex 3D flow recirculation is established, which involves flow of electrolyte down the side gaps (being a path of low resistance for return flow) as well as the usual return flow down the cathode side of each pair gap. The bubble-driven flow is not influenced by the mode of electrolyte distribution.The electrolyte flow due to the manifold and downcomer is somewhat secondary to the bubble driven flow. In the case of the downcomer distribution mode, the high injection velocity causes a very turbulent flow in the first 1–2 m down the cell from the downcomer, with several large vortices developing. This may lead to some sludge particles being entrained into the bulk of the cell.In the manifold pipe case, the jet from each hole is dissipated very quickly, within the first 10–20 cm. The jets are directed into the downward flowing zone of the bubble-driven recirculation, which leads to unstable and periodic behaviour on a large spatial scale.In both the manifold and downcomer cases, there is a marked two-zone vertical stratification in copper concentration."

Jan 1, 2016